2006 8

1 3

A ugust, 2006
V o.l 1, N o3

,
(,
[ ]
[

200433)

; ; ;
300MW , ,

, ;

[ ]

TK 262. 23+ 1

[ ]

[ ]

1673- 6214 ( 2006) 03- 0038- 04

Analysis of Scaling Substance A dhered to H ollow Copper

ConductingW ire of Internal CoolingW ater G enerator
Q IU Yan-L ,i YANG Zhen-Guo
(D ep ar tm ent of M aterials S cience, Fudan University, Shanghai 200433, China )
K ey word s: scaling substance; w ater cooling system; character ization; corrosion
Abstrac t: To so lve the phenom enon o f abno rm al temperature r ising o f generator stator slo ts o f 300MW un it, scaling substance adhe red
to the ho llow copper conducting w ire of gene rato r sta to r w as charac terized and analyzed by SEM, ED S and FT IR. T he experim enta l resu lts show ed tha t the sca ling substance we re m a inly po lytetra fluo roethylene b ind ing resin,

fiberg lass bund le, sea ling g erm and copper

ox ide from corrosion. The abno rma l rising tem pera ture o f the stator slo ts was due to scaling substance block ing ho llow copper conducting
w ire.

,
,

,
,

, ,

[ 2]

[ 1]

CO2 O2 , pH ,
O2
, ,

1
, ,

, , , ,

, ,
,

300MW
[ ]

[ ]

2006 4 4

[ ]

( 1980 - ) , , ,

2006 6 16

[ 3]

39

3. 1
#

5 ,
, 2 ( a)( b) , 2a

, 2mm; 2b
, ,
1mm, 2mm, 0. 5mm,
, 13 m ~ 25 m

1
Fig. 1 W ater-flow d iagram of cooling water in the generator

5 5 6 6

,
,

( a) M orph ology of one part icle

2

3 5 6 5
, ,
, 5mm
#

4 6 ,
0. 6mm, , ,

( b )M orphology of anoth er particle

#

Fig. 2 M orphology of scaling particle in the N o. 5 slot up

3 5# 6#
4 6#
F ig. 3 M orphology of scal ing part icle situating in th e N o. 5 and N o. 6 s lot F ig. 4 M orphology of sca ling part icle in the N o. 6 slot down

40

3. 2

( EDS)
#
5

5 6 69. 8%
11. 8%
18. 3%

5, : 45. 9% 39. 1%

6 6. 5 %

12. 1% 2. 5% ,

93. 5 % ,

5
F ig. 5

5#

ED S analys is of s trip-l ike p lane particle in the N o. 5 slot up

3. 3

5 ,

, 4

E ,
13 m ~ 25 m , 6,

2a
, 6,

2b

,
,

, ; 2b
, ,

5 6 ,

5 6

( a) M orphology

( b) EDS an alysis
6
Fig. 6 M orpho logy and ED S analys is of f iber- glass bund le used as comp arison

:
#

41

-1

( FT IR ) , 5 6

1381cm CH 3 1073

, 7,
,

cm ~ 1287cm C-O ,
- 1
743cm

-1

- 1

-1

- 1

3440cm OH 3072cm

FT IR

- 1

EDS,

H 2860cm

- 1

~ 2960cm CH 3
-1

CH 2
1731cm - C = O
1463cm

- 1

- 1

~ 1660cm

7 5# 6#
F ig. 7

In frared sp ectrum ana lysis of scaling particle in the N o. 5 and N o. 6 slot

, 5

( 2mm 6mm ),

, 2. 5mm,

#
#
5 6 , ,
,
#
6

,
,

,
:
O2 + H 2 O + 2Cu= Cu2 O+ 2OH
O2 + H 2 O + Cu= CuO + 2OH

( 1)

Cu2 O+ O 2 + H 2O = 2CuO+ 2OH

3

( 2)
-

CO 2 + H 2OH 2 CO3HCO + H
+

( 3)
+

( 4)

( 5)

2+

( 6)

Cu2 O+ 2H + 2H CO = 2Cu + 2H CO + H 2 O
+

CuO + 2H + 2H CO = Cu + 2HCO + H 2O

( 10 )

10

alloy by electrochem ical noise [ J] . C orrosion-NACE , 2002, 58:

337-343.

[ 8] U Bertocci U, G ab rielli C, H uet F. N o ise resistance appl ied to cor-

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I.

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[ 10] . ( ) [ M ]. ,

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[ J ]. , 2002, 22 ( 4 ) : 241-

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( 41 )

( 1)( 2) ( 3)
-

, OH ,
+
( 4) H OH ,

, ( 5)( 6)

Cu2 O CuO ,

,
,

( 3) ,

, ,

[ 4]

,
,
,

[ 1] . [ J] .
, 2000, ( 6) : 6-8.
[ 2] . [ J] . ,

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( 1)

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