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Figure 11.1: General molecular structure of starch. (Source: Courtesy Paul A. Seib.) Natural starch exists in a granular form. The granular shape and size are different in different plants (Figure 11.2). Corn starch granules are mainly spherical (Figure 11.2A), wheat starch has both spherical and disk-shaped granules (Figure 11.2B), and potato starch has a smooth granular surface and is mainly oval (Figure 11.2C). The disk-shaped wheat starch granule has an average diameter of 25 m, and the spherical-shaped granule has a smaller diameter of less than 10 m (Figure 11.3) [3]. A cornstarch granule has an average diameter of 10.3 11.5 m [4], whereas potato starch has a larger granule size with an average diameter of about 40 m [3].
http://www.globalspec.com/reference/34686/203279/chapter-11-plastics-derived-from-starchand-poly-lactic-acids