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.., ..
,
.
, .
-
[1].
,
. , ,
.
, .
,
, .
--
-
- -,
. .. ..
[2], . [3], .. [4] .
,
,
.1.
. / . 2007. .7. .5
816
. 1
,
. , ,
,
, , ,
.
, -
.
,
[2,3]
dci
z e d J i
dJ i
= i ci
,
= 0, (i = 1,2)
dx
Di
dx
kT
dx
,
d 2
2 = F ( z1c1 + z 2 c 2 )
dx
x [0, ],
(i = 1,2)
(1)
z i , Di , J i , ci - , ,
i- ; -
; - ; e = 1.6010-19 , k =1.3810-23 / , T
, ; F = 9.65104 / .
.
, ,
,
, ,
x = 0:
(0) = 0 .
0
i
(2)
(i=1,2)
c0
, i
,
z1c10 + z 2 c 20 = 0 .
,
- ,
.
,
, ,
. / . 2007. .7. .5
817
,
. ,
,
i- .
, , ,
x = :
n i j0
(i = 1,2) ,
zi F
Ji =
() = 0
.
> 0
(3)
0
0 - -;
0 .
0 , j0
, (1)
,
j0 .
j
, 0 ,
, (3.2) .
[5].
(1) ,
, (3.1)
Ji =
n i j0
(i = 1,2)
zi F
. (4)
, ,
dci
z e d
n i j0
= i ci
dx
kT dx z i FDi
(i = 1,2)
d 2
= F ( z1c1 + z 2 c2 )
dx 2
(5)
x = 0:
x = :
() = 0
. (6)
(5)-(6)
,
X =
j* =
;
z1 FD* c10
p=
c1
c10
n=
,
c2
c20
=
;
J0 = 0
0 ;
j* ,
n1 t1 - , [2].
,
(1.3) ,
;
m
. / . 2007. .7. .5
818
D* =
(z1 z 2 )D1 D2
z1 D1 z 2 D2 - ,
t1m =
z1 D1
z1 D1 z 2 D2 -
- [6].
(5)-(6)
d
dp
= p
p J0
dX
dX
, (7)
dn
d
=n
+ n J0
dX
dX
, (8)
d 2
= p + n
dX 2
,
(9)
X = 0:
p (0) = 1,
X = 1:
(1) = 1.
(11)
(7) - (9) ,
kT
e , z1 = 1 , z 2 = 1 .
n1 D*
(1 n1 ) D*
p =
n =
2 = 0 20
m
m
D2 (n1 t1 ) ,
D1 (n1 t1 ) ,
C1 F .
(9) = ( X )
0 ~
2,
, (7) (8) ,
. ,
,
.
, .. [6].
(7)-(11)
[7],
1 + Ke
p( X ) = 1 J 0 X + (1 J 0 )
1 Ke
1
1 X
2 (1 J )
(12)
2
1 X
2 (1 J )
1 Ke
n( X ) = 1 J 0 X (1 J 0 )1
1 X
2 (1 J )
1 + Ke
1 X
2 (1 J 0 )
(13)
( X ) =
p +n
2
1 Ke
ln 1 J 0 X + 2 ln
1 + Ke
1 X
)
.
1 X
2 (1 J 0 )
2 (1 J 0
(14)
K=
1 e2
1
1+ e2
0 ( 0 )
0 ( 0 )
. (15)
, (12) - (15)
J 0 ,
. / . 2007. .7. .5
819
0 ( 0 ) = 1
1
( p + n ) ln 1 J 0
2
,
, -,
J0 .
0 [8]
,
[9]. ,
dp
dn
A
1
dX dX
1 dX
p + An
0
=0
J0 B
1
dX
0 p + An
. (15)
A=
D2 C 20
FD1C10
B
=
j* .
D1C10 ,
(15),
2
n + p
0, 1 e
J0
f (J 0 ) = 0 ,
, [9].
f (J
0 .
f =
, 10 /3 NaCl,
.2.
. 2.
f (J 0 )
,
J
0 , f ( J 0 ) = 0 , [0.2, 0.4] .
.
, ,
. / . 2007. .7. .5
820
J
0 ,
.
. 1
.
1.
C0, /3
NaCl
NaF
10
0,305151
0,302319
1
0,288867
0,284302
0,5
0,279932
0,274561
J 0
MgSO4
0,304907
0,288452
0,279443
AgNO3
0,302588
0,284717
0,275037
NaNO3
0,304565
0,287866
0,278748
. 3. () ()
. / . 2007. .7. .5
821
, , NaCl 10
/3.
,
, . ,
,
.
, .
[10].
. 4.
,
,
10-3.
.
. ,
z1 = z 2 = 1
0 ( 0 )
1 e2
ln
e =
1
2 p 0 (1) 1 + e 2 0 ( 0 )
+1 +1
p0 (1)
+ 1 1
p0 (1)
.
(16)
(16) p 0 (1)
p 0 (1) = 1
1
( p n )J 0 = 10 3
2
,
.
.5 .6
NaCl, 10 160 /3. ,
(.5),
, (.6).
. / . 2007. .7. .5
822
. 5.
NaCl
. 6.
NaCl
. ,
.
..
.
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2. .., .. . .: , 1996. 396 .
3. Rubinstein I., Shtilman L. Voltage against current curves of cation exchange membranes.// J.
Phys. Chem. 1978. v.75, pp.231-246.
4. ..
// , 1990. .12, 8. . 675-680.
. / . 2007. .7. .5
823
5. Strygin V.V., Korzhov E.N. Asymptotical solution of boundary value problem for
electromembrane systems // Methods and Application of Analysis: Abstr. Intern. Symposium.
Hong Kong, 1994. p. 138.
6. .., ..
. .: , 1973. 272 .
7. .., ..
// , , :
- : 4- . :
, 2006 .4, . 306-311.
8. .., ..
// :
- : 4- . : ,
2007 .2, . 224 235.
9. Banasiak L.J., Kruttschnitt T.W., Schafer A.I. Desalination using electrodialysis as a function
of voltage and salt concentration // Desalination, 2007. v.205, pp.38-46.
10. .,
//
. : , 1999. . 135-143
. / . 2007. .7. .5