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TECHNOLOGY OF
PAINTS & COATINGS
WITH FORMULATIONS

TECHNOLOGY OF
PAINTS & COATINGS
WITH FORMULATIONS

Written By :
EIRI Board of Consultants & Engineers

4449, Nai Sarak, Main Road, Delhi-110 006 (India)


Ph.: 91-11-23918117, 23916431, 45120361, 23947058
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Printed and Published by :

4449, Nai Sarak, Main Road, Delhi-110 006 (India)


Ph.: 91-11-23918117, 23916431, 45120361, 23947058
E-Mail: eiribooks@yahoo.com & eiriprojects@gmail.com
Website: www.eiriindia.org, www.eiribooksandprojectreports.com

Marketed By:
EIRI PROJECT CONSULTANTS & PUBLISHERS
Roop Nagar, Delhi110007
Copy Reserved by Sudhir Gupta,
ISBN : 9789380772202
Printed in New Delhi (India)

The book is sold subject to the condition that it shall not, by way or
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regarding this book are Subject to Delhi Jurisdiction only

Printed and Published by Sudhir Gupta for


Engineers India Research Institute, 4449, Nai Sarak, Main Road,
Delhi-110 006

Preface
The Book Technology of Paints & Coatings with Formulations covers
almost all the basic and advanced details to setup own Unit. The Book Covers
Resins (Water Borne) for Coatings, High Solids Green Coatings (Air Drying),
Technology of Primer Compositions (Alkyl) Resings, Acrylic Polyols Technology,
Biodegradable Surface Coatings, Binders for Premium Paints, Cyclized rubber in
surface coatings, Coatings for Medical Application, Dacro Coating Epoxy Resin
Extraction, Modification and Applications of CNSL/Cardanol Based Epoxy Resin,
Elastomeric poly urea coatings, Formulation of 2K Water-borne Concrete Floor
Coatings, Green Coating, Herbal Coating, High Temperature Coatings Technology,
Infrared Spectroscopy : Its Relevance in the Field of Surface Coating, Marine
Paints & Coatings, Magnetic Paint, Nanotechnoloogy PU Coatings, Photo
Luminescent Paints, Polyaspartics, Phenolic Resins, Paints based on Agricultural
Materials, Polyester Powder Coatings, Paint Coating on Galvanized Steel in Coil
Coating line, Photocatalytic Coatings, Ketonic Resins, Radiation Cure Coatings,
Self-Healing - Coatings, Stealth Coatings for Aircraft and ships, Sol Gel Coatings,
Vacuum Metallizing Coating on Plastic Automotive Components, Plastic Packaging
for Paints, Silicone Resin Paints.
The book has been written for the benefit and to prove an asset and a handy
reference guide in the hands of new entrepreneurs and well established
industrialists.

4449, Nai Sarak, Main Road, Delhi-110 006 (INDIA)


E-mail : eiribooks@yahoo.com
www.eiriindia.org

Contents
1
Resins (Water Borne) for
Coatings .................................. 1-5
Epoxy Resins .................................... 1
Acrylic Resins ................................... 2
Alkyd Resins ..................................... 2
Polyester Resins ............................... 2
Polyurethane Resins ........................ 3
Anionic .............................................. 3
Cat ionic ............................................ 3
Non-Ionic .......................................... 3
Acetone process (Solution
process) ....................................... 4
Pre-polymer mixing process ............ 4
Hot melt process (Solvent free
method) ....................................... 4
Ketamine or Ketazine .................. 4
Self dispersing of solids ................... 4
Blocked isocyanates ........................ 5
crosslinking with melamine formaldehyde resins ........................ 5
Zirconium compounds ...................... 5
2
High Solids Green Coatings
(Air Drying) ............................ 6-23
Introduction ....................................... 6
Experimental .................................... 7
Materials ........................................... 7
Synthesis of Resins .......................... 9
Preparation of dry films ..................... 9
Characterization methods .............. 11
Results & Discussion ...................... 12
Physical Properties ......................... 12
Rheological Characteristics ........... 13
Molecular Weight Characteristics .. 13
VOC characteristics ........................ 13
Drying properties ............................ 14
FT- IR Study ..................................... 14
Differential Scanning Calorimeter
(DSC) study ............................... 15

Thermal properties ......................... 17


Mechanical properties .................... 17
Optical properties ........................... 18
Atomic Force Microscopic
(AFM) imaging ........................... 18
Chemical resistance and
Durability ................................... 18
Conclusions .................................... 23
3
Technology of Primer
Compositions (Alkyd
Resins) ................................ 24-31
Introduction ..................................... 24
Experimental .................................. 24
Synthesis of alkyd resin .................. 24
Synthesis of alkyd emulsion ........... 26
Stability of emulsion10 ................... 26
Synthesis of wood primers
and cement primers .................. 26
Results and discussions ................ 27
4
Acrylic Polyols Technology ..... 32-41
Introduction ..................................... 32
Basic chemistry ............................... 32
Synthesis of acrylic polyols ............ 32
Properties of acrylic polyols ........... 34
Applications of acrylic polyols ........ 35
Synthesis of acrylic-polyurethane hybrid coatings ................ 35
Modified acrylic polyols .................. 36
Dual UV/thermal cure systems ....... 37
Bio-acrylic polyols .......................... 38
OEM coatings based on Acrylic
Polyols ....................................... 38
Wood coatings ................................ 39
Industrial Coatings ......................... 39
Two component polyurethane
coatings ..................................... 39
Automotive refinishing coating ....... 40

5
Biodegradable Surface
Coatings .............................. 42-57
Introduction ..................................... 42
Biodegradable coatings ................. 43
Necessity of biodegradation .......... 43
Life cycle of biodegradable
coating ....................................... 44
Classification of biodegradable
coatings ..................................... 44
Natural biodegradable coatings .... 44
Synthetic biodegradable
coatings ..................................... 45
Synthesis of biodegradable
coatings ..................................... 45
Oils .................................................. 46
Lallemantia Iberica ......................... 46
Eurphorbia Legascae
(Vernonia oil) ............................. 46
Lesquerella oil ................................ 47
Oiticica oil ....................................... 47
Sucrose and insulin ........................ 48
Lignin .............................................. 49
Cellulose ........................................ 50
Starch .............................................. 51
Isocyanates ..................................... 52
Additives ......................................... 52
Plasticizer ....................................... 53
Rheology modifier .......................... 53
Biosurfactants ................................. 54
Polyhydroxyalkalonoates ............... 54
Polyesteramides ............................. 55
Interpenetrating polymers
from oils ..................................... 55
Polysaccharide resins .................... 55
Natural resins ................................. 56
Application of biodegradable
coatings ..................................... 57
Future of biodegradable
coatings ..................................... 57
6
Binders for Premium Paints .... 58-65
Introduction ..................................... 58
Why low odor? ................................ 60
Experimental .................................. 61

Testing of premium interior


brands in India .......................... 61
Formulating low VOC low
odor paint .................................. 61
Results and Discussions:
Odor and VOC ........................... 61
Paint Properties .............................. 62
Scrub Resistance ........................... 62
Stain Resistance ............................ 62
Burnish resistance .......................... 64
MTO Resistance ............................. 64
Conclusion ..................................... 64
7
Cyclized Rubber in Surface
Coatings .............................. 66-71
Structure ......................................... 66
Properties ....................................... 66
Typical properties ........................... 67
Physical data .................................. 67
Technical benefits of cyclized
rubber ........................................ 67
Solvents and compatibility ............. 67
Compatibility ................................... 68
Compatibility with drying oils .......... 68
Compatibility with resins ................ 68
Compatibility with plasticizers ........ 68
Specific gravity ............................... 69
Solubility and solvent mixtures ....... 69
Chemical resistance ....................... 69
Water resistance ............................. 70
Corrosion resistance ...................... 70
Adhesion ........................................ 70
Flexibility and impact resistance .... 70
Paint application ............................. 71
Application Areas ........................... 71
8
Coatings for Medical
Application .......................... 72-92
Introduction ..................................... 72
Medical coating characteristics ...... 72
Medical coating classification ........ 73
Application Methods ....................... 75

Polymers for medical application ... 77


Polyglycolide (PGA) ........................ 79
Polylactide (PLA) ............................ 79
Poly (E-caprolactone) ..................... 79
Poly(dioxanone) (a polyetherester). ........................................ 80
Poly(lactide-co-glycolide) ............... 80
Poly(glyconate) ............................... 81
Parylene ......................................... 82
Degradation .................................... 84
Factors That Accelerate Polymer
Degradation .............................. 84
Specialised medical coatings ........ 85
Drug-Eluting Stents ........................ 85
Application of stent coating ............ 86
DES Basics ..................................... 87
Tablet Coatings ............................... 90
Pigments ......................................... 92
Polishing ......................................... 92
Conclusion ..................................... 92
9
Dacro Coating ........................ 93-102
Dacro
Dacro
Dacro
Dacro
Dacro
Dacro

Structure ............................... 96
Process ................................ 97
Advantage ............................ 97
Analysis ............................... 99
Scope ................................. 100
Coating in India ................. 102

Curing of hybrid epoxy


polymers .................................. 110
Characterization of hybrid
resins: ...................................... 112
Hybrid polymers of epoxy resin
used in coating application ..... 113
Epoxy esters ................................. 113
Epoxy acrylics ............................... 113
Epoxy silicones ............................. 114
Epoxy urethanes .......................... 114
Conclusion and future directions . 115
11
Extraction, Modification
and Applications of
CNSL/Cardanol Based
Epoxy Resin ................... 117-153
Introduction ................................... 117
Extraction of CNSL ....................... 118
Studies on the cardanol
based novolac resins .............. 122
Studies on the epoxidized
novolac resins derived
from CNSL or cardanol ........... 126
Studies on the modification
of CNSL or cardanol ............... 129
Applications of CNSI7
Cardanol derived products ..... 138

10
Epoxy Resin ........................ 103-116

12
Elastomeric poly urea
coatings .......................... 154-162

Introduction ................................... 103


Structure: ...................................... 103
Epoxy resin coating ...................... 104
Hybridisation ................................ 106
The method of curing .................... 106
Modification of resin ..................... 106
Mixture of resins ........................... 106
Blending: ...................................... 107
Alloying ......................................... 107
Inter Penetrating Networks ........... 107
Sol-Gel method ............................. 108
Emulsion polymerization &
Dispersion polymerization ...... 109

Introduction ................................... 154


Chemistry ...................................... 155
Raw materials ............................... 157
Application of polyurea
coatings ................................... 159
Typical properties of polyurea
coatings ................................... 160
Application areas of olyurea
coatings ................................... 160
Advantages of polyurea
systems ................................... 161
Disadvantages of polyurea
systems ................................... 161

13
Formulation of 2K Waterborne Concrete Floor
Coatings ......................... 163-172
Introduction ................................... 163
Experimental: ................................ 164
Materials and Formulations .......... 164
Preparation of Drawdowns &
Concrete Panels ..................... 164
Performance Testing ..................... 165
Gloss Measurement: .................... 165
Adhesion testing: .......................... 165
Chemical resistance testing: ........ 165
Hot Tire resistance testing: ........... 166
Results & Discussions: ................. 167
Comparing liquid epoxy resins
Epoxy X with Epoxy W: ........... 167
Pot-life evaluation based on
gloss and adhesion: ................ 167
Chemical and solvent
resistance testing: ................... 169
Hot Tire resistance: ....................... 171
14
Green Coating ..................... 173-187
Need for green ............................. 173
What is green? ............................. 174
Rules and regulations .................. 174
VOC Definition in the US,
EU & UK .................................. 174
United States Definition ................ 174
European Union definition ........... 175
UK Coating Classification ............ 175
Regulationsforlead in India .......... 177
Regulations for lead in Europe .... 177
Regulationsfor lead in Australia ... 177
Regulationsforlead in US ............. 177
Pollution from paints ..................... 178
Solvents ........................................ 178
Pigments ....................................... 178
Additives ....................................... 178
Environmental impacts
and risks .................................. 178
Research and developments
in order to get greener
coatings ................................... 180

Low voc emulsion polymer


coating ..................................... 181
Low volatile ethylene glycol
derivatives ............................... 181
Fluorosurfactant ............................ 182
Green solvent ............................... 182
Emerging technologies ................ 185
Advantages of VIC ........................ 185
Ecofriendly waste disposal
technique ................................ 186
Its not easy being green .............. 186
15
Herbal Coating ..................... 188-200
Introductions ................................. 188
Turmeric in Herbal Paints ............. 189
Chemistry of turmeric .................... 190
Oleic acid ...................................... 190
Experimental ................................ 191
Materials and Methods ................. 191
Method of Extraction ..................... 193
Evaluation of Turmeric resin
extract ...................................... 193
Analysis of oleic Acid modified
Turmeric Resin ........................ 194
Results and discussion ................ 196
Analysis of Raw Material .............. 196
Extraction of resin from
turmeric ................................... 197
Analysis of turmeric Resin ............ 197
Evaluation of the Film
properties of Turmeric Resin ... 198
Modification of the termeric
Resin with Oleic acid .............. 199
Physical Properties ....................... 199
Film Properties ............................. 199
Composition ................................. 199
From the results ............................ 200
16
High Temperature Coatings
Technology ..................... 201-209
Introduction ................................... 201
Experimental ................................ 203
Composition of titanium oleate ..... 203

Preparation of titanium oleate ...... 203


Evaluation of titanium oleate ........ 204
Composition and evaluation
of aluminium paint ................... 205
Heat resistance of aluminium
paint ......................................... 205
Determination of weight loss
at different temperatures ......... 205
Results and discussion ................ 206
17
Infrared Spectroscopy : Its
Relevance in the Field of
Surface Coating ............. 210-216
Introduction ................................... 210
Sampling ...................................... 212
Amount: ......................................... 212
Preparation: .................................. 213
Analysis time: ................................ 213
Epoxy: ........................................... 214
Alkyd: ............................................ 214
18
Marine Paints & Coatings ... 217-225
Introduction ................................... 217
Key Performance requirements .... 217
Experimental ................................ 220
Material used: ............................... 220
Evaluation of film characteristic .... 220
Testing method and evaluation .... 220
Pot life ........................................... 220
Drying time ................................... 220
Cross Hatch Adhesion Testing ..... 221
Gloss Value ................................... 222
Erichsen Cupping Test ................. 223
Research significance .................. 224
Experimental investigation ........... 224
Result Analysis and Discussion ... 225
19
Magnetic Paint ..................... 226-235
Introduction ................................... 226
Preparation of Magnetic paint ...... 227
Ingredients to be used for
formulation .............................. 227
Application Technology ................ 230

Primer Layer ................................. 230


Back Coat Layer ........................... 231
Coating composition having
magnetic properties ................ 233
Areas of application ...................... 234
Application tips and
suggested uses ....................... 234
Painting on textured walls ............ 234
Mounting posters magnetically .... 234
Wall Decorations .......................... 234
Magnetic words and poetry .......... 235
20
Nanotechnoloogy ................ 236-253
Introduction to Nanotechnology
What is nanotechnology? ....... 236
Nanoscience Vs
Nanotechnology ...................... 236
Dimensional classification
of nanoscale: ........................... 238
Nanoscale in One Dimension ...... 238
Nanoscale in Two Dimensions ..... 238
Carbon Nanotubes: ...................... 238
Inorganic Nanotubes .................... 238
Nanowires .................................... 239
Biopolymers .................................. 239
Nanoscale in Three Dimensions .. 239
Nanoparticles ............................... 239
Fullerenes (carbon 60) ................. 240
Dendrimers ................................... 241
Quantum Dots ............................... 241
Technology ................................... 242
Synthesis and Assembly
of Nanomaterials: .................... 242
UV- curable coatings .................... 244
Anti-abrasion and anti-scratch
coatings ................................... 244
Anti-corrosion coatings ................. 245
Self-healing nanotechnology
antic orrosion coatings
as alternative to toxic
chromium ................................ 245
Super-hydrophobic coatings ........ 247
Barrier coatings ............................ 247
Oxylink Technology ....................... 248
Matte coatings .............................. 251
Self cleaning technology .............. 251

Making use of hydrophobic


and oil repellent property
of nanoparticles ....................... 251
Nanoparticles in high
performance coating ............... 252
Anti-fouling coating ....................... 252
Nanotechnology roof coating ....... 252
The risk factor ............................... 252
Health Issues ................................ 252
Environmental issues ................... 253
Future of nanotechnology ............ 253
21
PU Coatings ......................... 254-260
Introduction ................................... 254
Experimental ................................ 255
Materials ....................................... 255
Preparation of polyol .................... 255
Characteristics of epoxy
polyol (EP) ............................... 256
Characteristics of HDI ................... 256
Chemical compositions: ............... 256
Results and discussion ................ 258
FT IR Spectral analysis ................. 258
FT IR spectra of epoxy polyol: ...... 258
FT IR Spectra for polymer ............. 259
FT IR Spectra for polymer-H ......... 259
22
Photo Luminescent Paints . 261-267
Introduction ................................... 261
Mechanism of action .................... 261
Effect of temperature on
the afterglow ............................ 262
Manufacturing of the pigment ....... 262
With Polyurethane Resins ............ 265
With Epoxy Resins ....................... 265
Applications .................................. 266
Comparison between fluorescent and photo luminescent
paints and alternative
energy sources ....................... 267

Chemistry ...................................... 268


Reaction of aspartic acid ester
with isocyanate ....................... 270
Polyurethane/Polyurea/
Polyaspartks Whats the
Difference? .............................. 270
Reactivity: ..................................... 271
Applications .................................. 273
Limitation ...................................... 275
24
Phenolic Resins .................. 277-290
Introduction ................................... 277
Experimental ................................ 277
Materials ....................................... 277
Synthesis of phenol-cardanolformaldehyde novolac
type phenolic resins ................ 278
Epoxidation of phenol-cardanolformaldehyde novolac type
phenolic resin .......................... 279
Characterization ........................... 279
Fourier-transform Infrared (FT-IR)
spectroscopic analysis ............ 279
H-NMR ......................................... 281
spectroscopic analysis ................. 281
Gel permeation chromatographic
(GPC) technique ..................... 281
Differential Scanning
Calorimetry (DSC) ................... 282
Results and Discussion ................ 282
Synthesis of phenol-cardanolformaldehyde novolac type
phenolic resins ........................ 282
FT-IR spectroscopic analysis ........ 283
1H-NMR spectroscopic
analysis ................................... 286
Epoxidation of novolac
prepolymer .............................. 287
Differential Scanning
Calorimetric (DSC) analysis ... 289

23
Polyaspartics ...................... 268-276

25
Paints based on Agricultural
Materials ......................... 291-301

Introduction ................................... 268


What are Polyaspartic Esters? ..... 268

Introduction ................................... 291


Soybean ....................................... 292

Soybean oil-based waterborne


polyurethane system: .............. 293
Soybean oil-based polyols: .......... 293
Soybean oil-based wetting
and dispersing agents: ........... 293
Lignin ............................................ 294
Lignin based paints: ..................... 294
Corn .............................................. 295
Corn based paints: ....................... 295
Xanthum Gum ............................... 296
Starch ............................................ 297
Sugar based polymers ................. 298
Solvents ........................................ 299
Monomers ..................................... 300
Coalescents .................................. 300
26
Polyester Powder Coatings..302-309
Introduction ................................... 302
Using bi-functional hardener ........ 303
Co-extrusion of resins .................. 304
Polyester Dead Matt ..................... 305
Using reactive matting agent ........ 307
27
Paint Coating on Galvanized
Steel in Coil Coating line..310-322
Introduction ................................... 310
Preparing of substrate for
paint coating ............................ 312
Alkaline solution cleaning ............ 313
Conversion coatings .................... 313
Test conducted to study the
performance of the coated
product .................................... 313
Impact test ..................................... 313
Bending adhesion test ................. 314
Flexibility test ................................ 314
Hardness test (Pencil test) ............ 314
Chemical resistance test .............. 314
Salt spray test ............................... 314
Heat resistance test ...................... 315
MEK (Methyl ethyl ketone) test ..... 315
Coating characteristics ................. 315
Factors affecting the performance of paint coating ............ 315

Effect of tensions at various


sections ................................... 315
Effect of alkali and conversion
coating bath concentration ..... 317
Bending adhesion test ................. 318
Salt spray test ............................... 318
Hydrogen Evolution (Crater) ........ 318
Effect of peak metal temperature
in primer oven and top coat
oven ......................................... 319
Bending adhesion test ................. 320
Hardness test ................................ 321
Impact test ..................................... 321
MEK (Methyl ethyl ketone) test ..... 321
Uses of coatings ........................... 321
Conclusions .................................. 321
28
Photocatalytic Coatings ..... 323-331
Introduction ................................... 323
Materials ....................................... 323
Titanium dioxide ........................... 323
Silicone resin ................................ 324
Experimental ................................ 325
Methylene blue test ...................... 325
Cigarette smoke test ..................... 325
Outdoor-exposure ........................ 326
Results .......................................... 326
Comparison of titanium dioxide ... 326
Binder ........................................... 327
Interior paints ................................ 327
Exterior paints ............................... 329
Conclusion ................................... 329
29
Ketonic Resins .................... 332-339
Introduction ................................... 332
Aim of the present investigation ... 332
Experimental ................................ 333
Composition of ketonic resin ........ 333
Preparation of ketonic resin ......... 334
Evaluation ..................................... 334
Effect of heat on softening
point ......................................... 335
Effect of plasticization on film
properties ................................ 335

Effect of stoving on film


properties ................................ 335
Results and discussion ................ 335
30
Radiation Cure Coatings .... 340-355
Introduction ................................... 339
Curing mechanism ....................... 339
Raw materials for radiation
cure coatings ........................... 342
Oligomers ..................................... 342
Epoxy acrylates ............................ 343
Urethane acrylate ......................... 344
Polyester acrylates ....................... 346
Polyether acrylates ....................... 346
Amine modified polyether
acrylates .................................. 346
Acrylic acrylates ............................ 347
Miscellaneous oligomers ............. 347
Monomers ..................................... 347
Photo initiators .............................. 350
Additives ....................................... 350
Pigments ....................................... 351
Cation curing ................................ 351
Powder coatings ........................... 353
Application areas of radiation
cure coatings ........................... 354
Advantages and disadvantages
of radiation cure coatings ........ 355
Advantages ................................... 355
Disadvantages ............................. 355
31
Self-Healing - Coatings ....... 356-373
Introduction ................................... 356
Approaches .................................. 357
Liquid phase healing agent ......... 358
Microcapsulation .......................... 358
Phase separated healing agent ... 362
Hollow tubes or fibers ................... 363
Three-dimensional micro
vascular network ..................... 364
Solvent- promoted self-healing .... 364
Nanoparticles segregation ........... 365
Solid phase (Heat activated) ........ 365

Thermally rcmendable ................. 366


Thermoplastic/thermoset
blend ....................................... 366
Cyclic oligomers ........................... 366
Projectile puncture ....................... 368
Other approaches ......................... 368
Quantifying healing
effectiveness ........................... 370
Potential Application of Self
healing .................................... 371
32
Stealth Coatings for Aircraft
and ships ........................ 374-386
Detection techniques for an
aircraft ...................................... 374
Measuring stealth ......................... 374
Importance of Coatings in
Stealth Technology .................. 375
Additional expectations from
Stealth coatings ....................... 375
Types of Coatings used in
Stealth Technology .................. 376
A. Iron Ball Paint ........................... 376
Carbonyl Iron: ............................... 376
Silver-coated Cenosphere ........... 378
Typical Physical Parameters
of Cenospheres ....................... 378
Ferro fluids and non-magnetic
substances .............................. 379
Strontium 90 ................................. 380
Neoprene ...................................... 381
Coatings based on Gold and
Indium ...................................... 381
Radar stealth countermeasures
and limitations ......................... 381
Low frequency radar .................... 381
IR Stealth ...................................... 382
Stealth Coatings in Drugs ............ 383
Stealth Coatings in Foods ............ 383
Probable Abuses of Stealth
Coatings .................................. 384
Futuristic Coatings ........................ 384
Combined Infrared and Radar
Stealth ..................................... 384

33
Sol Gel Coatings .................. 387-403
Introduction ................................... 387
Types of Solgels ........................... 390
Coating process and coating
equipments ............................. 390
Spin coating .................................. 390
Dip coating ................................... 391
Roll /gravure coating .................... 391
Typical examples of uses
of Sol gel coatings ................... 392
Monocyclic aromatic
hydrocarbon sensors .............. 392
Sampling of benzene and
toluene .................................... 393
Carbon dioxide sensor ................. 394
Sol gel & nano technology ........... 396
Photonic solutions and sol gel ..... 397
Sol gel integrated optics ............... 398
Optical Gain materials .................. 399
Non linear materials ..................... 399
Elastomeric reinforcement
strategies ................................. 401
Topochemistry of wood
-inorganic composites ............. 402
34
Vacuum Metallizing Coating
on Plastic Automotive
Components ................... 404-411
Introduction ................................... 404
Vacuum Metallizing Coating
on plastic components ............ 405
Requirement of substrate
material ................................... 406
Pretreatment of substrate
surface ..................................... 407
Post-Treatment .............................. 410
Equipment .................................... 411
35

Conventional packing
materials .................................. 412
Advantages and disadvantages
of conventional packing
materials .................................. 413
Selection of the packing
materials .................................. 413
New generation packing
materials .................................. 413
Water soluble plastics for
packaging of water based
paints ....................................... 413
Introduction ................................... 414
Application for the paint Industry .. 414
Properties of water soluble
plastics .................................... 415
Water Solubility ............................. 415
Sealing properties ........................ 416
Oil and chemical resistance ......... 416
Strength and weathering
resistance ................................ 416
Biodegradable properties ............ 417
Moisture content ........................... 417
Static electricity/surface
resistivity .................................. 417
Moisture permeability and
Gas resistance ........................ 417
Advantages of water soluble
plastics .................................... 418
Disadvantages of water
soluble plastics ....................... 418
Different types of packaging ......... 418
Polymer coated steel .................... 419
Introduction: .................................. 419
Polymer coated steel and its
performance with solvents
(Table 1) .................................. 420
Application and benefits of
polymer coated steel
(Table 2) .................................. 420
Advantages of polymer
coated steel are ....................... 420

Plastic Packaging for Paints .... 412-421

36
Silicone Resin Paints .......... 422-431

Introduction ................................... 412


Basic requirements for
paint packaging ....................... 412

Introduction ................................... 422


Silicons Resin Emulsion
Paints ...................................... 422

SREP Technology ......................... 423


Silicone Resin Chemistry ............. 424
A functional network is created
in the construction material ..... 425
SREP Properties .......................... 425
Functional facade protection
retains a buildings value ........ 425
Excellent protection against
wetness ................................... 426
Dry facades prevent algae ........... 426
Facades that can breathe ............. 427
Long-lasting facade protection
saves renovation costs ........... 427

Weathering resistance ................. 427


Facades keep their color .............. 427
A permanently attractive
facade ...................................... 427
Simple & Fast Processing ............. 428
Easy to over paint ......................... 428
Fast and efficient ........................... 428
Solvent free & ecologically more
sound ...................................... 428
Extremely stable and nonchalking ................................... 429
Test methods: Certified
quality ...................................... 430

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