CNG TY TNHH ORGANO (VIT NAM)

CNG

PHIU AN TON HA CHT

SN PHM : ST III ClORUA

PHN 1: NHN DNG V SN PHM/CHT PHA CH CA CNG TY/CNG TY KINH DOANH

1.1

Nhn dng sn phm

Tn sn phm

St III Clorua

K hiu : St Clo, St iii Clo

Cng thc phn t : FeCl3
S CAS .: 7705-08-0
1.2 Cng ty cung cp/nhn dng kinh doanh
1.3 Cng ty cung cp
CNG TY TNHH ORGANO VIT NAM

PHN 2: THNH PHN/THNG TIN V THNH PHN CC CHT

Thnh phn
---------------------------------------

S CAS
------------

c hi
---------

St Clo

7705-08-0

PHN 3 : NHN DNG TNH C HI

Tng quan c hi
-------------------------NGUY HIM! N MN. GY CHY BT KZ B PHN NO TIP XC. C HI NU NUT PHI HOC HT
VO. NH HNG N GAN
D LIU SAF-T- (tm) Phn loi (Cung cp thun tin cho vic phn loi)
----------------------------------------------------------------------------------------------------------Phn loi sc khe: 3 - Nghim trng (Cuc sng)
Phn loi tnh chy: 0 - khng
Phn loi tnh phn ng: 2 Trung bnh
Phn loi tnh tip xc: 3 Nghim trng (n mn )
Thit b bo v Phng Th Nghim: TM CHN BO V, TP D V O KHOT PHNG TH
NGHIM; M TRM U C L THNG ; GNG TAY CAO SU
M s mu sc lu kho: mu trng (n mn)
----------------------------------------------------------------------------------------------------------Cc tc ng sc khe tim tng
----------------------------------

Ht vo:
Ph hy nng cc cc mng nhy v h h hp trn . Triu chng bao gm cm gic
nng, ho, th kh kh, vim thanh qun, th dc, au u, bun nn v nn
n mn. Nu t phi c th gy rt m ing, c h ng, d dy. C th gy v im h ng, n n
v tiu chy . L iu lng nh th t c nhng liu ln ( 30m g/ kg) c th gy bu n
n n, n n v tiu ch y . Vic i m u h ng urine l m t ch s mnh c a ng c s t.
P h hy gan, h n m v tip theo c th gy t vo ng, th i gian bnh c th l 3
ngy.
Tip xc vi da
n mn : .Triu chng l m t, au v nghim tr ng
Tip xc mt :
n mn : Tip xc c th gy m mt, mt, au v rt nghim trng. Phi nhim mn tnh.
Nut vo nhiu ln c th gy tn hi gan. Phi nhim lu ngy vi mt c th gy m mu
PHN 4 : BIN PHP S CU Y T
4.1 Sau khi ht phi: Th bng khng kh sch. H hp nhn to nu khng th c. C u n g c p o xy n u
t h k h . a n bc s n g ay l p t c .
4.2 Sau khi tip xc da : ngay lp tc x bng nc trong vng ti thiu 15 pht ng thi. ci b qun
o v giy nhim bn. a n bc s ngay lp tc. Git qun o trc khi s dng li. Ra giy tht
sch trc khi s dng li.
4.3 Sau khi tip xc vi mt : ra mt sch vi nc trong vng ti thiu 15 pht, chp mt lin tc. a
n bc s ngay lp tc .
4.4 Sau khi nut: KHNG C TNH LM CHO NN. Ung nhiu nc. Khng bao gi a vt g vo
ming mt ngi bt tnh. a n bc s ngay lp tc.
PHN 5: BIN PHP X L KHI C HA HON
5.1

Chy
Khng c xem c nguy c chy. Khi HCL lm rt da c th hnh thnh trong m chy

5.2

N
Khng c xem c nguy c gy n.

5.3

Phng tin dp tt la
Nc, ha cht kh, x bng hoc Cacbon dioxit. Khng s dng nc cha chy x vo cng hay cc
ngun nc.

5.4

Thng tin c bit

Trong trng hp chy, mc y qun o bo h v dng c tr th trong phng th nghim.
Trong trng hp xy ra chy, Phi mc trang phc bo h chng chy, eo mt n phng c ton mt c
trang b bnh th v thit b to p sut dng c chng nhn bi NIOSH

PHN 6: CC BIN PHP GIM THIU TAI NN

Cn thng bo cc khu vc r r hoc chy trn. Nhng ngi khng mc qun o bo h hoc khng cn
thit cn trnh xa cc khu vc chy trn. Mc cc phng tin bo h c nhn thch hp nh cp ti
Phn 8. Chy trn: Dn v trong thng cha ph hp ri mang thi b, s dng phng php khng lm
pht sinh bi. Quy nh UA (CERCLA) yu cu bo co chy trn v thi b ra t, nc khng kh khi vt
qu khi lng. S in thoi min ph ca Trung tm quc gia ng cu bo v vng bin ca M l (800)
424-8802
PHN 7: BO QUN V LU TR

Gi trong thng cha tht kn, bo qun ni kh ro, khu vc thong gi, Bo v khi cc h hng t
nhin. Cch ly khi cc cht tng tc nhau. Thng cha vt liu ny c th nguy hi khi ht do chng
cha cc cn ca sn phm ( bi, cht rn); c k cc cnh bo v phng nga lit k cho sn phm
PHN 8: KIM SOT PHI NHIM/BO V C NHN
8.1

8.2

Gii hn phi nhim trong khng kh:

-ACGIH gi tr ngng gii hn (TLV):
1 mg/m3 (TWA) Mui st ha tan nh Fe
H thng thng gi:
Nn xy dng h thng x khi chung hoc bi b trnh cng nhn khi phi nhim di gii hn phi
nhim trong khng kh. Nn xy dng h thng thng kh x khi ni b hn v n c th kim sot c
vic x thi cht nhim ti ngun, ngn cn s pht tn chung vo cc khu vc lm vic chung. Vui lng
tham kho ti liu ACGIH, thng kh cng nghip, S tay vn hnh xut, phin bn mi nht bit
thm chi tit. Cc mt n phng hi c c chp thun (NIOSH):
Nu gii hn phi nhim vt qu v kim sot k thut khng kh thi, c th eo mt n phng c c
bit dng ming (NIOSH loi 95 hoc b lc cao hn) gp 10 ln gii hn phi him hoc nng s dng
ti a, theo bt c ci no thp hn, c c quan hoc nh cung cp mt n phng c quy nh thch
hp.

C th eo mt n phng c c bit dng y gp 50 ln gii hn phi nhim hoc nng s dng

ti a, theo bt c ci no thp hn, c c quan hoc nh cung cp mt n phng c quy nh thch
hp. Nu c cc phn t du ( v d, cht bi trn, cht lng ct, cht du m.), s
dng NIOSH loi R hoc b lc P. Trong trng hp khn cp hoc v d trng hp khng xc
nh mc phi nhim, s dng sc p tuyt i ca mt n y , mt n phng c cung
cp kh. Cnh bo: Mt n lm sch kh khng bo v cng nhn trong trng hp thiu oxy.
8.3 Bo v da:
eo gng tay bo h v v sinh qun o
Tip xc mt: Sa sch mt vi vi nc trong khu vc lm vic. S
dng cc ming bo v che chn ha cht trong trng hp cc gii
php phi bi hoc bn nc c p dng.
PHN 9: CC TNH CHT VT L V HA HC
Th: Cc tinh th tan mu nu vng
Mi : Mi axit Hyclorit nh
Tnh tan: C th tan trong nc.
T trng: 2.90 ti 25C/4C
pH: Cha tm thy thng tin .
% bay hi theo th tch ti 21C (70F): 0
Nhit si: Cha tm thy thng tin Nhit
tan: 37C (99F)
T trng bc hi (khng kh=1): Cha tm thy thng tin.
p lc bc hi (mm Hg): 1.1 ti194C (381F)
T l bay hi (BuAc=1): Cha tm thy thng tin.
PHN 10: TNH PHN NG V N NH
n nh:
n nh trong iu kin lu tr v s dng thng thng . Cc
sn phm phn hy c hi:

Thi ra cc khi Clo c khi c t chy phn hy

Qu trnh polyme nguy hi :
Cht ny khng polyme ha
Tnh khng tng thch:
Kim loi, allyl chloride, sodium, potassium. S p h n n g v i n c s i n h r a c c k h c
hi v n mn
Cc iu kin cn trnh:
Khng tng thch.
PHN 11: CC THNG TIN C HI
Liu ung ti LD50: 316 mg/kg (khan); c k h o s t g y t b i n , t c n g n h s i n h s n .
--------\Danh sch bnh ung th \--------------------------------------------------------Hch NTP --Thnh phn
Bit
Khng xc nh Danh mc IARC
-------------------------------------------------------------- Ferric Chloride (7705-08-0)
khng
khng
khng
PHN 12: THNG TIN SINH THI
Hy hoi mi trng: cha tm
thy thng tin
c hi vi mi trng
24 Hr LC50 striped bass (fingerling): 6 mg/L (static);
24 Hr LC50 striped bass (larvae): 4 mg/L (static)
PHN 13: YU CU THI B
Sn phm
Khng c nguyn tc no cho vic phc hi v ti ch , vic ny cn c thc hin bng cc phng
tin thi b ph hp v ng quy nh. Mc d khng c lit k trong danh sch cc cht nguy hi
RCRA, cht ny cng c th sinh ra mt hoc nhiu cht nguy hi v cn thc hin cc phn tch thch hp
xc nh cc yu cu thi b c bit. X l, s dng hoc nhim bn sn phm ny c th lm thay i
cc phng thc qun l cht thi. Cc quy nh thi b ti a phng v nh nc c th khc vi cc quy
nh thi b lin ban
Bao b nhim bn
Thi b cc thng cha v cc cht khng s dng theo ng cc yu cu ca chnh quyn a phng, nh
nc v lin bang.
PHN 14: THNG TIN VN CHUYN
Trong nc (ng b D.O.T.)
----------------------Tn vn chuyn thch hp: CHT RN N MN, AXIT, V C, N.O.S. (ST CLORIT, 6-HYDRATE)
Phn cp nguy hi: 8
UN/NA: UN3260
Nhm bao b: III
Thng tin v kch thc sn phm: 220LB

Quc t (ng thy, I.M.O.)

-----------------------------

Tn vn chuyn thch hp: CHT RN N MN, AXIT, V C, N.O.S. (ST CLORIT, 6-HYDRATE)
Phn cp nguy hi: 8
UN/NA: UN3260
Nhm bao b: III
Thng tin v kch thc sn phm: 220LB
Quc t (ng hng khng I.C.A.O.)
----------------------------Tn vn chuyn thch hp: CHT RN N MN, AXIT, V C, N.O.S. (ST CLORIT, 6-HYDRATE)
Phn cp nguy hi: 8
UN/NA: UN3260
Nhm bao b: III
Thng tin v kch thc sn phm: 220LB
PHN 15: THNG TIN QUY NH
--------\Nhn kim k ha cht Phn 1\--------------------------------- Thnh phn
TSCA EC Nht c
-------------------------------------------------- --------------- St
Clo(7705-08-0)
C C C
C
--------\Nhn kim k ha cht phn 2\----------------------------------Canada-Thnh phn
Korea DSL NDSL Phil.
-------------------------------------------------------- ----- St
Clo (7705-08-0)
C C khng C
--------\Cc quy nh lin bng, quc t v nh nc Phn 1\----------------SARA 302------SARA 313-----Thnh phn
----------------------------------------St Clorua (7705-08-0)

RQ TPQ
Dan Danh mc ha cht
-------------------h---kh khng khn
Khng
sch
ng
g
--------\Cc quy nh lin bng, quc t v nh nc Phn 2\----------------RCRA-TSCAThnh phn
CERCLA
261.33
8(d)
--------------------------------------------------- -----St Clorua (7705-08-0)
1000
No
No

Quy c v kh ha cht : khng TSCA 12(b): khng

CDTA: Khng SARA
311/312: Acute: C Chronic: C Chy: No p sut: khng phn ng: khng
(Tinh khit / Rn
M Hazchem ca c
M: Bng lit k c hi 2R: Khng c ch r
. WHMIS: MSDS ny c chun b theo tiu chun c hi ca cc sn phm c kim sot, cc
quyd9i5nh (CPR) v ni dung MSDS theo tt c cc thng tin c CPR yu cu

PHN 16 CC THNG TIN KHC

Phn cp NFPA : Sc khe: 2 Tnh chy: 0 Tnh phn ng: 0
Nhn cnh bo c hi:
NGUY HIM! N MN!. G Y C H Y B T K Z V N G N O T I P X C . C H I N U N U T

PHI HOC HT VO. NH HNG N

Nhn phng nga:
Khng dnh vo mt, da hoc qun o. Khng ht kh bi
Gi thng cha kn.
Ch s dng h thng thng kh y Ra
sch sau khi s dng.
Nhn s cu:
Trong trng hp tip xc, ngay lp tc ra sch bng nc i vi vng tip xc nh da, mt trong vng ti
thiu 15 pht ng thi ci b qun o hoc giy b nhim bn. Git sch qun o trc khi s dng. Nu ht
vo, phi th khng kh sch. Nu khng th c, cn h cp nhn to. Nu th kh, cung cp thm oxy. Nu
nut phi, KHNG DNG CC BIN PHP LM CHO BUN NN. Ung nhiu nc. Khng bao gi cho g vo
ming ca ngi bt tnh. Trong tt c cc trng hp, lp tc a i bc s.

Thng tin trong phiu an ton ha cht ny da trn nhng kin thc mi nht ca chng ti
v dng thc hin cc bin php phng nga ri ro, tai nn.
Ha cht nguy him ny c th c nhng tnh cht nguy him khc ty thuc vo cch thc,
iu kin s dng v tip xc vi ha cht.