910

pH

6575

(50)

410h
1822

pH67

()

1.

2.

3.

/% <2

<2

3~10

30

15

39

70


1.

2.

3.

4.

30-50

90

90

32
352560
90min351030min
3020

CH2

COR 1

CH

COR 2

CH2

COR 3

3H2O

CH2

OH

CH

OH

CH2

OH

OH
-

R1COOH

+ R2COOH + R3COOH

pH5.5
1.0-1.520-35Sandobate WD0.25-1.5023hBaymol AN 260min30-352-3
20

50

NaOHNa2CO3
NaOHNa2CO3

NaOHNa2CO3



42

2.5%4090min

40-4536-38
1.0-1.52-41.5-2h
36-3820-30min

40

1mol/L



6010-15

1-21-5h35-40 5-7
1-2 2-3


1.

2.

3.

P-S-S-P1+2Na2S
P-SNa+ P1-SNa+ Na2S2

NaSH
Na2S+H2O
NaSH+NaOH
CaO+H2O
Ca(OH)2
Ca(OH)2
Ca2++2OHCa(OH)2 +2NaSH
Ca(SH)2+2NaOH
NaSHOH-
P-S-S-P1+H2O
P-SOH+P1-SH
P-SOHNaSHCa(SH)2
P-SOHNaSH
P-SONa+H2S
2 P-SOH+ Ca(SH)2
P-SO-Ca-OS-P+ 2H2S

H2S

Na2S+H2O
NaSH+NaOH
NaSHNaOH
Na2S



+Na2S+CaO
Na2S+ NaSH +CaO

18-222-33-6r/min
3-8Na2S 2.5-12g/L()
40120min
30min3-5min14-22h

2.512

10-20g/l
0.5-2

Na2SCaCl2

Na2SNaCl

Na2SCaCl2

Na2S+H2O
NaSH+NaOH
2NaOH+CaCl2
Ca(OH)2+2NaCl

Na2SCaCl2NaSHNaOHNaOH
Ca(OH)2NaCl

Na2SNaClNaSHNaOH
NaClNa2SO4

Na2SCaCl2

20-242Na2S2-3CaCl20.5-1
14-20h

Na2S6-12g/L
0.5-1.2

CH=NCH2SCH2


Na2SP
SOHPSH

PCH2SOH
PCHO+H2S
PCH2SH
PCH2OH+S

CH=NCH2SCH2

P1CH2SH+ HOCH2P
P1CH2SCH2P+ H2O
PCHO+H2NCH2P1
PCH2CH=NCH2P1+H2O

P1CH2SH
(SCaOS)
P1CH2SH+Ca(OH)2+HOSCH2P
P1CH2SCaOSCH2P+2H2O

CaO60

g/L

18-22



NaClO2

NaClO2ClO2ClO2

5 NaClO2+4HCl
4ClO2+5NaCl+2H2O

10 ClO2+4P-S-S-P+4 H2O
8P-SO3H+5Cl2
ClO2pH3-3.5

NaClO2

2-4
P216

Na2S
Na2S

pH

(NH4)2SO4NaCl

Na2S

Na2SS2-

0.827180min
w(Na2S)60%0.8%w(NaSH)60%
0.5% 3.5%Mollescal AB0.5%
260min
120min0.4
Mollescal AB20min40min27
7020min20min60min5min

Na2SNaHS

Na2S
Na2S

Na2S /NaHS

420

S2

150.162g

pH12
pH10g/L


1.
2
2. CaO5060
pH12
pH
3.

pH12
4.
14
20h
5.

2.5 18-22 18h

10EA0.5-.0.85

1.
2. 40
EA
3. 40min1h
4. 1h5min
5. 2030min

()

35mm1.3mm
0.6mm


()
()()

30
64

Ca(OH)2Ca2+
Ca2+

()

NUE0.6MPXEA

NaHS

P-S-S-P+2NaSH
2P-SH+ Na2S2
NaOH

Na2S

NaOH

Na2S(
36g/L812 g/L)Na2S

()
()


30
(30)30
2530
25

25

20

()
()()
()

()

()
()

1424h
36rmin(
60min35min)(
)

3090min

0.52-3

0.8-1

10-20h
:

1. ()
2.
3.

4.
5.

1
1.()

(
)
3.

(
)

2
4.

()
(

5.

()(swelling)

()

()
(plumping)

pH2
pH12



()(swelling)




()

()(plumping)

CaO







(
)

()pH(128)

+
+

+
+

H2O
HA
NaA
NaOH


Ca(OH) 2 2HA
CaA 2
2H2O

H2NPCOONa+HA==+H3NPCOO-+NaA

H2NPCOOCaCOOPNH2+HA
==2+H3NPCOO-+CaA2

(NH4)2SO4NH4ClNaHSO4
NaHSO3
HCOOHCH3COOH
CH3CHOHCOOH
H3BO3CO2


1.
2.
3.
4.
5.
6.
7.

CO2


NH4)2SO4NH4Cl
CaSO4

(NH4)2SO4
CaSO4(NH4)2SO4(NH4)2Ca(SO4)2

NH4ClCaCl2CaSO4
CaCl2

NH4Cl
NH4ClCa(OH)2CaCl2


()


H2SO4HCl

pH
H2SO4 CaSO4




()()
N2H2CO2

CO2

Ca(OH)2+ CO2
CaCO3+ CO2 +H2O

CaCO3
Ca(HCO3)2

pH8.3
pH8.3(4.4<pH<8.3)
Ca(HCO3)2Ca(OH)2

CO2

, CO2

NH3N

Decaltal AESLAN(BASF)
NH3N

NH3N
97NH3N

H2S

Na2S
Na2SpH
H2S

H2S
NaHSO3H2O2S2H2S

2/31/5

pH

pH6.58.5

pH26


1.

20-30min

2.
3.

4.30-35
5.



()


pH7.58.5
pH2.53.5

15
40min
60 180min
pH 3
pH 5h
pH
pH
pH pH

pHpH
pH

pH
pH

pH3.63.8

pH2.0
H2S041.2


NaAc(NH4)2CO3Na2S2O3NHCO3
Na2CO3()pH
3.0pH34.5

pH2.0()pH
pH(
)
(pH
)

(
)

pHpH

, Cl-
29(
59)

pH(<3)pH

()

(531)

531

25

20
25

30-40min
13

30min
16-22h


()
=

pH

pH

pH

pH
0.81

3090min
(
60min5min)


1. 5min

2.

3. 25

4.

5.
6.

7.




()
()

(pH3.85.4)
(4.66.2)
(3.14.4)

pH()

11822180min

(85)0.5(96)1.07

20
5min10min
30min30rain30min5min

pH2.8

()

25(
)
3050

()



()
80

(1)
()

()

5min

()
()
(piling)

(
)0.51.5m()
()()

(20)
(3)


(533)(534)

(535)
50

(
)

()

()



25
3050

()

(
)80


35mm
1.3mm
0.6mm

()



()
80

(1
)(
)

()

5min

()

()

()
0.51.5m()
()()

50

(
)

()

()


1.

2.
3.
4.