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Instructions: Answer as many items as you can. Read each question carefully and answer honestly. All information you need is in this paper. Good luck!
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MULTIPLE CHOICE. Choose the letter corresponding to the best answer. Which of the following set of quantum D. Same subshell and orbitals but different numbers is possible? shells A. n=1, l=0, ml=1, ms=1/2 3. For systems with positive changes in B. n=5, l=3, ml=-2, ms=-1/2 enthalpy and entropy, processes become C. n=2, l=1, ml=0, ms=0 spontaneous at __ D. None of these A. All temperatures Two electrons in the same atom which have B. Low identical values of quantum numbers l and C. High ml are said to be in ___ D. Absolute zero A. The same shell and subshell but in 4. Which of the following is a polar molecule? different orbitals A. RbCl B. Same shell but different subshells and B. BF3 orbitals C. CCl4 C. Same shell, subshell and orbitals D. PCl3
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Which of the following is false about the structure of thiocyanate ion? A. The C-N bond is a double bond. B. There are no lone pairs on C. C. There is a lone pair of electrons on N. D. The C-H bond is a single bond. Of the following, which is a state function? A. H B. q C. w D. All of the above The shorter the internuclear distance between two bonded atoms, the A. Less energy needed to break the bond B. Less multiple bonding character there is C. More resonance D. More energy needed to break the bond Which of the following is an unstable species and is bound not to exist? A. H2 B. He2+ C. Be2+ D. Be2 Which of the following pairs have similar molecular geometry? A. CH3+, CH3B. PF5, ClF5 C. H2O, NH2D. None of these Which of the following ions has the largest atomic radius? A. Na+ B. Mg+ C. O2D. FWhich of the following atoms has the largest first ionization energy? A. Rb B. Sr C. Al D. All have same magnitude of energy. What is the correct electronic configuration for a nickel atom? A. 1s22s22p64s23d23d23d23d13d1 B. 1s22s22p6 3s2 3p6 4s2 4p63d13d1 C. 1s22s22p63s23p63d10 D. none of these
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The Lewis structure for calcium hydride is A. [H:]-[Ca]2+[H:]B. [H:]-[Ca] + C. H-Ca-H D. Ca-H Which of the following is best represented by a set of resonance structures? A. Ammonium B. Methane C. Oxygen difluoride D. Sulfur dioxide What is the formal charge on N in nitrate ion? A. 2 B. 2C. 1 D. 1If there is a negative change in the Gibbs energy, then the reaction is said to be ___. A. Reversible B. Spontaneous C. Exothermic D. Endothermic In the experiment on Corrosion, the portion of the nail that was oxidized was ___ in color and acted as the __. A. White, anode B. Pink, anode C. Blue green, cathode D. Blue green, anode In the experiment on Corrosion, zinc acted as the __ while the nail is the __ A. Protected Anode; Sacrificial Cathode B. Protected Cathode; Sacrificial Anode C. Sacrificial Cathode; Protected Anode D. Sacrificial Anode; Protected Cathode Which of the following reactions is nonspontaneous? A. Neutralization of NaOH and HCl B. Freezing water in room temperature C. Combustion of octane fuel D. None of the above Which of the following statements is false? A. Ferrous hydroxide is formed by adding soluble Fe3+ sample to NaOH or NH3. B. Calcium will not precipitate to limiting and excess ammonia.
C. A Prussian blue precipitate will form when Fe2+ is added to potassium ferricyanide. D. The formula of the brown ring in the nitrate test is [Fe(NO)]2+. 21. Which of the following ionic compounds has the highest entropy? A. Calcium chloride B. Magnesium arsenate C. Sodium oxalate D. Tin(IV) oxide For numbers 22-26, refer to the structure of capsaicin below:
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The EGG, MGG, and hybridization of O1 is: A. Tetrahedral; angular; sp2 B. Trigonal planar; trigonal pyramidal; sp3 C. Tetrahedral; angular; sp3 D. Trigonal planar; angular; sp2 The difference/s between C2 and C5 is: A. Their EGG and hybridization B. Their MGG and hybridization C. Their EGG and MGG D. Their EGG, MGG, and hybridization How many and bonds are in capsaicin? A. 43 ; 5 B. 42 ; 4 C. 42 ; 5 D. 43 ; 4 What is the hybridization overlap in O4? A. sp2 sp3 B. sp3 sp2 C. sp2 sp2 D. sp3 sp3 The formal charge of N3 is __ and the hybridization overlap in C N3 C is __. A. 0; sp2-sp3-sp2 B. 0; sp3-sp3-sp2 C. +1; sp3-sp3-sp2 D. +1; sp2-sp3-sp2 Which of the following is true? A. Manganese(II) cations are dominant in basic medium.
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B. When organic chlorine and iodine are combined in a toluene-water mixture, there will be no visible reaction. C. A more acidic medium promotes corrosion of metals. D. Zinc, Nickel, and Cobalt can act as sacrificial anodes for Iron. What is the net heat change if 25.0 mL of 3.78 M sulfuric acid is neutralized by 50.0 mL of 1.90 M potassium hydroxide? A. -5.27 kJ B. 5.27 kJ C. 5.30 kJ D. -5.30 kJ What is the De Broglie wavelength and frequency of a photon with mass 1.0810-24 nanograms? A. 2.0510-7 m; 1.471014 s-1 B. 2.0510-6 m; 1.471015 s-1 C. 2.0510-6 m; 1.471014 s-1 D. 2.0510-7 m; 1.471015 s-1 If the uncertainty for a velocity of a photon is 3.1410-15 m/s, given that the mass of the photon is 7.0910-9 kg, what is the uncertainty of the position of the photon? A. 2.3710-12 m B. 2.6310-12 m C. 2.8610-12 m D. 2.4510-12 m Nitrogen gas and Hydrogen gas react to form ammonia gas. Given that Hf of ammonia is -46.3 kJ, how many grams of ammonia are produced if 176.7 kJ of heat is released? A. 65.0 g B. 130.0 g C. 7.63 g D. 3.81 g Which ion/s can give an interfering false ring for nitrate test? A. Thiocyanate only B. Ammonium and thiocyanate C. Thiocyanate, Bromide, Iodide D. Sulfate, Bromide, Thiocyanate
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MODIFIED TRUE OR FALSE. Write TRUE if the statement is true. Otherwise, determine what part of the statement made it false and offer corrections. 1. In the ozone layer, O3(g) absorbs harmful UV radiation and forms oxygen gas and gaseous oxygen atom. The entropy change for this process is equal to zero. 2. The 4f orbitals can accommodate a maximum of 10 e-. 3. Hesss Law is a consequence of the first law of thermodynamics. 4. On a humid day, we can observe water vapor to condense along the outer wall of cold drink bottles. The formation of the vapor is an endothermic process. 5. The form of carbon with a Ho formation value of zero is diamond. 6. The azimuthal quantum number tells us how far from the nucleus an electron is. 7. The oxidation state assigned to P in the phosphate ion is +5. 8. In the aluminum atom, the outermost electron has the quantum numbers n=3, l=1, m l=1, and ms=+1/2. 9. qsoln is still part of qcal even if the volumes of the solution used for calibration and calculation are not constant. 10. XeO2F2 has a trigonal bipyramidal electron group geometry, and a square pyramidal molecular group geometry. 11. Naphthalene, C10H8, is made up of two benzene rings stacked or glued together. The number of dominant resonance structures of naphthalene is two. 12. The order of hydrohalidic acids ionic character in increasing order is: I < Br < Cl < F. 13. Prussian blue precipitate from potassium ferricyanide indicates the presence of Fe3+ ions, while from potassium ferrocyanide indicates the presence of Fe2+ ions. 14. The net dipole moment of water explains sodium chlorides miscibility in it. 15. In excess ammonia, Zn2+ will form a colorless complex [Zn(NH3)2]2+, while in excess NaOH, Zn2+ will form a colorless complex [Zn(OH)4]2-. 16. Nitrate ion does not exhibit pi bond delocalization. 17. Adding potassium ferricyanide to Zn2+ will form yellow precipitate KZn[Fe(CN)6], while adding potassium ferrocyanide will form white precipitate KZn3[Fe(CN)6]. 18. There will be an exothermic change in heat if the system gives off heat to the surroundings, and the surroundings does work to the system. 19. An exothermic reaction from low entropy to high entropy will only proceed at high temperatures. 20. If a reaction is endothermic from high entropy to low entropy, the reverse reaction is non-spontaneous. CAUSE AND EFFECT. Determine the effect of the cause stated in the first column on the parameter in the second assuming all other variables are held constant. Effects: Increase, Decrease, No Effect Cause Actual molarity of the acid is greater than the recorded value. The cylinder used for measuring the base solution was wet. The student pulled the thermometer out of the set-up to take temperature readings. There is a tiny hole in the cork, exposing the inside of the calorimeter. Actual molarity of the base is greater than the recorded value.
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Effects: Becomes present, Becomes absent, No Effect (stays the same) Cause Parameter 6. Mossy Zinc and Aluminum metal were accidentally coiled together with iron Corroded Zinc nail. 7. Gelatin mixture was accidentally Appearance of Prussian blue added with concentrated NaOH (after 1 day) 8. KMnO4 was accidentally added in Persistence of Pink Color excess. 9. Litmus paper was accidentally dipped Indication of gaseous ammonia into unknown solution with NaOH. 10. Copper(II) nitrate was added with Dissolution to deep blue NaOH, then with excess ammonia. complex 11. Bromide sample was accidentally Pink-red toluene layer contaminated with iodide sample for Yellow toluene layer KMnO4 elimination test. IV.
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PROBLEM SOLVING. Read (without underestimation) the problems carefully, and solve for what is asked. There are ten problems in this part of the review.
50 mL of a wastewater sample near a lead-acid battery explosion site was acidified with 25 mL 6 M HCl, and was titrated with 32.6 mL of cerium(IV) sulfate solution. The cerium(IV) sulfate solution was prepared dissolving 250 g of the solid in 800 mL distilled water. e) If lead(II) and cerium(IV) becomes lead(IV) and cerium(III) during titration, WRITE the balanced equation of the redox reaction. f) CALCULATE the concentration of lead(II) ions in the wastewater sample.
d) CALCULATE the molecular formula of gallic acid. e) CALCULATE the molar heat of combustion of palmitic acid. f) WRITE the balanced equations for the combustion of palmitic acid and gallic acid. 6|DLRC Chem 16 LE2 Samplex
a) DRAW the first five periods of the DLRC-Land periodic table based on the information given above (You just need to draw blocks.) b) WRITE and DRAW the electronic configuration of DLRC-Land elements 28, 24, and 21. Give the quantum numbers of their last-entering electron. c) ARRANGE the following elements by their periodicity. Assume that like elements in Earth, DLRC-Land elements have their cationic and anionic forms. a. Atomic Radius: 7-, 162+ 62b. Ionization Energy: 2, 9, 13, 14 d) What rules in covalent bonding does DLRC-Land follow if our planets elements follow the octet rule and 18-electron rule? EXPLAIN. e) INDICATE which of the following hypothetical covalent compounds are possible to exist in DLRC-Land. If possible, DRAW their Lewis structures and indicate the electron-group geometry and moleculargroup geometry in each central atom. a. (6)(5)3 c. Hypothetical carbon chain (5)3(1)5 b. Hypothetical carbon chain (5)2(1)6 d. Hypothetical anion (13)(7)4 f) GIVE the hybridized DLRC-Land orbital that corresponds to (a) tetrahedral, (b) trigonal bipyramidal, and (c) octahedral electron-group geometry.
When 5 drops of E was added with 5 drops J, a brown precipitate formed. The precipitate turned colorless when added with 1 drop of L, but turned green when added with 3 drops of K. Solid F dissolves into a blue solution when added with L. When added with excess O, the solution turned deep blue. Only B and A released a basic gas (by litmus paper test) when added with 2 drops K. G, N, and P gave a brown ring when the test for nitrate was done. When 5 drops I was added with 2 drops 0.5 M P, a white precipitate formed, and it dissolved (with effervescence) in excess Q. When H was studied for the toluene elimination test, the toluene and aqueous layers turned yellowishbrown. When 10 mL I was added with 10 mL G, 0.972 g of brown-orange precipitate formed. When 5 mL N was added with 1 mL of 6 M K, 0.37 g of white precipitate formed. When 5 mL H was added with 5 mL of 1.0 M silver nitrate, 0.939 g of precipitate formed. When 10 mL B was added with 5 mL of 0.5 M P, 1.50 g of white precipitate formed, and it dissolved in excess organic acid Q. By records in the stock room, solution I was made by dissolving 73.89 g of it in 500 mL distilled water. By records in the stock room, solution N was made by dissolving 98.45 g of it in 600 mL distilled water.
After doing the said tests and observations, Air Asserc knew the corresponding compounds from A to Q. GIVE the corresponding compounds from A to Q. (NOTE: Some of the compounds have slight modifications from the compounds in the Chem 16 manual. Qualitative analysis alone is not enough to solve the problem.)
another alternative for propellants in space travel, but so far pentazole is known to be unstable and it does not last longer than a few seconds. e) DRAW the three most dominant resonance structures of pentazole anion. INDICATE the formal charges of each atom. GIVE the hybridization overlaps between the five nitrogen atoms for each resonance structure.
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Problem 8: Permanganometry
Permanganometry is a special redox titration that involves the use of permanganates, and it is an alternative to acid-base titration because permanganates can transform to different manganese species, depending on the pH of the solution. Standardization of KMnO4 is done by oxalic acid as the primary standard (You should know the formula of oxalic acid, based on inorganic nomenclature.) Oxalic acid was prepared by dissolving 0.63 g of oxalic acid crystals in 100 mL water. 20 mL of 0.1 M sulfuric acid is added to the oxalic acid solution to acidify the medium. The results of the standardization are as follows: Trial Starting Point Endpoint 1 0.0 mL 3.7 mL 2 3.7 mL 7.5 mL 3 7.5 mL 11.0 mL Organic acids (Acids containing C, H, and O) turn into carbon dioxide gas and water during titration. a) WRITE the balanced redox equation for standardization. b) CALCULATE the molarity of KMnO4 in each trial, and the average molarity of KMnO4. A Chem 16 student wants to find out the amount of Ascorbic Acid (MF = C6H8O6) in a sample of orange juice. A 25 mL orange juice sample was added with 25 mL distilled water, and was titrated with the KMnO4 solution. While titrating, the analyte slowly turned into a solution with brown precipitate. Trial Starting Point Endpoint 1 0.0 mL 5.6 mL 2 5.6 mL 11.6 mL 3 11.6 mL 17.0 mL c) WRITE the balanced redox equation for titration of ascorbic acid. d) CALCULATE the molarity of ascorbic acid in each trial, and the average molarity of ascorbic acid.
Problem 9: Olympicene
Olympicene (MW = 240.286 g/mol) is a special aromatic compound with five carbon rings stacked together like a benzene ring. It was recently synthesized by Anish Mistry and David Fox of the University of Warwick only for the purpose of celebrating the London 2012 Olympics. 1.00 g of olympicene (only containing C and H) was burned in excess oxygen and the combustion yielded 3.48 g carbon dioxide. a) CALCULATE the molecular formula of olympicene.
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The picture above is the carbon skeletal structure of olympicine. Based on experiments, only Ring 2 cannot undergo pi-bond delocalization. b) Can Ring 2 have all of its carbon atoms sp2 hybridized? EXPLAIN. c) GIVE three possible resonance structures of olympicene by assigning the C and H atoms, and double bonds. d) GIVE all possible hybridization overlaps in olympicene.
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