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The equations obtained from the four Gibbs equations by exploiting the exactness of the differentials of thermodynamics properties.
MAXWELLS RELATIONSHIP
After examine the four Gibbs relations, they are of the form
After differentiating:
With ( ) ( ) Simplifying the equations using the first two Gibbs relations from chap. 7 (entropy):
Nonreacting gas mixture is a mixture of two or more gases of fixed chemical composition which is described by specifying either the mole fraction or the mass fraction of each component.
Daltons law of addictive pressures: the pressure of a gas mixture is equal to the sum of the pressures each gas would exert if it existed alone at the mixture temperature and volume. Amagats law of addictive volumes: the volume of a gas mixture is equal to the sum of the volumes each gas would occupy if it existed alone at the mixture temperature and pressure.
and
Where
and
The apparent (or average) molar mass and gas constant of a mixture are expressed as
Also,
and
GAS MIXTURES :
and
P-v-T behavior of a real gas mixture can be predicted by using compressibility factor: Another way is to treat gas mixture as a pseudopure substance (Kays rule): component pressure component volume pressure fraction Pseudocritical pressure volume fraction partial pressure partial volume
Pseudocritical temperature
The extensive properties of a gas mixture : Can be determined by summing the contributions of each component of the mixture. The evaluation of intensive properties of a gas mixture : Involves averaging in terms of mass or mole fractions.