Professional Documents
Culture Documents
TECHNOLOGY OF
PAINTS & COATINGS
WITH FORMULATIONS
TECHNOLOGY OF
PAINTS & COATINGS
WITH FORMULATIONS
Written By :
EIRI Board of Consultants & Engineers
Marketed By:
EIRI PROJECT CONSULTANTS & PUBLISHERS
Roop Nagar, Delhi110007
Copy Reserved by Sudhir Gupta,
ISBN : 9789380772202
Printed in New Delhi (India)
The book is sold subject to the condition that it shall not, by way or
trade or otherwise, be lent, resold, hired out, or otherwise circulated
without the publishers prior written consent, in any form of binding
or cover other than in which it is published/compiled and without a
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has been prepared carefully, yet the publishers printer and compiler
do not hold any responsibility on the subject of the book. All disputes
regarding this book are Subject to Delhi Jurisdiction only
Preface
The Book Technology of Paints & Coatings with Formulations covers
almost all the basic and advanced details to setup own Unit. The Book Covers
Resins (Water Borne) for Coatings, High Solids Green Coatings (Air Drying),
Technology of Primer Compositions (Alkyl) Resings, Acrylic Polyols Technology,
Biodegradable Surface Coatings, Binders for Premium Paints, Cyclized rubber in
surface coatings, Coatings for Medical Application, Dacro Coating Epoxy Resin
Extraction, Modification and Applications of CNSL/Cardanol Based Epoxy Resin,
Elastomeric poly urea coatings, Formulation of 2K Water-borne Concrete Floor
Coatings, Green Coating, Herbal Coating, High Temperature Coatings Technology,
Infrared Spectroscopy : Its Relevance in the Field of Surface Coating, Marine
Paints & Coatings, Magnetic Paint, Nanotechnoloogy PU Coatings, Photo
Luminescent Paints, Polyaspartics, Phenolic Resins, Paints based on Agricultural
Materials, Polyester Powder Coatings, Paint Coating on Galvanized Steel in Coil
Coating line, Photocatalytic Coatings, Ketonic Resins, Radiation Cure Coatings,
Self-Healing - Coatings, Stealth Coatings for Aircraft and ships, Sol Gel Coatings,
Vacuum Metallizing Coating on Plastic Automotive Components, Plastic Packaging
for Paints, Silicone Resin Paints.
The book has been written for the benefit and to prove an asset and a handy
reference guide in the hands of new entrepreneurs and well established
industrialists.
Contents
1
Resins (Water Borne) for
Coatings .................................. 1-5
Epoxy Resins .................................... 1
Acrylic Resins ................................... 2
Alkyd Resins ..................................... 2
Polyester Resins ............................... 2
Polyurethane Resins ........................ 3
Anionic .............................................. 3
Cat ionic ............................................ 3
Non-Ionic .......................................... 3
Acetone process (Solution
process) ....................................... 4
Pre-polymer mixing process ............ 4
Hot melt process (Solvent free
method) ....................................... 4
Ketamine or Ketazine .................. 4
Self dispersing of solids ................... 4
Blocked isocyanates ........................ 5
crosslinking with melamine formaldehyde resins ........................ 5
Zirconium compounds ...................... 5
2
High Solids Green Coatings
(Air Drying) ............................ 6-23
Introduction ....................................... 6
Experimental .................................... 7
Materials ........................................... 7
Synthesis of Resins .......................... 9
Preparation of dry films ..................... 9
Characterization methods .............. 11
Results & Discussion ...................... 12
Physical Properties ......................... 12
Rheological Characteristics ........... 13
Molecular Weight Characteristics .. 13
VOC characteristics ........................ 13
Drying properties ............................ 14
FT- IR Study ..................................... 14
Differential Scanning Calorimeter
(DSC) study ............................... 15
5
Biodegradable Surface
Coatings .............................. 42-57
Introduction ..................................... 42
Biodegradable coatings ................. 43
Necessity of biodegradation .......... 43
Life cycle of biodegradable
coating ....................................... 44
Classification of biodegradable
coatings ..................................... 44
Natural biodegradable coatings .... 44
Synthetic biodegradable
coatings ..................................... 45
Synthesis of biodegradable
coatings ..................................... 45
Oils .................................................. 46
Lallemantia Iberica ......................... 46
Eurphorbia Legascae
(Vernonia oil) ............................. 46
Lesquerella oil ................................ 47
Oiticica oil ....................................... 47
Sucrose and insulin ........................ 48
Lignin .............................................. 49
Cellulose ........................................ 50
Starch .............................................. 51
Isocyanates ..................................... 52
Additives ......................................... 52
Plasticizer ....................................... 53
Rheology modifier .......................... 53
Biosurfactants ................................. 54
Polyhydroxyalkalonoates ............... 54
Polyesteramides ............................. 55
Interpenetrating polymers
from oils ..................................... 55
Polysaccharide resins .................... 55
Natural resins ................................. 56
Application of biodegradable
coatings ..................................... 57
Future of biodegradable
coatings ..................................... 57
6
Binders for Premium Paints .... 58-65
Introduction ..................................... 58
Why low odor? ................................ 60
Experimental .................................. 61
Structure ............................... 96
Process ................................ 97
Advantage ............................ 97
Analysis ............................... 99
Scope ................................. 100
Coating in India ................. 102
10
Epoxy Resin ........................ 103-116
12
Elastomeric poly urea
coatings .......................... 154-162
13
Formulation of 2K Waterborne Concrete Floor
Coatings ......................... 163-172
Introduction ................................... 163
Experimental: ................................ 164
Materials and Formulations .......... 164
Preparation of Drawdowns &
Concrete Panels ..................... 164
Performance Testing ..................... 165
Gloss Measurement: .................... 165
Adhesion testing: .......................... 165
Chemical resistance testing: ........ 165
Hot Tire resistance testing: ........... 166
Results & Discussions: ................. 167
Comparing liquid epoxy resins
Epoxy X with Epoxy W: ........... 167
Pot-life evaluation based on
gloss and adhesion: ................ 167
Chemical and solvent
resistance testing: ................... 169
Hot Tire resistance: ....................... 171
14
Green Coating ..................... 173-187
Need for green ............................. 173
What is green? ............................. 174
Rules and regulations .................. 174
VOC Definition in the US,
EU & UK .................................. 174
United States Definition ................ 174
European Union definition ........... 175
UK Coating Classification ............ 175
Regulationsforlead in India .......... 177
Regulations for lead in Europe .... 177
Regulationsfor lead in Australia ... 177
Regulationsforlead in US ............. 177
Pollution from paints ..................... 178
Solvents ........................................ 178
Pigments ....................................... 178
Additives ....................................... 178
Environmental impacts
and risks .................................. 178
Research and developments
in order to get greener
coatings ................................... 180
23
Polyaspartics ...................... 268-276
25
Paints based on Agricultural
Materials ......................... 291-301
33
Sol Gel Coatings .................. 387-403
Introduction ................................... 387
Types of Solgels ........................... 390
Coating process and coating
equipments ............................. 390
Spin coating .................................. 390
Dip coating ................................... 391
Roll /gravure coating .................... 391
Typical examples of uses
of Sol gel coatings ................... 392
Monocyclic aromatic
hydrocarbon sensors .............. 392
Sampling of benzene and
toluene .................................... 393
Carbon dioxide sensor ................. 394
Sol gel & nano technology ........... 396
Photonic solutions and sol gel ..... 397
Sol gel integrated optics ............... 398
Optical Gain materials .................. 399
Non linear materials ..................... 399
Elastomeric reinforcement
strategies ................................. 401
Topochemistry of wood
-inorganic composites ............. 402
34
Vacuum Metallizing Coating
on Plastic Automotive
Components ................... 404-411
Introduction ................................... 404
Vacuum Metallizing Coating
on plastic components ............ 405
Requirement of substrate
material ................................... 406
Pretreatment of substrate
surface ..................................... 407
Post-Treatment .............................. 410
Equipment .................................... 411
35
Conventional packing
materials .................................. 412
Advantages and disadvantages
of conventional packing
materials .................................. 413
Selection of the packing
materials .................................. 413
New generation packing
materials .................................. 413
Water soluble plastics for
packaging of water based
paints ....................................... 413
Introduction ................................... 414
Application for the paint Industry .. 414
Properties of water soluble
plastics .................................... 415
Water Solubility ............................. 415
Sealing properties ........................ 416
Oil and chemical resistance ......... 416
Strength and weathering
resistance ................................ 416
Biodegradable properties ............ 417
Moisture content ........................... 417
Static electricity/surface
resistivity .................................. 417
Moisture permeability and
Gas resistance ........................ 417
Advantages of water soluble
plastics .................................... 418
Disadvantages of water
soluble plastics ....................... 418
Different types of packaging ......... 418
Polymer coated steel .................... 419
Introduction: .................................. 419
Polymer coated steel and its
performance with solvents
(Table 1) .................................. 420
Application and benefits of
polymer coated steel
(Table 2) .................................. 420
Advantages of polymer
coated steel are ....................... 420
36
Silicone Resin Paints .......... 422-431