12

th
ABCD (Date: 25-09-2011) Review Test-5
PAPER-1
Code-A
ANSWER KEY
MATHS
SECTION-2
PART-A
Q.1 B
Q.2 C
Q.3 C
Q.4 A
Q.5 D
Q.6 B
Q.7 D
Q.8 B
Q.9 D
Q.10 A
Q.11 A,D
Q.12 C,D
Q.13 B,C,D
Q.14 A,C
Q.15 B,C
PART-B
Q.1 (A) R
(B) S
(C) Q
Q.2 (A) T
(B) P
(C) Q
(D) R
PHYSICS
SECTION-3
PART-A
Q.1 A
Q.2 D
Q.3 A
Q.4 C
Q.5 C
Q.6 BONUS
Q.7 A
Q.8 A
Q.9 A
Q.10 D
Q.11 B,D
Q.12 A,B,C,D
Q.13 A,D
Q.14 A,B,C,D
Q.15 C,D
PART-B
Q.1 (A) P, R, S
(B) Q
(C) S
Q.2 (A) P
(B) Q,T or Q
(C) S
(D) R
CHEMISTRY
SECTION-1
PART-A
Q.1 A
Q.2 D
Q.3 D
Q.4 C
Q.5 A
Q.6 A
Q.7 A
Q.8 C
Q.9 B
Q.10 C
Q.11 A,B,C,D
Q.12 A,B,D
Q.13 B,C,D
Q.14 A,B,C
Q.15 A,B,C,D
PART-B
Q.1 (A) Q,R
(B) P,Q
(C) R,S
Q.2 (A) Q,R
(B) T
(C) S
(D) P
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
[Sol. Van-Arkel method is used for the purificaiton of those metals which forms volatite iodide
Ti + 2I
2

C 250 50

A
TiI
4

C 50 14

A
Ti + 2I
2

|
]
Q.2
[Sol.
OH
+ CHCl
3

H ) ii (
KOH ) i (

OH
CHO
+
OH
CHO
(Major) (Minor)
Since from ortho position a more stable chelate with cation (K
+
) is possible also there are two ortho
position and one para position probability to perform ortho attack is high. ]
Q.3
[Sol. Self reduction is applied for the extraction of Cu, Pb and Hg ]
Q.4
[Sol. 3A (g) 2 B (g) + 2C(s)
t = 0 6 atm 0
t = 20 min (6 3x) atm 2x atm
t =

0 4 atm
But at t =

, the total pressure is 4.05 atm. The addition pressure is due to V.P. of solid, which is
(4.05 4) 0.05 atm
P
T
= P
A
+ P
B
+ V.P. of solid
or , 5.05 = (6 3x) + 2x + 0.05 x = 1
t
1/2
= 20 min t
75%
= 40 min, t
87.5%
= 60 min
t
93.75%
= 80 min Ans
Alternative :
If dissociation of A is not considered to be occurring fully.
then
A which would have reacted as per given data.
= slightly less than 6 atm
t
1/2
= slightly more than 20 min and hence option 'A' will be correct. ]
Q.5
[Sol. According to MOT, B
2
2
, C
2
2
are diamagnetic in nature and B
2
is paramagnetic in nature.
N N
O O
O
O
(diamagnetic) ]
CHEMISTRY
Code-A Page # 2
Paragraph for question nos. 6 to 8
[Sol.(6)At 1000C
(i) 2M + O
2
2MO AG = 921
(ii) 2C + O
2
2CO AG = 432
Required reaction MO + C
A
M + CO
|
Reaction (ii) Reaction (i)
AG = + ve
Reaction is non-spontaneous
At 1900C
2M + O
2
2MO AG = 300 kJ/mol
2C + O
2
2CO AG = 624 kJ/mol
Required reaction
MO + C

A
M + CO(g)
Reaction (ii) Reaction (i)
AG = ve
Reaction is spontaneous
(7) (AG)
overall
= (AG)
carbon
(AG)
metal oxide
= 0
(8) According to the graph (A) and (B) are correct option. ]
Q.9
[Sol. In Beckmann's only anti-group migrates. Whatever be the group is.]
Q.10
[Sol. NH
4
HS(s) NH
3
(g) + H
2
S (g)
P P
P + P + 2 (=P
He
) = 4
P = 1 atm ]
Q.11
[Sol.
Fe
C = O
Fe
C = O O = C
C

O
C
C

O
O
C
C
C

O
O
O
]
CHEMISTRY
Code-A Page # 3
Q.12
[Sol. (A)
O
CHO


NaOH
O
CHO
1
2
3
4
5
Intra aldol
|
o
O
(Major)

A
OH
O

reactivity aldehyde > Ketone

(B) Me
2
CHCHO
A

NaOH . conc
Cannizaro reaction
Due to Hindrance on Carbonyl .
Aldol does not happen. We get Me
2
CHCH
2
OH + Me CHCONa
2
O
.
(C)
Ph C C Ph
Me Ph
OH OH
conc.H SO
2 4
Ph C C Ph
Me Ph
OH OH
2
:

MeCC(Ph)
3
O
(D) Ph C C
O O
14 o+
o+
Me
OH
:
PhC
O
:
14
OH
C
O
Me HO C C
14
O OH
Ph
CH
3
]
Q.13
[Sol. Al l the metal i on contai ns t
2g
6
eg
0
configuration so Fe should be in +2 oxidation state and Co in +3
oxidation state but oxygen having tendency to show different type of oxidation state.
[x = oxidation state of O
2
]
(A) [FeCl(CN)
4
(O
2
)]
4
+2 1 4 + x = 4
x = 1 due to the presence of unparied e

in O
2

, it is an paramagnetic complex.
(B) [Co(CN)
5
(O
2
)]
4
+3 5 + x = 4
x = 2
O
2
2
is (diamagnetic) in nature.
(C) Fe
+2
= t
2g
6
eg
0

(diamagnetic)
(D) [Fe(CN)
5
(O
2
)]
5
+2 5 + x = 5, x = 2
O
2
2
(peroxide) is diamagnetic in nature. ]
CHEMISTRY
Code-A Page # 4
Q.14
[Sol. Ph C Me
O
Haloform
+ve
Aldol
+ve
O
H
do not give aldol (Bredt Rule) ]
Q.15
[Sol. (A) For conjugate apirs, K
a
. K
b
= K
w
K
a
= K
b
= 10
7
(B)
) C log p (
2
1
p
a
K H
) HA (
=
=

2
1

(7log 0.1) = 4.0
(C)
) C log p (
2
1
p
b
K OH
) A (
=
=
2
1

(7log 0.1) = 4.0
(D) [H
+
]
total
= [H
+
]
HA
+ [H
+
]
HCl
~ 0.01 M
pH = 2.0 ]
PART-B
Q.1
[Sol. (A) CH C H
3
Al(OEt) ,
3
A
O
CH COCH CH
3 2 3
O
H O
3
+
CH COOH + CH CH OH
3 3 2
NaHCO
3 Haloform
(Tischenko)
(B) Ph C H + CH
2
O
:
COOMe
COOMe
Knovenagel
PhCHCH
OH
COOMe
COOMe
H O
3
+
PhCHCH
OH
COOH
COOH
A
PhCHCH COOH
2
OH
| o
A
PhCH=CHCOOH
NaHCO , Br /H O
3 2 2
CHEMISTRY
Code-A Page # 5
(C)
PhMgCl
CO
2
Ph C O
O
:
H
+
Ph C OH
O
SOCl
2
Ph C Cl
O
MeMgCl
:
Ph C Cl
Me
O
:
Ph C = O
Me
Haloform
2,4 DNP
]
Q.2
[Sol. (P) P
92
U
235

|

o
1
3

87
Fr
223
(Q) A(g) B(g) + C(g)
t
1/2
o
a
1
from data so order is 2nd.
(R) C
m
= C
v
+
x 1
R

PV
2/3
= constant
C
P
+ 2R = C
v
+
x 1
R

P
1/3
T
2/3
= constant
3R =
x 1
R

+ 1 x =
3
1
PT
2
= constant
x =
2
3
x = 2
(S) 0.1M BCl
B
+
+ H
2
O

BOH + H
+
pH =
] C log pK pK [
2
1
b w

=
] 1 5 14 [
2
1
+
= 5
(T) [H
+
] =
2
0012 . 0 0008 . 0 +
= 0.001 = 1 10
3
M
pH = 3 ]
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. Given that 0 c k b k a
2 1

= + +
Now,
( )
( ) OQR Area
PQR Area
A
A
=
( ) ( )
( )
4
c b
2
1
a c a b
2
1
=

P(a)
Q(b)
b a
c a
O(0)

( ) { } ( ) { }
c b
c k 1 b k c k b k 1
2 1 2 1

+ + + +
= 4
(1 + k
1
) (1 + k
2
) k
1
k
2
= 4
Hence, k
1
+ k
2
= 3. Ans. ]
Q.2
[Sol. | A | = x + y + z
det.(adj.(adj. A)) = ( )
2
) 1 n (
A . det

= (det. A)
4
= 2
8
3
4
= 12
4
| A | = 12 x + y + z = 12
Using beggar method x + y + z = 9.
Number of matrix =
11
C
2
= 55. Ans.]
Q.3
[Sol. We have
(1 + x)
10
=
10
C
0
+
10
C
1
x +
10
C
2
x
2
+
10
C
3
x
3
+........ +
10
C
9
x
9
+
10
C
10
x
10
.......(1)
Also (x 1)
10
=
10
C
0
x
10

10
C
1
x
9
+
10
C
2
x
8
+........
10
C
9
x +
10
C
10
.......(2)
Multiplying (1) and (2), we get
( )
10
2
1 x
= ( )
10
10
10 9
9
10
1
10
0
10
x C x C ....... x C C + + + +
( )
10
10
9
10 9
1
10 10
0
10
C x C ....... x C x C + + + .......(3)
Comparing the coefficients of x
10
in (3) , we get
10
C
5
(1)
5
= ( ) ( ) ( ) ( ) ( )
2
10
10
2
9
10
2
2
10
2
1
10
2
0
10
C C ....... C C C + + Ans.]
Q.4
[Sol. f '(x) = f(x) =
1
) x ( f
) x ( ' f
=
ln (f(x)) = x + c
x = 0, f(0) = 1 c = 0
f(x) = e
x
g(x) = e
x
(x + 1)
2
e
x
= e
x
(x
2
+ 2x)
}

1
0
x
dx ) x ( g ) x ( f e
= ( )
}
+
1
0
2 x
dx x 2 x e =
|
1
0
2 x
x e = e Ans.]
MATHEMATICS
Code-A Page # 2
Q.5
[Sol. m = 5! 2 5! = 10 4! 5!
n = 4! 5!
Hence m = 10n k = 10 Ans.]
Q.6, 7, 8
[Sol.(i)

angle between b and a

is obtuse
hence
b a

s 0 (log
3
x)
2
+ 2log
3
x 1 s 0 x e (0, )
4
2
+ 4 s 0 e [1, 0]
Volume =
6
1
1 1 1
1 1
1 2

=
6
1
|
2
3 |
Since, e [1, 0]
Volume e
(

2
1
,
3
1
(ii)
c a

=
c b

0 c ) b a (

=

c b a

+ =
( ) k

2 i

) x log (
3
+ + = ( ) k

) x log ( i

) x (log
3 3
+ +
( ) k

+ +
x log x log
3 3
+ = ; 2 = log
3
x + and 1 = 1
= 2
log
3
x = 0 and log
3
x = 2
= 0
= 2, log
3
x = 2, = 0
k

2 a + =

2 b =

c + + =

7
| j

|
| k

2 j

3 |
| c a |
| c b |
=
+

=

(iii) c ) b a (

= b 2 a

+ b 2 a b ) c a ( a ) c b (

+ = +
1 c b =

, 2 c a =

log
3
x + log
3
x 1 = 1 ... (1)
log
3
x + 2 + 1 = 2
log
3
x = 1 ... (2)
log
3
x = 1, = 1
k

2 i

a + + =

b =

c + + =

| | a c c b b a

= | |
2
c b a

= 4. Ans.]
MATHEMATICS
Code-A Page # 3
Q.9
[Sol. Suppose o, | be two distinct roots in (0, 1) of the equation x
3
3x + p = 0
Let f(x) = x
3
3x + p.
As f(o) = 0 = f(|)
f(x) satisfies hypothesis of Rolle's theorem in [o, |] c (0, 1). So f '(c) = 0
3c
2
= 3 c = 1
But c must lies between o and |.
Hence p e |.
So, S
1
is false.
Also, S
2
is obviously true. Ans.]
Q.10
[Sol. We have
f(x) = tr.(A) =
=
3
1 i
ii
a
= x +
x
9
+ 2
As,
|
.
|

\
|
>
+
x
9
x
2
x
9
x
x +
x
9
> 6 (as x > 0 is given)
so, f(x) > 8
f
Min.
(x = 3) = 8
Also, S
2
is true and explaining S
1
also. Ans.]
Q.11
[Sol.
x= 1
(0,0)
t
2
( ,0) t
X
Y
y = sinx
( /2, 1) t
y = 1 + cos x
y=x +x 10x
3 2
Graph of f(x)
1
Clearly, from above graph, f(x) has local maximum at x =
2
t
and absolute maximum at x = 1. Ans.]
MATHEMATICS
Code-A Page # 4
Q.12
[Sol. (A) b a

= c a

either c b

= or c b a

.
(B) b a

= c a

either c b

= or c b || a

(C) True
(D) True. Ans.]
Q.13
[Sol. f(x) = ( ) ( )
|
.
|

\
|

t
|
.
|

\
|

t

x sin sin
2
x cos cos
2
1 1
=
( )
( ) ( ) ( )

t s < t t
t
=
|
.
|

\
|

t
|
.
|

\
| t
=
|
.
|

\
|
t
t
|
.
|

\
|
t
t
t
s < t
t
t = |
.
|

\
| t
|
.
|

\
| t
= |
.
|

\
|
t
t
|
.
|

\
|
t
t
t s <
t
|
.
|

\
|

t
= |
.
|

\
|
t
t
|
.
|

\
|

t
t
s s
|
.
|

\
|

t
2 x 3 , ) 2 x (
4
x
2
5
2
3
x ) 2 x (
2
) x 2 (
2
2
3
x ,
4
x
2
x
2
3
x x
2
x 2
2
x
2
, x
2
x
2
x
2
2
x 0 , x
2
2
2
2
2
2
2
2
f(x) =
( ) ( )
|
.
|

\
|

t
|
.
|

\
|

t

x sin sin
2
x cos cos
2
1 1
O
y
t/2
t
3 /2 t 2t
x
t
2
/4
t
2
/4 f(x) =
(

t
e
|
.
|

\
|

t
2
, 0 x x
2
2
,
f(x) =
( )
|
.
|

\
|
t
t
|
.
|

\
|

t
x
2
x
2
f(x) =
2
x
2
|
.
|

\
|

t
; x e
(

\
|
t
t
,
2
f(x) = (t x)
2

4
2
t
, t < x s
2
3t
,
f(x) =
4
2
t
(2t x)
2

2
3t
< x s 2t
At x = t, f(x) is not differentiable
At x = t, it is local as well as global minimum.
Range :
(

t t
4
,
4
2 2
,
I = }
t
2
0
dx ) x ( f = }
t
|
.
|

\
|

t
2
0
2
dx x
2
Using king
I =
}
t
2
0
2
dx x =
2
0
3
3
x
t
(

(
=
24
3
t
Ans.]
MATHEMATICS
Code-A Page # 5
Q.14
[Sol. As, a
1
+ a
2
+ a
3
= 126
and a
2
=
2
a a
3 1
+
=
3
126
= 42.
The numbers in A.P. are 42 d, 42, 42 + d.
Let g
1
= A, g
2
=AR; g
3
= AR
2
AR = 34 and A + AR
2
= 85
R
34
+ 34R = 85 34R
2
85R + 34 = 0
34R
2
68R 17R + 34 = 0 (R 2)(2R 1) = 0
For R = 2, A = 17
g
1
= 43 + d = 17 d = 26 (Rejected)
for R =
2
1
, A = 68
g
1
= 43 + d = 68 d = 25
Common difference of A.P. = 25 and common ratio of G.P. is
2
1
Ans.]
Q.15
[Sol. Given,
7
b
13
a
= =
15
k
= k (say)
a = 13k, b = 7k, c = 15 k
Now, cos A =
bc 2
a c b
2 2 2
+
=
) 15 ( ) 7 ( 2
169 225 49 +
=
105 2
105

=
2
1
A = A =
3
t
cos B =
ac 2
b c a
2 2 2
+
=
) 15 ( ) 13 ( 2
49 225 169 +
=
26
23
cos C =
ab 2
c b a
2 2 2
+
=
) 7 ( ) 13 ( 2
225 49 169 +
=
26
1
.
As, cos C < 0,
ZC is obtuse. So AABC is obtuse.
Also,
k 35
k 26 k 35
s 2
a 2 s 2
s
a s
a s
s
r
r
1

A
A
= =
k 35
k 9
=
35
9
Also,
2
s
A
=
) k 35 ( ) k 35 (
4 A sin bc
2
1
|
.
|

\
|
=
2
k 35 35
2
3
k 15 k 7 4
2
1
=
35 35
3 105
=
35 : 3 3
Also, tan
|
.
|

\
|
2
C B
=
|
.
|

\
|
+

c b
c b
cot
2
A
=
3
k 15 k 7
k 15 k 7
|
.
|

\
|
+

= 3
22
8
= 3
11
4
.
Now, verify alternatives. Ans.]
MATHEMATICS
Code-A Page # 6
PART-B
Q.1
[Sol.
(A) Let the point of intersection of curves y
2
= 2ax (a > 0) and xy =
2 4
be P(x
1
, y
1
).
Now, y
2
= 2ax
) y , x ( P
1 1
dx
dy
(

(
=
1
y
a
= m
1
... (1)
Also, xy =
2 4

1
1
) y , x ( P
x
y
dx
dy
1 1

=
(

(
= m
2
... (2)
As, m
1
m
2
= 1 x
1
= a ...(3)
As, x
1
y
1
= 2 4 y
1
=
a
2 4
So, P
|
|
.
|

\
|
= =
a
2 4
y , a x
1 1
Also, Point P must satisfy
y
1
2
= 2ax
1
2
a
32
= 2a
2
a
4
= 16 a = 2. Ans.
(B)

f (x) is differentiable in R
Hence ) x ( f Lim
x
must exist and is finite
y = f (x) must have a horizontal asymptote
O
y=1
x
y=f(x)
(0,4)
as x then only ) x ( f Lim
x
will exist
) x ( ' f Lim
x
= 0
( ) ) x ( ' f ) x ( f Lim
x
+

= 3
) x ( f Lim
x
= 3 Ans.
(C) y = mx + (n + 2 x) or y + x (n + 2) mx = 0 ( ) ) 2 n ( y + + (1 m) (x 0) = 0 m e R
Fixed point is the point of intersection of lines y = n + 2 and x = 0.
Family of lines which passes through (0, n + 2)
Hence n + 2 = 3 n = 1. Ans.]
MATHEMATICS
Code-A Page # 7
Q.2
[Sol.
(A) Given, C : y
2
= px
3
+ q .......(1)
2y
dx
dy
= 3px
2

dx
dy
=
y 2
px 3
2
.......(2)
Put x = 2 and y = 3 in (1), we get 9 = 8p + q .......(3)
Also, from (2), we get
) 3 , 2 ( M
dx
dy
(

(
=
6
) 4 ( p 3
= 2p = 4 .......(4)
From (2) and (3), we get p = 2, q = 7.
Hence, (p q) = 2 ( 7) = 2 + 7 = 9. Ans.
(B) We have
o
o =
cosec 2 1 0
1 cosec 2 1
0 1 1
V
= 4 cosec
2
o 1 2cosec o
=
1 ec cos
2
ec cos 4
2

o
1
o
=
4
5
4
1
ec cos 4
2

|
.
|

\
|
o

|
.
|

\
| t
= o
2
V
east l = 1
4
4
4
5
16
9
4 = = ]
(C) We have
1 1
x x sin

1 x
x x cos
= 0
(sin x x) ( cos x x
2
) = 0
Either sin x = x or cos x = x
2
Hence, number of real roots are 3. Ans.
(D) Given, tan A =
4
1
, tan B =
3
2
, tan C =
5
1
and tan D = d
Now, A + B + C + D = 2t
tan (A + B) = tan (C + D)
ab 1
b a

+
=
1 cd
d c

+

|
.
|

\
|
+
3
2
4
1

|
.
|

\
|
1 d
5
1
=
|
.
|

\
|

6
1
1

|
.
|

\
|
+ d
5
1
Solving 39 d = 65
d =
3
5
3 | tan D | = 3
3
5
= 5. Ans.]
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. C =
d
0
e
(A + (k 1) xl)
C =
d
0
e
(a + (k 1) l(a vt)
linear ]
Q.2
[Sol.
dt
dN
=
hf
IA
=
4
1
dt
dN
0
v
S
=
e
hf

e
|
3 =
e
hf

e
|
v' =
e
hf 2

e
|
= 2 3 +
e
|
= 6 +
e
|
> 6 ]
Q.3
[Sol. h =
g r
cos s 2

u
60
60
u cos
h
=
u cos

u cos
6
=
60 cos
4
cos u =
4
3
]
Q.4
[Sol. =
p
h
=
n
0

=
n p
h
0
p
0
=
n
p
]
Q.5
[Sol. R+ i| v
1
+ ]
Q.6
[Sol. AE =
2
2
mL 8
h
= Et ]
PHYSICS
Code-A Page # 2
Q.7
[Sol. L
1
> L
0

0 1
t t
E E <

0 1
t t
>
red light can be absorbed and infrared scattered. ]
Q.8
[Sol. 620 =
t
E
1240
E
t
= 2eV =
2
2
mL 8
h
L
2
=
m 8
h h
E
t
=
2 10 1 . 9 2
10 6 . 6 1240
34
34

= 2.27 10
10
m ]
Q.9
[Sol. Q = CV C+ V| ]
Q.10
[Sol. Friction on rolling body is static. ]
Q.11
[Sol. Line y = x is perpendicular to EF

j

or
j

+
]
Q.12
[Sol. R =

t
=
t

= same
AV = iR = same
i same
i
2
R same. ]
Q.13
[Sol. V = Ed = 5000 0.5 10
3
= 2.5 volt.
r R +
c
= i =
1 . 5
c
iR = 2.5
1 . 5
5 c
= 2.5
c = 2.55 V
F =
0
2
2e
o
E =
0
e
o
PHYSICS
Code-A Page # 3
=
2
1
E
2
e
0
=
2
1
(5000)
2
8.85 10
12
=
4
25
10
6
8.85 = 2.21 10
4
0
A
Q
e
= E
Q = e
0
AE = 8.85 10
12
100 10
4
5000 = 42.25 10
11
i = 0.5 A ]
Q.14
[Sol. i
at t = 0
=
2 1
2 1
R R
R R
+
c
=
5
100
6 = 120 AA
i at t = =
2
R
c
= 20A
i varies between 20 & 120 A ]
Q.15
[Sol. Q = CV
C =
|
e
d
A
0
C+
Q +, V = constant
U =
2
1
CV
2
+ ]
PART-B
Q.1
[Sol. [Q] Energy is not conserved during motion. In all other cases energy is conserved
K in case Q is minimum.
[P] K
rot
= fRu u =
R 2

=
2
f
=
2
mR 1
) 2 / ( sin mg
+
u
=
6
sin mg u
v = ) 2 / ( sin g 2 u = u sin g
at pure rolling
v = u sin g y cos u t
= er =
2
mR
2
1
R t R cos g u
PHYSICS
Code-A Page # 4
t =
u
u
cos g 3
sin g
=
u
u
sin g 3
sin g
=
u sin g 9

w =
R
sin g 2 u

u sin g 9

=
9
sin g 4
R
1 u
2
1
Ie
2
=
9
1
m lg sin u
[R] K
R
= 0
[S]
3
sin mg u
]
Q.2
[Sol.
+ ve
]