Chemistry: Unit -1

c`v_i Aev (States of Matter) c`v_i Aev t cavbZ ZvcI Pvci Dci
wbfi Ki c`v_i wZbwU wfb fZ Aev cKvk Ki - 1. KwVb 2. Zij 3. Mvm c`v_i GB wZbwU Aevi cv_K welq 1| wbw` AvKvi 2| wbw` AvqZb 3| NbZ KwVb AvQ AvQ AbK ewk bB Zij bB AvQ Kg Kg Kg AvQ LyeB Kg Kg Mvm bB bB LyeB Kg AZ ewk mePq Kg AvQ AvQ AvQ Zij wUK c`v_ AvjvK ag c`kb Ki ej KvjKzjUi, Nwo cfwZ BjKUwbK h digit c`kbx c`v_ wnme eeZ nq| Zij wUK Zvcgvv mse`K wnme KvR Ki| b, Kvvi wkiv agbxZ i cevn evav mbvKib eeZ nq| D`vniY t (i) bvd_vwjb WvB KvewwjK GwmW I WvB Aj Gi cwj GUvi (ii)8- cUvBj evB wdbvBj-8KvevbvBUvBj (iii) 4,4-WvBwg_vw AvRw ebwRb cfwZ| 2| cvRgv Aev t AwZ DP Zvcgvv Kvb c`v_ Mvmxq Aevq AvqwbZ ev PvRhy _vK| c`v_i Mvmxq Aevq Avqb I BjKUbi cvkvcvwk _vKvi Gic AevK cvRgv Aev ej | gb ivLZ ne t AvqvwWb, NH4Cl, CO2 Kc~i, bvc_vwjb BZvw` c`v_i DacvZb (Sublimation) NU | NaCl jebi MjbvsK (Melting Point) (815oC) K Zvcgvvi (25oC)Dci-ZvB KwVb N2 Gi zUbvsK (-196oC) K Zvcgvvi wbP-ZvB Mvm

4| msKvPbkxj Zv 5| AvKlb ej mev waK 6| Abyi MwZ Kb AvQ AveZb bB vbvi bB

N.B. c`v_i Aevi mv_ AvtAvbweK kw I MwZkwi mK: KwVb Aev t Av t KYv AvKlb kw > MwZ kw Zij Aev t Av t KYv AvKlb kw = MwZ kw Mvmxq Aev t Av t KYv AvKlb kw < MwZ kw GQvovI c`v_i Aviv `ywU Aev iqQ 1) Zij wUKv Aev 2) cvRgv Aev 1| Zij wUK Aev t wKQy KjvmvKvi Re c`v_ AvQ hjv D Kij mivmwi ^Q Zij icvwiZ nIqvi c~e GKwU A^Q Zij cwiYZ nq| c`v_i G AevK Zij wUK Aev (Liquid crystal) ej| G Aevq c`v_wU Zij c`v_i bvq cevwnZ nZ cvi | Avevi KwVb wUKi gZv wgvwK AvKwZi AvbweK MVb ARb KiZ cvi|
ewk t

Sample-Questions
1. wbi Kvb ei KYvjvi aygv Kb MwZ iqQ? [Dhaka University: 2006-07] (A) NaCl (s) (B) H2O (l) (C) H2O (g) (D) H2 (g) 2. NaCl (s), H2O (l) Ges CO2 (g) Gi ga MwZkxj KYvmg~n mg wbi Kvb DwwU mwVK bq ? [Dhaka University: 2004-05] (A) NaCl (s) G KYvmg~ni Kej Kb MwZ iqQ (B) H2O (l) G KYvmg~ni Kej vbvi MwZ iqQ (C) CO2 (g) Gi ga CO2 Abyi Kb, N~bb Ges vbvi MwZ iqQ (D) NaCl (s) I H2O (l) Gi ga KYv mg~ni N~bb me bq| 3. Kvb c`v_i Avt AvbweK kw I c`v_i Kbvmg~ni MwZkw cvq mgvb nj c`v_wU (A) KwVb Aevq _vKe

Ziji gZ wKQyUv cevn ag I cUvb AvQ | KwVb Kjvm ev Crystal Gi gZ `pZv ag iqQ| AvjvK ag c`kb Ki|
eenvi t

FOCUS : My Intelligent Choice

(B) Zij wUK Aevq _vKe (C) Zij Aevq _vKe (D) Mvmxq Aevq _vKe| 4. Mvmxq c`v_i KvbwU mwVK bq ? (A) AvqZb wbw` bq (B) Avt gvbweK AvKlb Acv Abyi vbvi MwZ AwaK| (C) AZ Kg msKvPbkxj (D) NbZ LyeB Kg 5. wbPi KvbwU c`v_i Aevi Rb mwVK bq? [Medical Test:2007-08] (A) Zij wUK Aevq c`v_mg~n AvjvK ag c`kb Ki (B) AvqwbK hMmg~n Kjvm AvKvi KwVb Aevq _vK (C) NaCl jebi zUbvsK (815oc) K Zvcgvvi Dci (D) Zij c`v_i ejvq Avt AvbweK AvKlY KwVb c`v_i Pq Kg| 6. cvRgv Aev c`v_i Kvb aiYi Aev?

[Shahjalal U University: 2007-08]

(A) KwVb Aev AvqwbZ Aev (C) Zij Aev Aev

(B) (D) Mvmxq

Solution 1. Ans: (A) | KwVb Aevq Abymg~ni

aygv KbMwZ _vK | Zij Aevq Kb I vbvi MwZ _vK| Mvmxq Aevq Kb, AveZb I vbvi MwZ AbK ewk _vK| Same as before. Ans: (B) | Ans: (C) | see N.B. Ans: (C) | c`v_i wZbwU Aevi cv_K `e| Ans: (C) | zUbvsK bq MjbvsK| Ans: (D) | Mvmxq Aevq AvqwbZ _vK|

2. 3. 4. 5. 6.

(cwZwU cki Di AekB eyS eyS wkLZ ne)

GK bRi Mvm m~ mg~n (Laws of ases at a lance) m~ eqji m~ cqvM m~i weewZ MvwYwZK cKvk

Pvjmi m~

M jymvKi Pvci m~ Pvjmi weK m~ AvfvM Wvi m~ Wvbi AvswkK Pvc m~

wi Zvcgvvq Mvmi wi Zvcgvv wbw` fii 1 V AvqZb I NbZi Dci Pvci Kvb Mvmi AvqZb P cfve cKvk Ki | MvmwUi Dci chy Pvci ev PV=K evvbycvwZK wi Pvc Mvmi wi Pvc wbw` fii Kvb VT AvqZbi Dci Zvcgvvi Mvmi AvqZb ev Pvc Zvi cig V = KT cfve, cigk~b Zvcgvv (0K Zvcgvvq mgvbycvwZK / -273oC) I j mK avibv `q | wi AvqZb Mvmi wi AvqZb wbw` fii PT Pvci Dci Zvcgvvi cfve Kvb Mvmi Pvc Zvi cig P = KT cKvk Ki | Zvcgvvq mgvbycvwZK

Mvnvgi

Mvmi Abyi msLv I gvjvi AvqZb mwKZ Z_ c`vb Ki | Mvm wgkbi gvU Pvc I Dcv`vb Mvmi AvswkK Pvc wbYq Av` Mvmi Pvc wbYq wewfb Mvmi AvbweK

GKB Zvcgvv I Pvc mg AvqZbi mKj Mvm mg msLK Aby _vK Kvb wbw` Zvcgvvq Kvb Mvm ev evi cii wewqvnxb wgkbi gvU Pvc Gi Dcv`vbjvi AvswkK Pvci mgwi mgvb | wbw` Pvc I Zvcgvvq Kvb

Vn

P = P1 + P2 + P3 + ........ + Pn

FOCUS : My Intelligent Choice

evcb m~ evcb I wbtmib Dfq chvR

fi wbYq Kiv hvq Mvmi evcb nvi Zvi NbZi d2 gji wewfb eMgyjvi evvbycvwZK = d1 AvBmvUvci c_Kxib M2 Mvmi NbZ evcb nvi == mwKZ Z_ cvIqv hvq| M1 evcb I wbtmib nvii cv_Ki wfwZ Mvm wgkbi Dcv`vb mg~n c_KxKiY me|

iLvi bv g Isotherm mgZvc iL v

wewfb Mvm m~ _K cv jLwP mK jLvwPi wb` k Ki eqji m~ P Ges V nZ T3 cvIqv hvq P V T2 T1 PV T1 P-1 isotherm P1 V P2 P3 isobar P

T
V Isobar mgPvc iL v Pvjmi m~ V Ges T

T
-273c Isocore MjymvKi Pvcxq m~ P Ges T P T [QKwU fvjfve coZ ne| GLvb _K wewfbfve ck nZ cvi] N.B: Pvc Lye ewk Ges Zvcgvv Lye Kg Mvm m~jv chvR bq| (A) Zvcgvv (B) Pvc (C) AvqZb (D) NbZ 3. Absolute Zero Temperature (cigb Zvcgvv) Gi avibv cvIqv hvq Kvb my _K ? (A) AvfvMWvi m~ (B) Pvjmi m~ (C) Mvmi mg^q m~ (D) eqji m~ 4. Kvb jLwPwU viv GKwU g~jwe`yMvgx mijiLv cvIqv hve? (A) P vs V (B) V vs P-1 (C) PV vs P (D) V vs T 5. wbPi KvbwU mZ bq ? (A) eqji m~ nZ cvIqv P/V jLwPwU GKwU mij iLv (B) Pvjmi m~ nZ cvIqv V/T jLwPwU GKwU mij iLv isocore Oc

Sample-Questions
1. wi AvqZb wbw` fii Kvb Mvmi Pvc H Mvmi ev Kjwfb Zvcgvvi mgvbycvwZK-GwU njv: [RU.06-07] (A) Pvjmi weK m~ (B) Wvbi AvswkK Pvc m~ (C) M-jymvKi Pvci m~ (D) Mvnvgi Mvm-evcb my 2. eqji m~ KvbwUi cwieZb nq bv? [RU.2007-08]

FOCUS : My Intelligent Choice

(C) eqji m~ nZ cvIqv P/V jLwPwU mgZvc iLv (D) Pvjmi m~ nZ cvIqv V/T jLwPwU mgPvc iLv

Mvmi

Answers: 1. (A) 2. (A) 3. (B) 4. (B) 5. (A)

evcb I wbtmib (Diffusion and Effusion) evcbi ejvq cvi fZi I evBi GKB Pvc _vK| wbtmibi ejvq cvi fZi AwaK Pvc _vK, evBi Kg Pvc _vK| evcb nj Abymg~ni gi ^ZtzZ cwqv| wbtmib nj `Z evwnK kwi cfvevaxb cwqv| evcb Mvm, Zij wKsev KwVb gvag NUZ cvi| Ze wbtmib ev Abyevcb Kej Mvmi NU| h Mvm hZ fvix A_vr h Mvmi NbZ hZ ewk Zvi evcb ev wbtmib nvi ZZ Kg|

Abymg~ni MwZeMi weZib Maxwell Gi eM eUb m~ viv evLv Kiv hvq| H2 Gi AvbweK fi Kg nIqvi KviY Gi Abymg~ni MwZeM mePq ewk|

STP : 0C/273K,76 cm(Hg)/ 1atm /101.325

KPa

SATP : 25C/298K, 100 KPa,Vm=24.789 Sample-Questions

1. evwnK Pvci cfve mi wQ` c_ w`q Mvm mRvi ei nq AvmvK ej- [Khulna University.2007-08] (A) Diffusion (B) Effusion (C) Osmosis (D) Osmotic pressure 2. wbi KvbwU gvjvi Mvm aeK R Gi mwVK gvb bq? [Medical Test: 2007-08 & 2005-06] (A) wjUvi evqygj Pvc GKK, R=0.082 L atm k-1 mol(B) SI GKK, R = 8.314 JK-1 mol-1 (C) CGS GKK, R = 8.314 JK-1 mol-1 (D) Kvjwi GKK, R = 1.987 cal K-1 mol-1 3. wbi KvbwU Mvmi MwZZi ^xKvh bq ? (A) Abymg~ni AvqZb Mvmvavii AvqZbi Zzjbvq bMY| (B) msNli dj Abymg~ni MwZi w`K cwiewZZ nq| (C) Abymg~ni msNl mg~n wwZvcK (D) Abyi Mo MwZkw Mvmi cig Zvcgvvi evbycvwZK 4. H2 AYymg~ni MwZeM mePq ewk| Gi KviY nQ[National University: 2006-07] (A) AYymg~ni ga weKlY kw wqvkxj (B) AYymg~ni Dci gvaKlY kw wqvkxj bq (C) AYymg~ni MwZc_ Zv`i ga Kvbic msNl NU bv (D) AYyi AvYweK fi mePq Kg 5. Kvb AevK STP ej? [C.U.2007-08] (A) 0C, 76 cm (Hg) (B) 0C, 760 cm(Hg) (C) 273 K, 76 cm (H2O) (D) -273 K, 76 cm(Hg) (E) -273 K, 1atm

wewfb GKK gvjvi Mvm aeK R Gi gvb

1)

wjUvi evqygj Pvc GKK, R= 0.0821 Latm K-1mol-1 2) SI GKK, R= 8.314 JK-1 mol-1 3) CGS GKK, R=8.32JK-1mol-1=8.32107ergK1 mol-1 4) Calorie GKK,R=1.987 Cal K-1mol-1 Boltzmann Constant Aby cwZ Av`k Mvm aeKi gvbK Boltzmann Constant ej| GK K viv cKvk Kiv nq| 1) Latm GKK, K==1.3610-25Latmk-1 molecule-1 2) SI GKK, K==1.3810-23Jk-1 molecule-1 Mvmi MwZZ (Kinetic Theory of Gases) Abymg~ni gvU AvqZb Mvmvavii gvU AvqZbi Zzjbvq bMY| cviwiK msNli dj Abymg~ni MwZi w`K cwiewZZ nq| Abymg~ni msNl mg~n wwZvcK Mvmvavii Dci Abymg~ni msNli dj cvIqv hvq| Abymg~ni Mo MwZkw Mvmi cig Zvcgvvi mgvbycvwZK gb ivLZ ne t wevbx R.J. Clausius Av`k Mvmi MZxq mgxKiY (kinetic equation of ideal gases) PV=mNc2 cwZv Kib|

FOCUS : My Intelligent Choice

Answers: 1. (B) 2. (C) 3. (D) 4. (D) 5. (A)

Av`k Mvm mgxKiY (Ideal gas equation)

Av`k Mvm mgxKiY wewfbfve cKvk Kiv hvq | hgb i) PV = nRT . (h Kvb cwigvY Mvmi ) ii) PV = RT . (hLb , n=1gvj) iii) PV =

W RT (M AvbweK fi wewk W M

AvbWyRi cixv Abyhvqx Zvcgvv AekB mw Zvcgvvi (critical temperature) wbP wbZ ne| Critical States (msKU ev vw ) of Gases. iZc~Y wKQy Mvmi msKU Pvc AvqZb I ZvcgvvGas Critical Critical Critical temperature Pressure Volume (oC) (atm) (ml mole-1) H2 -240.C 12.8 atm 64.51 ml mol-1 O2 118.80oC 49.7 atm 74.42 mol-1 o CO2 31.1 C 72.9 atm 95.65 ml mol-1 N.B. Kvb Mvmxq c`v_i Zvcgvv vw ev msKU Zvcgvvi wbP _vKj ZvK ev wnme Mb Kiv nq |

Ze

Mvg cwigvb Mvmi )

PV1 P2V2 1 = iv) (h Kvb cwigvY Mvmi T1 T2

) Av`k Mvm mgxKiYi eenvi t 1| Mvmi AvbweK fi wbYq 2| Mvmi NbZ wbYq GQvov mgxKiY eenvi Ki, Mvmi gvj msLv, AYyi msLv, AvqZb, Zvcgvv, Pvc cfwZ wnmve Kiv hvq|

Sample-Questions

Av`k Mvm(Ideal gas) I eve Mvm(Real gas) K) Av`k Mvmi ewk t Kg Zvcgvv I Pvc PV = nRT mgxKiY gb Pj wi Zvcgvvq Afixb kw Gi AvqZbi Dci wbfikxj bq| A_vr ()T = 0 [GLvb , u= AfixY kw] L) eve ev Abv`k Mvmi ewk t PV = nRT mgxKiY gb Pj bv| Ze wbPvc I DP Zvcgvvq eve Mvm mg~n Av`k Mvmi bvq AvPib Ki | Mvmi AYyi wbR^ AvqZb I wbR`i ga AvKlY ej we`gvb| eve Mvmi Rb chvR nj fvbWvi Iqvjm mgxKiY t ( P +

1. Kvb Aevq Av`k AvPiY nZ GKwU Mvmi mePq ekx wePzwZ NU? [2007-08] (A) High temperature and low pressure (B) Low temperature and low pressure (C) High temperature and high pressure (D) Low temperature and high pressure Ans: (D) Note: 8. eve Mvm KLb Av`k Mvmi AvPiY c`kb Ki? [RU.2007-08] A) P 1atm I DP Zvcgvv B) P 1atm I DP Zvcgvv C) P=1atm I wb Zvcgvv D) P =1atm I DP Zvcgvv 13. fvvi Iqvjm& mgxKiYi ic Kvb&wU? [R.U.2007-08] A) P

n2a )(V nb) = nRT V2

N.B. AvgvMvi cixv Abyhvqx wb Zvcgvv I DP Pvc Av`k AvPiY _K mePq ewk wePzwZ NU|

n2a (V+nb) = nRT V2

na 2 P + 2 (V-nb) = nRT B) V n2a P + 2 (V-nb) = nRT C) V

D) P +

Mvm ZijxKibi Dcvq

i) ii) Mvmi Zvcgvv nvm Ki Mvmi Dci Pvc cqvM Ki| Ryj- _gmb cixv Abyhvqx Mvmi ZijxKiYi kZ- Low temperature and high pressure

a (V-nb) = nRT V2

FOCUS : My Intelligent Choice

25.

19.

eve Mvm Av`k Mvmi mgxKiY PV=nRT gb Pj bv| [N.U.2006-07] A) Mvm AYyi AvqZb AwZ bMY B) Mvmi AYyi wbR^ AvqZb AvQ C) Mvmi AYyi MwZeM Lye ewk D) Mvmi AYyi wbR^ AvqZb I wbR`i ga AvKlY ej we`gvb fvbWvi Iqvjm& aeK amwVK GKK-[C.U.2006-07] A) atm.L2mol-2 B) atm.L-2mol-2 C) Lmol-2 D) atm2L-1mol-1 -1 E) atm.mol

c`v_i KwVb Aev (Solid state of Matter) KvVvgvi Dci wfw Ki KwVb c`v_ 2 cKvi1) `vbv`vi (Crystalline) 2) A`vbv`vi (amorphous) GKK Kvl (Unit cell) : Kvb wUKi (Crystal) h z`Zg Ask, hvi ga me gwjK Ask cybivew Qvov we`gvb ZvK GKK Kvl ej| cZKwU GKK Kvl Gi AvUwU Kvbv (corner) eviwU avi (edge) Ges QqwU cZj (face) _vK| D`vniY a=b=c=90 NaCl , Wvqg, avZzmg~n hgb-Cu, Ag kZwUb (SnO2), TiO2, SnCl2 KNO3, iw^K mvjdvi, BaSO4 Na2SO4. 10H2O ,S8, wRcmvg, FeSO4. 7H2O K2Cr2O7, H3BO3, CuSO4. 5H2O KvjmvBU, CaCO3, NaNO3, eid MvdvBU, avZz, KvqvUR A) a=b=c B) a=bc C) ab=c D) a=2b=c 30. wbi KvbwU Kjvmi mwVK kYx wefvMi D`vniY bq? [M.A.- 2006-07] A) Cubic : NaCl B) Orthorhombic : KNO3 C) Monoclinic : FeSO4. 7H2O D) Hexagonal : CaCO3 Ans: (D) Note: nvMvbvji D`vniY = MvdvBU, avZz, KvqvUR|

Kjvmi kbx 1| NbK (Cubic) 2| UUvMvbvj (teragonal) 3| A_viw^K (Orthwrhombic) 4| gbvwKwbK (monoclinic) 5| UvBwKwbK (Triclinic) 6| i^vnWvj (Rhomubohedral) 7| nvMvbvj (Hexagonal)

A `yiZi mK a=b=c a=bc

Sample-Questions
9. KNO3 Kvb kYxi Kjvm? [R.U.200708] A) wKDweK B) UUvMvbvj C) A_viw^K D) gbvwKwbK nvMvbvj Kjvm KvbwU? [R.U.2006-07] A) Wvqg B) kZ wUb C) MvdvBU D) KvjmvBU x,y,z A eivei GKK `yiZK h_vg a,b,c w`q cKvk Kij UUvMvbvj Kjvmi A `yiZi mK ne[R.U.2007-08]

27.

14.

FOCUS : My Intelligent Choice

Solution (cwZwU cki Di AekB eyS eyS wkLZ ne)

[N.B : GB jKPvi aygv Theoritical Ask AvjvPbv Kiv nqQ, Mathmetical problems jKPvi-4 G AvjvwPZ nqQ|]

E) 8.31 calK-1 mol-1 3. 00c Zvcgvv cig j KZ? [CU.2007-08] A) 00C B) 750 K C) 273 K D) 298 K E) 300 K

Ex-Questions of Dhaka University (cwZwU cki Di AekB eyS eyS wkLZ ne)
3. GKB Zvcgvvq GKB AvqZbi c_g cv 1 mol N2 Ges wZxq cv 1 mol CO2 ivLv njv| wbi Kvb DwwU mwVK bq? [2004-05] (A) 1g cv Pvc wbZi (B) 1g cv N2 Abyi MwZ DPZi (C) Dfq cv AYyi msLv mgvb (D) Dfq cv Abymg~ni Mo MwZkw mgvb Ans: (B) Note : GKB Zvcgvv I AvqZbi -= ev, P1 = P2 A_vr 1g cv Pvc wbZi bq eis Dfq cv Pvc mgvb| (A) chvq mviYxi mKj gj cKwZZ cvIqv hvq (B) jnK Mvmxq Aevq icvwiZ Kiv hvq bv (C) 120 Zvcgvvq cvwbi Zij Aev Ame (D) Av: AvbweK AvKlb AvQ ejB Mvmi ZijxKiY me| Ans: (D) 5. wKic Pvc I Zvcgvvq Kvb eve Mvm PV=nRT mgxKiYwU gvUvgywU gb Pje? [RU.2007-08] A) DP Pvc; DP Zvcgvv B) DP Pvc; wb Zvcgvv C) wb Pvc; DP Zvcgvv D) wb Pvc; DP Zvcgvv

10.

11.

SI GKK mveRbxb Mvm aeKi gvv KZ?[R.U.2007-08] A) L AtmK-1mole-1 B) J K-1 mole-1 C) N K-1 mole-1 D) Cal K-1 mole-1 KZ wWMx mjwmqvm Zvcgvvq evqy Zij cwiYZ nq? 08] A) -273 B) -180 C) -184 D) -132 mv`v wfwUIj Kvb&wU? [R.U.2007-08] A) FeSO4.7H2O B) ZnSO4.7H2O C) MgSO4. 7H2O D) CaSO4. 2H2O eqji m~i KvbwU mZ? [C.U.2006-07] A) V wi B) P wi C) T wi D) T cwieZbkxj E) P &V wi wi Zvc Kvb Mvmi Pvc wb evoj AvqZb ne: [C.U. 200607] A) wb B) AaK C) Pvib D) GK PZz_vsk E) GK ZZxqvsk KZ Zvcgvvq mvwWqvg KvivBW Mj? [C.U.2006-07] A) 800 C B) 500 C C C) 100 D) 200 C E) 150 C ^vfvweK Zvcgvvq Kvb gwjK avZz Zij Aevq _vK? [C.U.2006-07] A) mxmv B) cvi` C) wjw_qvg D) KvWwgqvg E) meB [R.U.2007-

12.

17.

5. wbPi KvbwU mZ? [2001-02]

18.

20.

21.

Other University Questions

1. Kvb&wU Mvm aeK RGi gvb bq? [CU.2007-08] A) 8.20 10-2 L atm K-1 mol-1 B) 8.20 10-3 L atm K-1 mol-1 C) 8.32 107 erg K-1 mol-1 D) 8.31 JK-1 mol-1 22.

S.I.GKK gvjvi Mvm aeK R Gi gvb nj-[K.U.06-07] A) 0.0821 L.atm/K/mol B) 0.0821 Joule/K/mol C) 8.316 J oule/K/mol

FOCUS : My Intelligent Choice

23.

D) 8.316 107 Joule/K/mol Mvmi AYyjvi MwZi Dci[K.U.2006-07] A) AwfKl kwi Kvb cfve bB B) AwfKl kwi mvgvb cfve AvQ C) gvavKl kwi Kvb cfve bB D) gvavKl kwi mvgvb cfve AvQ Answer : 1. b, 2. a, 3. c, 4. b, 5. a, 6. b, 7. a, 8. a, 9. c, 10. b, 11. a, 12. b, 13. c, 14. b, 15. d, 16. a, 17. d, 18. b, 19. a, 20. a, 21. b, 22. c, 23. a, 24. c, 25. d, 26. c, 27. c, 28. c, 29. c, 30. d.

1.

2.

gb ivLZ ne t Pvjmi m~i MvwbwZK fvlv, Vt = VO(1+)

3.

msKvPbkxjZv

bvsK

Z=

PV RT

(Av`k Mvmi Rb Z=1) Mvm wgkbi Kvb Dcv`vbi AvswkK Pvc = m Dcv`vbi gvj fMvsk wgkbi gvU Pvc| KvwLZ Mvmi Pvc (Pg )=Av` Mvm wgkYi Pvc(P0)GKBZvcgvvqcvwbi ev Pvc(f)

4.

wb KvbwUi Aby mg~ni MwZeM mePq ewk? a) H2 Aby b) O2 Aby c) N2 Aby d) Cl2 Aby Note: nvBWvRbi (H2) AvbweK fi mePq Kg nIqvq Gi Abymg~ni MwZeM mePq ewk| Mvnvgi evcb (Diffusion law) m~i cqvM bq KvbwU? a) AvbweK wbYq b) NbZ wbYq c) Mvm wgkbi Dcv`vb c_KxKiY d) GKB gji wewfb AvBmvUvc c_KxKiY nxiKi Kjvm KvVvgvi bvg Kx? a) Cubic b) Tetragonal c) Orthorhombic d) Hexagonal Kvb mKwU wg_v? a) Vt = Vo c) = =

273 + t 273
d) c =

b) PV = RT

M2 M1

3RT M

5.

v) M =

W RT dRT = (d NbZ wewk V P P

Mvmi )

Practice-Questions
6. wRcmvg Kvb aibi Kjvm? [RU.2007-08] A)NbK B) gbvwKwbK C) UvBwKwbK D) A_viw^K NaCl Gi mve MvVwbK AvKwZ wK ne? [CU.2007-08] A) NbKxq B) AZjxq C) iwLK D) PZz jxq E) wfyRvKwZ 6.

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2.

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Practice Sheet
(At first try yourself, then check Answers)

GKK Kvli KvbwU chvR? a) AvUwU Kvbv, QqwU avi I eviwU cZj b) eviwU Kvbv, QqwU avi I AvUwU cZj c) QqwU Kvbv, AvUwU avi I eviwU cZj d) AvUwU Kvbv, eviwU avi I QqwU cZj wbi KvbwU c`v_i Aev bq? a) Gaseous b) Plasma c) Liquid Crystal d) Lattice crystal Zij wUK (liquid crystal) Gi eenvi bq KvbwU? a) Digit c`kbx ic b) Temperature sensor wnme c) wbDwKqvi fusion MelYvi d) i cevn evav ev eKR kbvKiY c`v_i Avt AvbweK ej Kvb factor Gi Dci wbfi Ki bv? a) Electrostatic force (wi e`ywZK AvKlY ej) b) Crystal lattice energy c) Polarity of covalent compound d) Velocity of the atoms

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38. 40.

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Mvmi NbZ I evcb nvii Z_ cvIqv hvq Kvb m~ _K? a) Boyles law b) Grahams Law c) Gay- Lussacs Law d) Daltons Law Ideal gas equation- Gi eenvi KvbwU? a) cig Zvcgvv j wbYq b) Mvmi NbZ wbYq c) gvjvi Mvm aeK wbYq d) Mvmi AvswkK Pvc wbYq Kvb Zijxf~Z Mvmi Zvcgvv 5K| mjwmqvm j G Zvcgvv KZ? a) -5c b) 268c c) -278c d) -268c NaCl Kvb kYxi Kjvm? a) Cubic b) Monoclinic c) Rhombohedral d) Tetragonal AvgvMvi Kvf gZ KvbwU mwVK? a) mgAvqZbi mKj Mvm mgvb msLK Aby _vKe b) eve Mvm, Av`k Mvm _K wePzwZ NU c) Mvmi AvqZb cvi Zzjbvq bMb d) Mvmi gvjvi AvqZb 22.4 L (STP-Z) Kvjwi GKK R- Gi gvba) 2.72 Cal b) 0.891 Cal c) 3.02 Cal d) 1.987 Cal AvBmv_vgvj Kvf cvIqv hvqa) eqji m~ nZ b) Pvjmi m~ nZ c) Pvci m~ nZ d) KvbwU _KB bq wi T I P G h Kvb Av`k Mvmi evcbi nvi NbZia) mgvbycvwZK b) e vbycvwZK c) eMg~ji evvbycvwZK d) eMgyji mgvbycvwZK CO2 Gi msKU Zvcgvv KZ? a) 31c b) 31.1c c) 30c d) 34c KvbwU AYyi MwZ bq? a) Kb MwZ b) AveZb MwZ c) KwYK MwZ d) vbv i MwZ

44.

45.

KwVb Aevq Abymg~ni Kvb MwZ _vKa) Kb MwZ b) NyYb MwZ c) vbvi MwZ d) meKwU KvbwU mZa) Abymg~ni Mo MwZkw cig Zvcgvvi mgvby cvwZK b) wbg Zvcgvv I DPZvc eve Mvm
Av`k Mvmi AvPiY Ki

c) mgPvc iLv cvIqv hvq eqji my d) Mvmi NbZ cig Zvcgvvi mgvbycvwZK 46. KvbwU Wvbi AvswkK Pvc m~i kZ? a) wbw` Zvcgvv b) wbw` Zvcgvvi cii wewqvhvM Mvm c) wbw` Zvcgvvq wewqvnxb Mvm d) wi Zvcgvv I Pvc 47. KvbwU Mvnvgi evcb m~i cqvM bq? a) AvbweK fi wbYq b) Mvm wgkbi Dcv`vbmg~ni c_KxKiY c) GKB gji wewfb AvBmvUvc c_KxKiY d) Mvmi AvswkK Pvc wbYq 48. 32g AwRbi Rb fvbWvi Iqvjm mgxKiY KvbwU? a) (P + ) (v b) = RT b) (P + ) (v b) = RT c) (P + ) (v b) = RT d) (P + ) (v- b) = RT Answer : 1. a, 2. b, 3. a, 4. c, 5. d, 6. d, 7. c, 8. d, 9. b, 10. b, 11. d, 12. b, 13. a, 14. c, 15. a, 16. d, 17. c, 18. c, 19. b, 20. c, 21. d, 22. d, 23. b, 24. b, 25. c, 26. a, 27. d, 28. c, 29. a, 30. b, 31. a, 32. b, 33. b, 34. d, 35. a, 36. b, 37. c, 38. d, 39. a, 40. a, 41. c, 42. b, 43. c, 44. a, 45. a, 46. a, 47. d, 48. b, 49. a, 50. b, 51. b, 52. b, 53. a, 54. b, 55. d, 56. b, 57. c, 58. c, 59. c, 60. a, 61. d, 62. a, 63. c, 64. c, 65. c. my`i eenviB mIqve| Avj-nv`xm

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