K C CALCULATIONS

1) Calculate Kc for the following equilibrium at a particular temperature, given the results of an analysis of the equilibrium mixture which show that the concentration of SO2 = 0.23, O2 = 1.37, and SO3 = 0.92 mol dm -3. 2 SO2(g) + O2(g) 2 SO3(g) 2) Some PCl5 was heated in a sealed container at 250C, resulting in the following equilibrium. Analysis of the equilibrium mixture showed that it contained 0.0042 moles of PCl5, 0.040 moles of PCl3 and 0.040 moles of Cl2. The total volume was 2.0 dm 3. Calculate the concentration of each species at equilibrium and then Kc. PCl5(g) Cl2(g) + PCl3(g) 3) 2.0 moles of PCl5 vapour are heated to 500 K in a vessel of volume 20 dm 3. The equilibrium mixture contains 1.2 moles of chlorine. Calculate Kc for the equilibrium at 500K. PCl5(g) PCl3(g) + Cl2(g) 4) The following equilibrium is established at 444C when 1.0 mol of HI is contained. It is found that the HI has undergone 22% dissociation. Calculate Kc . 2 HI(g) H2(g) + I2(g) An aqueous solution is made by dissolving 1.0 moles of AgNO 3 and 1.0 moles of FeSO4 in water and making up to 1.00 dm 3. When equilibrium is established, there was found to be 0.44 moles of Ag+. Calculate Kc. Ag+(aq) + Fe2+(aq) 7) Ag(s) + Fe3+(aq) 7) 200.0 g of ethyl ethanoate and 7.0 g of water were refluxed together. At equilibrium, the mixture contained 0.25 mol of ethanoic acid. Calculate K c for the hydrolysis of ethyl ethanoate. CH3COOCH2CH3(l) + H2O(l) CH3COOH(l) + CH3CH2OH(l) 8) When 1.0 moles of steam and 1.0 moles of carbon monoxide were allowed to reach equilibrium, 33.3 % of the equilibrium volume is hydrogen. Calculate K c at this temperature (you will need to think very carefully about equilibrium quantities). H2O(g) + CO(g) H2(g) + CO2(g) 8) 5) 4) 1)

K p CALCULATIONS
1.0 moles of PCl5 vapour are heated to 500 K in a sealed vessel. The equilibrium mixture, at a pressure of 625 kPa, contains 0.6 moles of chlorine. Calculate Kp. PCl5(g) PCl3(g) + Cl2(g) A mixture of 1.9 moles of H2 and 1.9 moles of I 2 were allowed to reach equilibrium at 710 K. The equilibrium mixture was found to contain 3.00 moles of HI. Calculate Kp. H2(g) + I2(g) 2 HI(g) 3) For the equilibrium below calculate Kp if pO2 = 100 kPa, pSO 2 = 250 kPa, pSO 3 = 500 kPa. 2 SO2(g) + O2(g) 2 SO3(g) 2 moles of sulphur dioxide and 1 mole of oxygen were mixed and allowed to reach equilibrium in the presence of a suitable catalyst under a total pressure of 500000 Pa. At equilibrium, 0.67 moles of oxygen were present. Find Kp. 2 SO2(g) + O2(g) 2 SO3(g) 2 moles of X was heated to a temperature of 2000C until equilibrium was established under a total pressure of 8 x 107 Nm -2. At equilibrium, X was found to have undergone 20% dissociation. Calculate Kp. X(g) Y(g) + 2 Z(g) 6) 2 moles of A was mixed with 2 moles of B and the mixture allowed to reach equilibrium at 500C. The equilibrium mixture was found to contain 1 mole of A. Calculate Kp. 2 A(g) + B(g) 3 C(g) In the following reaction at 700 K, the amount of each gas present at equilibrium is 0.96 moles of NO2, 0.04 moles of NO, and 0.02 moles of O2. If Kp = 6.8 x 10-6 atm, what must the total pressure have been to achieve this particular equilibrium mixture? 2 NO2(g) 2 NO(g) + O2(g) Calculate the number of moles of each species at equilibrium if 5 moles of CO 2 and 1 mole of H2 are mixed at 1000 K, given that Kp = 0.72 at this temperature (you will need to use a quadratic equation to solve this). CO2(g) + H2(g) CO(g) + H2O(g)

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