60%

CA

CAChemical Abstracts
CA

1 Alkanes
-ane 1
1

C1-16

CH4

methane,

C9H20

nonane,

C2H6

ethane,

C10H22

decane,

C3H8

propane,

C11H24

undecane,

C4H10

butane,

C12H26

dodecane,

C5H12

pentane,

C18H28

tridecane,

C6H14

hexane,

C14H30

tetradecane,

C7H16

heptane,

C15H32

pentadecane,

C8H18

octane,

C16H34

hexadecane,

CH3

methyl

methyl

CH3CH2

ethyl

ethyl

CH3CH2CH2

n-propyl

propyl

CH3CHCH3

isopropyl

(1-methyl ethyl)

CH3CH2CH2CH2

n-butyl

butyl

CH3(CH2)3CH2

n-pentyl n-amyl

pentyl

isopentyl isoamyl

(3-methyl butyl)

neopentyl

(2,2-dimethyl propyl)

CH3
CH3CHCH2CH2
CH3
CH3

C CH2
CH3

2 Unsaturated

Hydrocarbon

-ane -ene -adiene-atriene

( 3 )
3

CH2=CH2

ethylene

ethylene,

CH3CH=CH2

propylene

propene,

1-butylene

1-butene,

(CH3)2C=CH2

isobutylene

propene, 2methyl

CH3CH2CH2CH=CH2

1-amylene

1-pentene,

isoprene

1,3butadiene,2-methyl-

CH3CH2CH = CH2
4

CH3
CH2 = CH - C =CH2

alkenyl-ene -enyl
CA ( 4)

 4

CH2=CH

CH2 = CHCH2
3

CH3CH = CH
3

CH3CH = CHCH
4

vinyl

ethenyl

allyl

(2-propenyl)

propenyl

(1-propenyl)

2-

(2-butenyl)

HCCH

acetylene

ethyne,

CH3CCH

methyl acetylene

propyne,

dimethyl acetylene

2-butyne,

propenyl acetylene

3penten1yne,

CH3C

CCH3

2 1

CH3CH = CH

CH

3 Aromatic Hydrocarbon Compounds

2
O, P m 6
6

benzene

benzene,

naphthalene

naphthalene,

anthracene

anthracene,

phenanthrene

phenanthrene,

1
2

7
6

3
5

1
2

7
6

3
5

10

10

4
5

2
1

6
7

10
8

CH3

toluene

toluene

benzene, methyl-

o-xylene

benzene, 1,2-dimethyl-

p-xylene

benzene, 1,4-dimethyl-

m-xylene

benzene, 1,3-dimethyl-

CH3
CH3

CH3

CH3

CH3

CH3

CH = CH2

styrene

styrene

benzxene,ethenyl-

CA

-aryl-yl 7
7

phenyl

phenyl

-naphthyl
-

-naphthyl
(1-naphthalenyl)

-naphthyl

-naphthyl
(2-naphthalenyl)

CH2 -

benzyl

benzyl
(phenylmethyl)

CH3

p-tolyl

p-tolyl
(4-methyl phenyl)

4 Organic Halides
8-- 10
8
4

methyl chloride

methane,chloro-

CH2Cl2

methylene dichloride

methane,dichloro-

CHCl3

chloroform

methane, trichloro-

CCl4

carbon tetrachloride

methane, tetrachloro-

CH3CH2Br

ethyl bromide

ethane, brormo-

1,2

ethylene dibromide

ethane, 1,2-dibromo-

CH2=CHCl

vinyl chloride

ethylene, chloro-

CH2-CH-CH2Cl

allyl chloride

1-propene, 3-chloro-

phenyl chloride

benzene, chloro-

p-phenylene dichloride

benzene, 1,4-dichlorop-dichlorobenzene

CH3Cl

CH2 CH2
Br

Br

Cl

Cl

Cl

fluoro

fluoride

Cl

chloro

chloride

Br

bromo

bormide

iodo

iodide
10

CH2

methylene

methylene
methylidene

CH3CH2

1,2-

ethylene

dimethylene
1,2-ethandiyl

(CH2)3

trimethylene

trimethylene
1,3-propandiyl

p-phenylene

1,4-phenylene

ethylidene

ethylidene

CH3CH

5 Alcohols, Phenols and Ethers

( 11)
5

 11

CH3OH

methyl alcohol

carbinol

methanol,

C2H5OH

ethyl alcohol

methyl carbinol

ethanol,

CH3CH2CH2OH

n-propyl alcohol

ethyl carbinol

1-propanol,

isopropyl alcohol

dimethyl carbinol

2-propanol,

CH2(CH2)3OH

n-butyl alcohol

propyl carbinol

1-butanol,

CH3

3-2
1

CH3CHCH3
OH

CH3 - C = CHCH2OH

CH2OH

2-buten-1-ol,
3-methyl-

benzyl alcohol
12

phenylmethanol,

CH2 - CH2
OH

OH

HO(CH2)3OH

1,3-

ethylene glycol

1,2-ethanediol,

trimethylene glycol

1,3-propanediol,

glycerol

1,2,3-propanetriol,

CH2CHCH2

OH OHOH

13

OH

phenol

phenol,

OH
8

1-naphthol

-naphthol
1-naphthalenol,

3
5

OH

-naphthol

2-naphthol
2-naphthalenol,

CH3

OH

p-cresol

HO

OH

p-hydroquinone

phenol, 4-methyl1,4-hydroquinone
1,4-benzenediol,

Br

OH

p-bromophenol

phenol, 4-bromo-

bisphenol A

phenol, 1-methylethylidene bis-

CH3
HO

OH

CH3

 14

CH3CH2OCH2CH3

CH3OCH2CH2CH2CH3
CH3O

diethyl ether ethyl ether

ethane, 1,1-oxybis-

n-butyl methyl ether

butane, 1-methoxy-

methyl phenyl ether anisole

benzene, methoxy-

15

CH3O-

methoxy

C2H5O-

ethoxy

C3H7O-

propoxy

phenoxy

16

ethylene oxide

1,2-epoxyethane

1,2-

propylene oxide

1,2-epoxypropane

oxirane, methyl-

oxiranemethanol,

CH2 - CH2
O

CH3CHCH2
O
CH2CHCH2OH

glycidol

2,3-epoxy-1-propanol

furan

furan

oxirane,

furan,

6 Nitrogenous Organic Compounds

CA
17

17

CH3NH2
CH3NHC2H5

methyl amine

methanamine,

ethyl methyl amine

ethanamine, N-methyl-

NH2

aniline

benzenamine,
aniline

Tetramethyl ammonium
chloride

methanaminium,
N,N,N-trimethyl-, chloride

o-toluidine

benzenamine, 2-methylo-toluidine

-naphthyl amine

1-maphthalenamine

trimethylene diamine

1,3-propanediamine,

o-phenylene diamine

1,2-benzenediamine,

(2-phenyl ethyl) amine

benzeneethanamine,

(CH3)4NCl

NH2
CH3
NH2

H2N(CH2)3NH2
NH2
NH2

CH2CH2NH2

18

CH3CH2CHCH3
NO2

2-

butane, 2-nitro-

benzene, nitro-

NO2

CH3
O2N

NO2

benzene, 1-methyl-2,4,6-trinitro-

2,4,6-trinitrotoluene

NO2

azo- azo
18

CH3

CH3

CH3 - C - N = N - C - CH 3

,-azobis

propanenitrile, 2-methyl-,

isobutyronitnle

2,2-azobis-

azobisbenzene

diazene, diphenyl-

CN

CN
N=N

7 Aldehydes and Ketones

CA ( 20)
20

CH2O

formaldehyde

formaldehyde,

CH3CHO

acetaldehyde

acetaldehyde,

CH3CH2CHO

propionaldehyde

propanal,

CH3CH2CH2CHO

n-butyraldehyde

butanal,

CH3(CH2)3CHO

n-valeraldehyde

pentanal,

-methyl butyraldehyde

butanal, 2-methyl-

acrolein

2-propenal,

benzaldehyde

Benzaldehyde,

CH3
CH3CH2CHCHO

CH2=CHCHO
CHO

21

CH3CCH3

acetone

2-propanone,
acetone

2-

methyl propyl ketone

2-pentanone,

cyclohexanone

cyclohexanone,

diphenyl ketone
benzophenone

methanone, diphenyl-

CH3CCH2CH2CH3
O
O

C
O

8 Carboxylic Acids and Substitute Carboxylic Acids

 CA ( 22)
22

HCOOH

formic acid

formic acid,

CH3COOH

acetic acid

acetic acid,

CH3CH2COOH

propionic acid

propanoic acid,

CH3(CH2)2COOH

n-butyric acid

butanoic acid,

CH3(CH2)3COOH

n-valeric acid

pentanoic aicd,

CH3(CH2)4COOH

n-caproic acid

hexanoic acid,

lactic acid

CH3CHCOOH

propanoic acid,

OH

2-hydroxy-

CH2=CHCOOH

acrylic acid

2-propenoic acid,

oxalic acid

ethanedioic acid,

malonic acid

propandioic acid,

adipic acid

hexanedioic acid,

maleic acid

2-butenedioic acid, Z-

fumaric acid

2-butenedioic acid, E-

COOH
COOH
CH2

(CH2)4

COOH
COOH
COOH
COOH

C=C

HOOC

HOOC
H

C=C

H
COOH

H
COOH

COOH

benzoic acid

benzoic acid,

phthalic acid

1,2-benzene-dicarboxylic
acid,

2-phenyl acetic acid

benzeneethanoic acid,

cyclohexane
carboxylic acid

cyclohexanecarboxylic
acid,

COOH
COOH

CH2COOH

COOH

10

 23

CH3COCl

acetyl chloride

ethanoyl chloride,
acetyl chloride

CH3CH2CH2COF

butyryl fluorine

butanoyl fluorine,

benzoyl chloride

benzoyl chloride,

COCl

24

O
CH3C
O
CH3C
O

acetic anhydride

acetic acid, anhydride

phthalic anhydride

1,3-benzofurandione,
phthalic acid anhydride
1,2-benzene dicarboxylic acid
anhydride

maleic anhydride

2,5-furandione,
maleic acid anhydride
Z-2-butendioic acid anhydride

C
O2
C
1

O
HC - C
O
HC - C
O

25

CH3COOC2H5
COOC6H5

CH3

CH3

CH3CHCH2CH2COOCHCH2CH3

CA

Ethyl acetate

acetic acid, ethyl ester

phenyl benzoate

benzoic acid, phenyl ester

4-
2-

sec-butyl
isohexanoate

pentanoic acid, 4-methyl-,

(1-methylpropyl)ester

-ic -oic -amide

N ( 26)

11

 26

acetamide,

benzamide,

CH3CONH2
CONH2

CH3CON(CH3)2

NN-

H2NCNH2

acetamide, N,N-dimethyl-

urea,

27

CH2CH2 CH2 CH2C = O

CH2CH2CH2 CH2 CH2C = O

2-piperidinone,

-caprolactam
6-hexanolactam

2H-azepin-2-one,
hexahydro-

28

O
29

CH3C

CA

-valerolactam
5-pentanolactam

NH

CH3CHCH2CH2C = O

NH

butyramide
butanamide,

CH3CH2CH2CONH2

CA

-valerolactone

oxolan-2-one,

4-pentanolactone

4-methyl-

O
NH

CH3C

acetimide,

O
O
C

phthalimide
NH

1H-isoindole-1,3(2H)-dione,

C
O

12

 30

CH3CN

CN

CH2=CHCN

CN
CH2 = C

CA

methyl cyanide

acetonitrile,

phenyl cyanide

benzonitrile,

vinyl cyanide

acrylonitrile
2-propenenitrile,

vinylidene cyanide

propanedinitrile, methylene

ethyl cyanide

propanenitrile,

CN

CH3CH2CN

9 Polyfunctional Compounds
1
CA

2
3
4
5
6
7
8
9
10
11

(12)(13)(14)
31

31

R4 N

R 4 P+

ammonium
phosphonium

oxonium

sulfonium

R3 O
R3 S

-COOH

-carboxylic acid

- (C)OOH

-oic acid

carboxy-

-SO3H

-sulfonic acid

sulfo-

-COOR

-carboxylic acid r-ester

r-oxycarbonyl-

- (C) OOR

-oic acid r-ester

-COX

-carboxyl halide

- (C)OX

-oyl halide

-CONH2

-carboxamide

- (C)ONH 2

-amide

-CN

-carbonitrile

haloformyl-

aminocarbonyl-

cyano-

13

- (C)N

-nitrile

nitrilo-

-CHO

-carbaldehyde

formyl-

- (C)HO

-al

oxo-

-one

oxo-

-OH

-ol

hydroxy-

-SH

-thiol

mercapto-

-O-O-H

-hydroperoxide

hydroperoxy-

(C) = O

-NH2

-amine

amino-

=NH

-imine

imino-

32

32

halo

NO2

nitro

NCO

isocyanato

N = N

diazo

OR

Roxy

SR

Rthio

thio

oxy

SO2

sulfonylidene

SO

sulfinylidene

CH2CO

acetyl

acetyloxy

CH3C - O O
33

OH
CH3CO2CH2CHCH3

2-

acetic acid, (2-hydroxypropyl) ester

2-

2-pentanone, oxime

benzaldehyde, phenylhydrazone

NOH
CH3CCH2CH2CH3

CH = NNH

14