ResoNET 2012 Sample Test Paper

Academic Session : 2012-13
Practice, Persistence and Performance

Sample Test Papers
(Resonance National Entrance Test : ResoNET - 2012)
For Yearlong Classroom Contact Programmes (YCCPs) : IIT-JEE Division
For Class - X, XI, XII
IIT-JEE AIEEE AIPMT NTSE KVPY OLYMPIADS SAT
STPFXII1213
Page - 1
Sample Test Paper (STP)
For ResoNET-2012
I N D E X
Copyright reserved 2012-13.
All rights reserved. Any photocopying, publishing or reproduction of full or any part of this material is strictly prohibited. This material belongs to only the applicants
of RESONANCE for its various Selection Tests (ResoNET) to be conducted for admission in Academic Session 2012-13. Any sale/resale of this material is
punishable under law. Subject to Kota Jurisdiction only.
S.
No.
Content Eligibility
Course
Applied
Target
Page
No.
1
How to Prepare for the Resonance
National Entrance Test (ResoNET)-2012:
List of reference books
N.A. N.A. ResoNET 2012 1
2
Resoonance Support Material to Prepare
for the Resonance National Entrance Test
(ResoNET)-2012
3
General Instructions for the Examination
Hall
4 Syllabus for ResoNET-2012 N.A. N.A. ResoNET 2012 4
5
Sample Test Paper- I (STP-I): Test Paper Class-X Appearing/ Passed
students (Moving from
Class-X to Class-XI)
VIKAAS (JA) &
VIPUL (JB)
IITJEE 2014 9
6
Sample Test Paper-I (STP-I) : Answer
Key, Hints & Solution
Class-X Appearing/ Passed
students (Moving from
Class-X to Class-XI)
VIKAAS (JA) &
VIPUL (JB)
IITJEE 2014 20
7
Sample Test Paper-II (STP-II): Test Paper Class-XI Appearing /
Passed students (Moving
from Class-XI to Class-XII)
VISHWAAS (JF) IITJEE 2013 27
8
Sample Test Paper-II (STP-II) : Answer
Class-XI Appearing /
from Class-XI to Class-XII)
VISHWAAS (JF) IITJEE 2013 42
9
Sample Test Paper-III (STP-III) : Test
Paper
Class-XII Appearing /
from Class-XII to Class-
XIII)
VISHESH (JD) &
VIJAY (JR)
IITJEE 2013 50
10
Sample Test Paper-III (STP-III) : Answer
Class-XII Appearing /
from Class-XII to Class-
XIII)
VISHESH (JD) &
VIJAY (JR)
IITJEE 2013 64
11
Sample ORS Answer Sheet for Resonance
National Entrance Test (ResoNET)-2012 N.A. N.A. ResoNET 2012 75
The Sample Test Papers (STPs) are only for reference and guidance. The sample papers given in the booklet are actually the papers of previous year's ResoNET
conducted by Resonance for its various courses.
Note : Resonance reserves the right to change the pattern of selection test (ResoNET). Pervious year papers do not guarantee that the papers for this year
selection test will be on the same pattern. However, the syllabus of the test paper will be equivalent to the syllabus of qualifying school/board examination
and as given on page no. 4.
HOW TO PREPARE FOR THE RESONANCE NATIONAL ENTRANCE TEST (ResoNET) - 2012
For Class-X appearing / passed students (Class-X to Class-XI Moving) :
Study thoroughly the books of Science (Physics & Chemistry) and Maths of Classes IX & X. (NCERT & Respective Board)
For Class-XI appearing / passed students (Class-XI to Class-XII Moving):
1. Study thoroughly the books of Physics, Chemistry and Maths of Class XI (Respective Board).
2. Refer to the following books (only Class-XI syllabus) to increase the level of competence:
Physics : Concepts of Physics by H.C. Verma Vol. I & II
Chemistry : NCERT Books
Maths : Higher Algebra By Hall & Knight; Co-ordinate Geometry By S.L. Loney ; Plane Trigonometry By S.L. Loney
For Class-XII appearing / passed students (Class-XII to Class-XIII Movi ng) :
1. Study thoroughly the books of Physics, Chemistry and Maths of Classes XI & XII (Respective Board).
2. Refer to the following books (Class-XI & Class-XII syllabus) to increase the level of competence :
Physics : Concepts of Physics by H.C. Verma Vol-I & II
Chemistry : Physical Chemistry By R.K. Gupta, Organic Chemistry By Morrison & Boyd, Organic Chemistry By I. L. Finar,
Inorganic Chemistry By J.D. Lee, Objective Chemistry By Dr. P. Bahadur
Maths : Higher Algebra By Hall & Knight; Co-ordinate Geometry By S.L. Loney; Plane Trigonometry By S.L. Loney, Differential
Calculus By G.N. Berman; Integral Calculus By Shanti Narayan; Vector Algebra By Shanti Narayan ; MCQ By A Das Gupta.
STPFXII1213
Page - 2
For More Practice of RESONANCE NATIONAL ENTRANCE TEST (ResoNET) - 2012
Resonance Practice Test Papers (PTPs)
To support the preparation of ResoNET; Resonance Practice Test Papers (PTPs) of last few years with Answer Key, Hints & Solutions
are available on demand. Following Sets of Practice Test Papers (PTPs), in hard copy, are available with us :
S.
No.
PTP
Set
Content Eligibility Course (Code) Target Remark
1 Set-A 10 Papers Set (PTPs) Class-X Appearing/Passed students
VIKAAS (JA) &
VIPUL (JB)
IIT-JEE 2014
Answer Key,
Hints & Solutions
2 Set-B 10 Papers Set (PTPs) Class-XI Appearing/Passed students VISHWAAS (JF) IIT-JEE 2013
Answer Key,
Hints & Solutions
3 Set-C 10 Papers Set (PTPs) Class-XII Appearing Passed students
VISHESH (JD) &
VIJAY (JR)
IIT-JEE 2013
Answer Key,
Hints & Solutions
Interested students may collect the PTPs from Resonance Study Centres or Corporate Office at Kota (at Plot No. A-46, A-52, Near
City Mall, Jhalawar Road, Reception) by paying an additional fees of Rs.300/- only per set. Any of the above Practice Test Papers
(PTPs) sets may be procured through post / courier from 'Resonance Eduventures Pvt Ltd' by sending a Bank Demand Draft (DD)
of Rs. 300/- in favour of 'Resonance' and payable at Kota. A student may send the request application on plain paper along with
prerequisite fees to the institute to collect any of the sets of Practice Test Papers (PTPs). Please, mention clearly your name and
Roll Number (Application Form No.) on the back of the DD and which set of Practice Test Papers (Set A, B or C) is required by
you in the request application.
ResoNET Online Practice Test Papers (OPTPs)
To support the preparation of ResoNET; interested students may practice the ResoNET Test Papers online through ResoNET Online
Practice Test Papers (OPTPs) on Resonance Website: http://elpd.resonance.ac.in
Students can buy these Online Test papers at http://elpd.resonance.ac.in
S. No. Content Eligibility Course Code Target Fee(Taxes included)
1 3 Tests (OPTPs) Class-X Appearing/Passed students VIKAAS (JA) & VIPUL (JB) IIT-JEE 2014 Rs. 300/-
2 6 Tests (OPTPs) Class-X Appearing/Passed students VIKAAS (JA) & VIPUL (JB) IIT-JEE 2014 Rs. 500/-
3 3 Tests (OPTPs) Class-XI Appearing/Passed students VISHWAAS (JF) IIT-JEE 2013 Rs. 300/-
4 6 Tests (OPTPs) Class-XI Appearing/Passed students VISHWAAS (JF) IIT-JEE 2013 Rs. 500/-
5 3 Tests (OPTPs) Class-XII Appearing/Passed students VISHESH (JD) & VIJAY (JR) IIT-JEE 2013 Rs. 300/-
6 6 Tests (OPTPs) Class-XII Appearing/Passed students VISHESH (JD) & VIJAY (JR) IIT-JEE 2013 Rs. 500/-
ResoNET Prepratory Guide (RPG)
(Only for Class X to XI moving students)
To support the preparation of ResoNET; interested students (only for Class X to XI moving students) may study, learn, understand
and strengthen the fundamentals of Class IX & X through ResoNET Prepratory Guide (RPG). The salient features of RPG are as
follows :
1. Brief theory of ResoNET syllabus (for Class X to XI moving students).
2. Solved and Unsolved illustrations / examples.
3. Selected questions for practice.
Interested students may collect the RPG from Resonance Study Centres or Corporate Office at Kota (at Plot No. A-46, A-52, Near
City Mall, Jhalawar Road, Reception) by paying an additional fees of Rs.300/- only. The RPG may also be procured through post
/ courier from 'Resonance Eduventures Pvt Ltd' by sending a Bank Demand Draft (DD) of Rs. 300/- in favour of 'Resonance' and
payable at Kota. A student may send the request application on plain paper along with prerequisite fees to the institute to collect
the RPG. Please, mention clearly your name and Roll Number (Application Form No.) and ResNET Prepratory Guide (RPG) on
the back of the DD.
STPFXII1213
Page - 3
Note: The student should consider the following instructions to be written on the front page of the test
paper of ResoNET to be made available in the examination hall.
1. This booklet is your Question Paper. (r l-ni ii i r )
2. The Question Paper Code is printed on the top right corner of this sheet. ( i i ; -
+ i i - i r i r )
3. Blank papers, clip boards, log tables, slide rule, calculators, mobile or any other electronic
gadgets in any form are not allowed to be used. (iii i^, l i , i î iii, -i;
, - -, -i i; i li ; - il i li ii - i ^ i ini ri r )
4. Write your Name & Application Form Number in the space provided in the bottom of this
booklet. (; - i l ^ ln -ii - i r= r r = = =r ( i )
5. Before

answering the paper, fill up the required details in the blank space provided in the Objective
Response Sheet (ORS). ( i r r , ORSii- - l ^ ln -iii - ^
l((ii i i )
6. Do not forget to mention your paper code and Application Form Number neatly and clearly in
the blank space provided in the Objective Response Sheet (ORS) / Answer Sheet. (-i l-ni
- l ^ ln -ii - i i i ( i r r = = =r -- ii i i )
7. No rough sheets will be provided by the invigilators. All the rough work is to be done in the blank
space provided in the question paper. (li-i ,ii i; ii- ri i iî| i i
- l ^ iii -ii - ri i r)
8. No query related to question paper of any type is to be put to the invigilator.
(li-i i lin li i i i; i )
Question Paper
(>r)
9. Marks distribution of questions is as follows. ( i ini i i l((i l i r |)
Correct Wrong Blank
1 to 15 30 to 39 51 to 59
Only one correct
(+ + |+- =;|)
3 -1 0
16 to 19 40 to 43 60 to 61
One or more than one correct Answer
(+ r + = |=r+ |+- =;|)
4 0 0
20 to 28 44 to 49 62 to 64 Comprehensions (-e) 4 0 0
29 50 65
Matrix Match Type
(=|c= == +r)
6 [1, 2, 3, 6] 0 0
Marks to be awarded Part - I
(Mathematics)
Part - II
(Physics)
Part - III
(Chemistry)
Type
Name : _________________________________ Application Form Number : _______________
Note: The above instructions are for reference purpose only. The actual instructions in the Test Paper of
ResoNET in the examination hall may vary.
GENERAL INSTRUCTIONS IN THE EXAMINATION HALL
(|=rr -r + | =r=r- | r)
STPFXII1213
Page - 4
CLASS- X (CHEMISTRY)
Basic : Cooling by evaporation. Absorption of heat. All things accupy
space, possess mass. Definition of matter ; Elementary idea about
bonding.
Solid, liquid and gas : characteristics-shape, volume, density; change
of state - melting, freezing, evaporation, condensation, sublimation.
Elements, compounds and mixtures: Heterogeneous and
homogeneous mixtures; Colloids and suspension.
Mole concept: Equivalence - that x grams of A is chemically not equal
to x grams of B; Partical nature, basic units: atoms and molecules; Law
of constant proportions; Atomic and molecular masses; Relationship of
mole to mass of the particles and numbers; Valency; Chemical formulae
of common compounds.
Atomic structure: Atoms are made up of smaller particles: electrons,
protons, and neutrons. These smaller particles are present in all the
atoms but their numbers vary in different atoms.
Isotopes and isobars.
Gradations in properties: Mendeleev periodic table.
Acids, bases and salts: General properties, examples and uses.
Types of chemical reactions : Combination, decomposition, displ-
acement, double displacement, precipitation, neutralisation, oxidation
and reduction in terms of gain and loss of oxygen and hydrogen.
Extractive metallurgy : Properties of common metals ; Brief discussion
of basic metallurgical processes.
Compounds of Carbon: Carbon compounds; Elementary idea about
bonding; Saturated hydrocarbons, alcohols, carboxylic acids (no
preparation, only properties). Soap - cleansing action of soap.
_________________________
_________________________
CLASS - X (MATHEMATICS)
Number Systems : Natural Numbers, Integers, Rational number on
the number line. Even - odd integers, prime number, composite numbers,
twin primes, divisibility tests, Co-prime numbers, LCM and HCF of
numbers.
Representation of terminating/non-terminating recurring decimals, on
the number line through successive magnification. Rational numbers
as recurring/terminating decimals. Ratio and proportions.
Polynomials : Polynomial in one variable and its Degree. Constant,
Linear, quadratic, cubic polynomials; monomials, binomials, trinomials,
Factors and multiplex. Zeros/roots of a polynomial/equation.
Remainder theorem, Factor Theorem. Factorisation of quadratic and
cubic polynomials
Standard form of a quadratic equation ax
2
+ bx + c = 0, (a = 0). Relation
between roots and coefficient of quadratic and relation between
discriminant and nature of roots.
Linear Equation : Linear equation in one variable and two variable
and their graphs.
Pair of linear equations in two variables and their solution and
inconsistency
Arithmetic Progressions (AP) : Finding the n
th
term and sum of first
n terms.
Trigonometry : Trigonometric ratios of an acute angle of a right-
angled triangle, Relationships between the ratios.
Trigonometric ratios of complementary angles and trigonometric
identities. Problems based on heights and distances.
Coordinate Geometry : The cartesian plane, coordinates of a point,
plotting points in the plane, distance between two points and section
formula (internal). Area of triangle. Properties of triangle and quadrilateral.
(Square, Rectangle rhombus, parallelogram).
Geometry :
Lines : Properties of parallel and perpendicular lines.
Triangle : Area of a triangle, Properties of triangle, similarity and
congruency of triangles.
Medians, Altitudes, Angle bisectors and related centres.
Geometrical representation of quadratic polynomials.
Circle : Properties of circle, Tangent, Normal and chords.
Mensuration : Area of triangle using Herons formula and its application
in finding the area of a quadrilateral.
Area of circle ; Surface areas and volumes of cubes, cuboids,
spheres (including hemispheres) and right circular cylinders/cones
and their combinations.
Statistics : Mean, median, mode of ungrouped and grouped data.
Probability : Classical definition of probability, problems on single
events.
Logarithm & exponents : Logarithms and exponents and their
properties.
Interest : Problem based on simple interest, compound interest and
discounts.
Mental Ability : Problem based on data interpretation, family relations,
Logical reasoning.
Direct & Indirect variations : Ratios & proportions, Unitary method,
Work and time problems.
_________________________
_________________________
CLASS - X (PHYSICS)
Mechanics : Uniform and non-uniform motion along a straight line ;
Concept of distance and displacement, Speed and velocity, accelaration
and relation ship between these ; Distance-time and velcocity - time
graphs.
Newtons Law of motion ; Relationship between mass, momentum,
force and accelaration ; work done by a force ; Law of conservation
of energy.
Law of gravitation ; acceleration due to gravity.
Electricity and magnetism : Ohms law ; Series and parallel combi-
nation of resistances ; Heating effect of current.
Magnetic field near a current carrying straight wire, along the axis of
a circular coil and inside a solenoid ; Force on current carrying con-
ductor ; Flemings left hand rule ; Working of electric motor ; Induced
potential difference and current
Electric generator : Principle and working ; Comparision of AC and
DC ; Domestic electric circuits.
Optics : Rectilinear propagation of light ; Basic idea of concave mir-
ror and convex lens ; Laws of refraction ; Dispersion.
_________________________
_________________________
CLASS - XI (CHEMISTRY)
Some Basic Concepts of Chemistry : Particulate nature of matter,
laws of chemical combination, Daltons atomic theory : concept of
elements, atoms and molecules.
Atomic and molecular masses. Mole concept and molar mass ;
percentage composition and empirical and molecular formula ; chemical
reactions, stoichiometry and calculations based on stoichiometry.
Structure of Atom : Discovery of electron, proton and neutron ;
atomic number, isotopes and isobars.
Thompsons model and its limitations, Rutherfords model and its
limitations, concept of shells and sub-shells, dual nature of matter and
light, de Broglies relationship, Heisenberg uncertainty principle, concept
of orbitals, quantum numbers, shapes of s, p, and d orbitals, rules for
filling electrons in orbitals - Aufbau principle, Pauli exclusion principle
Syllabus of ResoNET-2012
STPFXII1213
Page - 5
and Hunds rule, electronic configuration of atoms, stability of half filled
and completely filleld orbitals.
Classification of Elements and Periodicity in Properties :
Significance of classification, brief history of the development of periodic
table, trends in properties of elements - atomic radii, ionic radii, inert
gas radii, ionization enthalpy, electron gain enthalpy, electronegativity,
valence.
Chemical Bonding and Molecular Structure : Valence electrons,
ionic bond, covalent bond, bond parameters, Lewis structure, polar
character of covalent bond, covalent character of ionic bond, valence
bond theory, resonance, geometry of covalent molecules, VSEPR theory,
concept of hybridization involving s, p and d orbitals and shapes of
some simple molecules,
molecular orbital theory of homonuclear diatomic molecules (qualitative
idea only), hydrogen bond.
States of Matter : Gases and Liquids : Three states of matter,
intermolecular interactions, type of bonding, melting and boiling points,
role of gas laws in elucidating the concept of the molecule, Boyles
law, Charles law, Gay Lussacs law, Avogadros law, ideal behavior,
empirical derivation of gas equation, Avogadros number ideal gas
equation, deviation from ideal behaviour, Liquefaction of gases, critical
temperature.
Liquid State - Vapour pressure, viscosity and surface tension
(qualitative idea only, no mathematical derivations)
Thermodynamics : Concepts of system, types of systems, sur-
roundings, work, heat, energy, extensive and intensive properties,
state functions.
First law of thermodynamics - internal energy and enthalpy, heat ca-
pacity and specific heat, measurement of AU and AH, Hesss law of
constant heat summati on, enthal py of bond dissoci ation,
combustion, formation, atomization sublimation, phase transition, ion-
ization, and dilution.
Introduction of entropy as a state function, free energy change for
spontaneous and non-spontaneous process, equilibrium.
Equilibrium : Equilibrium in physical and chemical processes,
dynamic nature of equilibrium, law of mass action, equilibrium
constant, factors affecting equilibrium - Le Chateliers principle ; ionic
equilibrium - ionization of acids and bases, strong and weak electro-
lytes, degree of ionization concept of pH. Hydrolysis of Salts (elemen-
tary idea), buffer solutions, solubility product, common ion effect (with
illustrative examples).
Redox Reactions : Concept of oxidation and reduction, redox reac-
tions,
oxidation number, balancing redox reactions, applications of redox
reaction.
Hydrogen : Position of hydrogen in periodic table, occurrence, iso-
topes, preparation, properties and uses of hydrogen ; hydrides - ionic,
covalent and interstitial ; physical and chemical properties of water,
heavy water ; hydrogen peroxide - preparation, reactions and struc-
ture ; hydrogen as a fuel.
s-Block Elements (Alkali and Alkaline Earth Metals) :
Group 1 and Group 2 elements : General introduction, electronic
configuration, occurrence, anomalous properties of the first element
of each group, diagonal relationship, trends in the variation of proper-
ties (such as ionization enthalpy, atomic and ionic radii), trends in
chemical reactivity with oxygen, water, hydrogen and halogens ; uses.
Preparation and properties of some important compounds:
Sodium carbonate, sodium chloride, sodium hydroxide and sodium
hydrogen carbonate
CaO, CaCO
3
, and industrial use of lime and limestone, Ca.
General Introduction to p-Block Elements : Group 13 elements :
General introduction, electronic configuration, occurrence, variation
of properties, oxidation states, trends in chemical reactivity, anoma-
lous properties of first element of the group ;
Boron - physical and chemical properties, some important compounds
borax, boric acids, boron hydrides. Aluminium : uses, reactions with
acids and alkalies.
Group 14 elements ; General introduction, electronic configuration,
occurrence, variation of properties, oxidation states, trends in chemi-
cal reactivity, anomalous behaviour of first element. Carbon - catena-
tion, allotropic forms, physical and chemical propeties ; uses of some
important compounds : oxides.
Important compounds of silicon and a few uses : silicon tetrachloride,
silicones, silicates and zeolites.
Principles of qualitative analysis : Determinantion of one anion and
one cation in a given salt
Cations - Pb
2 +
, Cu
2+
, As
3+
, Al
3+
, Fe
3+
, Mn
2+
, Ni
2 +
, Zn
2+
, Co
2+
, Ca
2+
, Sr
2+
,
Ba
2+
, Mg
2+
,
+
4
NH
Anions - , NO , SO , SO , S , CO

2
2
4
2
3
2 2
3
3
2
4 2
3
4

3
3
COO CH O C , PO , , Br , Cl , NO , NO I
(Note : Insoluble salts excluded)
Organic chemistry - Some Basic Principles and Techniques
General introduction, methods of purification, qualitative and
quantitative analysis, classification and IUPAC nomenclature of
organic compounds.
Electronic displacements in a covalent bond : free radicals, carbocations,
carbanions ; electrophiles and nucleophiles, types of organic reac-
tions
Classification of Hydrocarbons : Al kanes : Nomencl ature,
isomeri sm, conformati ons (ethane only), physical propeties,
chemi cal reactions i ncludi ng free radi cal mechani sm of
halogenation, combustion and pyrolysis.
Alkenes : Nomenclatures, structure of double bond (ethene),
geometrical isomerism, physical properties, methods of preparation ;
chemical reactions : addition of hydrogen, halogen, water, hydrogen
hal i des (Markovni kov s addi ti on and peroxide effect),
ozonolysis, oxidation, mechanism of electrophilic addition.
Alkynes : Nomenclature, structure of triple bond (ethyne), physical
properties, methods of preparation, chemical reactions : acidic
character of alkynes, addition reaction of - hydrogen, halogens, hy-
drogen halides and water.
Aromatic hydrocarbons : Introduction, IUPAC nomenclature ;
Benzene : resonance, aromaticity ; chemical properties : mechanism
of electrophilic substitution - nitration sulphonation, halogenation, Friedel
Crafts alkylation and acylation ; directive influence of functional group
in mono-substituted benzene; carcinogenicity and toxicity.
_________________________
_________________________
CLASS - XI (MATHEMATICS)
Functions: Sets and their representations. Empty, finite and infinite
sets, Subsets, Union and intersection of sets, Venn diagrams.
Pictorial representation of a function domain, co-domain and range of
a function domain and range of constant, identity, polynomial, rational,
modulus, signum and greatest integer functions with their graphs.
Sum, difference, product and quotients of functions.
Trigonometric Functions: Measuring angles in radians and in
degrees and conversion from one measure to another. Signs of
trigonometric functions and sketch of their graphs. Addition and
subtraction formulae, formulae involving multiple and sub-multiple angles.
General solution of trigonometric equations.
Complex Number: Algebra of compl ex numbers, addi tion,
multiplication, conjugation, polar representation, properties of modulus
and principal argument, triangle inequality, cube roots of unity, geometric
interpretations.
Quadratic equations : Quadratic equations with real coefficients,
formation of quadratic equations with given roots, symmetric functions
of roots.
Sequence & Series : Arithmeti c, geometri c and harmoni c
progressions, arithmetic, geometric and harmonic means, sums of finite
arithmetic and geometric progressions, infinite geometric series, sums
of squares and cubes of the first n natural numbers.
Logarithm & exponents: Logarithms and exponents and their
properties. Exponential and logarithmic series.
STPFXII1213
Page - 6
Binomial Theorem: Binomial theorem for a positive integral index,
properties of binomial coefficients. Binomial theorem for any index.
Permutations and combinations: Problem based on fundamental
counting principle, Arrangement of alike and different objects, Circular
permutation, Combination, formation of groups.
Straight Line : Cartesian coordinates, distance between two points,
section formulae, shift of origin. Equation of a straight line in various
forms, angle between two lines, distance of a point from a line; Lines
through the point of intersection of two given lines equation of the
bisector of the angle between two lines, concurrency of lines; Centroid,
orthocentre, incentre and circumcentre of a triangle.
Conic Sections : Equation of a circle in various forms, equations of
tangent, normal and chord. Parametric equations of a circle, intersection
of a circle with a straight line or a circle, equation of a through the
points of intersection of two circles and those of a circle and a straight
line.
Equations of a parabola, ellipse and hyperbola in standard form, their
foci, directrices and eccentricity, parametric equations, equations of
tangent and normal locus problems.
Mental Ability : Problem based on data interpretation, family relations
& Logical reasoning.
_________________________
_________________________
CLASS - XI (PHYSICS)
General : Units and dimensions, dimensional analysis; least count,
significant figures; Methods of measurement and error analysis for
physical quantities pertaining to the following experiments: Experi-
ments based on using Vernier calipers and screw gauge (microme-
ter), Determination of g using simple pendulum, Youngs modulus by
Searles method.
Mechanics : Kinematics in one and two dimensions (Cartesian
coordinates only), projectiles; Uniform Circular motion; Relative
velocity.
Newtons laws of motion; Inertial and uniformly accelerated frames of
reference; Static and dynamic friction; Kinetic and potential energy;
Work and power; Conservation of linear momentum and mechanical
energy.
Systems of particles; Centre of mass and its motion; Impulse; Elastic
and inelastic collisions.
Law of gravitation; Gravitational potential and field; Acceleration due to
gravity; Motion of planets and satellites in circular orbits; Escape ve-
locity.
Rigid body, moment of inertia, parallel and perpendicular axes
theorems, moment of i nertia of uniform bodi es wi th si mpl e
geometrical shapes; Angular momentum; Torque; Conservation of an-
gular momentum; Dynamics of rigid bodies with fixed axis of
rotation; Rolling without slipping of rings, cylinders and spheres; Equi-
librium of rigid bodies; Collision of point masses with rigid bodies.
Linear and angular simple harmonic motions.
Hookes law, Youngs modulus.
Pressure in a fluid; Pascals law; Buoyancy; Surface energy and sur-
face tensi on, capi l lary rise; Vi scosi ty (Poi seuil l e s equation
excluded), Stokes law; Terminal velocity, Streamline flow, equation of
continuity, Bernoullis theorem and its applications.
Waves : Wave moti on (plane waves only), l ongitudinal and
transverse waves, superposition of waves; Progressive and station-
ary waves; Vibration of strings and air columns;Resonance; Beats;
Speed of sound in gases; Doppler effect (in sound).
Thermal physics : Thermal expansion of solids, liquids and gases;
Calorimetry, latent heat; Heat conduction in one dimension; Elementary
concepts of convection and radiation; Newtons law of cooling; Ideal
gas laws; Specific heats (Cv and Cp for monoatomic and diatomic
gases); Isothermal and adiabatic processes, bulk modulus of gases;
Equivalence of heat and work; First law of thermodynamics and its
applications (only for ideal gases); Blackbody radiation: absorptive
and emissive powers; Kirchhoffs law; Wiens displacement law,
Stefans law.
_________________________
_________________________
CLASS - XII (CHEMISTRY)
PHYSICAL CHEMISTRY
General topics : Concept of atoms and molecules; Daltons atomic
theory; Mole concept; Chemical formulae; Balanced chemical equations;
Calculations (based on mole concept) involving common oxidation-
reduction, neutralisation, and displacement reactions; Concentration in
terms of mole fraction, molarity, molality and normality.
Gaseous and liquid states : Absolute scale of temperature, ideal
gas equation; Deviation from ideality, van der Waals equation; Kinetic
theory of gases, average, root mean square and most probable
velocities and their relation with temperature; Law of partial pressures;
Vapour pressure; Diffusion of gases.
Atomic structure and chemical bonding : Bohr model, spectrum
of hydrogen atom, quantum numbers; Wave-particle duality, de Broglie
hypothesis; Uncertainty principle; Qualitative quantum mechanical
picture of hydrogen atom, shapes of s, p and d orbitals; Electronic
configurations of elements (up to atomic number 36); Aufbau principle;
Paulis exclusion principle and Hunds rule; Orbital overlap and covalent
bond; Hybridisation involving s, p and d orbitals only; Orbital energy
diagrams for homonuclear diatomic species; Hydrogen bond; Polarity
in molecules, dipole moment (qualitative aspects only); VSEPR model
and shapes of molecules (linear, angular, triangular, square planar,
pyramidal, square pyramidal, trigonal bipyramidal, tetrahedral and
octahedral).
Energetics : First law of thermodynamics; Internal energy, work and
heat, pressure-volume work; Enthalpy, Hesss law; Heat of reaction,
fusion and vapourization; Second law of thermodynamics; Entropy;
Free energy; Criterion of spontaneity.
Chemical equilibrium : Law of mass action; Equilibrium constant,
Le Chateliers principle
(effect of concentration, temperature and pressure); Significance of
AG and AGo in chemical equilibrium; Solubility product, common ion
effect, pH and buffer solutions; Acids and bases (Bronsted and Lewis
concepts); Hydrolysis of salts.
Electrochemistry : Electrochemical cells and cell reactions; Standard
electrode potentials; Nernst equation and its relation to DG;
Electrochemical series, emf of galvanic cells; Faradays laws of
electrolysis; Electrolytic conductance, specific, equivalent and molar
conductivity, Kohlrauschs law; Concentration cells.
Chemical kinetics : Rates of chemical reactions; Order of reactions;
Rate constant; First order reactions; Temperature dependence of rate
constant (Arrhenius equation).
Solid state : Classification of solids, crystalline state, seven crystal
systems (cell parameters a, b, c, ), close packed structure of solids
(cubic), packing in fcc, bcc and hcp lattices; Nearest neighbours, ionic
radii, simple ionic compounds, point defects.
Solutions : Raoults law; Molecular weight determination from lowering
of vapour pressure, elevation of boiling point and depression of freezing
point.
Surface chemistry : Elementary concepts of adsorption (excluding
adsorption isotherms); Colloids: types, methods of preparation and
general properties; Elementary ideas of emulsions, surfactants and
micelles (only definitions and examples).
Nuclear chemistry : Radioactivity: isotopes and isobars; Properties
of rays; Kinetics of radioactive decay (decay series excluded), carbon
dating; Stability of nuclei with respect to proton-neutron ratio; Brief
discussion on fission and fusion reactions.
INORGANIC CHEMISTRY
Isolation/preparation and properties of the following non-
metals : Boron, silicon, nitrogen, phosphorus, oxygen, sulphur and
halogens; Properties of allotropes of carbon
(only diamond and graphite), phosphorus and sulphur.
Preparation and properties of the following compounds :
Oxides, peroxides, hydroxides, carbonates, bicarbonates, chlorides
and sulphates of sodium, potassium, magnesium and calcium; Boron:
diborane, boric acid and borax; Aluminium: alumina, aluminium chloride
STPFXII1213
Page - 7
and alums; Carbon: oxides and oxyacid (carbonic acid); Silicon:
silicones, silicates and silicon carbide; Nitrogen: oxides, oxyacids and
ammonia; Phosphorus: oxides, oxyacids (phosphorus acid, phosphoric
acid) and phosphine; Oxygen: ozone and hydrogen peroxide; Sulphur:
hydrogen sulphide, oxides, sulphurous acid, sulphuric acid and sodium
thiosulphate; Halogens: hydrohalic acids, oxides and oxyacids of
chlorine, bleaching powder; Xenon fluorides.
Transition elements (3d series) : Definition, general characteristics,
oxidation states and their stabilities, colour (excluding the details of
electronic transitions) and calculation of spin (only magnetic moment),
Coordination compounds: nomenclature of mononuclear coordination
compounds, cis-trans and ionisation isomerisms, hybridization and
geometries of mononuclear coordination compounds (linear, tetrahedral,
square planar and octahedral).
Preparation and properties of the following compounds :
Oxides and chlorides of tin and lead; Oxides, chlorides and sulphates
of Fe
2+
, Cu
2+
and Zn
2+
; Potassium permanganate, potassium dichromate,
silver oxide, silver nitrate, silver thiosulphate.
Ores and minerals : Commonly occurring ores and minerals of iron,
copper, tin, lead, magnesium, aluminium, zinc and silver.
Extractive metallurgy : Chemical principles and reactions only
(industrial details excluded); Carbon reduction method (iron and tin);
Self reduction method (copper and lead); Electrolytic reduction method
(magnesium and aluminium); Cyanide process (silver and gold).
Principles of qualitative analysis : Groups I to V (only Ag
+
, Hg
2+
,
Cu
2+
, Pb
2+
, Bi
3+
, Fe
3+
, Cr
3+
, Al
3+
, Ca
2+
, Ba
2+
, Zn
2+
, Mn
2+
and Mg
2+
); Nitrate,
halides (excluding fluoride), sulphate and sulphide.
ORGANIC CHEMISTRY
Concepts : Hybridisation of carbon; Sigma and pi-bonds; Shapes of
simple organic molecules; Structural and geometrical isomerism; Optical
isomerism of compounds containing up to two asymmetric centres,
(R,S and E,Z nomenclature excluded); IUPAC nomenclature of simple
organic compounds (only hydrocarbons, mono-functional and bi-
functional compounds); Conformations of ethane and butane (Newman
projections); Resonance and hyperconjugation; Keto-enol tautomerism;
Determination of empirical and molecular formulae of simple compounds
(only combustion method); Hydrogen bonds: definition and their effects
on physical properties of alcohols and carboxylic acids; Inductive and
resonance effects on acidity and basicity of organic acids and bases;
Polarity and inductive effects in alkyl halides; Reactive intermediates
produced during homolytic and heterolytic bond cleavage; Formation,
structure and stability of carbocations, carbanions and free radicals.
Preparation, properties and reactions of alkanes : Homologous
series, physical properties of alkanes (melting points, boiling points
and density); Combustion and halogenation of alkanes; Preparation of
alkanes by Wurtz reaction and decarboxylation reactions.
Preparation, properties and reactions of alkenes and alkynes:
Physical properties of alkenes and alkynes (boiling points, density and
dipole moments); Acidity of alkynes; Acid catalysed hydration of alkenes
and alkynes (excluding the stereochemistry of addition and elimination);
Reactions of alkenes with KMnO
4
and ozone; Reduction of alkenes
and alkynes; Preparation of alkenes and alkynes by elimination reactions;
Electrophilic addition reactions of alkenes with X
2
, HX, HOX and H
2
O
(X=halogen); Addition reactions of alkynes; Metal acetylides.
Reactions of Benzene : Structure and aromaticity; Electrophilic
substitution reactions: halogenation, nitration, sulphonation, Friedel-
Crafts alkylation and acylation; Effect of ortho, meta and para directing
groups in monosubstituted benzenes.
Phenols : Acidity, electrophilic substitution reactions (halogenation,
nitration and sulphonation); Reimer-Tieman reaction, Kolbe reaction.
Characteristic reactions of the following (including those
mentioned above): Alkyl halides: rearrangement reactions of alkyl
carbocation, Grignard reactions, nucleophilic substitution reactions;
Alcohols: esterification, dehydration and oxidation, reaction with
sodium, phosphorus halides, ZnCl2/concentrated HCl, conversion of
alcohols into aldehydes and ketones; Ethers:Preparation by
Williamsons Synthesis; Aldehydes and Ketones: oxidation,
reduction, oxime and hydrazone formation; aldol condensation, Perkin
reaction; Cannizzaro reaction; haloform reaction and nucleophilic
addition reactions (Grignard addition); Carboxylic acids: formation
of esters, acid chlorides and amides, ester hydrolysis; Amines:
basicity of substituted anilines and aliphatic amines, preparation from
nitro compounds, reaction with nitrous acid, azo coupling reaction of
diazonium salts of aromatic amines, Sandmeyer and related reactions
of diazonium salts; carbylamine reaction; Haloarenes: nucleophilic
aromatic substitution in haloarenes and substituted haloarenes
(excluding Benzyne mechanism and Cine substitution).
Carbohydrates: Classification; mono- and di-saccharides (glucose
and sucrose); Oxidation, reduction, glycoside formation and hydrolysis
of sucrose.
Amino acids and peptides : General structure (only primary structure
for peptides) and physical properties.
Properties and uses of some important polymers : Natural
rubber, cellulose, nylon, teflon and PVC.
Practical organic chemistry : Detection of elements (N, S, halogens);
Detection and identification of the following functional groups: hydroxyl
(alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl,
amino and nitro; Chemical methods of separation of mono-functional
organic compounds from binary mixtures.
_________________________
_________________________
CLASS - XII (MATHEMATICS)
Complex Number and Quadratic equations: Algebra of complex
numbers, addition, multiplication, conjugation, polar representation,
properties of modulus and principal argument, triangle inequality, cube
roots of unity, geometric interpretations.
Quadratic equations with real coefficients, formation of quadratic
equations with given roots, symmetric functions of roots.
Sequence & Series: Arithmetic, geometric and harmonic progressions,
arithmetic, geometric and harmonic means, sums of finite arithmetic
and geometric progressions, infinite geometric series, sums of squares
and cubes of the first n natural numbers.
Logarithms and their properties. Permutations and combinations,
Binomial theorem for a positive integral index, properties of binomial
coefficients.
Binomial theorem for any index, exponential and logarithmic series.
Matrices & Determinants: Matrices as a rectangular array of real
numbers, equality of matrices, addition, multiplication by a scalar and
product of matrices, transpose of a matrix, determinant of a square
matrix of order up to three, inverse of a square matrix of order up to
three, properties of these matrix operations, diagonal, symmetric and
skew- symmetri c matrices and their properties, sol utions of
simultaneous linear equation in two or three variables.
Probability : Addition and multiplication rules of probability, conditional
probability, bayes theorem, independence of events, computation of
probability of events using permutations and combinations.
Straight Line : Cartesian coordinates, distance between two points,
section formulae, shift of origin. Equation of a straight line in various
forms, angle between two lines, distance of a point from a line; Lines
through the point of intersection of two given lines equation of the
bisector of the angle between two lines, concurrency of lines; Centroid,
orthocentre, incentre and circumcentre of a triangle.
Conic Section: Equation of a circle in various forms, equations of
tangent, normal and chord. Parametric equations of a circle, intersection
of a circle with a straight line or a circle, equation of a through the
points of intersection of two circles and those of a circle and a straight
line.
Equations of a parabola, ellipse and hyperbola in standard form, their
foci, directrices and eccentricity, parametric equations, equations of
tangent and normal locus problems.
Three dimensions: Direction cosines and direction ratios, equation
of a straight line in space, equation of a plane, distance of a point from
a plane
Vectors: Addition of vectors, scalar multiplication, dot and cross
products, scalar triple products and their geometrical interpretations.
STPFXII1213
Page - 8
Position vector of a point dividing a line segment in a given ratio. Projection
of a vector on a line.
Function: Real valued functions of a real variable, into, onto and one-
to-one functions, sum, difference, product and quotient of two functions,
composite functions, absolute value, polynomial, rational, trigonometric,
exponential and logarithmic functions. Even and odd functions, inverse
of a function, composite function.
Limit, Continuity & Derivability: Limit and continuity of a function,
limit and continuity of the sum, difference, product and quotient of two
functions, LHospital rule of evaluation of limits of functions even and
odd functions, inverse of a function, continuity of composite function.
intermediate value property of continuous functions.
Differentiation: Derivative of a function, derivative of the sum,
difference, product and quotient of two functions, chain rule, derivatives
of polynomial, rational, trigonometric, inverse trigonometric, exponential
and logarithmic functions. Derivatives of implicit functions, derivatives
up to order two.
Tangent & Normal: Geometrical interpretation of the derivative,
tangents and normal.
Maxima & Minima: Increasing and decreasing functions, maximum
and minimum values of a function, rolles theorem and Lagranges
Mean value theorem.
Integral calculus: Integration as the inverse process of differentiation,
indefinite integrals of standard functions, integration by parts, integration
by the methods of substitution and partial fractions.
Definite integrals and their properties, fundamental theorem of integral
calculus. Application of definite integrals to the determination of areas
involving simple curves.
Formation of ordinary differential equations, solution of homogeneous
differential equations, separation of variables method, linear first order
differential equations.
Trigonometry: Trigonometric functions, their periodicity and graphs
addition and subtraction formulae, formulae involving multiple and sub-
multiple angles, general solution of trigonometric equations.
Relations between sides and angles of a triangle, sine rule, cosine
rule, half-angle formula and the area of a triangle, inverse trigonometric
functions (principal value only)
_________________________
_________________________
CLASS - XII (PHYSICS)
General : Units and dimensions, dimensional analysis; least count,
significant figures; Methods of measurement and error analysis for
physical quantities pertaining to the following experiments: Experi-
ments based on using Vernier calipers and screw gauge (microme-
ter), Determination of g using simple pendulum, Youngs modulus by
Searles method, Specific heat of a liquid using calorimeter, focal length
of a concave mirror and a convex lens using u-v method, Speed of
sound using resonance column, Verification of Ohms law using volt-
meter and ammeter, and specific resistance of the material of a wire
using meter bridge and post office box.
Mechanics : Kinematics in one and two dimensions (Cartesian coor-
dinates only), Projectile Motion; Uniform Circular Motion; Relative Ve-
locity.
Newtons laws of motion; Inertial and uniformly accelerated frames of
reference; Static and dynamic friction; Kinetic and potential energy;
Work and power; Conservation of linear momentum and mechanical
energy.
Systems of particles; Centre of mass and its motion; Impulse; Elastic
and inelastic collisions.
Law of gravitation; Gravitational potential and field; Acceleration due to
gravity; Motion of planets and satellites in circular orbits; Escape
velocity.
Rigid body, moment of inertia, parallel and perpendicular axes
theorems, moment of inertia of uniform bodies with simple geometrical
shapes; Angular momentum; Torque; Conservation of angular momen-
tum; Dynamics of rigid bodies with fixed axis of rotation; Rolling with-
out slipping of rings, cylinders and spheres; Equilibrium of rigid bodies;
Collision of point masses with rigid bodies.
Linear and angular simple harmonic motions.
Hookes law, Youngs modulus.
Pressure in a fluid; Pascals law; Buoyancy; Surface energy and sur-
face tension, capillary rise; Viscosity (Poiseuilles equation excluded),
Stokes law; Terminal velocity, Streamline flow, equation of continuity,
Bernoullis theorem and its applications.
Waves : Wave motion (plane waves only), longitudinal and transverse
waves, superposition of waves; Progressive and stationary waves;
Vibration of strings and air columns;Resonance; Beats; Speed of sound
in gases; Doppler effect (in sound).
Thermal physics : Thermal expansion of solids, liquids and gases;
Calorimetry, latent heat; Heat conduction in one dimension; Elementary
concepts of convection and radiation; Newtons law of cooling; Ideal
gas laws; Specific heats (Cv and Cp for monoatomic and diatomic
gases); Isothermal and adiabatic processes, bulk modulus of gases;
Equivalence of heat and work; First law of thermodynamics and its
applications (only for ideal gases); Blackbody radiation: absorptive
and emissive powers; Kirchhoffs law; Wiens displacement law,
Stefans law.
Electricity and magnetism : Coulombs law; Electric field and poten-
tial; Electrical potential energy of a system of point charges and of
electrical dipoles in a uniform electrostatic field; Electric field lines; Flux
of electric field; Gausss law and its application in simple cases, such
as, to find field due to infinitely long straight wire, uniformly charged
infinite plane sheet and uniformly charged thin spherical shell.
Capacitance; Parallel plate capacitor with and without dielectrics; Ca-
pacitors in series and parallel; Energy stored in a capacitor.
Electric current; Ohms law; Series and parallel arrangements of resis-
tances and cells; Kirchhoffs laws and simple applications; Heating
effect of current.
BiotSavarts law and Amperes law; Magnetic field near a current-
carrying straight wire, along the axis of a circular coil and inside a long
straight solenoid; Force on a moving charge and on a current-carrying
wire in a uniform magnetic field.
Magnetic moment of a current loop; Effect of a uniform magnetic field
on a current loop; Moving coil galvanometer, voltmeter, ammeter and
their conversions.
Electromagnetic induction: Faradays law, Lenzs law; Self and mutual
inductance; RC, LR and LC circuits with d.c. and a.c. sources.
Optics: Rectilinear propagation of light; Reflection and refraction at
plane and spherical surfaces; Total internal reflection; Deviation and
dispersion of light by a prism; Thin lenses; Combinations of mirrors and
thin lenses; Magnification.
Wave nature of light: Huygens principle, interference limited to Youngs
double-slit experiment.
Modern Physics : Atomic nucleus; Alpha, beta and gamma radia-
tions; Law of radioactive decay; Decay constant; Half-life and mean
life; Binding energy and its calculation; Fission and fusion processes;
Energy calculation in these processes.
Photoelectric effect; Bohrs theory of hydrogen-like atoms; Character-
istic and continuous X-rays, Moseleys law; de Broglie wavelength of
matter waves.
STPFXII1213
Page - 9
SAMPLE TEST PAPER -I
(For Class-X Appearing / Passed Students)
Course : VIKAAS (JA) & VIPUL (JB)
Correct Wrong Blank
1 to 20 39 to 46 52 to 59
Only one correct
(+ + |+- =;|)
3 -1 0
21 to 28 47 to 50 60 to 63
(+ r + = |=r+ |+- =;|)
4 0 0
29 to 36 Comprehensions (-e) 4 0 0
37 to 38 51 64
Matrix Match Type
(=|c= == +r)
6 [1, 2, 3, 6] 0 0
(Mathematics)
Part - II
(Physics)
Part - III
(Chemistry)
Type
PART - I
SECTION - I(=r=- I)
Straight Objective Type (=|=r n|a +r)
This section contains 20 multiple choice questions. Each question has choices (A), (B), (C) and (D), out
of which ONLY ONE is correct.
; i - 20 rl(-i r| - 4 l(- (A), (B), (C) nii (D) r, l- l ri r|
1. The HCF of 20x
5
38x
4
+ 43x
4
25x
2
and 15x
5
19x
4
+ 4x
3
is
20x
5
38x
4
+ 43x
4
25x
2
i 15x
5
19x
4
+ 4x
3
i -... r
(A) x
2
(x
2
+ 1) (B) x
2
(x
2
1) (C) x
2
(x + 1) (D) x
2
(x 1)
2. A valid reason for concluding that 635 is not a perfect square of an integer is that
635 li ii i (^ ri r ;i ri ii r l
(A) It is an odd integer (r l(i- ii r) (B) it ends with 5 (r 5 -in r )
(C) it ends with 35 (r 35 -in r ) (D) sum of its odd digits is 8 (; l(i- i i i^ 8 r)
3. The missing number in the following sequence is :
1, 3, 3, 6, 7, 9, ?, 12, 21
>- 1, 3, 3, 6, 7, 9, ?, 12, 21 i nin r
(A) 10 (B) 11 (C) 12 (D) 13
4. Given : x > 0, y > 0, x > y and z = 0. The inequality which is not always correct is ?
li r : x > 0, y > 0, x > y nii z = 0, ii l-i ( ri ri riî`
(A) x + z > y + z (B) x z > y z (C) xz > yz (D)
2
z
x
>
2
z
y
5. A bag contains '5 red balls and some blue balls' only. If the probability of drawing a blue ball is double the
probability of a red ball, the number of blue balls in the bag is
i - ( '5 i ^ nii ii ^' r| l ii ^ i li i ilni i ^ i li
i ilni i î r, ni i - ii î i i r
(A) 5 (B) 10 (C) 15 (D) 20
6. Recurring decimal 35 2 . 0 , when expressed in the form
q
p
, is (where p and q are integers and q = 0).
i(ni i-( 35 2 . 0 i
q
p
- n i r (ri p nii q ii r nii q = 0)
(A)
1000
235
(B)
990
243
(C)
990
233
(D)
990
223
.
STPFXII1213
Page - 10
7. The radii of the bases of two right circular solid cones of same height are 3 cm and 4 cm, respectively. The cones
are melted and recast into a solid sphere of radius 5 cm. Then the heights of the given cones is
i -i +i; (i -iii (-iii -i ii iii i lii >-i 3 cm nii 4 cm r| ii i lii
5 cm lii i -i îi ii ini r, ni l ^ ii i +i;i r
(A) 10 (B) 30 (C) 20 (D) 90
8. How many numbers between 200 and 600 are divisible by 4, 5, and 6 ?
i 200 nii 600 i - ln ii 4, 5 i 6 ii r `
(A) 6 (B) 7 (C) 8 (D) 9
9. There are four prime numbers written in ascending order. The product of the first three is 385 and that of the last
three is 1001. The last number is :
i ii ii i n >- - lii ini r| i- ni i î 385 r nii ln- ni i î 1001 r|
ni ln- i r :
(A) 11 (B) 13 (C) 17 (D) 19
10. A is thrice as efficient as B, and B is twice as efficient as C. If A, B and C work together, how long will they take
to complete a job which B completes in 10 days ?
A, B ni î i i r nii B, C i î i i r| l A, B ( C ii - i n r ni ( ln l
- ii l- i i -in ^ l B i i i 10 l - i ni r ?
(A)
9
20
days (l) (B)
9
11
days (l)
(C) 3 days (l) (D) None of these (;- i; ri)
11. In the given figure, EF || AD and ED || AC. If BF = 4 cm, FD = 6 cm and BE = 8 cm, then BC = _______.
i ^; iln - EF || AD i ED || AC. l BF = 4 cm, FD = 6 cm nii BE = 8 cm, n BC =_______.
(A) 12 cm (B) 15 cm
(C) 25 cm (D) none of these (;- i; ri)
12. If ABC is a quarter circle and a circle is inscribed in it and if AB = 1 cm, find
radius of smaller circle.
l ABC (-i i iii; r, l (-i ii ini r i l
AB = 1 cm i- (-i i lii nin i|
(A) 1 2 (B) ( ) 2 / 1 2
B
C
A
1cm
1cm
(C) 2 / 1 2 (D) 2 2 1
13. If the polynomial ax
3
4x
2
+ 3x + 3 when divided by x 3 leaves the remainder 2 more than the remainder left on
dividing x
3
4x + a in divided by x 2, then the value of a is
l r ax
3
4x
2
+ 3x + 3 i x 3 l(iiln li ini r, ni in ii, x
3
4x + a i x 2 l(iiln
in ii 2 li r, ni a i -i riî
(A) 0 (B) 1 (C) 2 (D) 3
14. A man, whose eyes are at a height of 10 m above water level, is standing on the deck of a ship. He observes the
angle of elevation of the top of a vertical tower as 45 and the angle of depression of the image of the top of the
tower in water as 60. The distance of the tower from the man is
ln l ii -n 10 m +i; r ri (deck) ii r| (r ini r l -i(
iii i ii 45 r nii -i( iii - lnl i (- ii 60 r| ln -i( i i riî
(A) 10 ) 2 6 ( + (B) 10 ) 1 3 ( + (C) 20 ) 1 3 ( + (D) 20 ) 2 6 ( +
STPFXII1213
Page - 11
15. If m, n are natural numbers, m > n sum of m
th
and n
th
term of an increasing AP is 2m and their product is
m
2
n
2
, then (m + n)
th
term of the AP is
l m, n in i ri ( m > n ri, l ni r; -in i m

( nii n

( i i^ 2m ri nii i î
m
2
n
2
ri, ni -in i i (m + n)

(i riî
(A)
n m
n m
2 2
+
(B)
n m
) n m (
2 2
+
(C) (m 2)
2
(D) m
2
+ n
2
+ mn
16. If two regular polygon are such that ratio between their number of sides is 1 : 2 and ratio of measures of their
interior angle is 4 : 5, then the number of sides of polygons are
l i -ri ; i r l i iii i in 1 : 2 r nii niii i in 4 : 5 ri, ni rii
- iii i i r
(A) 4, 8 (B) 3, 6 (C) 5, 10 (D) 6, 12
17. p,q and r are three positive numbers and Q =
2
r q p + +
. If (Qp) : (Qq) : (Qr) = 2 : 5 : 7, then find the ratio of
p,q and r ?
l p,q ( r ni ii-- i ri nii Q =
2
r q p + +
l (Qp) : (Qq) : (Qr) = 2 : 5 : 7 ni p,q ( r i in riî?
(A) 9 : 7 : 12 (B) 12 : 9 : 7 (C) 12 : 7 : 9 (D) 7 : 9 : 12
18. A fathers age is equal to the sum of the ages of his 3 children. In 9 years his age will be equal to the sum
of the two eldest sons ages and 3 years after that his age will be equal to the sum of the ages of his eldest
and youngest children. Again 3 years after that his age will be equal to the sum of the ages of his two
youngest children. Find the fathers present age ?
lni i - ni i i - i^ i r| 9 (ii in i - i ii i - i^
i riî nii 3 (i in i - ( i- i i - i^ i riî| ;
ni (i in i - i i- ii i - i^ i riî lni i (n-i - riî ?
(A) 32 years ((i) (B) 36 years ((i) (C) 40 years ((i) (D) 44 years ((i)
19. If cosu + cos
2
u = 1, then sin
12
u + 3 sin
10
u + 3 sin
8
u + sin
6
u + 2 sin
4
u + 2 sin
2
u 2 =
(l cosu + cos
2
u = 1 r, ni sin
12
u + 3 sin
10
u + 3 sin
8
u + sin
6
u + 2 sin
4
u + 2 sin
2
u 2 =)
(A) 0 (B) 1 (C) 2 (D) 3
20. If o, | are the roots of x
2
+ x + 1 = 0 and , o are the roots of x
2
+ 3x + 1 = 0, then (o ) (| + o) (o + o)
(| ) =
l x
2
+ x + 1 = 0 - o,| ri nii x
2
+ 3x + 1 = 0 - ,o ri, ni (o ) (| + o) (o + o) (| ) =
(A) 2 (B) 4 (C) 6 (D) 8
SECTION - II (=r= - II)
Multiple Correct Answers Type (; =;| =-r +r)
This section contains 8 multiple correct answer(s) type questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONE OR MORE THAN ONE is/are correct.
; i - 8 r ri -i i r| - 4 l(- (A), (B), (C) nii (D) r, l- i
li l(- ri r (r)|
21. Which statement(s) is/are correct? (l ii - ii / i ri r)
(A) Quadrilateral with opposite sides parallel is a parallelogram.
(l(in -in iii (ii ni, -in ni rini r)
(B) A concyclic parallelogram is a rectangle. ( >i -in ni, in rini r|)
(C) A parallelogram, the diagonals of which intersect at right angles is a square.
( -in ni, l l(i i (n ln n r, (^ rini r)
(D) A quadrilateral, the diagonal of which bisect each other at right angles is a rhombus.
( ni l l(i i l,iiln n r, -ni rini r)
STPFXII1213
Page - 12
22. If the following system of linear equations 2x + 3y = 7, 2ox + (o + |)y = 28 has infinite number of solutions,
then
l ii -iii l li 2x + 3y = 7 , 2ox + (o + |) y = 28 n r r , ni
(A) o = 4 (B) o = 8 (C) | = 4 (D) | = 8
23. In figure ABCD is a square of side 14 cm. With centres A, B, C and D four circles
are drawn such that each circle touch externally two of the remaining three circles.
Let x be the area and y be the perimeter of the shadded region, then
li -, ABCD (^ r li ii 14 cm r| i A, B, C nii D (i i (-ii i ;
i iii ini r l - (-i ii nii (-ii - i i i; -i | l iiln
-ii i -ii x nii l-i y r, ni

(A) x = 154 (B) x = 42 (C) y = 44 (D) y = 88
24. A sequence is defined by a
n
= n
3
6n
2
+ 11n 6, (n e N), then
>- a
n
= n
3
6n
2
+ 11n 6, (n e N) ,ii liilin li ini r , ni
(A) first three terms are negative (r ni ~ii-- r |)
(B) first three terms are zeroes (r ni i r |)
(C) all terms except first three are negative (r ni i i i i ii ~ii-- r |)
(D) all terms except first three are positive (r ni i i i i ii ii-- r |)
25. If
19
31
= 1 +
b / a
1
1
1
1
1
1
1
1
1
+
+
+
+
then ( l
19
31
= 1 +
b / a
1
1
1
1
1
1
1
1
1
+
+
+
+
ni)
(A) ab = 6 (B) a
2
+ b
2
= 13 (C) a b = 1 (D) a + b = 5
26. If the two sides of a triangle is 14 cm and 22 cm then which can be the third side of that triangle ?
l lii i i ii 14 cm ( 22 cm r, ni l - ii lii i nii ii ri ni r
(A) 7 cm (B) 9 cm (C) 37 cm (D) 34 cm
27. Vijay has been invited for dinner in a club. While walking through the garden path towards the building, he
observe that there is an electric rod on the top of the building. From the point where he is standing, the angles
of elevation of the top of the electric rod and the top of the building are | and u respectively. If the heights of the
electric rod and the building are p and q respectively, mark all the correct statements.
l( i i-i - iliii l ii ini r| î - -rn r (r -ii iii l(nn ini r| l
l (r ii r (ri l(nn iii i -ii iii i ii >-i | i u r| l l(nn i
-ii i +i;i >-i p nii q r| ri ii i il|
(A) The height of the tower is
u |
u
tan tan
tan p
(-ii i +i;
u |
u
tan tan
tan p
r)
(B) The height of the electric rod is
) tan (tan
tan q
u |
u
(l(nn i +i;
) tan (tan
tan q
u |
u
r)
(C) The height of the tower is
u u
|
tan tan
tan p
(-ii i +i;
u u
|
tan tan
tan p
r)
(D) The height of the electric rod is
u
u |
tan
) tan (tan q
(l(nn i +i;
u
u |
tan
) tan (tan q
r)
28. If the point (2, 0), (7, 0),
|
|
.
|
\
|
2
3 5
,
2
9
, (x, y) are the vertices of a rhombus, then a value of x is
l l (2, 0), (7, 0),
|
|
.
|
\
|
2
3 5
,
2
9
, (x, y) -ni iii ri, ni x i -i r
STPFXII1213
Page - 13
(A)
2
19
(B)
2
1
(C)
2
9
(D)
2
1
SECTION - III (=r= - III)
Comprehension Type (q r=r +r)
This section contains 2 paragraphs. Based upon each paragraph, 4 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
;= =r= = 2 -e (paragraphs) ;| + -e r=rr|n 4 ;|+-| r + =-r ;| +
+ 4 |+- (A), (B), (C) nrr (D) ; , |= = |= + =;| ;|
Paragraph for Question Nos. 29 to 32
( 29 = 32 + | -e)
In the following figure, the smaller triangle represents the teachers; the
big triangle, the politicians; the circle, the graduates and the rectangle,
the members of parliament. Different regions are being represented by the
letters of english alphabet
l ii -, i-i lii, ii i lin ni r nii i lii, nii i
lin ni r| (-i, -i-i i lin ni r nii in, -i i
lin ni r| - l(li -iii i î (i-ii -ii ,ii ^^
lin li î r

On the basis of the about diagram, answer the following questions :
+ l ^ li iii l i i -i il
29. Who among the following are graduates or teachers but not politicians ?
lllin - i ,i -in i i r n ni ri ri ?
(A) B, G (B) G, H (C) A, E (D) E, F
30. Who among the following politicians are graduates but not the members of parliament ?
lllin - i ,i ni -in r n i - ri r ?
(A) B, C (B) L, B (C) D, L (D) A, H, L
31. Who among the following politicians are neither teachers nor graduates ?
lllin - i ,i ni, ni i r i ri -in r ?
(A) E, F (B) D, E (C) C, D (D) L, H
32. Who among the following members of parliament is a graduate as well as a teacher?
lllin - i ,i i -, -in r nii i r ?
(A) G (B) F (C) C (D) H
( 33 = 36 + | -e)
Read the following information carefully and answer the questions given below it
Six flats on a floor in two rows facing North and Sourth are alloted to P, Q, R, S, T and U. Q gets a North facing
flat and is not next to S. S and U get diagonally opposite flats. R next to U, gets a Sourth facing flat and T gets
a North facing flat
l ^; i i i( l i i l ^ i -i il
n -i i lni - l - ,i -i i l-ii lii - r, P, Q, R, S, T i U i i(l-n r| Q
-i i - ,i -i - r i r S -i î ri r S nii U -i l(i i l(in liii - l-in
r| R, U i^ nii l-ii - - ,i ini r i T -i i - ,i -i - r
33. Which of the following combinations get South facing flats ?
l - l -r -ii i - ,i l-ii - r ?
(A) QTS (B) UPT (C) URP (D) None of these (;- i; ri)
STPFXII1213
Page - 14
34. Whose flat is between Q and S ? (Q nii S i l-in -i ii r ?)
(A) T (B) U (C) R (D) P
35. If the flats of T and P are interchanged, whose flat will be next to that of U ?
l T nii P -i - n r ni U -i i^ li -i riî `
(A) P (B) Q (C) R (D) T
36. Flats other than SU, which are diagonally opposite to each other are
SU i(i ( -i i l(i l(in li l-in r
(A) QP (B) QR (C) PT (D) PS
SECTION - IV (=r=- IV)
Matrix - Match Type (=|c=== +r)
This section contains 2 question. The question contains statements given in two columns which have to be
matched. Statements (A, B, C, D) in Column-I have to be matched with statements (p, q, r, s) in Column-II. The
answers to these questions have to be appropriately bubbled as illustrated in the following example.
If the correct matches are A-p , A-r , B-p , B-s , C-r , C-s and D-q, then the
correctly matched answer will look like in bubbled matrix. One option in
ColumnI may have one or more than one correct options in ColumnII. Marks
will be awarded only if an option in ColumnI is matched with all correct options
in Column-II. Each correct matching will be awarded 1 mark
and if all the matchings are correct then 6 marks will be awarded.
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
; i - 2 r| - - i i- - (- (statements) l r r li - (match) i r| i-
(Column-I) - l ^ (ni (A, B, C, D) i i- (Column-II) - l ^ (ni (p, q, r, s) - i r| ; i
-i l ^ iri i ln -i i ii iii r| l ri - A-p, A-r, B-p, B-s,
C-r, C-s nii D-q r , ni ri l(li i l ^ -i i 4 x 4 - l- (matrix) - ii i î r | i-I - l(-
i i-II i ii l(-i - ii i ni r| i l-iln - i l i^ | l i-
I li l(- i i-II ii ri l(-i - ii î| - ri - l 1 i l i ^ nii
ii - ri ri^ n 6 i l i^|
37. Column (-ni) Column (-ni)
(A) If o and | are the roots of x
2
5x + 3 = 0, then
19
2 2
| + o
is equal to (p) 1
l x
2
5x + 3 = 0 - o ( | r , ni
19
2 2
| + o
i r
(B) The value of 5 4 9 4 1 4 1 ) 5 2 ( + + + in simplified form is (q) 2
5 4 9 4 1 4 1 ) 5 2 ( + + + i n- r
(C) The value of
2
3 21 2 10
|
.
|
\
|
+ in simplified form is (r) 1
2
3 21 2 10
|
.
|
\
|
+ i n- r
(D) If a + b + c = 0, then
4 4 4
2 2 2 2
c b a
) c b a (
+ +
+ +
has value equal to (s) 7
l a + b + c = 0 ri, ni
4 4 4
2 2 2 2
c b a
) c b a (
+ +
+ +
i -i r
STPFXII1213
Page - 15
38. Column (n--r ) Column (n--r )
(A) If the points (1, 2), (5, 6) and (a, 2) are collinear, (p) 0
then the value of a is
l l (1, 2), ( 5, 6) nii (a, 2) i r , ni a i -i r
(B) The value of log
2
log
2
log
3
log
3
27
3
is (q) 2
log
2
log
2
log
3
log
3
27
3
i -i r
(C) If the system of equations 3x + y = 1 (r) 4
(2k 1) x + (k 1) y = 2k + 1 has no solution,
then the value of k is
l -ii li 3x + y = 1
(2k 1) x + (k 1) y = 2k + 1 i i ; r ri r , ni
k i -i r
(D) ABC is an isosceles right triangle with AC = BC, (s) 7
then AB
2
= xAC
2
, where the value of x is
ABC -l,ir -i i lii r , l- AC = BC,
ni AB
2
= xAC
2
, ri x i -i r
PART - II (-rrn - II)
SECTION - I (=r=- I)
This section contains 8 multiple choice questions. Each question has choices (A), (B), (C) and (D), out of which
ONLY ONE is correct.
39. The current i in the circuit of figure is - (li li - iii i r)
(A) 2 amp. (B)
. amp
2
1

(C) . amp
4
1
(D) 1 amp.
40. If the focal length of a concave mirror is 10 cm and the object is placed at a distance of 12 cm from the mirror
then find the distance between the object and image formed. : (10 -i. i i (n i 12
-i. i l ii r| lnl nii (-n - i nin i|)
(A) 60 cm (B) 48 cm (C) 72 cm (D)
11
50
cm
41. Soft iron is used to manufacture electromagnets because their : (- iri l(nn i - - rini r il)
(A) coercive force is high (i lîri li r|)
(B) retentivity is high (i iii iini li r|)
(C) area of hysteresis curve is large ( ili- (> i -ii li rini r|)
(D) magnetic saturation limit is high but retentivity and coercive force are small
(i ir nn i-i li rini r l ^ri iini nii lîri l r|)
42. A body of mass 10 kg revolves in a circle of diameter 0.40 m, making 1000 revolutions per minute. Calculate its
linear velocity. (10 kg -i i (-n 0.40 m i (i (-iii i 1000 ln -i- ^ln
ri r| (-n l ii i nin i|)
STPFXII1213
Page - 16
(A)
3
200t
m/s (B)
3
2t
m/s (C)
3
20t
m/s (D) t 2 . 0 m/s
43. Force of 50 N is applied to stop a body of mass 20 kg moving initially with a speed of 15 m/s, then the distance
travelled by body before it stops : ( 20 kg -i (ii ^ln-i (-n i i l ; 50 N îi ini
r| ii - (-n 15 m/s i i ^ln-i r| ni r (-n ,ii n i i nin i|) :
(A) 40 m (B) 45 m (C) 50 m (D) 100 m
44. Two solid spheres of same radius (R) and of same material are placed in such a way that their centres are 2R
apart. The gravitational force between them is directly proportional to :
(i -i î, - i lii (R) r nii -i ii r, ;i ; i ii ini r l ii i - i
i 2R r| ; - ^-(iii l -iiln r|)
(A) R
2
(B) R
2
(C) R
4
(D) R
4
45. A balloon of mass 1000 kg is floating at some height. If 100 kg mass is released from the balloon (without
changing volume of the ballon). Then the acceleration of the balloon is : [g = 10 ms
2
]
(1000 kg -i i îi (i n +i; ii(-ii - ri r| l î 100 kg -i li li
i (î i ii li) ni î i -(i riî|) [g = 10 ms
2
]
(A) 1.1 ms
2
upward (+ i i) (B) 1.1 ms
2
downward (i i i)
(C) 10 ms
2
upward (+ i i) (D) 10 ms
2
downward (i i i)
46. Light ray AB incidents on a plane mirror XY at an angle of incidence 50. The second plane mirror is placed in
such a way that the reflected ray BC (from the mirror XY) retraces its path after reflection from the second mirror.
Angle of inclination of two mirrors will be :(ii i li AB -n i XY 50 in ii ilnn ri ni
r| i -n i ; i ii ini r l -n i XY i(lnn li BC i i(lnn ri
i i- ini r| ii ii - i-l ni( ii r)
(A) 25 (B) 50 (C) 75 (D) 90
This section contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE THAN ONE is/are correct.
; i - 4 r ri -i i r| - 4 l(- (A), (B), (C) nii (D) r, l- i li
l(- ri r (r)|
47. A beam of green light is incident from air and after refraction enters water. In comparision to that in air :
((i ilnn r ii i li, (n i - ( i ni r | (i i n i - )
(A) Speed of light is less in water ( - ii i i ri î)
(B) Frequency of light is less in water ( - ii i i(l-i - ri î)
(C) Wavelength of light is less in water ( - ii i n ^ - ri î)
(D) Speed of light is more in water ( - ii i i ii ri î)
48. A tunnel is made across the earth passing through its centre. A particle is released from the one end of the
tunnel when the particle is at the centre of the earth then which of the following is non zero.
( ^ (i ^ni r| i, ^ l ii ini r l i (i r ni l
- i i r|)
(A) mass (-i) (B) weight (ii) (C) acceleration (-(i) (D) velocity ((^)
49. Mark the correct statement(s) . (ri i i ;l^n il)
(A) if speed of a body is varying, its velocity must be varying .
(l (-n i i ni r ni i (^ lln l(lnn riî )
(B) if velocity of a body is varying, its speed must be varying
(l (-n i (^ l(lnn rini r ni i i ii lln l(lnn riî)
STPFXII1213
Page - 17
(C) a body moving with varying velocity may have constant speed
((-n i l(lnn (^ ^ln-i r l i ln r ni r)
(D) a body moving with varying speed may have constant velocity
( (-n li i l(lnn rini r ni ;i (^ ln r ni r )
50. From the top of a tower of height 200 m, a ball A is projected up with 10 m

s
1
and two seconds later
another ball B is projected vertically down with the same speed. Then : (Take g = 10 m/s
2
)
(200 m +i; i -ii ^ i + i n 10 m/s (^ -iln i i i ^ B i
-i i i i n -iln li ini r ni) (g = 10 m/s
2
ll)
(A) both A and B will reach the ground simultaneously (A nii B ii ii ii -i rni r )
(B) the ball A will hit the ground 2 seconds later than B hitting the ground
(^ A, ^ B -i i in -i -ini r)
(C) both the balls will hit the ground with the same velocity (ii ^ -i (^ -i i -ini r)
(D) none of these (;- i; ri)

SECTION - III (=r=- III)
This section contains 1 question. Each question contains statements given in two columns which have to be
correctly will look like in bubbled matrix. Each statement in ColumnI may have
one or more than one correct options in ColumnII. One Mark will be awarded for
each statement in ColumnI is matched with all correct options in Column-II. If all
the statements in column-I are correctly matched to their
correct options in column-II , then 6 marks will be awarded.
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
(Column-I) - l ^ (ni (A, B, C, D) i i- (Column-II) - l ^ (ni (p, q, r, s) - i r| ;
i -i l ^ iri i ln -i i ii ii i r | l ri -
A-p, A-r, B-p, B-s, C-r, C-s nii D-q r, ni ri l(li i l ^ -i i 4 x 4 -l- (matrix) - iii î r|
i-I - (-i i i-II i ii l(-i - ii i ni r| i-I - (-i
i i -II ii ri l(-i - i l i li iî| l i -I ii i-ii i i-
II ii ri l(-i - li î ni 6 i l i^|
51. A particle is moving along a straight line. Its velocity varies with time as v = kt, where k is a positive constant and
t is the time. Match the graphs in Column II with the statements in Column I and indicate your answer by
darkening appropriate bubbles in the 4 4 matrix given in the ORS.
i ii li ^ln ri r | ;i ( ^ - ii ; i ni r v = kt, ri k ii-- lni
r i t - r| i- II - îi i i- I - l ^ (ni - il i -i i i ^; ORS - ln
i i ii 4 4 -l- - ii;|
Column (+r=-) Column (+r=-)
(A) Acceleration versus time curve (p)
-(i i - (>
(B) Acceleration versus displacement curve (q)
-(i i l(-ii (>
(C) Velocity versus time curve (r)
(^ i - (>
STPFXII1213
Page - 18
(D) Displacement versus time curve (s)
l(-ii i - (>
PART - III
This section contains 8 multiple choice questions. Each question has choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
52. The highest value of e/m (charge / mass ratio) for anode rays has been observed when the discharge tube is
filled with : (i lii l e/m (i(i / -i in) i lin- -i in rini r l( li - l
- ii ^ ii r; ri )
(A) nitrogen (i;-i) (B) oxygen (ii) (C) hydrogen (ri; i ) (D) helium (ril-)
53. Which of the following are isoelectronic species? (l - -;-il -iii ii r )
+
3
CH ,

2
NH ,
+
4
NH ,
3
NH
(i) (ii) (iii) (iv)
(A) I, II, III (B) II, III, IV (C) I, II, IV (D) II, I
54. The time taken for 80 g of uranium (t
1/2
= 4.5 10
9
years) to decay to 10 g would be :
(80 g l- (t
1/2
= 4.5 10
9
(i) 10 g n -i ri - lni - ^î|)
(A) 4.5 10
9
years (B) 9.0 10
9
years (C) 13.5 10
9
years (D) 18.0 10
9
years
55. Volume of the 10 g of gas X is 5.6 litre at STP. What will be the molecular weight of X ?
(STP 10 g ^ X i in 5.6 i- r| X i iii i riî `)
(A) 40 (B) 50 (C) 60 (D) 20
56. In which of the following arrangement, the order is not according to the property indicated against it ?
(l - ii >-, ii ^ îi i ri ri r|)
(A) Al
3+
< Mg
2+
< Na
+
< F
; ionic size (il ii)

(B) B < C < N < O ; first ionisation enthalpy (i- i i-i)
(C) I < Br < F < Cl ; electron gain enthalpy (with negative sign) (;-i ^ri i-i (~ii-- lr lrn))
(D) Li < Na < K < Rb ; metallic radius (iil-( lii)
57. The simplest formula of a compound containing 50% X (atomic mass 10 u) and 50% Y (atomic mass 20 u) is :
(50% X (-il( -i 10 u) nii 50% Y (-il( -i 20 u) n il^ i n- i r )
(A) XY
2
(B) X
2
Y (C) X
2
Y
3
(D) XY
58. What is the pH of 0.001M NaOH aqueous solution ? (0.001M NaOH i l( i pH riî `)
(A) 3 (B) 11 (C) 6 (D) 14
59. The structure of 4-Methyl- 2-hexyne is : (4--li- 2-ri; i i r )
(A)
3
3 2 3
CH
|
CH CH CH CH CH C H = (B)
3
3 2 3
CH
|
CH C C CH CH C H
(C)
3
3 2 3
CH
|
CH CH CH C C C H (D)
3
3 2 2 2
CH
|
CH C C CH CH CH
STPFXII1213
Page - 19
This section contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONE OR MORE THAN ONE is/are correct.
li l(- ri r (r)|
60. Identify the correct with respect to ozone : (ii i - - i i ril|)
(A) Ozone is formed in the upper atmosphere by a photochemical reaction involving dioxygen.
(ii i l-ii +i (ini(i - i;ii i ii iil lil>i ,ii rini r|)
(B) Ozone is more reactive than dioxygen. (ii i;ii li l>iii r|)
(C) Ozone is diamagnetic whereas dioxygen is paramagnetic.
(ii lni r l i;ii i r|)
(D) Ozone protects the earths inhabitants by absorbing ultraviolate-radiations.
(ii iî l(lii i (iilin (i l-in i(i i -ii ni r|)
61. Which of the following are non-linear structures ? (l - ii i (i il^ r `)
(A) C
2
H
2
(B) H
2
O (C) O
3
(D) I
3
62. Constituent metals of the alloy german silver are : (l-iin - l-( i i- iin r )
(A) Zn (B) Cu (C) Fe (D) Ni
63. Which of the following is(are) sulphide ore(s) (l - ii,i -i; - r,r|)
(A) Galena (î) (B) Zinc blende (l )
(C) Cinnabar (l i) (D) Argentite ( -i;-)
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
C-r, C-s nii D-q r , ni ri l(li i l ^ -i i 4 x 4 - l- (matrix) - ii i î r | i-I - (-i
i i -II i ii l(-i - ii i ni r | i -I - (-i i
i-II ii ri l(-i - i l i li iî| l i-I ii i-ii i
i-II ii ri l(-i - li î ni 6 i l i^|
64. Match the column : (|- n--rr +r ==|n +|||)
Column-I Column-II
+r=-I +r =-II
Molecule (i) Number of CH bonds (CH ii i i)
(A) Ethane (i) (p) 2
STPFXII1213
Page - 20
(B) Ethene (ii) (q) 4
(C) Ethyne (ii;) (r) 6
(D) Propane (i) (s) 8
ANSWER KEY TO SAMPLE TEST PAPER-I
1. D 2. C 3. D 4. C 5. B 6. C 7. C
8. A 9. B 10. A 11. C 12. A 13. B 14. B
15. A 16. D 17. B 18. B 19. B 20. D 21. AB
22. AD 23. BC 24. BD 25. ABCD 26. BD 27. AD 28. ABC
29. C 30. A 31. D 32. B 33. C 34. A 35. C
36. A 37. (A - p),(B - r),(C - s),(D - q) 38. (A - s),(B - p),(C - q),(D - q)
52. C 53. B 54. C 55. A 56. B 57. B 58. B
59. C 60. ABCD 61. BC 62. ABD 63. ABC 64. (A - r),(B - q),(C - p),(D - s).
HINTS & SOLUTION TO SAMPLE TEST PAPER-I
1. 20x
5
38x
4
+ 43x
4
25x
2
= x
2
(20x
3
38x
2
+ 43x 25)
= x
2
(x 1)(20x
2
18x

+ 25)
15x
5
19x
4
+ 4x
3
= x
3
(x 1)(15x 4)
H.C.F. -... = x
2
(x 1)
2. All terms which ends with 35 is not a perfect square.
(35 -in ri (ii ii i li i ii i (^ ri rini r)
3.
Required number ii- i = 7 + 6 = 13
4. Let -ii z < 0
zx < zy
so xz > zy is not correct always. (n xz > zy ( ri ri riî|)
5. Let there be x blue balls in the bag.
Total number of balls in the bag = (5 + x)
P
1
= Probability of drawing a blue ball =
x 5
x
+
P
2
= Probability of drawing a red ball =
x 5
5
+
P
1
= 2P
2
|
.
|
\
|
+ x 5
x
= 2
|
.
|
\
|
+ x 5
5
x = 10
6. Let x =
35 2 . 0
STPFXII1213
Page - 21
10x =
35 . 2
1000x = 235.35 . +
99
35
990x = 233
x =
990
233
x =
2
3
, y =
2
3
7. Let h be the height of each cone
then
3 2
2
2
1
R
3
4
h r
3
1
h r
3
1
t = t + t
3 2 2
5
3
4
h 4
3
1
h 3
3
1
t = t + t
h =
16 9
5 4
3
+
= 20 cm.
8. Every such number must be divisible by L.C.M. of 4, 5, 6 i.e.60.
Such numbers are 240, 300, 360, 420, 480, 540
Clearly, there are 6 such numbers.
9. Let the given prime numbers be a, b, c, d. Then, abc = 385 and bcd = 1001.
1001
385
bcd
abc
=
13
5
d
a
=
.
So, a = 5, d = 13.
10. B takes 10 days to finish the job
A will take
3
10
days to finish it. C will take 20 days to finish it.
Together they will finish the work in
=
10 20
1
10
1
1
3
+ +
=
9
20
days.
11. We have EF||AD and ED||AC
and BF = 4 cm.
FD = 6 cm.
BE = 8 cm.
In triangle BAD
EF ||AD
A
E
B
F D
C
EA
BE
FD
BF
=

6
4
=
EA
8
EA =
4
48
= 12 cm, AB = 8+12 = 20 cm
Now from triangle ABC
ED || AC
EA
BE
DC
BD
=
or
DC BD
BD
+
=
EA BE
BE
+
STPFXII1213
Page - 22
BC
10
=
20
8
BC =
8
200
= 25 cm
12. In right tangle triangle OAB
AB
2
+ BO
2
= OA
2
x
2
+ x
2
= (1 x)
2
2x
2
= x
2
+ 1 2x
x
2
+ 2x 1 = 0
x =
2
4 4 2 +
x = 1
2
taking positive sign
x = 2 1
13.
x 2 x
a x 4 x ) 2 x (
2
3
+
+
x
3
2x
2
+ 2x
2
4x
remainder is a ii r
Now remainder of ii
|
|
.
|
\
|
+ +
) 3 x (
3 x 3 x 4 ax
2 3
= a + 2
9 a 9 x 4 ax 3 ax
3 x 3 x 4 ax ) 3 x (
2
2 3
+ +
+ +
ax
3
3ax
2
+ 3ax
2
+ 9ax 4x
2
+ 12x + 9ax 27a 9x 27
so 27 27a + a + 2 = 3
26 = 26a a = 1
14. From the diagram li i
AABC
AC = y 10
and ini AACD -
AC
10 y +
= tan60 = 3 =
10 y
10 y +
y = 10( 2 3 + )
Required distanceii- i = (y 10) = 10( 2 3 + ) Ans.
15. T
m
+ T
n
= (m + n) + (m n) = 2m
T
m
. T
n
= (m + n) (m n) = m
2
n
2
Let a, d be the first term and common difference respectively.
-ii a, d >-i i- i(n r|
a + (m 1) d = m + n
a + (n 1) d = m n
(m n) d = 2n
d =
n m
n 2
T
m + n
= a + (m + n 1) d
STPFXII1213
Page - 23
= [a + (m 1) d ] + nd
= (m + n) + n
n m
n 2
T
m + n
=
n m
n m
2 2
+
16. Let the side of first polygon (-ii i- ri i ii) = x
then the side of second polygon (ni l,ni ri i ii) = 2x
Now interior angle of a regular polygon is ( - ri i inl ii)
u =
n
2
t
t (where n is the side) (ri n ii r)
Given (li î r )
2
1
u
u
=
5
4
|
|
|
|
.
|
\
|
t
t
t
t
x 2
2
x
2
=
5
4
x / 1 1
x / 2 1
=
5
4
x = 6
17. Givenli î r Q =
2
r q p + +
and i
2
p Q
=
5
q Q
=
7
r Q
Let
2
p Q
=
5
q Q
=
7
r Q
= k
Putting value of Q i -i i
2
p r q +
=
5
q p r +
=
7
r q p +
= k
q + r p = 2k ........(i)
r + p q = 5k ........(ii)
p + q r = 7k ........(iii)
Equation (i) + equation (ii) equation (ii) + (iii) Equation (iii) + (i)
2r = 7k 2p = 12k 2q = 9k
r =
2
k 7
p = 6k z =
2
k 9
p : q : r 6k :
2
k 9
:
2
k 7
12 : 9 : 7
18. Let the father's present age be F and C
1
, C
2
, C
3
be the present ages of his children in the decreasing order so
(lni i (n-i i F i C
1
, C
2
, C
3
i-n >- - i i i )
F = C
1
+ C
2
+ C
3
F + 9 = (C
1
+ 9) + (C
2
+ 9) F = C
1
+ C
2
+ 9 C
3
= 9
(F + 12) = (C
1
+ 12) + (C
3
+ 12) F = C
1
+ C
3
+ 12 C
2
= 12
(F + 15) = (C
2
+ 15) + (C
3
+ 15) F = C
2
+ C
3
+ 15 C
1
= 15
so F = 15 + 12 + 9
F = 36 years ((i)
20. o + | = 1, o | = 1
+ o = 3, o = 1
STPFXII1213
Page - 24
To find nin r (o ) (| + o) (o + o) (| )
= (o| + oo | o)(o| o + |o o)
= (oo |) (|o o)
= o|o
2
o
2
o |
2
o + o|
2
{o| = o = 1}
= o
2
o
2
|
2
+
2
= [(

+ o)
2
(2o)] [(o

+ |)
2
2o|]
= 9 8 + 1 = 8
21. only A and B is correct (( A ( B - r|)
22.
28
7 3
2
2
=
| + o
=
o
o = 4, o + | = 12
| = 8
24. a
n
= n
3
6n
2
+ 11n 6 = (n 1)(n 2)(n 3)
26.
|AB AC| < BC < AB + AC 8 < BC < 36
27. From figure li
tan | =
AB
q p +
tan | =
AB
q
q
q p +
=
u
|
tan
tan
p tan u + q tan u = q tan |
p =
u
u |
tan
) tan (tan q
q =
u |
u
tan tan
tan p
28. A.
|
|
.
|
\
|
2
3 5
,
2
9
Let-ii A
|
|
.
|
\
|
2
3 5
,
2
9
, B(2, 0) and i C(7,0)
are fixed points the position of fourth point D(x, y) can be lie this
iii l D (x, y) l-i ri ni r|
STPFXII1213
Page - 25
x
1
=
2
9
+ 5, x
2
=
2
9
5
x
1
=
2
19
x
2
=
2
1
x
3
=
2
9
32.
37. (A) o + | = 5, o | = 3
o
2
+ |
2
= (o + |)
2
2o| = 25 6 = 19
(B) ) 5 2 (
5 4 9 4 1 4 1 + + +
{(a + b)
2
= a
2
+ b
2
+ 2ab
(2
5
)
( )
2
2 5 4 1 4 1 + + +
(2
5
)
5 4 8 1 4 1 + + +
(2
5
) ) 5 2 ( 4 1 + +
(2
5
)(2 +
5
) = 4 5 = 1
(C)
2
3 21 2 10
|
.
|
\
|
+
= 10 + 2
21
+ 3 2
3 21 2 10 +
= 13 + 2
21
2
21 6 30 +
= 13 + 2
21

( )
2
3 21 2 +
= 13 + 2
21
6 2
21
= 7
(D) To findnin r
4 4 4
2 2 2 2
c b a
) c b a (
+ +
+ +
= ?
=
4 4 4
2 2 2 2 2 2 4 4 4
c b a
a c 2 c b 2 b a 2 c b a
+ +
+ + + + +
from A a
4
+ b
4
+ c
4
= 2(a
2
b
2
+b
2
c
2
+ c
2
a
2
)
] a c c b b a [ 2
] c a 2 c b 2 b a 2 [ 2
2 2 2 2 2 2
2 2 2 2 2 2
+ +
+ +
= 2
38. (A) 1(6 + 2) + (5)(2 2) + a(2 6) = 0
8 + 20 4a = 0
4a = 28 a = 7
(B) log
2
log
2
log
3
log
3
27
3
= log
2
log
2
log
3
log
3
3
9
= log
2
log
2
log
3
9 = log
2
log
2
2 = log
2
1 = 0
(C)
1 k 2
3
=
1 k
1
=
1 k 2
1
+
3k 3 = 2k 1
STPFXII1213
Page - 26
k = 2
1 k
1
=
1 k 2
1
+
(D) AB
2
= AC
2
+ CB
2
AB
2
= AC
2
+ AC
2
AB
2
= 2AC
2
(Since AC = CB)
k = 2
40. Given : f = 10 cm, u = 12 cm, v = ?
by mirror formula
12
1
v
1
10
1
u
1
v
1
f
1
+ =
+ =
by solving, we get v = 60 cm
i.e. image will form in same side of object at 60 cm from mirror.
46.
50
N
X
40
A
B
C
50
Y
Ray BC retraces its path when A fall on second mirror perpendicularly, so as per figure L BYC will be euqal to
50.
48. At the centre of the earth gravitational field is zero.
So, at centre of gravitational force (i.e. weight) of particle and acceleration of particle is zero, whereas its speed
is maximum.
50. s = ut +
2
at
2
0 = 10t
2
t 10
2
t = 2 s
Hence A & C are correct.
n A ( C ri r|
51. (A), (B)
v = kt Acceleration a =
dt
dv
= k = constant
a = constant (straraight line)
i.e. acceleration is constant irrespective of the value of displacement and time.
(C) v = kt (straight line)
(D) v = kt
v = 0 + kt .............(i)
From v = u + at .............(ii) (equation of motion)
By comparing (i) & (ii)
u = 0, a = k
From v
2
= u
2
+ 2ax v
2
= 0 + 2kx
x =
k 2
v
2
(parabola).
58. [OH
] = 10
3
So, [H
+
] = 10
11
pH = log [H
+
]
pH = 11
STPFXII1213
Page - 27
SAMPLE TEST PAPER-II
(For Class-XI Appearing / Passed Students)
Course : VISHWAAS (JF)
Correct Wrong Blank
1 to 15 32 to 41 53 to 61
Only one correct
(+ + |+- =;|)
3 -1 0
16 to 21 42 to 45 62 to 63
(+ r + = |=r+ |+- =;|)
4 0 0
22 to 30 46 to 51 64 to 66 Comprehensions ( -e ) 4 0 0
31 52 67
Matrix Match Type
(= |c = = = +r)
6 [1, 2, 3, 6] 0 0
(Mathematics)
Part - II
(Physics)
Part - III
(Chemistry)
Type
PART - I
SECTION - I(=r=- I)
1. If |z i| s 2 and z
0
= 5 + 3i then the maximum value of |iz + z
0
| is
l |z i| s 2 nii z
0
= 5 + 3i r, ni |iz + z
0
| i lin- -i r
(A) 2 + 31 (B) 7 (C) 31 2 (D) None of these (;- i; ri)
2. The value of 1
2
2
2
+ 3
2
4
2
+ 5
2
6
2
+ ....+ 99
2
100
2
is :
1
2
2
2
+ 3
2
4
2
+ 5
2
6
2
+ ....+ 99
2
100
2
i -i r
(A) 100 (B) 5050 (C) 2500 (D) 2520
3. Sita has 4 different and simmi has 7 different toys. Number of ways in which they can exchange their toys so
that each keeps her inital number of toys, is
ini 4 nii îni 7 lili lii ini r, ni nii i i i riî| l ii i ili liii i
i i -i in r liii i |
(A) 329 (B) 334 (C) 332 (D) 345
4. The equations of the perpendicular bisectors of the sides AB and AC of a AABC are x y = 0 and
x + y = 0 respectively. If the point A is (1, 2) then the equation of the altitude of AABC through A is
lii ABC i ii AB i AC -l,iii -ii x y = 0 i x + y = 0 r| l A(1, 2) r, n A
i AABC iii i -ii r
(A) 14x + 23y = 0 (B) 14x 23y = 0 (C) 2x y 4 = 0 (D) x 2y = 0
5. The digits, from 0 to 9 are written on 10 slips of paper (one digit on each slip) and placed in a box. If three of the
slips are drawn and arranged, then the number of possible different arrangements is
i^ 10 -i 0 9 (- - ) li i - ii ini r| l ; -i - ni
-i i (l-in li ini r, n l(li iil(n >-i i i r
(A) 1000 (B) 720 (C) 810 (D) None of these (;- i; ri)
6. First term of a G.P. having positive common ratio exceeds the second term by 2, if the sum of first infinite terms
of the series is 50, then the third term of the series is : (ii-- i(in i îi-i i i i- ,
2 li r| l ; îi-i i n i i i^ 50 r, n i i nii r)
(A)
5
32
(B)
5
34
(C)
5
36
(D) None of these (;- i; ri)
STPFXII1213
Page - 28
7. Vertices of A ABC are A (0 , 0) , B (3 , 1) and C (1 , 3) . The equation of line parallel to BC and intersecting
the sides AB and AC such that perpendicular distance of the line from origin is
2
1
, is
A ABC iii A (0 , 0) , B (3 , 1) nii C (1 , 3) r | BC -in ii i AB nii AC i ln ni r nii li
- l (n i
2
1
r, i -ii r
(A) x + y
2
1
= 0 (B) x + y +
2
1
= 0
(C) 2 x + 2 y 2 = 0 (D) 2 x + 2 y + 2 = 0
8. If the solution set of the inequality ) x 5 x ( log log
2
5
9 . 0
+ + > 0, then contains n integral values, then n =
l l-i ) x 5 x ( log log
2
5
9 . 0
+ + > 0 ri i - n ii -i ini ri, ni n =
(A) 7 (B) 8 (C) 6 (D) 10
9. A cone of height 24cm and radius of base 6cm is made up of modelling clay. A child reshapes it in the form of a
sphere, then the radius of the sphere is
li l---i r i i +i; 24 -i. nii iii i lii 6 -i. r| i ; î -
ll-n (reshapes) ni r, ni î i lii r
(A) 2 (B) 4 (C) 5 (D) 6
10. Given figure shows a circle with centre at O, ZAOB = 30, and OA = 6 cm,
then area of the shaded region is
l ^ li - (-i i O r nii ZAOB = 30, ( OA = 6 cm r, ni
iiln -ii i -ii r
(A) 3t 9 cm
2
(B) 3t cm
2

(C) 9 3t cm
2
(D) 3t 9 3 cm
2
11. If AD =
2
1
BD, then the value of sinu is : (l AD =
2
1
BD r, n sinu i -i r)
(A)
2 2
x 5 y 9
x
+
(B)
2 2
x 5 y 9
x 2
B
A
C
D
y
x
(C)
2 2
x 5 y 3
x
(D)
2 2
x 4 y 3
x 2
12. The value of

g x ( )
}
1
1
g (x) + [x] dx where [ . ] is the greatest integer function and g (x) is continous and
differentiable for all x is ( g x ( )
}
1
1
g (x) + [x] dx i -i r ri [ . ] -r-i- ii nii g (x) ii x l
nn ( (i r|)
(A) g'(1) g'(1) 2 (B) g' (1) g'(1) + 2 (C) 2 (D) 1
13. Domain of f (x) =
x sin | x sin |
1
(i in r) is
(A) No solution (i; r ri) (B) ((2n + 1)t , 2 (n + 1)t) , n e I
(B) [2nt, (2n + 1)t], n e I (D) None of these (;- i; ri)
STPFXII1213
Page - 29
14. If all words formed by the letters of the word PARKAR are arranged alphabatically then 99
th
word is
l PARKAR i -ii i i î i ii i (l-in li ini r, n 99( i riî
(A) PARAKR (B) PARKRA (C) PARKAR (D) PARARK
15. In the given sequence one number is wrong. Identify the wrong number :
4, 7, 16, 43, 126, 367, 1096
i ^; i - i ^n r| ^n i i ril :
4, 7, 16, 43, 126, 367, 1096
(A) 367 (B) 7 (C) 43 (D) 126
; i - 6 r ri -i i r| - 4 l(- (A), (B), (C) nii (D) r, l- i l
i l(- ri r (r)|
16. If A, B, C are angles of AABC and tan A tan C = 3, tan B tan C = 6, then
l lii ABC ii A, B, C r i tan A tan C = 3, tan B tan C = 6, n
(A) A =
4
t
(B) tan A tan B = 2
(C)
C tan
A tan
=
2
3
(D) tan
3
A + tan
3
B = tan
3
C + 3 tan A tan B tan C = 0
17. Chords of a hyperbola
2
2
a
x

2
2
b
y
= 1 are drawn passing through a fixed point (2h, 2k), then the locus of their
mid-points is :
ln(
2
2
a
x
2
2
b
y
= 1 i i(i, l-i l (2h, 2k) ^ni r, n - l i li r
(A) a hyperbola similar to the given hyperbola if
2
2
a
h
>
2
2
b
k
( ln( i l ^ ln( - r l
2
2
a
h
>
2
2
b
k
)
(B) an ellipse if
2
2
a
h
=
2
2
b
k
( ii(-i l
2
2
a
h
=
2
2
b
k
)
(C) a conic with centre (h, k) ( ii( li (h, k) r|)
(D) a conic with centre (2h, 2k) ( ii( li (2h, 2k) r|)
18. If a , b , c are positive numbers in G.P. and log

|
.
|
\
|
a
c 5
, log

|
.
|
\
|
c 5
b 3
, log

|
.
|
\
|
b 3
a
are in A.P, then which of the
following is/are correct ?
l ii-- i a , b , c îi-i i - r i log

|
.
|
\
|
a
c 5
, log

|
.
|
\
|
c 5
b 3
, log

|
.
|
\
|
b 3
a
-in i - r, n l -
ii,i i ri r ?
(A) b =
3
5
c (B) a , b , c cannot be the sides of a triangle
(a , b , c lii i ii ri ri ni)
(C) a =
9
c 25
(D) a =
9
5
c
STPFXII1213
Page - 30
19. If (t
2
, 2t) is one end of a focal chord of the parabola y
2
= 4x, then which is (are) true
l (t
2
, 2t) ( y
2
= 4x i iii i(i i li ri, ni l - ii, - r
(A) length of the focal chord is
2
t
1
t |
.
|
\
|
+ (iii i(i i i;
2
t
1
t |
.
|
\
|
+ r)
(B) slope of the focal chord is
1 t
t 2
2
(iii i(i i (ini
1 t
t 2
2
r)
(C) mid-point of focal chord is focus (iii i(i i - l, ili r)
(D) focal-chord is angle bisector of tangent and the normal at (t
2
, 2t) to the parabola
(( (t
2
, 2t) -i ii i li i , iiii(i r)
20. In the figure shown, O is centre of the circle and ZDAB = 50, then
i l ^ li -, (-i i O r nii ZDAB = 50 , ni
(A) x = 100
(B) y = 140
(C) x = 110
(D) y = 130
21. Let f(x) = min {1, cosx, 1 - sinx}; t s x s t, then : (l f(x) = min {1, cosx, 1 - sinx}; t s x s t, ni)
(A) f is not differentiable at 0 (f, 0 (i ri r)
(B) f is differentiable at t/2 (f, t/2 (i r)
(C) f has a local maxima at 0 (f, 0 n- l ini r)
(D) none of these (;- i; ri)
;= =r= = 3 -e (paragraphs) ;| + -e r=rr|n 3 ;|+-| r + =-r ;| +
+ 4 |+- (A), (B), (C) nrr (D) ; , |= = |= + =;| ;|
22 = 24 + | -e
Let P,Q,R,S and T be five sets about the quadratic equation (a 5) x
2
2ax + (a 4) = 0, a = 5 such that
P : All values of a for which the product of roots of given quadratic equation is positive.
Q : All values of a for which the product of roots of given quadratic equation is negative.
R : All values of a for which the product of real roots of given quadratic equation is positive.
S : All value of a for which the roots of given quadratic equation are real.
T : All values of a for which the given quadratic equation has imaginary roots.
On the basis of above information, answer the following questions :
-ii P,Q,R,S i T l,iin -ii (a 5) x
2
2ax + (a 4) = 0, a = 5 i-i i - r|
P : a ii -i l l l,iin -ii -i i î ii-- r|
Q : a ii -i l l l,iin -ii -i i î ~ii-- r|
R : a ii -i l l l,iin -ii (i-nl( -i i î ii-- r|
S : a ii -i l l l,iin -ii - (i-nl( r|
T : a ii -i l l l,iin -ii - i-l r|
=rn r+r| + r=rr |- r + =-r |||
22. Which statement is correct regarding sets P, Q and R
- P, Q nii R i - ii i - r
STPFXII1213
Page - 31
(A) P Q = | (B) R
_
P (C) P Q
_
R' {4, 5} (D) All of the above
where R' is the set of real numbers. (in ii ri R' (i-nl( ii i - r| )
23. Which statement is correct regarding sets P, R and T
- P, R nii T i - ii i - r
(A) P
_
R (B) R
_
T (C) T
_
P (D) P R = T
24. Which statement is correct
ii i - r
(A) Least positive integer for set R is 2 (- R i n- ii-- ii 2 r)
(B) Least positive integer for set R is 3 (- R l n- ii-- ii 3 r)
(C) Greatest positive integer for set T is 3 (- T lin- ii-- ii 3 r)
25 = 27 + | -e
In a sequence of (4n + 1) terms the first (2n + 1) terms are in AP whose common difference is 2, and the last (2n
+ 1) terms are in GP whose common ratio 0.5. If the middle terms of the AP and GP are equal, then
(4n + 1) i l >- - i- (2n + 1) .. - r li i(n 2 r, nii ln- (2n + 1) ^.. - r
li i(in 0.5 r, l .. nii ^. . - -i ri, ni
25. Middle term of the sequence is : (>- i - r)
(A)
1 2
2 . n
n
1 n
+
(B)
1 2
2 . n
n 2
1 n
+
(C) n . 2
n
26. First term of the sequence is : (>- i i- r)
(A)
1 2
2 . n 2 n 4
n
n
+
(B)
1 2
2 . n 2 n 4
n
n
(C)
1 2
2 . n n 2
n
n
(D)
1 2
2 . n n 2
n
n
+
27. Middle term of the GP is : (îi-i i i - r)
(A)
1 2
2
n
n
(B)
1 2
2 . n
n
n
(C)
1 2
n
n
(D)
1 2
n 2
n

28 = 30 + | -e
Let S
1
, S
2
, S
3
be the circles x
2
+ y
2
+ 3x + 2y + 1 = 0, x
2
+ y
2
x + 6y + 5 = 0
and x
2
+ y
2
+ 5x 8y + 15 = 0, then
-iil S
1
, S
2
, S
3
ni (-i >-i x
2
+ y
2
+ 3x + 2y + 1 = 0, x
2
+ y
2
x + 6y + 5 = 0
nii x
2
+ y
2
+ 5x 8y + 15 = 0 ri, ni
28. Point from which length of tangents to these three circles is same is
(r l l nii (-ii -i ii i i; i ri, riî
(A) (1, 0) (B) (3, 2) (C) (10, 5) (D) ( 2, 1)
29. Equation of circle S
4
which cut orthogonally to all given circle is
(-i S
4
i l l ^ (-ii i iii ln ni r, i -ii r
(A) x
2
+ y
2
6x + 4y 14 = 0 (B) x
2
+ y
2

+ 6x + 4y 14 = 0
(C) x
2
+ y
2
6x 4y + 14 = 0 (D) x
2
+ y
2
6x 4y 14 = 0
30. Radical centre of circles S
1
, S
2
, & S
4
is
S
1
, S
2
( S
4
(-ii i -i-i r
STPFXII1213
Page - 32
(A)
|
.
|
\
|
5
8
,
5
3
(B) (3, 2) (C) (1, 0) (D)

|
.
|
\
|
2
3
,
5
4

This section contains 1 question. The question contains statements given in two columns which have to be matched.
Statements (A, B, C, D) in Column-I have to be matched with statements (p, q, r, s) in Column-II. The answers to
these questions have to be appropriately bubbled as illustrated in the following example.
correctly matched answer will look like in bubbled matrix. One option in Column
I may have one or more than one correct options in ColumnII. Marks will be
awarded only if an option in ColumnI is matched with all correct options in Column-
II. Each correct matching will be awarded 1 mark
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
C-r, C-s nii D-q r , ni ri l(li i l ^ -i i 4 x 4 - l- (matrix) - ii i î r| i-I - l(-
31. Column - I (n--r - I) Column-II (n--r-II)
(A) The system of equations lx + y + z = 1, x + ly + z = l, (p) 4
x + y + lz = l
2
have no solution, then |l| is equal to
-ii li lx + y + z = 1, x + ly + z = l, x + y + lz = l
2
i i; r ri r, ni |l| =
(B) If f(x) = sin
2
x + sin
2
(x + 2p/3) + sin
2
(x + 4p/3) then the value of (q) 2
8f
|
.
|
\
|
t
15
is equal to
l f(x) = sin
2
x + sin
2
(x + 2p/3) + sin
2
(x + 4p/3) ri, ni
8f
|
.
|
\
|
t
15
i -i r
(C) Number of odd divisors of 2
10
3
5
7
2
is equal to (r) 12
2
10
3
5
7
2
l(i- iii i i r
(D) Least positive integral solution of the equation (s) 18
|2x| |x 4| = x + 4 is
-ii |2x| |x 4| = x + 4 i n- ii-- ii r r|
PART - II
32. The position vector of a particle is given as r
= (t
2
4t + 6)
i
+ (t
2
) j
. The time after which the velocity vector and

STPFXII1213
Page - 33
acceleration vector becomes perpendicular to each other is equal to: (li i i l-iln li r
= (t
2
4t + 6)
i
+ (t
2
) j
li ini r| (r - nin i (^ li,-(i li - (n ri)

(A) 1sec (B) 2 sec (C) 1.5 sec (D) not possible i( ri r
33. The velocity - time graph of a particle is as shown in figure: (li i i (^ - (> lin r)
(A) It moves with a constant acceleration throughout. (r r-ii ln -(i ^ln-i r|)
(B) It moves with an acceleration of constant magnitude but changing direction at the end of every two second
(r r-ii -i l-ii -(i ni r n -(i i lii - i i ini r|)
(C) The displacement of the particle is zero (i i l(-ii i r|)
(D) The velocity becomes zero at t = 4 second (i i (^ t = 4 i r|)
34. In the figure shown, all the surfaces and pulleys are smooth. Also the strings
are inextensible and light. The acceleration of the 6 Kg block will be: [Take g
= 10 m/s
2
] (lii ^ li -, ii nr nii lii iiilrn r nii
-i l(ni ( r-i r| 6 Kg i i -(i riî ) [g = 10 m/s
2
]
(A) 5 m/s
2
(B) 1 m/s
2
(C) 3 m/s
2
(D) 2 m/s
2
35. A uniform thin rod is bent in the form of closed loop ABCDEFA as shown in the figure. (-i ni i
-i liii ABCDEFA ii î r|)

The ratio of moment of inertia of the loop about x-axis to that about y-axis is.
(i- - i x--i ln -( iii i y--i ln -( iii in r|)
(A) > 1 (B) < 1 (C) = 1 (D) = 1/2
36. Two particles of medium disturbed by the wave propagation are at x
1
= 0 and x
2
= 1cm. The respective
displacements (in cm) of the particles can be given by the equations :(x
1
= 0 nii x
2
= 1cm -i- i i n^
i ,ii iil(n rin r| ii l(-ii (-i -) >-i l -iii ,ii l i n r) :
y
1
= 2sin3tt
y
2
= 2sin(3tt t/8)
The wave velocity is : (n^ (^ r) :
(A) 16 cm/sec (B) 24 cm/sec (C) 12 cm/sec (D) 8 cm/sec.
37. A sounding body emitting a frequency of 150 Hz is dropped from a height. During its fall under gravity it crosses
a very small balloon moving upwards with a constant velocity of 2m/s one second after it started to fall. The
difference in the frequency observed by the man in balloon just before and just after crossing the body will be:
(given that -velocity of sound = 300m/s; g = 10m/s
2
)
STPFXII1213
Page - 34
( (l - (ii l li i(l-i 150 Hz r, +i; lîi ini r ^-(i -ii - lî 1
i r rn i- î i ln (^ 2m/s + i i ^ln-i r i i ni r ni î - l-in ln
,ii î i i -i r nii -i i - iiii i(l-i - n riî
(li î r l (l i (^ = 300m/s; g = 10m/s
2
)
(A) 12 (B) 6 (C) 8 (D) 4
38. In the figure shown, the time period and the amplitude respectively when m is released from rest when the spring
is relaxed is: (the inclined plane is smooth)
(lii ^ li -, l-^ ni( lrn ( l(i-i(-ii - r ni m i -n i i(ni nii ii- >-i ri^ (n
n li r|)
(A) 2t
m
k
,
mg
k
sin u
(B) 2t
m
k
sin u
,
2 mg
k
sin u
(C) 2t
m
k
,
mg
k
cos u
(D) none of these ;- i; ri
39. Figure shows a light, inextensible string attached to a cart that can
x
1 x
2
A
h=3m
(0,0)
x
y
slide along a frictionless horizontal rail aligned along an x axis. The
left end of the string is pulled over a small pulley, of negligible mass
and friction and fixed at height h = 3m from the ground level. The cart
slides from x
1
= 3 3 m to x
2
= 4 m and during the move, tension in
the string is kept constant 50 N. Find change in kinetic energy of the
cart in joules. (Use 3 = 1.7)
(liii r-i, l(-niln -i i li î i i x -i li l-in iii lrn - ^ln ni
r, ii ini r| i li r-i nii iii rin i-i lii ,ii -i h = 3m +i; nii ri r| îi x
1
=
3 3 m x
2
= 4 m n lni r nii ^ln ii -i - ni( T = 50 N ln ii ini r ni îi i ^ln +i
- l(n ( -) riî) ( 3 = 1.7)
(A) 50 (B) 150 (C) 200 (D) 3 50
40. For a fluid which is flowing steadily, the level in the vertical tubes is best represented by
(-iii (ilrn ( l, +(ii li - n (- lin li ini r)
(A) (B) (C) (D)
41. A small coin of mass 40 g is placed on the horizontal surface of a rotating disc. The disc starts from rest and is
given a constant angular acceleration o = 2 rad/s
2
. The coefficient of static friction between the coin and the disc
is
s
= 3/4 and coefficient of kinetic friction is
k
= 0.5. The coin is placed at a distance r = 1 m from the centre
of the disc. The magnitude of the resultant force on the coin exerted by the disc just before it starts slipping on
the disc is : (Take g = 10 m/s
2
)
i-i li li -i 40 î- r, i i-ni r ni -iln nr
ii ini r| ni l-ii(-ii ii rini r nii ; o = 2 l/
2
i ln
STPFXII1213
Page - 35
iii -(i i n r| ni ( l - -iln iii îi
s
= 3/4 r
nii ^ln iii îi
k
= 0.5 r| l i ni r = 1 -i i i
ii ini r| l ni l -i r ni ,ii l îi
î riî(il g = 10 m/s
2
)
(A) 0.2 N (B) 0.3 N (C) 0.4 N (D) 0.5 N
; i - 4 r ri -i i r| - 4 l(- (A), (B), (C) nii (D) r, l- i l
i l(- ri r (r)|
42. Heat is supplied to a certain homogeneous sample of matter at a uniform rate.
Its temperature is plotted against time as shown in the figure. Which of the
following conclusions can be drawn?
(A) its specific heat capacity is greater in the solid state than in the liquid state.
(B) its specific heat capacity is greater in the liquid state than in the solid state.
(C) its latent heat of vaporization is greater than its latent heat of fusion.
(D) its latent heat of vaporization is smaller than its latent heat of fusion.
li -i^ ii - i - +-i i i ^;| i l li
ni i - ii î iii î| i l ^ lii - ii ri r`
(A) ;i l(li- +-iiilni -i (-ii - ( (-ii -ii li r|
ni
-
(B) ;i l(li- +-iiilni ( (-ii - -i i -ii li r|
(C) ;i (i i ^n +-i ^ i ^n +-i li r|
(D) ;i (i i ^n +-i ^ i ^n +-i - r|
43. The acceleration of a particle is
,
a =

100 x + 50. It is released from x = 2. Here '

a

' & '

x

' are in S.I. units: (
i i -(i a =100 x + 50 r, ; x = 2 -n li ini r, ri '

a

' nii '

x

' S.I.,ln - r)
(A) the particle will perform SHM of amplitude 2 m. (i 2 m ii- i SHM î| )
(B) the particle will perform SHM of amplitude 1.5 m. (i 1.5 m ii- i SHM î|)
(C) the particle will perform SHM of time period 0.63 seconds. (i i SHM i i(ni 0.63 sec. riî|)
(D) the particle will have a maximum velocity 15 m/s. (i i lin- (^ 15 m/s riî|)
44. A rigid body is in pure rotation, that is, undergoing fixed axis rotation. Then which of the following statement(s)
are true.
l i, ii ^ln ri r| r ii ^ln l-i -i ln r ni ni l - i i - r
(A) You can find two points in the body in a plane perpendicular to the axis of rotation having same velocity. (ii
-i (n n - l - i l ri n r li (^ -i r| )
(B) You can find two points in the body in a plane perpendicular to the axis of rotation having same acceleration.
(ii -i (n n - l - i l ri n r li -(i -i r| )
(C) Speed of all the particles lying on the curved surface of a cylinder whose axis coincides with the axis of
rotation is same. ( li -i , ii -i ini r, (>i - l-in ii li i i -i r|)
(D) Angular speed of the body is same as seen from any point in the body. (l l-in li ii l i-i
l i iii i -i r|)
45. In a tug of war, the team that exerts a larger tangential force on the ground wins, winning team not moving.
Consider the period in which a team is dragging the opposite team by applying a larger tangential force on the
STPFXII1213
Page - 36
ground. Which of the following works are negative? (-iii i - i -i- iin ii -i ii
îni r, in ini r, ini r; -i- l-i r, (r -ni -i l- -i- i -i- i ii ii î
ii ni r| ii i ~ii-- riî|)
(A) work through string by the losing team on the wining team.
(rii r; -i- ,ii -i -i- ini r; -i- li î i )
(B) work by the ground on the wining team. (iin ,ii ini r; -i- li î i)
(C) work by the ground on the losing team. (iin ,ii rii r; -i- li î i)
(D) total external work on the two teams. (ii -i-i ,ii li î i= i)
;= =r= = 2 -e (paragraphs) ;| + -e r=rr|n 3 ;|+-| + =-r ;| +
+ 4 |+- (A), (B), (C) nrr (D) ; , |= = |= + =;| ;|
46 = 48 + | -e
A uniform bar of length 6

a & mass 8

m lies on a smooth horizontal table. Two point masses m & 2

m moving in
the same horizontal plane with speeds 2 v

and v respectively strike the bar as shown & stick to the bar after
collision. (6

a i; ( 8

m -i i - li -iln - ii r| i l -i m ( 2m -i
-iln n - >-i 2v ( v i ii i -in r ( - i l in r|)
46. Velocity of the centre of mass of the system is : (li -i i (^ r)
(A)
2
v
(B) v (C)
3
2v
(D) Zero 'kw U;
47. Angular velocity of the rod about centre of mass of the system is: (li -i ln i iii
(^ r)
(A)
5a
v
(B)
15a
v
(C)
3a
v
(D)
10a
v
48. Total kinetic energy of the system, just after the collision is: (- -i i li i ^ln +i r)
(A)
5
3
mv
2
(B)
25
3
mv
2
(C)
15
3
mv
2
(D) 3 mv
2
49 = 51 + | -e
A block B is placed over a cart which in turn lies over a smooth horizontal floor. Block A and block C are
connected to block B with light inextensible strings passing over light frictionless pulleys fixed to the cart as
shown. Initially the blocks and the cart are at rest. All the three blocks have mass m and the cart has mass M(M
= 3m). Now a constant horizontal force of magnitude F is applied to block A towards right. ( i B i
îi + i li ini r i l l -iln iin r| i A nii i C i i B r-i iiilrn
STPFXII1213
Page - 37
lii (i îi liii i r) ^ ri r-i l(ni -i ii ini r| ii - i ( îi l(i- -
r| - i i -i m r nii îi i -i M(M = 3m) r| ln -iln li l-ii F r ;i
ii n i A iiln li ini r|)

49. Assuming friction to be absent everywhere, the magnitude of acceleration of cart at the shown instant is : ( -ii
iii r ^r l-in r, l ^ -ii îi i -(i r)
(A)
m 6
F
(B)
m 4
F
(C)
m 3
F
(D) 0
50. Taking friction to be absent everywhere the magnitude of tension in the string connecting block B and block C is:
(r -il l iii r ^r l-in r ni i B ( i C i i (ii -i - ni( i l-ii r)
(A)
9
F
(B)
6
F
(C)
3
F
(D)
3
F 2
51. Let the coefficient of friction between block B and cart is ( > 0) and friction is absent everywhere else. Then the
maximum value of force F applied to block A such that there is no relative acceleration between block B and cart
is : (-ii l i B ( î i - ii i ^ ii

( > 0) r nii r ^r ii i l-in r | n F i lin- -i i
ri î i l i A ; nr îi ini r l i B ( î i - i ; i l-i -(i ri )
(A) mg (B) 2

mg (C) 3

mg (D) 4

mg
This section contains 1 question. The question contains statements given in two columns which have to be matched.
correctly matched answer will look like in bubbled matrix. One option in Column
I may have one or more than one correct options in ColumnII. Marks will be
awarded only if an option in ColumnI is matched with all correct options in Column-
II. Each correct matching will be awarded 1 mark
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
C-r, C-s nii D-q r , ni ri l(li i l ^ -i i 4 x 4 - l- (matrix) - ii i î r| i-I - l(-
52. In column-I condition on velocity, force and acceleration of a particle is given. Resultant motion is described in
column-II. u
= initial velocity,
F
= resultant force and v
= instantaneous velocity. ( . ( u
, v
, and
F
are nonzero
vectors) -ni-I - i (^, ( i -(i l ^ r| lii-i ^ln -ni-II - i ^; r| u
= ili
(^,
F
= lii-i nii v
= ni--ili (^ ( u
, v
, nii
F
i li r)
STPFXII1213
Page - 38
Column-I (n--r-I) Column-II (n--r-II)
(A) 0 F u =

and
F
= constant (p) path will be circular path

0 F u =

nii
F
= ln i (-iii riî
(B) 0 F u =

and
F
= constant (q) speed will increase

0 F u =

nii
F
= ln i î|
(C) 0 F v =

all the time and |

F
| = constant (r) path will be straight line

and the particle always remains in one plane.
0 F v =

ii - nii |
F
| = ln i i ii riî
i r-ii ri n - rni r|
(D) j
3 i
2 u =
and acceleration at all time j
9 i
6 a =
(s) path will be parabolic

j
3 i
2 u =
nii ii - -(i j
9 i
6 a =
i ( riî
PART - III
This section contains 9 multiple choice questions. Each question has choices (A), (B), (C) and (D), out of which
ONLY ONE is correct.
53. The radius of the first Bohr orbit of hydrogen atom is 0.59 . The radius of the third orbit of He
+
will be :
(ri;i -ii l i- i -ii i lii 0.59 r| He
+
i nni -ii i lii l riî| )
(A) 8.46 (B) 0.705 (C) 1.59 (D) 2.38
54. Bond order of N
2
molecule is : (N
2
i i i>- l r )
(A) 3 (B) 2 (C) 1 (D) 0
55. In the equilibrium reaction 2HI (g) H
2
+ I
2
which of the following expressions is true ?
(i lil>i 2HI (g) H
2
+ I
2
-, l - ii ri r|)
(A) K
p
= K
c
(B) K
c
= 2K
p
(C) K
p
> K
c
(D) K
c
= K
p
(RT)
2
56. Which of the following diagram correctly describes the behaviour of a fixed mass of an ideal gas ?
(T is measured in K) ( ii ^ lln -i (ri i l - ii ii nini r ` (T i K ,ii
-iln li î r))
(A) (B) (C) (D)
57. Number of H
+
ions present in 250 ml of lemon juice of pH = 3 is :
(pH = 3 (i 250 ml - - l-in H
+
ii i i l r :)
(A) 1.506 10
22
(B) 1.506 10
23
(C) 1.506 10
20
(D) 13.012 10
21
58. Baking powder is : (l^ i l r )
(A) NaHCO
3
(B) NaHCO
3
.6H
2
O (C) Na
2
CO
3
(D) Na
2
CO
3
.10H
2
O
59. Which of the following gives propyne on hydrolysis ? (l - i i- ii; ni r `)
(A) Al
4
C
3
(B) Mg
2
C
3
(C) B
4
C (D) La
4
C
3
STPFXII1213
Page - 39
60. The correct IUPAC name of the given compound is : (l ^ il^ i ri IUPAC i- r )
(A) 5-Amino-3-bromo-4-chloro-2-hydroxycyclopentane-1-carbonitrile
(5--ii-3-i-i-4-ii-2-ri;iii;i--1-iii;-i;)
(B) 1-Amino-3-bromo-2-chloro-4-hydroxycyclopentane-5-carbonitirle
(C) 2-Amino-4-bromo-3-chloro-5-hydroxycyclopentane-1-carbonitirle
(D) 2-Amino-3-chloro-3-bromo-5-hydroxycyclopentane-1-nitrile
(2--ii-3-ii-3-i-i-5-ri;iii;i--1-i;-i;)
61. The number of possible enantiomer pairs that can be produced during monochlorination of Butane is
- -iiiiii ii (i i( lnli -i i i r
(A) 2 (B) 3 (C) 4 (D) 1
; i - 2 r ri -i i r| - 4 l(- (A), (B), (C) nii (D) r, l- i li
l(- ri r (r)|
62. Which of the following methods of expressing concentration are independent of temperature ?
(ini i n (ii (r l(li i ni-i li ri ni r, l r ?)
(A) Molarity (-ini) (B) Molality (-ini)
(C) % w/w (ii,ii lnin) (D) Mole fraction (-ili)
63. Which amongs the following are correctly matched. (lllin - i ri -ln r :)
(A) & CH
2
=CHCH=C=CHCH=CH
2
are ring chain isomers.
( nii CH
2
=CHCH=C=CHCH=CH
2
( ii -i((i r| )
(B) & are positional isomers.
( nii l-iln -i((i r| )
STPFXII1213
Page - 40
(C) & are chain isomers.
( nii ii -i((i r|)
(D) & are functional group isomers.
( nii l>i-- -r -i((i r|)
; i - 1 (paragraphs) r| - iiiln 3 rl(-i -i r| -
4 l(- (A), (B), (C) nii (D) r , l- l ri r|
Conditions of geometrical isomerism :
(I) Geometrical isomerism arises due to the presence of a double bond or a ring structure.
(i.e. , N = N or ring structure)
Due to the rigidity of double bond or the ring structure to rotate at the room temperature the molecules exist in
two or more orientations. This rigidity to rotation is described as restricted rotation / hindered rotation / no
rotation.
(a) (Restricted Rotation)
(b) (Restricted Rotation)
(II) Different groups should be attached at each doubly bonded atom. For example
and are identical but not geometrical isomers.
On the other hand, following types of compounds can exist as geometrical isomers :
C = C
a
b
a
b
, C = C
a
b
a
d
or C = C
a
b
d
e
64 = 66 + | -e
r|=n| ==rnr + | r+ rn :
(I) il-ln -i((ni il^ - l,i i ( i l-in ri - rini r|
( l , N = N i ( i)
i-in il^ - l-in l,i i ( i r -iii i -ri i ni ri ii -n ii
i( ri rini r, l i i li ri in rin r| ii - - r l-i; ri lnlin ii (restricted
rotation), ii (no rotation) rini r|
(a) (lnlin ii)
STPFXII1213
Page - 41
(b) (lnlin ii)
(II) il-ni -i(l(i - l,i ,ii i -iii i ii ii ini lili -iii i -ri i
rii ilr| iri -
i - i r l il-ln -i((i|
; l(in, l i il^ il-ni -i((ni lin n r|
C = C
a
b
a
b
, C = C
a
b
a
d
i(i C = C
a
b
d
e
64. Which of the following compounds will show geometrical isomerism ?
(l - ii il^ il-ni -i((ni iini r `)
(A) But-2-ene (--2-; ) (B) Propene ( ii)
(C) But-1-ene ( --1-;) (D) Benzene (i)
65. Which is a pair of geometrical isomers ?
l - ii - il-ni -i((ni iini r `
(I) (II)
(III) (IV)
(A) (I) and (nii) (II) (B) (I) and (nii) (III) (C) (II) and (nii) (IV) (D) (III) and (nii) (IV)
66. Which of the following compound can not show geometrical isomerism ?
(l - ii il^ i-ini -i((ni ri iini r `)
(A) (B) (C) (D)
This section contains 1 question. Each question contains statements given in two columns which have to be matched.
If the correct matches are A-p , A-r , B-p , B-s , C-r , C-s and D-q, then the correctly
will look like in bubbled matrix. Each statement in ColumnI may have one or more
than one correct options in ColumnII. One Mark will be awarded for each statement
in ColumnI is matched with all correct options in Column-II. If all the statements in
column-I are correctly matched to their
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
STPFXII1213
Page - 42
C-r, C-s nii D-q r , ni ri l(li i l ^ -i i 4 x 4 - l- (matrix) - ii i î r| i-I - (-i
67. Columm - I Columm - II
(+r=-I) (+r=-II)
(A) (AG
system
)
T,P
= 0 (p) Process is in equilibrium
((AG
li
)
T,P
= 0) (lil>i i - r|)
(B) AS
system
+ AS
surrounding
> 0 (q) Process is nonspontaneous
(AS
li
+ AS
(ini(i
> 0) (lil>i -(n r|)
(C) AS
system
+ AS
surrounding
< 0 (r) Process is spontaneous
(AS
li
+ AS
(ini(i
< 0) (lil>i -(n r|)
(D) (AG
system
)
T,P
> 0 (s) System is unable to do useful work
((AG
li
)
T,P
> 0) (li n i i r|)
ANSWER KEY TO SAMPLE TEST PAPER-II
1. B 2. B 3. A 4. C 5. B 6. A 7. B
8. B 9. D 10. A 11. B 12. D 13. B 14. C
15. D 16. AB 17. AC 18. ABC 19. AB 20. AD 21. AC
22. D 23. C 24. B 25. A 26. B 27. D 28. B
29. D 30. A 31. (A - q), (B - r), (C - s), (D - p)
32. A 33. B 34. C 35. B 36. B 37. A 38. A
39. A 40. A 41. D 42. AC 43. BCD 44. CD 45. ACD
46. D 47. A 48. A 49. D 50. C 51. C
52. (A - r) ; (B - q,s) ; (C - p) ; (D - q,r) 53. D 54. A 55. A 56. A
57. C 58. A 59. B 60. C 61. A 62. BCD 63. ACD
64. A 65. C 66. A 67. (A - p, s); (B - r) ; (C - q, s) ; (D - q, s).
HINTS & SOLUTION TO SAMPLE TEST PAPER-II
1. |iz + z
0
| = |i(z i) 1 +5 + 3i| = |i(z i) + 4 + 3i|
s |i| | z i| + | 4 + 3i | s 1 . 2 + 5 = 7
2. (1
2
2
2
) + (3
2
4
2
) + (5
2
6
2
) + ....+ (99
2
100
2
)
= (1 + 2) (1 2) + (3 + 4)(3 4) + (5 + 6) (5 6) +.....+ (99 + 100)(99 100)
= 3 7 11..........199
a = 3, d = 4 and = 199
= a + (n 1) d
199 = 3 + (n 1)( 4)
199 + 3 = (n 1)( 4)
n 1 =
4
196
= 49
n = 50
STPFXII1213
Page - 43
S
50
=
2
50
[ 3 199]
= 25 [ 202] = 5050.
3. Required number of ways are = Exactly one toy is exchanged + exactly two toys exchanged + exactly 3 toys
exchanged + 4 toys exchanged
=
4
C
1

7
C
1
+
4
C
2

7
C
2
+
4
C
3

7
C
3
+
4
C
4

7
C
4
= 329
nii i i = liii nii i i + i lii nii i i + ni lii
nii i i + i lii nii i i|
=
4
C
1

7
C
1
+
4
C
2

7
C
2
+
4
C
3

7
C
3
+
4
C
4

7
C
4
= 329
7. Slope of line parallel to line BC is 1. (ii BC -in ii i (ini 1 r|)
Equation of line parallel to BC is x + y + = 0. (BC -in ii i -ii x + y + = 0 r|)
2
1
2
0 0
=
+ +
=
2
1
Since, line x + y + = 0, intersects AB and AC,
l ii x + y + = 0, AB i AC i i-ni r,
=
2
1
x + y +
2
1
= 0
8.
) x 5 x ( log log
2
5
9 . 0
+ +
> 0
log
5
) x 5 x (
2
+ + < 1
(x
2
+ 5 + x)
1/2
< 5 and x
2
+ x + 5 > 0
x
2
+ 5 + x < 25
x
2
+ x 20 < 0
(x + 5) (x 4) < 0
x e (5, 4)
n = 8
11. AD =
2
1
BD
Given AB = x
AD + BD = x
2
1
BD + BD = x
BD =
3
2
x
STPFXII1213
Page - 44
Now by AABC
BC =
2 2
x y
And by ABCD
CD =
2 2
BC BD +
=
2 2 2
x y x
9
4
+
CD =
3
x 5 y 9
2 2
sin u =
CD
BD
=
3
x 5 y 9
x
3
2
2 2
=
2 2
x 5 y 9
x 2
Sol. (22 to 24)

a 5 = 0
x
2

|
.
|
\
|
5 a
a 2
x +
|
.
|
\
|
5 a
4 a
= 0
If roots are o and |, then
l - o i | ri , ni
For P : o| =
|
.
|
\
|
5 a
4 a
> 0
or ae (,4) (5, )
P = {a : a e (, 4) (5, ) }
For Q : o| =
|
.
|
\
|
5 a
4 a
< 0
or a e (4, 5)
Q = {a : a e (4,5)}
For R : D > 0 and (i ) o| > 0
2
2
) 5 a (
a 4

) 5 a (
) 4 a ( 4
> 0 and (i )
|
.
|
\
|
5 a
4 a
> 0
2
) 5 a (
20 a 9
> 0 and (i )
|
.
|
\
|
5 a
4 a
> 0
a e
|
.
|
,
9
20
and (i ) a e (,4) (5, )
R =
)
`
|
.
|
e ) , 5 ( 4 ,
9
20
a : a
For S : D > 0
S =
)
`
|
.
|
e } 5 { ,
9
20
a : a
For T : D < 0
a <
9
20
T =
)
`
|
.
|
\
|
e
9
20
, a : a
STPFXII1213
Page - 45
22. (a) P Q = |
(b) R
_
P
(c) P Q = {a : a e {(,4) (5,) (4,5)}
= R' {4,5}
23. T
_
P
24. R =
)
`
e ) , 5 ( 4 ,
9
20
a : a
Least positive integer of R is 3.
Sol. (25 to 27)
Let 1
st
term be a . and common difference is 2. (-ii i- a i i( n 2 r |)
T
2n + 1
= a + 4n = A (say)

r =
2
1
Middle term of AP = T
n + 1
(-in i i - = T
n + 1
)
Middle term of GP = T
3n + 1
(^ . i i - = T
3n + 1
)
T
n + 1
= a + 2n T
3n + 1
= A . r
n
=
n
2
) n 4 a ( +
(a + 2n) =
n
2
n 4 a +
2
n
a + 2n2
n
= a + 4n
a =
1 2
2 . n 2 n 4
n
n
T
2n + 1
= a + 4n =
1 2
2 . n 2 n 4
n
n
+ 4n
=
1 2
2 . n 2
n
n
=
1 2
n 2
n
1 n
+
T
3n + 1
=
n
2
n 4 a +
=
) 1 2 ( 2
n 2
n n
1 n
+
=
1 2
n 2
n
28. Point from which length of tangents to these circle is same is radical centre
S
1
S
2
= 0 4x 4y 4 = 0 x y 1 = 0
S
2
S
3
= 0 6x + 14y 10 = 0 -3x + 7y 5 = 0
3x 3y 3 = 0
4y 8 = 0 y = 2 x = 3
29. If circle be drawn taking radical centre as centre and length of tangents from radical centre to any circle as
radius will cut all the three circles orthogonally
Length of tangent =
1 4 9 4 9 + + + +
=
1
S =
27
Equation of circle (x 3)
2
+ (y 2)
2
= 27
S
4
: x
2
+ y
2
6x 4y 14 = 0
30. S
1
S
2
= 0 x y 1 = 0
S
1
S
4
= 0 9x + 6y + 15 = 0 3x + 2y + 5 = 0
3x 3y 3 = 0
5y + 8 = 0 y = 8/5 x = 3/5
31. (A) D =
1 1
1 1
1 1
= 0
3
+ 2 3 = 0 = 1, = 2, = 1 for = 1, there are infinite number of solutions
for = 2, there is no solution | | = 2
(B) f(x) = 1 cos (2x + 2t/3) cos (2t/3) + sin
2
(x + 4t/3)
=
2
3

2
1
cos 2x
2
1

|
|
.
|
\
|
|
.
|
\
| t
+ + |
.
|
\
| t
+
3
8
x 2 cos
3
4
x 2 cos =
2
3
f
2
3 15
= |
.
|
\
|
t
8f
|
.
|
\
|
t
15
= 12
STPFXII1213
Page - 46
(C) Number of odd divisors = (5 + 1) (2 + 1) = 18
(D) We do not require negative solutions.
consider 0 s x s 4 2x + x 4 = x + 4 2x = 8 x = 4
Since x = 4 is a solution, therefore, we do not require solutions greater than 4.
Thus the least positive integral is 4.
32. r
= (t
2
4t + 6) i
+ t
2
j
; v
=
dt
r d
= (2t 4) i
+ 2t j
, a
=
dt
v d
= 2 i
+ 2 j
if
a
and
v
are perpendicular l
a
nii
v
- (n r
a
. v
= 0
(2 i
+ 2 j
). ((2t 4) i
+ 2t j
) = 0
8t 8 = 0
t = 1 sec.
Ans. t = 1 sec.
34. All the blocks will be having the same.
acceleration along the length of the string.
So, Applying Newtons law along the string on A,B & C.
6g 2g sin30
0
2g = (6 + 2 + 2)a
3g = 10a a =
10
g 3
or a = 3 m/s
2
Ans. a = 3 m/s
2
35. Moment of inertia of semicircular portions about x and y axes are same. But moment of inertia of straight
portions about x-axis is zero.
i(-iii iiî x nii y -ii ln -( iii -i r n x--i ln ii iiî i -( iii i r|
I
x
< I
y
or
I <
I
I
y
x
36. Given e = 3t
f =
t
e
2
= 1.5,
Also Ax = 1.0 cm
Given, | =
x
2
A
8
t
=
t 2
1
= 16 cm v = f = 16 1.5 = 24 cm/sec
37.
|
|
.
|
\
|
=
s
v v
v v
f f
0
0
when approaching : f
a
=
(
+
10 300
2 300
150
when receding : (
=
10 300
2 300
150
r
f
f
a
f
r
~ 12 Hence (A).
38. At equilibrium :
mg sin u = kA
A =
K
sin mg u
and time period for spring block system is :
T =
k
m
2t
Hence (A)
STPFXII1213
Page - 47
39. Displacement of the point of 'A' of the string
=
2 2
) 3 ( ) 3 3 ( +
2 2
3 4 +
= 6 5 = 1 m
A

k = Work done by tension = 50 1 = 50 Joule.
40. (A) From continuity equation, velocity at cross-section (1) is more than that at cross-section (2).
(A) i n- -ii -i i- (1) ( ^ , -i i- (2) ( ^ li r |
Hence ; P
1
< P
2
(; i ; P
1
< P
2
)
Hence (A) . (;l (A))
41. The friction force on coin just before coin is to slip will be : f =
s
mg
l l r l iii : f =
s
mg
Normal reaction on the coin ; N = mg
l li lnl>i ; N = mg
The resultant reaction by disk to the coin is
l l- ,ii lii-i lnl>i r
=
2 2
f N + =
2 2
s
2
) mg ( ) mg ( + = mg
2
1 +
= 40 10
3
10
16
9
1 +
= 0.5 N
42. Slope of graph is greater in the solid state i.e., temperature is rising faster, hence lower heat capacity.
The transition from solid to liquid state takes lesser time, hence latent heat is smaller.
î i i -i (-ii - ii r| i.e., ni ni ni r, n +-iiilni - r| -i ( l(n - - -
î n ^n +-i - r|
43. a = 100x + 50.
e
2
= 100.
and mean position is at
100x + 50 = 0 x = 1/2 m.
and as the particle is released at x = 2; so the amplitude will be 1.5 m.
T =
10
2 2 t
=
e
t
= 0.63 sec. V
max
= eA = 10
2
3
= 15 m/s.
44. All points in the body, in plane perpendicular to the axis of rotation revolve in concentric circles. All points
lying on circle of same radius have same speed (and also same magnitude of acceleration) but different
directions of velocity ( also different directions of acceleration)
Hence there cannot be two points in the given plane with same velocity or with same acceleration.
As mentioned above, points lying on circle of same radius have same speed.
Angular speed of body at any instant w.r.t. any point on body is same by definition.
(-n - i i -i (n n ii l i (-ii - li -i n r | -i lii (-i ii l i
i -i i (nii -(i i ii -i l-ii) r l ( ^ i lii (-(i i lii ii) li r |
;l l ^ n - i l i( ri r li ( ^ (nii -(i ii -i) -i ri |
+ r nii î r l -i lii i (-i l i i -i i r |
li -ii (-n i i ii i (-n l-in li l i -i liiii -i ri ni r |
Sol. (46 to 48)
(i) Cons. linear momentum
STPFXII1213
Page - 48
2m.v + 2v.m = 0 = MV
cm
V
cm
= 0
(ii) As ball sticks to Rod
Conserving angular momentum about C
2v.m. 2a + 2mva = Ie
=
|
|
.
|
\
|
+ +
2 2
2
a 4 . m a . m 2
12
a 36 . m 8
6mv.a = 30 ma
2
.e e =
a 5
v
(iii) KE =
2
1
Ie
2
=
2
1
. 30 ma
2

2
2
a 25
v
=
5
mv 3
2
.
49. The free body diagram of cart is
î i i - n (-n li r |
Hence net horizontal force on cart is zero.
acceleration of cart is zero.
;l î i - -i ln i r |
î i i -(i i r |
50. The acceleration of each block is equal and equal to
m 3
F
.
Tension in required string can be found by applying Newton's second law to block C.
T
2
= ma =
3
F
.
- i i -(i -i r nii
m 3
F
i r |
i C - i l,ni l- î i( i i - ni( nin li i ni r |
T
2
= ma =
3
F
.
51. For block B to just slip on the cart, the friction force on cart is mg. The net force on cart is thus mg.
Hence acceleration of cart is a =
m 3
mg
=
3
g
.
required force F = (m + m + m + M) a = 2mg
î i i B -i l l, î i ii i mg r | î i - ; i mg r |
;l , î i i -(i a =
m 3
mg
=
3
g
.
i( F = (m + m + m + M) a = 2mg
52. (A) F
= constant and 0 F u =

Therefore initial velocity is either in direction of constant force or opposite to it. Hence the particle will
move in straight line and speed may increase or decrease.
(B) 0 F u =

and F
= constant
initial velocity is perpendicular to constant force, hence the path will be parabolic with speed of particle
increasing.
(C) 0 F v =

means instantaneous velocity is alway perpendicular to force. Hence the speed will remain
constant. And also | F |

= constant. Since the particle moves in one plane, the resulting motion has to be
circular.
(D) j
3 i
2 u =
and
j
9 i
6 a =
. Hence initial velocity is in same direction of constant acceleration, therefore

particle moves in straight line with increasing speed.
(A)
F
= ln nii 0 F u =

STPFXII1213
Page - 49
n ili ( ^ i ni ln i lii - ri î i ; l(ln ri î| n i iii ii - ^ln î n i
i i- ni r |
(B) 0 F u =

nii F
= ln
ili ( ^, ln (n ri î, n i ( ri î l- i i i î|
(C) 0 F v =

ii n ni--ili ( ^ r- ii (n ri î| n i ln ri î| nii | F |

= ln, lii-i ^ln
(-iii ri î| l i r- ii ri n - rni r |
(D) j
3 i
2 u =
nii
j
9 i
6 a =
n ili ( ^ ln -(i i lii - ri ri î| n i iii ii - ni i

ii i î|
53. For H-like particles (like He
+
),
r
n
=
Z
2
n
0
a
=
2
2
) 3 ( 59 . 0
= 2.38 (Ans. is 2.655 )
55. 2HI (g) H
2
+ I
2
An = 2 2 = 0
K
p
= K
c
(RT)
An
K
p
= K
c
(RT)
0
K
p
= K
c
56. By Charle's law, at constant
T
V
, P = const. i.e., V = k.T. Hence, plot of V vs T is a straight line passing through
the origin. (i- l-ii l-i i
T
V
, P = l-ii i.e., V = k.T n V vs T i î i r i l
- l ^ ri r| )
60.
2-Amino-4-bromo-3-chloro-5-hydroxycyclopentane-1-carbonitirle
2--ii -4-i-i -3-ii -5-ri; iii;i --1-ii i;- i;
61. CH
3
CH
2
CH
2
CH
3

v h / Cl
2
+
(d + )
62. Only Molarity depend on temperature molality, mole -fracction & % w/w do not depend on temperature.
63. & are functional group isomers.
nii l>i-- -r -i((i r|
64. Follow conditions of geometrical isomerism. (il-ni -i((ni lin i in ii|)
STPFXII1213
Page - 50
SAMPLE TEST PAPER-III
(For Class-XII Appearing / Passed Students)
Course : VISHESH (JD) & VIJAY (JR)
Correct Wrong Blank
1 to 15 32 to 41 53 to 61
Only one correct
(+ + |+- =;|)
3 -1 0
16 to 21 42 to 45 62 to 63
(+ r + = |=r+ |+- =;|)
4 0 0
22 to 30 46 to 51 64 to 66 Comprehensions (-e ) 4 0 0
31 52 67
Matrix Match Type
(= |c = = = +r)
6 [1, 2, 3, 6] 0 0
(Mathematics)
Part - II
(Physics)
Part - III
(Chemistry)
Type
PART - I
This section contains 15 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
; i - 15 rl(-i r| - 4 l(- (A), (B), (C) nii (D) r, l- |= + =;| r|
1. The curve y e
xy
+ x = 0 has a horizontal tangent at the point
(> y e
xy
+ x = 0 l l -iln -i ii r
(A) (1, 1) (B) (0, 1) (C) (1, 0) (D) no point (i; l ri)
2. b
and c
are two non-collinear vectors such that a
|| ( c b

) , then ( b a
)
.
( c a

) is equal to
b
( c
i ii li ; i r l a
|| ( c b

) , ni ( b a
)
.
( c a

) =
(A) ) c b ( | a |
.
2

(B) ) c a ( | b |
.
2

(C) ) b a ( | c |
.
2

(D) none of these (;- i; ri )
3. If p is length of tangent from the point (1, 2) to the circle 3x
2
+ 3y
2
+ 12x + 18y 1 = 0 then 3p
2
=
l l (1, 2) (-i 3x
2
+ 3y
2
+ 12x + 18y 1 = 0 iii ^; -i ii i i; p ri, ni 3p
2
=
(A) 60 (B) 62 (C) 64 (D) none of these (;- i ; ri )
4. If S
n
=
=
+ +
n
1 r
4 2
r r 1
r
, then S
10
is equal to (l S
n
=
=
+ +
n
1 r
4 2
r r 1
r
, ni S
10
i r )
(A)
111
210
(B)
421
110
(C)
111
110
(D)
111
55
5. If (8cos
4
x 4cos
3
x 8cos
2
x + 3cosx + 1) is expressed as (cos px cos qx), then
l (8cos
4
x 4cos
3
x 8cos
2
x + 3cosx + 1) i (cos px cos qx) - n li i , ni
(A) p = 4, q = 3 (B) p = 8, q = 3 (C) p = 8, q = 2 (D) none of these (;- i ; ri)
6. The sum of all the numbers which can be formed by using the digits 1, 3, 5, 7 all at a time and which have
no digit repeated is
i 1, 3, 5, 7 llin ii i i i^ i riî, l li ii i i(l-i ri i ^; ri`
(A) 16 4! (B) 1111 3! (C) 16 1111 3! (D) 16 1111 4!.
STPFXII1213
Page - 51
7. If z
1
& z
1
represent

adjacent

vertices

of

a regular polygon of

n

sides with centre at the origin & if
Im
Re
z
z
1
1
2 1 =
then the value of n is equal to :
l n i ii - r i li - l ri , i i iii z
1
( z
1
lln l in r nii
Im
Re
z
z
1
1
2 1 =
ri , ni n i -i r
(A) 8 (B) 12 (C) 16 (D) 24
8. The graph of the function y = f(x) is as shown in the figure. Then
which one of the following could represent the graph of the function
y = |f(x)| ?
y = f(x) i ii liii r| n y = |f(x)| i ii r
(A)
1 2 0 2
x
y
1
(B)
1
2 0
2
x
1
yyy
(C)
1 2 0
2
x
1
0
yyy
(D)
1 2 0
2
x
1
yyy
9. An extreme value of 4sin
2
x + 3cos
2
x 24 sin
x
2
24 cos
x
2
, where 0 s x s
2
t
, is
4sin
2
x + 3cos
2
x 24 sin
x
2
24 cos
x
2
i - -i, ri 0 s x s
2
t
r, r
(A) 4 +
2
(B) 4 (1 6 2 ) (C) 21 (D) 4
10. The number of ways to select three numbers in AP from the first 2n natural numbers is.
i- 2n in ii - ni i i l -in i - r, nii i i r
(A) n(n + 1) (B) n(n 1) (C) n
2
1 (D) n
2
+ 1
11. }
+
2
x x ) x 1 (
dx
= ( }
+
2
x x ) x 1 (
dx
=)
(A)
x 1
) 1 x ( 2
+ C (B)
1 x
) 1 x ( 2
+
+ C (C)
1 x
) 1 x ( 2
+
+ C (D)
1 x
) 1 x ( 2
+ C
12. A tangent to the circle x
2
+ y
2
= 1 is perpendicular to a tangent to the circle x
2
+ y
2
= 9. If locus of the point of
intersection of the tangents is x
2
+ y
2
= a, then the value of a is
(-i x
2
+ y
2
= 1 i -i ii, (-i x
2
+ y
2
= 9 i -i ii (n r| l -i iii ln l i
li x
2
+ y
2
= a ri, ni a i -i r
(A)
8
(B) 10 (C)
10
(D) 8
13. An ellipse with foci (3, 1) and (1, 1) passes through the point (1, 3) its eccentricity is
l (1, 3) ^ (i nii (3, 1) i (1, 1) ili (i ii(-i i -ni r
(A)
1 2
(B)
1 3
(C)
2 3
(D)
3 2
STPFXII1213
Page - 52
14. Three numbers are chosen at random without replacement from {1,2,.......10}. The probability that the
minimum of the chosen number is 3 or their maximum is 7 is
- {1,2,.......10} - ni i il (li (i ln-iiln l) i ini r, ni i ^; ii -
n- i 3 nii lin- i 7 ri i ilni riî
(A)
20
11
(B)
20
7
(C)
40
11
(D)
40
7
15. If A =
(
(
(
0 0 1
0 1 0
1 0 0
then (l A =
(
(
(
0 0 1
0 1 0
1 0 0
r, ni )
(A) A is zero matrix (A i ir r) (B) A
2
= I
(C) A
1
does not exist (A
1
i l-n-( ri r) (D) A = (1) I
SECTION - II (=r=- II)
Multiple Correct Answer Type (; =;| |+- +r)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct.
; i - 6 r l(- r| - -i l 4 l(- (A), (B), (C) nii (D) r, l- + r + =
|=r+ =;| r|
16. If maximum and minimum values of the determinant
x 2 sin 1 x cos x sin
x 2 sin x cos 1 x sin
x 2 sin x cos x sin 1
2 2
2 2
2 2
+
+
+
are o and | respectively,,
then :
l ili
x 2 sin 1 x cos x sin
x 2 sin x cos 1 x sin
x 2 sin x cos x sin 1
2 2
2 2
2 2
+
+
+
lin- ( n- -i >-i o nii | r, ni
(A) o + |
99
= 4 (B) o
3
|
17
= 26 (C)
|
o
= 3
(D) a triangle can be construced having its sides as o |, o + | and o + 3|
(ii o |, o + | nii o + 3| lii ii i ni r|)
17. g(x) = f(x
2
) + f(1 x
2
) and f''(x) < 0 for 0 s x s 1, then
g(x) = f(x
2
) + f(1 x
2
) nii 0 s x s 1 l f''(x) < 0 r , ni
(A) g(x) decreases in
|
|
.
|
\
|
2
1
, 0
( g(x) ,
|
|
.
|
\
|
2
1
, 0
- ri-i r | )
(B) g(x) increases in
|
|
.
|
\
|
2
1
, 0 ( g(x),
|
|
.
|
\
|
2
1
, 0 - (i -i r | )
(C) g(x) decreases in
|
|
.
|
\
|
1 ,
2
1
( g(x),
|
|
.
|
\
|
1 ,
2
1
- ri-i r | )
(D) g(x) increases in
|
|
.
|
\
|
1 ,
2
1
( g(x) ,
|
|
.
|
\
|
1 ,
2
1
- (i -i r | )
STPFXII1213
Page - 53
18. The differential equation, x
dx
dy
+
dx
dy
3
= x
2
( ( -ii x
dx
dy
+
dx
dy
3
= x
2
)
(A) is of order 1 (i >- 1 r ) (B) is of degree 2 (i i l- 2 r )
(C) is linear ( ii r ) (D) is non linear ( ii r )
19. A line passes through (3, 0). The slope of the line, for which its intercept between y = x 2 and y = x + 2
subtends a right angle at the origin, may be.
l (3, 0) ^ (ii ii i iii y = x 2 i y = x + 2 - ni -l -ii ini
r, ni ; ii i (ini r
(A)
2
(B)
2
(C)
2
1
(D)
2
1
20. Let f(x) =

2
] x [ 1
]) x [ ( tan
+
t t
, then which of the following is/are TRUE ?
( [.] represents greatest integer function )
-iil f(x) =
2
] x [ 1
]) x [ ( tan
+
t t
r, ni l - i i - r
(ri [.] -r-i- ii i nini r )
(A) f(x) is a constant function (f(x) r)
(B) f(x) is continuous at x = 0 (x = 0 f(x) nn r)
(C) f(x) is discontinuous at x = 0 (x = 0 f(x) nn r )
(D) f(x) is continous function for all values of x (x ii -ii l f(x) nn r)
21. If the equation 4
x
a . 2
x
a + 3 = 0 has at least one real solution, then a e
l -ii 4
x
a . 2
x
a + 3 = 0 - - (i-nl( r r, ni a e
(A) (0, ) (B) (1, ) (C) [2, ) (D) [6, 2]
Comprehension Type (r=r +r)
This section contains 3 groups of questions. Each group has 3 multiple choice questions based on a paragraph.
Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
; i - 3 -r r| - -r - iiiln 3 r l(-i r| - -i l 4 l(-
(A), (B), (C) nii (D) r, l- l ri r|
22 = 24 + | -e
Consider system of equations -iil -ii li
x y + z + 1 = 0
2x + 3y + z 3 = 0
x + y + 3z 2 = 0
22. System of equations has unique solution, then : (-ii li l,ni r ini r, ni )
(A) = 3, 14 (B) = 13, 4
(C) = 3, 4 (D) no value of ( i i; -i ri)
23. System of equations has infinitely many solutions, then : (-ii li ri i i n r, ni)
(A) = 2 (B) = 4
(C) = 13 (D) no value of ( i i; -i ri)
STPFXII1213
Page - 54
24. System of equations is in-consistent, then : (-ii li ^n ri ri, ni)
(A) = 14 (B) = 4, 3
(C) = 13 (D) no value of ( i i; -i ri)
25 = 27 + | -e
Read the following passage carefully and answer the questions.
|- -e +r =r+ a+ | | n r + =-r ||
Let f(x) x
3
ax
2
+ bx 1, g(x) x
3
bx
2
+ ax 1 be polynomials with complex coefficients and o, | be roots
of f(x) = x
3
.
-iil f(x) = x
3
ax
2
+ bx 1, g(x) = x
3
bx
2
+ ax 1 i r r, l îi (i-nl( i i-l ri n r
i o, | -ii f(x) = x
3
- r|
25. If roots of g(x) = 0 are in A.P. then
l g(x) = 0 - -in i - ri, ni
(A) a = b (B) 2a
3
+ 27 = 9ab (C) 9ab = 2b
3
+ 27 (D) ab
3
+ 27 = 9ab
26. If a, b are roots of x
2
+ x + 2 = 0, then f(x) g(x)
l a, b -ii x
2
+ x + 2 = 0 - ri, ni f(x) g(x)
(A) x
6
+ x
5
+ x
4
+ x
3
+ x
2
+ x + 1 (B) x
6
x
5
+ x
4
x
3
+ x
2
x + 1
(C) x
6
+ x
5
x
4
+ x
3
x
2
+ x 1 (D) x
6
+ 2x
5
x
4
+ 2x
3
x
2
+ 2x + 1
27. If a + b = 1 and a
1
, a
2
are values of 'a' for which o, | are connected by
|
o
+
o
|
=
3
4
, then equation with roots
a
1
, a
2
is
l a + b = 1 i 'a' i -i a
1
, a
2
r l l o, | i
|
o
+
o
|
=
3
4
r r, ni a
1
, a
2
-i (ii
-ii r
(A) 4x
2
3x + 3 = 0 (B) 3x
2
4x + 3 = 0 (C) 4x
2
+ 3x + 3 = 0 (D) 3x
2
+ 4x + 3 = 0
28 = 30 + | -e
A bag contains 8 black, 3 red and 9 white balls. If 3 balls are drawn at random, the probability that
^ - 8 ii , 3 i nii 9 ^ r| l 3 ^ il i ini r
28. They are 2 black and 1 white is
2 ii nii 1 ri i ilni riî
(A)
95
21
(B)
95
17
(C)
95
23
(D)
96
19
29. The balls are one of each colour is
- ^ i ^ ri i ilni r
(A)
95
21
(B)
95
18
(C)
95
17
(D)
96
23
30. The balls are drawn in the order black, red, white is
^ ii, i, >- - li i ilni r
(A)
95
18
(B)
95
21
(C)
95
3
(D)
95
7
STPFXII1213
Page - 55
SECTION - IV (=r= - IV)
This section contains 1 questions. Each question contains statements given
in two columns which have to be matched. Statements in Column are labelled
as A,B,C and D whereas statements in Column are labelled as p,q,r and
s. The answers to these questions have to be appropriately bubbled as
illustrated in the following example.
If the correct matches are A-p , A-r , B-p , B-s , C-r , C-s and D-q ,
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
then the correctly bubbled matrix will look like the following :
; i - 1 r| - - i i- - (- (statements) l r r li
- ( mat ch) i r | +r = ( Col umn- I ) - l ^ (n i
(A, B, C, D) i +r= (Column-II) - l ^ (ni (p, q, r, s) - i r|
; i -i l ^ iri i ln -i i ii iii r|
l ri - A-p, A-r, B-p, B-s, C-r, C-s nii D-q r, ni ri l(li i l
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
^ -i i 4 x 4 -l- (matrix) i iii î r|
31. Column Column
(n--r ) (n--r )
(A) Number of ways of distributing 7 books to 2 children is (p) 126
7 -ni i 2 i - i - ni r
(B) The value of
2
C
2
+
3
C
2
+
4
C
2
+ ............ +
11
C
2
is (q) 128
2
C
2
+
3
C
2
+
4
C
2
+ ............ +
11
C
2
i -i r
(C) The number of five digit numbers in which every digit exceeds the (r) 136
immediately preceding digit is
5 i i i lni i ri î li - -i
( ii r `
(D) The coefficient of x
24
in expansion of
17
3
2
x
1
x |
.
|
\
|
+
is (s) 220
17
3
2
x
1
x |
.
|
\
|
+
i - x
24
i ^ ii r
PART - II
This section contains 10 multiple choice questions. Each question has choices (A), (B), (C) and (D), out
of which ONLY ONE is correct.
32. A man wearing a hat of extended length 12 cm is running in rain falling vertically downwards with speed
10 m/s. The maximum speed with which man can run, so that rain drops do not fall on his face (the length of his
face below the extended part of the hat is 16 cm) will be : ( ln 12 cm ii r; i; i -ii r r
10 m/s (^ +(ii i i i l^ ri in - ini r| i-i i i lin- i, nil in i
r ri l^ ( r i -ii i r ii^ i i i; 16 cm r) riî)
(A) 7.5 m/s (B) 13.33 m/s (C) 10 m/s (D) zero i
STPFXII1213
Page - 56
33. A particle is projected at an angle of 60 from a horizontal plane. Then the path of projectile cannot appear a
straight line to an observer: ( i i -i ln n 60 i i -iln li ini r ni li -i i -i
i i ii ri nin ri ni r| l -i)
(A) moving with constant acceleration in horizontal direction
(-iln lii - ln -(i ^ln-i ri|)
(B) moving with constant velocity in horizontal direction
(-iln lii - ln (^ ^ln-i ri|)
(C) moving downwards with constant acceleration '

g

'
(ln -(i g i i i ^ln-i ri|)
(D) none of these. (;- i; ri)
34. A particle is moving in the vertical plane. It is attached at one end of a string of length whose other end
is fixed. The velocity at the lowest point is u. The tension in the string is
T
and velocity of the particle is v
at any position. Then, which of the following quantity will remain constant.
( i +(i i n - ^lnii r | ;i i; i -i l i i î r li i li
l-i r | ln- l ( ^ u r | -i - ni(
T
nii li l-iln i i ( ^ v
r ni l - i i ili
l-ii ri î) :
(A) v T

(B) kinetic energy (C) Gravitational potential energy (D) v T

(A) v T

(B) ^ln +i (C) ^ -(i l-iln +i (D) v T

35. A solid conducting sphere of radius a is enclosed in a concentric shell of radius b > a. The charge on the inner
sphere is 3 C and on the conducting shell is 10 C. The potential difference between the conductors is V. If
+ 10 C additional charge is given to the outer shell, the new potential difference is
(lii a i -i i î i b > a lii i i i lii r i r | inl î 3 C i( i
r i i i i 10 C i( i r | ii i l(i(in V r | l iri i i i + 10 C lnln i( i
li i, ni i l(i(in ri î)
(A) V (B) V/2 (C) 2V (D) Zero (i )
36. In the circuit shown, the galvanometer shows zero current.
The value of resistance R is :(lii li - ^-(i-i- -
iii i -i i r ni lnii R i -i riî) :
(A) 1 O (B) 2 O
(C) 4 O (D) 9 O
37. The gravitational potential energy of a satellite revolving around the earth in circular orbit is 4 MJ. The additional
energy (in MJ) that should be given to the satellite so that it escapes from the gravitational field of earth is :
(Assume earth's gravitational force to be the only gravitational force on the satellite and no atmospheric resis-
tance).
((i ii i (-ii -ii - i- (i li ^r i ^--(i l-ini +i 4MJ r| ^r i i ^; lnln +i
i -i (MJ -), l r (i ^-(i -ii i i|)
(-ii r l ^r ( (i i ^-(i i ni r i i; (i-i lnii ri r|)
(A) 2 (B) 3 (C) 4 (D) 1
38. Figure shows a part of network of a capacitor and resistors.
The potential indicated at A, B and C are with respect to
the ground. The charge on the capacitor in steady state is:
B
A
C
2O
4O
8O
4O
+8V
+4V
+6V
1 F
10V
(l ^ li - iili i lni ii ni i ii^
liii î r | l A, B i C lii ^ l(i( iin
(i l-) i -i r | -iii (-ii - , iili i( i r |)
(A) 4 C (B) 6 C (C) 10 C (D) 16 C
STPFXII1213
Page - 57
39. The radius of a coil of wire with N turns is 0.22 m, and 3.5 A current flows clockwise in the coil as shown.
A long straight wire carrying a current 54A toward the left is located 0.05 m from the edge of the coil. The
magnetic field at the centre of the coil is zero tesla. The number of turns N in the coil are :
(N (ii i i lii 0.22 m r i ;- lii i l-iii(-i (clockwise) lii - iii (ilrn ri
ri r | ii ni i i li 0.05 m i i n - r , - ii n 54 A iii (ilrn
ri ri r | i i -i i i r | i - i i i i N r )
(A) 4 (B) 6 (C) 7 (D) 8
40. A long capillary tube of mass 20 mg, radius
t
2
mm and negligible thickness, is
partially immersed in a liquid of surface tension 0.1 N/m. Take angle of contact
zero and neglect buoyant force of liquid. The force required to hold
the tube vertically, will be - (g = 10 m/s
2
)
(-i 20 mg, lii
t
2
mm ( ^ -i -i; i i lii i i 0.1
N/m - ni( (i ( - i li i n r | -i i i i i n r
nii ( -i( i ^ -in r - i +( i
l i( i -i ri î `) (g = 10 -i., .
2
)
(A) 2 mN (B) 1 mN (C) 0.5 mN (D) 4 mN
41. Rigidity modulus of steel is q and its youngs modulus is Y. A piece of steel of crosssectional area A is
changed into a wire of length L and area A/10 then :
--i i ni ^ ii q nii ^ -i-ini ^ ii Y r | A -i i- -i i --i - i L i; nii
A / 10 -i i ni - i ini r | n
(A) Y increases and q decrease (B) Y and q remains the same
(C) both Y and q increase (D) both Y and q decrease
(A) Y î nii q i- î| (B) Y nii q -i r ^ |
(C) Y nii q i i ^ | (D) Y nii q i i i- ^ |
This section contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE THAN ONE is/are correct.
li l(- ri r (r)|
42. Figure shows two blocks A and B connected to an ideal pulley string system.
In this system when bodies are released then : (neglect friction and take g
= 10 m/s
2
)
li - ii i i l A nii B ii lii-i li r| ;
li - li i -n n r ni (iii i ^ -i nii
g = 10 -i.,.
2
)
(A) Acceleration of block A is 1 m/s
2
(A l i -(i 1 -i./ .
2
r |)
(B) Acceleration of block A is 2 m/s
2
(A l i -(i 2 -i./ .
2
r |)
(C) Tension in string connected to block B is 40 N
(B i -i - ni( 40 N r |)
(D) Tension in string connected to block B is 80 N
(B i -i - ni( 80 N r |)
STPFXII1213
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43. A beam of light having frequency v is incident on an initially neutral metal of work function | (hv > | ). Then
(i(l-i v i ii i | (hv > | ) (i iin (ii - i(lin) ilnn rini r ni)
(A) all emitted photoelectrons have kinetic energy equal to (hv |).
(ii -ln i-i ;-ii i ^ln +i (hv |) i riî|)
(B) all free electrons in the metal, that absorb photons of energy hv completely, may not be ejected out of
the metal. (iin - l-in ii -- ;-i i hv +i i-ii i ini i(iilin n r, iin ir
-ln ri ri n r|)
(C) after being emitted out of the metal, the kinetic energy of photoelectrons decreases continuously as
long as they are at a finite distance from metal. (iin ir -ln ri in i-i ;-i i ^ln
+i ln n n i-ni r n ( iin lln i rin r|)
(D) the emitted photo electrons move with constant speed after escaping from the field of metal.
(iin -ii ir l in -ln i-i ;-i ln i ^ln n r|)
44. In youngs double slit experiment, slits are arranged in such a way that besides central bright fringe, there
is only one bright fringe on either side of it. Slit separation d for the given condition cannot be (if is
wavelength of the light used) : ( ^ l,l i ^ - , l i i ; i (l-in li ini r l i
-ii l i(i, ( -ii l ; li n ni r | i - l-iln l l i
- i ri ri ni ( - ii i n ^ r ) :
(A) (B) /2 (C) 2 (D) 3/2
45. Both a point source of sound & an observer are at rest. If air starts blowoing then
((l i l -iin ( ini ii l-i r| l r(i ri ii ri ini r ni)
(A) The velocity of sound will change ((l i (^ l(lnn riî|)
(B) The frequency detected by the observer will change (ini ,ii i î i(l-i l(lnn riî|)
(C) The wavelength of sound will change ((l i n^ l(lnn riî|)
(D) The intensity of the sound will change. ((l i ni(ni l(lnn riî| )
SECTION - III
Comprehension Type
=r= - III
q r=r +r
4 l(- (A), (B), (C) nii (D) r , l- l ri r|
46 = 48 + | -e
A monoatomic ideal gas is filled in a nonconducting container. The gas can be compressed by a movable
nonconducting piston. The gas is compressed slowly to 12.5% of its initial volume.
-ii ii ^ i i ii - ii ini r | ^ i ^ln i i l-- iln
li i ni r | ^ i ili in 12.5% n ii ii iln li ini r |
46. The percentage increase in the temperature of the gas is : (^ ni - lnin (l,)
(A) 400% (B) 300% (C) 87.5% (D) 0%
47. The ratio of the initial adiabatic bulk modulus of the gas to the final value of adiabatic bulk modulus of the gas is
:

(^ ili ,i- in -i-ini îi i ln- ,i- in -i-ini îi ii in r)
(A) 32 (B) 1 (C) 1/32 (D) 1/4
STPFXII1213
Page - 59
48. The ratio of work done by the gas to the change in internal energy of the gas is :
(^ ,ii l ^ i i ^ i inl +i - l(n ii in r )
(A) 1 (B) 1 (C) (D) 0
49 = 51 + | -e
In the figure shown the loop placed in the plane of the paper has radius 'R', self inductance 'L' and zero resistance.
A uniform magnetic field B = B
0
sinet is applied (B
0
and e are positive constants) normal to the plane of the
paper. Initially the loop has zero current : (lin li - i^ n - i i lii 'R', -(-( 'L' nii i
lnii r| -i i -ii B = B
0
sinet (B
0
nii e ii-- lni r) i^ n (n iiln li ini
r| ii - - i iii r|)
49. Direction of current in the loop at t =
e
t
3
: (t =
e
t
3
- iii i lii riî) :
(A) clockwise (l-iii(n )
(B) anticlockwise ((i-i(n)
(C) no current will flow at that time ( - i; iii (ilrn ri riî)
(D) cannot be determined (îi ri n)
50. The current in the loop at time t =
e
t
6
5
is : (t =
e
t
6
5
- - iii riî) :
(A)
L 2
R B
2
0
t
clockwise (l-iii(n) (B)
L 2
R B
2
0
t
anticlockwise ((i-i(n)
(C)
L 2
R B 3
2
0
t
clockwise (l-iii(n) (D)
L 2
R B 3
2
0
t
anticlockwise ((i-i(n)
51. The magnitude of self induced emf in the loop will : ( - -(ln l(nn (ir i l-ii)
(A) depend on value of L (L -i li riî|) (B) not depend on value of R (R -i li ri riî|)
(C) not depend on B
0
(B
0
li ri riî|) (D) depend on B
0
(B
0
li riî|)
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
STPFXII1213
Page - 60
52. Two identical uniform solid smooth spheres each of mass m each approach each other with constant velocities
such that net momentum of system of both spheres is zero. The speed of each sphere before collision is u. Both
the spheres then collide. The condition of collision is given for each situation of column-I. In each situation of
column-II information regarding speed of sphere(s) is given after the collision is over. Match the condition of
collision in column-I with statements in column-II.
i - -i l îii î li - i -i m r i n ln (î ; nr i
i r r l ii î li i lii-i (^ i r| - î i - ( i u r| ii î n -in r|
- i in -ni-I i - l-iln l i ^; r| -ni-II i - l-iln - - i-- ri i i i i
^; r| - i in i l -ni-I - i ^; r (r -ni-II - l ^ (ni -ln i|
Column- Column-
(A) Collision is perfectly elastic and head on (p) speed of both spheres after collision is u
(B) Collision is perfectly elastic and oblique (q) velocity of both spheres after
collision is different
(C) Coefficient of restitution is e =
2
1
and (r) speed of both spheres after collision
collision is head on is same but less than u.
(D) Coefficient of restitution is e =
2
1
and (s) speed of one sphere may be more than u.
collision is oblique
n--r- n--r-
(A) - i ni -i-i r ( - i r (p) - i i i î i i i u r |
(B) - i ni -i-i r ( ln r (q) - i i i î i ( ^
^ ^ r
(C) - i -i(-i e =
2
1
nii (r) - i i i î i i i -i r
- - i r | u - r |
(D) - i -i(-i ^ ii e =
2
1
(s) î i i u li ri
nii - ln r | ii ni r |
PART - III
53. Which has maximum internal energy at 290 K ? (290 K lin- inl +i li rini r `)
(A) Neon gas (li ^) (B) Nitrogen gas (i;-i ^)
(C) Ozone gas (ii ^) (D) Equal (-i)
54. 2.5 L of a sample of a gas at 27C and 1 bar pressure is compressed to a volume of 500 mL keeping the
temperature constant, the percentage increase in pressure is :
27C ni i 1 i i ^ 2.5 L - i 500 mL in n -iiln n r, l- ni ln rni
r, n i - ln % (l, riî|
(A) 100 % (B) 400 % (C) 500% (D) 80%
STPFXII1213
Page - 61
55. Which of the following contains the greatest number of atoms ? (l - i -ii i lin- i ini r`)
(A) 1.0 g of butane (C
4
H
10
) (1.0 g - (C
4
H
10
) (B) 1.0 g of nitrogen (N
2
) (1.0 g i;-i (N
2
)
(C) 1.0 g of silver (Ag) (1.0 g l-( (Ag) (D) 1.0 g of water (H
2
O) (1.0 g (H
2
O)
56. Select the correct statement : (ri i l )
(A) Perxenate ion is [XeO
6
]
4
with octahedral geometry. (l - i [XeO
6
]
4
i il-ln -i r )
(B) XeF
2
is bent molecule with 3 lone pairs (l.p) (3 ii - (l.p.) ii XeF
2
- i r ; iln i i r )
(C) XeOF
4
, XeF
4
, XeO
2
F
2
all contains one lone pair only (XeOF
4
, XeF
4
, XeO
2
F
2
ii ( ii - in r)
(D) None of these (;- i ; ri )
57. In electrolysis of Al
2
O
3
by Hall-Heroult process : (riri-- l(li ,ii Al
2
O
3
l(nn i- - )
(A) cryolite Na
3
[AlF
6
] lowers the melting point of Al
2
O
3
and increases its electrical conductivity.
>iii;- Na
3
[AlF
6
], Al
2
O
3
î i - ni r nii ;i l(nn ini i ini r|
(B) Al is obtained at cathode and probably CO
2
at anode
Al ii in rini r nii i(ni CO
2
i in rini r|
(C) both (A) and (B) are correct ((A) nii (B) ii ri ri r|)
(D) none of the above is correct ( in - i; ri|)
58. The correct IUPAC name of the complex:
l i ri IUPAC i- r
C = N
OH
OH
H
3
C
C = N
H
3
C
CoCl
2
is :
(A) Dichloridodimethylglyoximecobalt(II) (i;iii i; -lii;il-ii--(II)
(B) Bis(dimethyglyoxime)dichloridocobalt(II) (l (i;-lii;il-)i;iiiii-- (II)
(C) Dimethylglyoximecobalt(II) chloride (i;-lii;il-ii--(II) ii;)
(D) Dichlorido(dimethylglyoximato)cobalt(II) (i;i ii l(i;-lii;il--N, N)-ii--(II)
59. Observe each pair of cations. In which case (s) first is more stable than the second :
l ii -i i -ii il| ;- l - - ri ii i -ii li -iii r :
(W) , (X) ,
(Y) , (Z) ,
(A) Only in W (B) Only in X and Y (C) Only in Z (D) Only in W and Z
STPFXII1213
Page - 62
60. The solvolysis in aqueous acetone is fastest in,
i i-i - ni( l(iii l>i ni r|
(A) (B) (C) (D)
61. Which of the following reaction is not feasible ?
ii lil>i i( ri r `
(A)

4
LiAlH

(B)

3
NaHCO
+ CO
2
| + H
2
O
(C)

HCl
Cl
O
(D)
3
3
3
CH
|
Br C CH
|
CH

ether / Na

2 3
3
CH C CH
|
CH
= +
3
3
3
CH
|
H C CH
|
CH
This section contains 2 multiple correct answer(s) type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE THAN ONE is/are correct.
li l(- ri r (r)|
62. Given
E
Ag Ag
+
/
= 0.80V,
E
Mg Mg
2+
/
= 2.37V, , E
Cu Cu
2+
/
= 0.34V,
E
Hg Hg
2+
/
= 0.79 V..
Which of the following statements is/are correct
li î r|
E
Ag Ag
+
/
= 0.80V,
E
Mg Mg
2+
/
= 2.37V, , E
Cu Cu
2+
/
= 0.34V,
E
Hg Hg
2+
/
= 0.79 V r|
lllin - ii,i i - r|
(A) AgNO
3
can be stored in copper vessel (AgNO
3
i i ii - i n r|)
(B) Mg(NO
3
)
2
can be stored in copper vessel (Mg(NO
3
)
2
i i ii - i n r)
(C) CuCl
2
can be stored in silver vessel (CuCl
2
i l-( ii - i n r|)
(D) HgCl
2
can be stored in copper vessel (HgCl
2
i i ii - i n r|)
STPFXII1213
Page - 63
63. Which of the following compounds will have C
2
axis of symmetry.
l - i ilî - C
2
-l-ni i -i l-in r|
(A) (B) (C) (D)
SECTION - III
Comprehension Type
=r= - III
q r=r +r
4 l(- (A), (B), (C) nii (D) r , l- l ri r|
64 = 66 + | -e
Compound (X) (C
8
H
7
N) on treatment with cold SnCl
2
/dil.HCl (aqueous), produces Y (C
8
H
8
O). (Y) on heating
with sodium acetate in acetic anhydride followed by acidification forms (Z) (C
10
H
10
O
2
). All these compounds
(X,Y,Z) on oxidation under severe conditions form a diacid which gives only one mononitro isomer in nitrating
mixture.
il^ (X) (C
8
H
7
N) i lil>i - SnCl
2
/n HCl (i), i Y (C
8
H
8
O) in rini r| (Y) i il-
ri;i; - il- i-- ii ^- nii ii il^ (Z) (C
10
H
10
O
2
) in rini r| ii
il^ (X,Y,Z) i l- ll-ilni - iii i;l in r i l i;-ii l-i lil>i
( -iii;-i -i((i n r|
64. The reductive ozonolysis products of (Z) are :
(Z) i i iii i- in -i riî
(A)
CH
3
CHO
+ CHO
COOH
(B) CHO H C
3
+
COOH
COOH
(C)
COOH
CHO
COOH +
CH
3
(D) CHO + H C
3
COOH
CHO
65. What is not true about (Y) ? ((Y) l i ri ri r `)
(A) It can give cannizzaro reaction ( lii lil>i ni r|)
(B) It gives Iodoform test positive ( iii- i-ii ii-- ni r|)
(C) It gives Tollen's test positive ( -i i-ii ii-- ni r|)
(D) It gives 2, 4-DNP test positive ( 2, 4-DNP i-ii ii-- ni r|)
STPFXII1213
Page - 64
66. (X) + CO
2
The compound W is :
(X)
ili i-
+ CO
2
il^ W r
(A) (B)
(C) (D)
p q r s
p q r s
p q r s
p q r s
A
B
C
D
p q r s
67. Match each of the reactions given in column I with the corresponding product(s) given in column II.
+r= I - l ^ - lil>i i +r= II - l ^ ^n -i,-ii ii - il|
Column I Column II
+r= I +r= II
(A) Cu + dil HNO
3
(p) NO
(B) Cu + conc HNO
3
(q) NO
2
(C) Zn + dil HNO
3
(r) N
2
O
(D) Zn + conc HNO
3
(s) Cu(NO
3
)
2
/ Zn(NO
3
)
2
STPFXII1213
Page - 65
ANSWER KEY TO SAMPLE TEST PAPER-III
1. B 2. A 3. B 4. D 5. A 6. C 7. A
8. B 9. B 10. B 11. A 12. B 13. A 14. C
15. B 16. ABC 17. BC 18. ABD 19. CD 20. ABD 21. C
22. C 23. D 24. B 25. C 26. A 27. B 28. A
29. B 30. C
31. (A) (q), (B) (s), (C) (p), (D) (r)
32. A 33. D 34. A 35. A 36. A 37. A 38. A
39. A 40. B 41. B 42. B,D 43. B,.C 44. B,C 45. A,C
46. B 47. C 48. B 49. B 50. B 51. D
52. (A) p,q ; (B) p,q ; (C) q,r ; (D) q,r
53. C 54. B 55. A 56. A 57. C
58. A 59. D 60. A 61. C 62. BC
63. ABCD 64. D 65. B 66. A
67. A p, s ; Bq, s ; C r, s ; D q, s
HINTS & SOLUTION TO SAMPLE TEST PAPER-III
1. y + x = e
xy

dx
dy
+ 1 = e
xy

)
`
+ y
dx
dy
x
Now for horizontal tangent ( -iln -i ii l)
dx
dy
= 0 1 = e
xy
(y) .........(1)
Hence option (B) is satisfying the relation(i) (n l(- (B) i (i) i n- ni r|)
2. a
|| ( c b

)
so a
perpendicular to b
, a
perpendicular to c
(n a
, b
(n r , a
, c
(n r| )
) c a (
.
) b a (

=
2 1
n
| c | | a | n
| b | | a |

.
b
1
=
=
2 1
2
n
| c || b | | a |
.
2
=
= |
a
|
2
) c b (

.
3. x
2
+ y
2
+ 4x + 6y
3
1
= 0
p =
3
1
2 . 6 1 . 4 4 1 + + +
=
3
62
3p
2
= 62
5. Given expression = 8 cos
2
x (cos
2
x 1) (4cos
3
x 3cosx) + 1
= 8 cos
2
x sin
2
x cos 3x + 1
= 1 2sin
2
2x cos 3x
= cos 4x cos 3x
9. 4 sin
2
x + 3 cos
2
x 24 (sin
2
x
+ cos
2
x
)
= 3 + sin
2
x 24 (sin
2
x
+ cos
2
x
)
STPFXII1213
Page - 66
Let sin
2
x
+ cos
2
x
= t. Then t
2
= 1 + sin x, 1 s t s 2 and the expression becomes
(-iil sin
2
x
+ cos
2
x
= t r, ni t
2
= 1 + sin x, 1 s t s 2 nii l - l(lnn ri ini r|)
3 + (t
2
1)
2
24t = t
4
2t
2
24t + 4
Let (-iil) f(t) = t
4
2t
2
24t + 4
f'(t) = 4t
3
4t 24 = 4(t 2) (t
2
+ 2t + 3) < 0 { 1 s t s 2 }
f(t) is a decreasing function. (f(t) ri-i r|)
minimum value of f(t) is at t = 2 and minimum value = 4 (1 6 2 )
(t = 2 f(t) i n- -i = 4 (1 6 2 ))
maximum value of f(t) is at t = 1 and maximum value = 21
(t = 1 f(t) i lin- -i = 21)
10. Let m be the smallest of the choosen numbers and d be the common difference.
then m + 2d s 2n
1 s d s (

2
m n 2
where [ . ] is the greatest integer function.
For a given value of m, the number of choices of d is (

2
m n 2
The total number of ways =
=
(

2 n 2
1 m
2
m n 2
= (n 1) + (n 1) + (n 2) + (n 2) + .....+ 1 + 1
= 2{(n 1) + (n 2) + .... + 1} = n(n 1)
11. Let I = }
+
2
x x ) x 1 (
dx
Put 1 +
x
=
t
1
x 2
1
dx =
2
t
1
dt
I =
}
|
.
|
\
|

2
1
t
1
1
t
1
1

2
t
dt 2
=
}

1 t 2
dt 2
=
1 t 2 2
+ c = 2
1
x 1
2
+
+C
= 2
x 1
x 1
+
= 2
x 1
1 x
.
12. Given circles are
x
2
+ y
2
= 1 ..... (1)
x
2
+ y
2
= 9 ..... (2)
P
1
3
C
From the figure, CP =
9 1+
=
10
the locus is x
2
+ y
2
= 10
a = 10
STPFXII1213
Page - 67
13. S'P + SP = 2a
a = 1 2 +
2ae = SS' = 2 e =
1 2
14. The number of ways choosing 3 numbers from 1,2,.......10 is
10
C
3
= 120
if 3 < a < b, the number of ways of chosing a, b is
7
C
2
= 21
if c < d < 7, the number of ways of chosing c, d is
6
C
2
= 15
if 3 < e < 7, there are 3 numbers for e the required probability =
120
3 15 21+
=
40
11
15.
(
(
(
0 0 1
0 1 0
1 0 0

(
(
(
0 0 1
0 1 0
1 0 0
=
(
(
(
1 0 0
0 1 0
0 0 1
16. Applying C
1
C
1
+ C
2

+ C
3

, we get
x 2 sin 1 x cos x 2 sin 2
x 2 sin x cos 1 x 2 sin 2
x 2 sin x cos x 2 sin 2
2
2
2
+ +
+ +
+
=
1 0 0
0 1 0
2
+
(Applying R
2
R
2
R
1
, R
3
R
3
R
1
)
= 2 + sin2x
o = 3, | = 1
Now, o | = 2, o + | = 4 and o + 3| = 6. Thus (o |) + (o + |) = 6 = (o + 3|)
So, o | , o + | , o + 3| cannot form a triangle.
C
1
C
1
+ C
2

+ C
3

i i^
x 2 sin 1 x cos x 2 sin 2
x 2 sin x cos 1 x 2 sin 2
2
2
2
+ +
+ +
+
=
1 0 0
0 1 0
2
+
(R
2
R
2
R
1
, R
3
R
3
R
1
i^ )
= 2 + sin2x
o = 3, | = 1
o | = 2, o + | = 4 nii o + 3| = 6. n (o |) + (o + |) = 6 = (o + 3|)
n o | , o + | , o + 3| lii ri i ni r|
17. g'(x) = 2x { f'(x
2
) f'(1 x
2
) }
Since f'(x) is decreasing ( l f'(x) ri-i r |)
hence for (n) x
2
< 1 x
2
x <
2
1
, g'(x) > 0
x
2
> 1 x
2
x >
2
1
, g'(x) < 0
decreasing in
|
|
.
|
\
|
1 ,
2
1
and increasing in
|
|
.
|
\
|
2
1
, 0
(
|
|
.
|
\
|
1 ,
2
1
- ri-i r nii
|
|
.
|
\
|
2
1
, 0
- (i -i r |)
18. x
dx
dy
+
dx
dy
3
= x
2
x
2
dx
dy
|
.
|
\
|
x
2

dx
dy
+ 3 = 0
it is of order 1, degree 2 and is non linear
STPFXII1213
Page - 68
19. Equation of straight lines is ( ii i -ii)
(y x + 2) ( y + x 2) = 0 ....(1)
y
2
(x 2)
2
= 0 y
2
x
2
+ 4x 4 = 0
Let equation of line passing through (3, 0) is (r (3, 0) ^ni r|)
y = mx 3m ....(2)
Homogenising (1) with the help of (2), we get (-ii (1) i (2) i rini -iin i )
y
2
x
2
+ 4x
|
.
|
\
|
m 3
mx y
4
2
m 3
mx y
|
.
|
\
|
= 0
Now, coefficient of x
2
+ coefficient of y
2
= 0 (x
2
i îi + y
2
i îi = 0)
m 3
m 4
+
2
m 9
4
(1 + m
2
) = 0
3
4

2
m 9
4
(1 + m
2
) = 0 m =
2
1
21. t = 2
x
t
2
at a + 3 = 0
2
2
a
t |
.
|
\
|
=
4
a
2
+ a 3 =
4
) 2 a )( 6 a ( +
> 0
a e (, 6] [2, )
t =
2
) 2 a )( 6 a ( a +
= 2
x
> 0
a cannot be negative and a > 2
Sol. (22, 23, 24)
Augmented matrix is
(
(
(

2 3 1
3 3 2
1 1 1 1
1 3 3
1 2 2
R R R
R 2 R R
,
~
(
(
(
+

3 2 1 0
5 2 5 0
1 1 1 1

+

2 3 3
R
5
1
R R

(
(
(
(
+
+

) 1 ( 3 ) 2 (
5
1
2 0 0
5 2 5 0
1 1 1 1
~
(
(
(
(
(

2
5
12
0 0
5 2 5 0
1 1 1 1
2
unique solution if
2
12 = 0 = 4, 3
If = 3 or 4, then
(
(
(

2 0 0 0
5 2 5 0
1 1 1 1
no solution
there is no value of for which the given system of equations has infinite solutions
STPFXII1213
Page - 69
25. Let A d, A, A + d be roots
A d + A + A + d = b A =
3
b
must satisfy g(x) = 0
27
b
3

9
b
3
+
3
ab
1 = 0
9ab = 2b
3
+ 27
26. a + b = 1, ab = 2, a
2
+ b
2
+ 2ab = 1 a
2
+ b
2
= 3
f(x) . g(x) = x
6
(a + b) x
5
+ (a + b + ab) x
4
(a
2
+ b
2
+ 2) x
3
+ (a + b + ab) x
2
(a + b) x + 1
= x
6
+ x
5
+ x
4
+ x
3
+ x
2
+ x + 1
27. f(x) = x
3
ax
2
bx + 1 = 0
o + | =
a
b
, o| =
a
1
o + | = 1
a
1
, o| =
a
1
Given
o|
| + o
2 2
=
3
4
3
o|
o| | + o 2 ) (
2
=
3
4
a
1
a
1
2
a
1
1
2
|
.
|
\
|

=
3
4
1 + 2 .
a
1
+
2
a
1
2 .
a
1
=
a 3
4
1 +
2
a
1
=
a 3
4
3a
2
+ 3 = 4a 3x
2
4x + 3 = 0 is required equation
28. Probability =
3
20
1
9
2
8
C
C . C
=
18 . 19 . 20
3 . 9 . 7 . 8
=
95
21
29. Probability =
3
20
1
9
1
3
1
8
C
C . C . C
=
18 . 19 . 20
6 . 9 . 3 . 8
=
95
18
30. P(BRW) =
20
8
.
19
3
.
18
9
=
95
3
31. (A) Required = 2
7
= 128
(B)
2
C
2
+
3
C
2
+
4
C
2
+ ............ +
11
C
2
=
3
C
3
+
3
C
2
+ ........ +
11
C
2
=
12
C
3
= 220
(C) Required = selecting 5 digits out of 9 =
9
C
5
= 126
(D)
17
C
r
(x
2
)
17 r

r
3
x
1
|
.
|
\
|
r =
5
24 2 17
= 2
17
C
2
= 136
STPFXII1213
Page - 70
32. V
R/G(x)
= 0 , V
R/G(y)
= 10 m/s
Let, velocity of man = v
-ii l i-i i (^ = v
tan u =
12
16
=
3
4
then, v
R/man
= v (opposite to man)
12 cm
1
6

c
m
u
For the required condition :
n, v
R/man
= v (i-i l(ln)
i ^; l-iln l :
tan u =
) x ( M / R
) y ( M / R
V
V
=
v
10
=
3
4
V =
4
3 x 10
= 7.5 Ans.
34. The tension vector T
is always normal to velocity vector. Hence v T

is always zero.
A is correct choice.
35. The potential difference between the two conductors (i ii i l(i(in)
AV =
0
1
4
Q
e t
|
.
|
\
|

b
1
a
1
is independent of the charge on the outer shell. (i l iri i i i( i -(ni r |)
Q
1
Q
2
a
b
Potential difference will remain same. (;l l(i(in -i r î|)
36.
If pot. drop between A and B is also 2V, then no currrent will pass through the gelvanomter.
Pot. drop across R =
|
.
|
\
|
+ 5 R
12
R = 2
12 R = 2R + 10
R = 1 O
37. PE = 4 MJ
TE = 2MJ
The additional energy required to make the satellite escape = +2MJ.
^ r i l lnln +i = +2MJ.
38.
4V 6V 6V
4O 2O 4O
8O
1F 10V

6V
1O
8O
1F 10V
E =
4
1
2
1
4
1
4
4
2
6
4
8
+ +
+ +
= 6 V; Q = 4V 1F = 4C
39.
) r d ( 2
i .
1 0
+ t
=
r 2
i N
2 0

N =
2
1
i
i
.
) r d (
r
+ t
=
5 . 3
54
.
) 27 . 0 ( 22
7 22 . 0
= 4
STPFXII1213
Page - 71
40. The free body diagram of the capillary tube is as shown in the figure. Net force F required to hold tube is
(i lii i i ii li ii i î r | - i r l F r )
F = force due to surface tension at cross-section ( -i i- - ni( ii )
(S
1
+ S
2
) + weight of tube (- i ii)
F
Free body daigram
of capillary tube
T2 R t
mg
S
1
S
2
T2 R t
F
lii i
ii li
T2 R t
mg
S
1
S
2
T2 R t
= (2tRT + 2tRT) + mg = 4tRT + mg
= 4t
t
2
10
3
0.1 + 20 10
6
10 = 1 mN
41. q and Y are properties of material.
These coefficients are independent of geometry of body.
42. Applying NLM on 40 kg block
40 lî l - l- î
400 4T = 40 a
For 10 kg block T = 10.4 a
Solving a = 2m/s
2
40kg
10kg
4a
T
2T
2T
4T
a
10kg
4a
T
2T
2T
4T
a
10kg
4a
T
2T
2T
4T
a
10 lî. l l T = 10(4 a)
r a = 2m/s
2
T = 80 N
43. (A) All emitted photo electrons have kinetic energies ranging from 0 to hn f
0
. Hence false.
(B) Some free electron may lose energy within metal due to collision and cannot escape the metal. Hence
true.
(C) Since metal is positively charged it will attracted emitted photoelectrons. Hence true.
(A) ii -ln i-i ;-ii i ^ln +i 0 hv |
0
i - rini r| n (n ^n r|
(B) iin - l-in -- ;-ii i - in +i - ril ri ni r nii iin ir ri l n r|
n (n - r|
(C) l iin ii-- i(lin r r -ln i-i ;-ii i ilin î n (n - r|
44. d sinu =
For first bright fringe. (There will be one bright fringe on both sides of central bright fringe and both are
called first bright fringe.)
i- -ii l l ( i l i i i -ii l ri -ii l rini r |)
sinu =
1
d
s
d > .
If d = 2, two maxima will be formed.
l d = 2 r ni i l- ^|
STPFXII1213
Page - 72
46. Let initial temperature and volume be T
0
and V
0
. Since the process is adiabatic, the final temperature and
volume is TV
1
= T
0
V
0
1
( =
3
5
for monoatomic gas)
T =
3
2
0
0
0
8 / V
V
T
|
|
.
|
\
|
= 4T
0
percentage increase in temperature of gas is
4 100 100 = 300%
-ii ili ni ( in T
0
( V
0
r | l >- ,i - r n ln- ni ( lnin - i
TV
1
= T
0
V
0
1
( =
3
5
-ii ^ l)
T =
3
2
0
0
0
8 / V
V
T
|
|
.
|
\
|
= 4T
0
^ ni - lnin (l,
4 100 100 = 300%
47. Adiabatic Bulk modulus B = V
dV
dP
= P =
v
nRT
,i - in -i-in ^ ii B = V
dV
dP
= P =
v
nRT

T
V
V
T
B
B
0
0
f
i
=
=
0
0
0
0
T 4
8 / V
V
T
=
32
1
48. For adiabatic process dQ = 0
,i - >- - dQ = 0
dU + dW = 0 or
dU
dW
= 1.
49. at t =
e
t
3
, B is increasing in inward direction
t =
e
t
3
, B i i ri r
50. | = Li
at t =
e
t
6
5
| = BA
| = B
0
sin e
e
t
6
5
. tR
2
|

=

2
B0
.
tR
2
= Li i =
L 2
R B
2
0t
52. In all cases speed of balls after collision will be same. In case of elastic collision speed of both balls after
collision will be u, otherwise it will be less than u.
STPFXII1213
Page - 73
ii l-ilni - - i ^ i i i -i ri î| - l-iln - -i-i - i i i ^ i i i
u r ii r u - ri î|
53. Internal energy of a gas (^ i ilnl +i) =
2
f
nRT
Internal energy of a gas (^ i ilnl +i) f
54. Using (i^) p
1
V
1
= P
2
V
2
1 2.5 = 0.5 P
2
= 5 bar.
% increase in pressure (% i - (l,) =
bar 1
bar ) 1 5 (
100% = 400 %.
55. Compound mole of molecule mole of atom No. of atom
r |n+ r + =r =rr + =r =rr +| ==r
C
4
H
10
58
1
14
58
1
58
14
N
A
N
2
28
1
2
28
1
14
1
N
A
Ag
108
1
108
1
108
1
N
A
H
2
O
18
1
3
18
1
6
N
A
Hence C
4
H
10
has maximum number of atoms. (n C
4
H
10
-ii i lin- i ini r|)
56.
Xe
O
O
O
O
O
O
Perxenate ion [XeO ]
6
4-
Xe
F
F
XeF (Linear)
2
Xe
F
F
F
F
XeOF (one l.p.)
4
O
Xe
F
F
F
F
XeOF (one l.p.)
4
Xe
F
O
O
F
XeO F (one l.p.)
2 2
STPFXII1213
Page - 74
57. Na
3
[AlF
6
] 3NaF + AlF
3
NaF and AlF
3
both are ionic compounds and so ionise to give ions. This increases the electrical conductivity
and lowers the melting point of Al
2
O
3
.
At cathode : Al
3+
(melt) + 3e
Al.
At anode : C(s) + O
2
(melt) CO (g) + 2e
; C(s) + 2O
2
(melt) CO
2
(g) + 4e
.
Na
3
[AlF
6
] 3NaF + AlF
3
NaF, AlF
3
ii il il^ r i iln ri i n r| ;l l(nn ini in r| nii Al
2
O
3
î
l i - n r|
ii : Al
3+
(^ln) + 3e
Al.
i C(s) + O
2
(^ln) CO (g) + 2e
; C(s) + 2O
2
(^ln) CO
2
(g) + 4e
.
58. Correct name is dichloridodimethylglyoximatecobalt (II)
ri i- i;iiii; -lii;il-i i--(II)
59. In (W) since CH bond is weaker than CD bond so hyperconjugation stability is more in I.
In (X) only +I effect is present which is more for C(CD
3
).
In (Y) only +I which is more for CD
3
In (Z) I effect of CCl
3
group will make II cation highly unstable.
(W) - CH i CD i rini r, ;l ln- -iii-( I - li riî|
(X) - ( +I ii( l-in r, ;l C(CD
3
) i ii( li riî|
(Y) - ( +I ii( l-in r, ;l CD
3
i ii( li riî|
(Z) - CCl
3
i I ii( r, ;l II ii -li -ii; riî|
60. (Most stable carbocation)
61. (A) is feasible ((A) i( r|)
(B) is feasible. ((B) i( r|)
(C) is not feasible. ((C) i( ri r|)
(D) is feasible by product in Wurtz reaction. ((D) (- lil>i - r -i i( r|)
STPFXII1213
Page - 75
62. Lower S.R.P. containing ion can displace higher S.R.P. containing ion.
n- -i l(i( n i n- -i l(i( n i i l(-iiln ni r|
64.
66.
67. (A) 3Cu + 8HNO
3
(dilute HNO
3
)

2NO + Cu(NO
3
)
2
+ 4H
2
O
(B) Cu + 4HNO
3
(concentrated)

2NO
2
+ Cu(NO
3
)
2
+ 2H
2
O
(C) 4Zn + 10HNO
3
(dilute)

4Zn(NO
3
)
2
+ N
2
O + 5H
2
O
(D) Zn + 4HNO
3
(concentrated)

Zn(NO
3
)
2
+ 2NO
2
+ 2H
2
O
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Academic Session : 2012-13

Practice, Persistence and Performance

; ionic size (il ii)

12. The value of

Paragraph for Question Nos. 28 to 30

(B) (3, 2) (C) (1, 0) (D)

SECTION - IV (=r=- IV)

. The time after which the velocity vector and

li ini r| (r - nin i (^ li,-(i li - (n ri)

= resultant force and v

= constant (p) path will be circular path

= constant (q) speed will increase

all the time and |

| = constant (r) path will be straight line

and acceleration at all time j

(s) path will be parabolic

Sol. (22 to 24)

. Hence initial velocity is in same direction of constant acceleration, therefore

ii n ni--ili ( ^ r- ii (n ri ^i| n i ln ri ^i| nii | F |

n ili ( ^ ln -(i i lii - ri ri ^i| n i iii ii - ni i

are two non-collinear vectors such that a

20. Let f(x) =

and velocity of the particle is v

(B) kinetic energy (C) Gravitational potential energy (D) v T

(B) ^ln +i (C) ^ -(i l-iln +i (D) v T

is always normal to velocity vector. Hence v T

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