Class Xii Cbse 2009 Board Chemistry Solutions

1
Class XII, Chemistry
Board Exam 2009 Solutions
Code no 56/1
1. Metallic substances are conductors in solid state as well as in molten state

Ionic substances are insulators in solid state but conductors in molten
state and in aqueous solution. (1)
2. The process of changing the colloidal particles in a sol into the insoluble
precipitate by addition of some suitable electrolytes is known as coagulation
process. (1)
3.Pyrometallurgy is the branch of metallurgy which consists of the thermal

treatment of minerals and metallurgical ores and their concentrates to bring
about physical and chemical transformations in the materials to enable
recovery of valuable metals. (1)
4.Red phosphorus is polymeric which consists of chains of P4 tetrahedra

linked together whereas white phosphorus consists of a single tetrahedron
(1)
5. Hexen-3-ol (1)
6.
(1)
7. In aqueous solutions, the increasing order of basic strengths is:
(CH3)2NH > CH3NH2 > (CH3)3N > NH3
(1)
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8. It indicate the number of carbon atoms present in both the monomers of

nylon 6,6 which are hexamethylene diamine and adipic acid. (1)
9. Lead storage battery is a secondary cell. (1/2)
Anode: Pb(s) + SO4 2- (aq) → PbSO4 (s) + 2e- (1/2)
Cathode: PbO2(s) + SO4 2- (aq) + 4H+(aq) + 2e- → PbSO4 (s) + 2H2O(l)

(1/2)
Overall cell reaction:
Pb(s) + PbO2(s) + 2H2SO4 (aq) → 2PbSO4 (s) + 2H2O(l) (1/2)
Or
◦
MnO4-(aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O(l) E = +1.51V
◦
Sn4+ (aq) + 2e- → Sn2+ (aq) E = -0.15V
Cathode reduction reaction:

MnO4 (aq)  8H (aq)  5e  Mn2  (aq)  4H2O (l)
Anode-Oxidation reaction:
Sn2+ (aq) → Sn4+ (aq) + 2e-
Redox equation:
2MnO4-(aq) + 16H+(aq) + 5Sn2+ (aq) → 2Mn2+ (aq) + 8H2O(l) + 5Sn4+ (aq)
(1)
◦ ◦
Cell potential = E reduction - E oxidation (1/2)
= 1.51 - (-0.15)
= 1.66 V (1/2)
10. (i) An elementary step in a reaction is a chemical reaction in which one

or more of the reactants react directly to form products in a single reaction
step. (1)

3
(ii) Rate of a reaction is defined as the rate of decrease in concentration of

any on of the reactants or the rate of increase in concentration of any one of
the products. (1)
11.(i) In this method ,the impure metal acts as anode which undergoes
oxidation and pure metal acts as cathode which undergoes reduction. The
metal ions deposit on the cathode as metal. (1)
(ii) Vapour phase refining is based on the principle that metal is converted to
its volatile compound and collected which decomposes to give pure metal.
(1)
12.
(i) 2XeF2 + 2H2O → 2Xe + 4HF + O2 (1)
(ii) 2PH3 + 3HgCl2 → Hg3P2 + 6HCl (1)
13.
(i) 2MnO4-(aq) + 5C2O42- (aq) + 16H+(aq)→ 2Mn2+ (aq) + 8H2O + 10CO2
(1)
(ii) Cr2O72- (aq) + 6Fe2+(aq) + 14H+(aq)→ 2Cr3+ +6Fe3+(aq) + 7H2O

(1)
14.
(i) will undergo S N 1 reaction faster than
because is a tertiary alkyl halide and is a

secondary alkyl halide (1 Mark)

4
(ii) will undergo S N 1 reaction faster than
because is a
secondary alkyl halide and is a
primary alkyl halide. (1)
15. (i)
HI 
(1)
(ii) CH3CH2CH=CH2 + HBr → CH3CH2CH-CH3

│
Br
(1 Mark)
16. Four bases in DNA are Adenine ,Guanine, Thymine and Cytosine
(1)
Thymine is not present in RNA. (1)
17. Vitamin A and D are fat soluble vitamins.

5
Sources Disease
A Carrots, butter Xerophthalmia
(1)
D Exposure to sunlight, Rickets
fish (1)
18.
Thermoplastic polymers Thermosetting polymers
Molecular Structure Linear or slightly Cross linked or heavily

branched long chain branched molecules
molecules (1)
Behaviour Can undergo softening
on heating and Do not soften on
hardening on cooling heating
(1)
Ans.19
k = 0.0051 min-1
[A0] = 0.10 M
t = 3 hours = 3× 60 min
k = 2.303 log [A0] (1)
t [A]
0.0051 = 2.303 log 0.1 (1)

3× 60 [A]
log [A] = -1.39
[A] = 4.074 × 10-2 M (1)
Ans.20. a = 409 pm, r = ?

6
21. Ecell = 0.422 V
◦ + ◦ 2+
Since E Ag /Ag >E Cu /Cu
So, Ag / Ag is cathode and Cu2+/Cu is the anode.

7
Ecell  Ereduction  EOxidation

 0.80  0.34
 0.46V (1 / 2 )
Cell Re action : 2Ag  Cu  Cu2   2Ag
2
0.059 Cu2   Ag
Ecell  E cell 

log 2
(1 / 2 )
n  Ag  Cu
0.059 [0.1]
Ecell  0.46  log
2 [Ag ]2
2
0.422  0.46  0.029{log[0.1]  log  Ag  }
log[.1]  2log  Ag   1.310
(log101 )  2log[Ag ]  1.310
1  2log[Ag ]  1.310
2.310
2log  Ag   (1 )
2
log  Ag   1.155

 Ag   Antilog(1.155)
 Ag   0.0699M (1 )
22. (i) If an electrolyte is added to a hydrated ferric oxide sol , the colloidal
particles get precipitated (1)
(ii) Scattering of light takes place and the the path of the beam is
illuminated (1)
(iii) The colloidal particles move towards oppositely charged

electrodes, get discharged and precipitated (1)
23. (i) The splitting of the degenerate d orbitals into eg and t2g orbitals due
to the presence of ligands in a definite geometry is called crystal field
splitting. (1)
(ii) Linkage isomerism arises in coordination compounds containing

ambidentate ligands in which two different atoms of the same ligand can
form coordinate bond with metal ion
8
Example: Co(NH3 )5 NO2  Cl2 and Co(NH3 )5 ONO Cl2 (1)
(iii) Ligands which can bind the central metal atom through two different
atoms are called ambidentate ligands
Example: SCN ,NCS (1)
OR
[Co(NH3)6]3+
Co3  (Ground state) 3d6 4s0 4p0
d2sp3 hybridisation of Co3+
Structural shape – Octahedral
Hybrid Orbitals- d2sp3
Magnetic behaviour- Diamagnetic (1)
Cr(NH3 )6 
3

9
Cr3  (Ground state) 3d3 4s0 4p0
d2sp3 Hybridisation of Cr3 
Structural shape – Octahedral
Hybrid Orbitals- d2sp3
Magnetic behaviour- Paramagnetic (1)
Ni(CO)4
Ni - 3d8 4s2
sp3 hybrid orbitals of Ni

10
Structural shape- tetrahedral
Hybid orbitals- sp3
Magnetic behaviour- Diamagnetic (1)
24.(i) Hydrogen bonding in ethanol causes the boiling point of ethanol to be higher
(1)
(ii) Phenol on releasing a proton forms phenoxide win which is resonance

stablised .So, phenol is more acidic than ethanol. (1)
(iii) NO2 groupshas -I effect or electron withdrawing inductive effect. (1)
25 (i) Ability to show variable oxidation state and to form complexes
(ii) Lanthanoid contraction
(iii) 5f, 6d and 7s levels are of comparable energies.
26 (a)
(1)
(b)
(1)

11
(c)
(1)
27. (i) Non ionic detergents do not contain any ion in their constitution.
(1)
(ii) Food preservatives are substances which present spoilage of food

due to microbial growth. (1)
(iii) Disinfectants are chemicals which either kill or prevent the

growth of microorganisms .They cannot be applied on a living tissue. (1)
28. (a) (i)Mole fraction of a component is the ratio of number of moles of

the component to the total number of moles of all the components.
(1)
(ii) Van’t Hoff factor is the ratio of normal molar mass to the abnormal
molar mass. (1)
Van’t Hoff factor is the ratio of observed value of colligative property to
calculated value of colligative property assuming no association or
dissociation.
(b) Mass of protein = 100mg = 0.1 g
V= 10 mL
(1)

12
(1)
M = 13.98 g
Molar mass of protein=13.98 g (1)
Or
(a)
(i) All the properties which depend on the number of solute particles
irrespective of their nature relative to the total number of particles
present in the so solution are known as colligative properties. (1)
(ii) Molality of solution is the number of moles of solute present in 1
kilogram of solvent. (1)
(b)
pn2  KH x
XN2 (in air)  0.78
1000
nH2O   55.5mol (1)
18
Sincenn2  nH2O
nN2
xn2 
nH2O
nN2  0.78 * 55.5  43.29 mol (1)
Since 43.29 moles of N2 are present in 1000 ml of water,

concentration= 43.29 molar. (1)
Ans. 29.(a) (i) H2S2O8

13
(1)
(ii) HClO4
(1)
(b) (i) N is more electronegative than P. So lone pair of electrons is

concentrated more on nitrogen. (1)
(ii) Oxygen has a small size as compared to sulphur. So, the lone pairs on
oxygen repel each other. Thus, the O-O bond is weak whereas in case of
sulphur, the lone pair do not repel to the same extent.
As a result, S-S bond is stronger than O-O bond. So, S has a greater
tendency for catenation than oxygen. (1)
1
(iii) The net energy release for  X  (aq) is more negative for
X2 (g) 
2
fluorine as compared to chlorine i.e. sum of dissociation energy, electron
gain enthalpy and hydration energy is more negative for fluorine. So, it a
stronger oxidising agent than chlorine. (1)
Or
(a) (i) H2S2O7

14
(1)
(ii) HClO3
(1)
(b) (i) Because of partial double bond character of (N-O) bond. (1)
(ii) The axial bonds due to more repulsion are longer than
equatorial bonds. (1)
(iii) ICl is an interhalogen compound having electronegativity

difference. The I-Cl bond is more reactive than I2 . (1)
30. (a)
(i) Aldehydes which do not have an -hydrogen atom undergoes self
oxidation and reduction on treatment with concentrated alkali. (1)
(ii) Carboxylic acids having an -hydrogen are halogenated at the -
position on treatment with chlorine or bromine in the presence of
small amount of red phosphorus to give - halocarboxylic aids. (1)
(b) (i) Propanal and propanone
Fehling’s test

CH3CH3CHO  2Cu2   5OH  CH3CH2COO  Cu2O  3H2O
Re d ppt
Propanone being a ketone will not give this test. (1)
15
(ii) Acetophenone and benzophenone

Iodoform test
Benzophenone does not give this test. (1)
(iii) Phenol and Benzoic and
FeCl3 test
C6H5OH  FeCl3  (C6H5O )6  Fe]3   3HCl

Blue violet colour
Benzoic acid does not give this test. (1)
OR
(a)
(i)
(1)
(ii)

16
(1)
(b)

17
(1)
CrO3
CH3  CH2  CH2  CH2  OH   CH3  CH2  CH2  COOH
C B
dehydration
(1)
CH3  CH2  CH2  CH2  OH 
H2O
 CH3  CH2  CH  CH2
But  1  ene
(1)


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Class XII, Chemistry

Board Exam 2009 Solutions

1. Metallic substances are conductors in solid state as well as in molten state

3.Pyrometallurgy is the branch of metallurgy which consists of the thermal

4.Red phosphorus is polymeric which consists of chains of P4 tetrahedra

Get the best brains on your side.

8. It indicate the number of carbon atoms present in both the monomers of

9. Lead storage battery is a secondary cell. (1/2)

Anode: Pb(s) + SO4 2- (aq) → PbSO4 (s) + 2e- (1/2)

Cathode: PbO2(s) + SO4 2- (aq) + 4H+(aq) + 2e- → PbSO4 (s) + 2H2O(l)

Overall cell reaction:

Pb(s) + PbO2(s) + 2H2SO4 (aq) → 2PbSO4 (s) + 2H2O(l) (1/2)

Cathode reduction reaction:

10. (i) An elementary step in a reaction is a chemical reaction in which one

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(ii) Rate of a reaction is defined as the rate of decrease in concentration of

(ii) 2PH3 + 3HgCl2 → Hg3P2 + 6HCl (1)

(ii) Cr2O72- (aq) + 6Fe2+(aq) + 14H+(aq)→ 2Cr3+ +6Fe3+(aq) + 7H2O

(i) will undergo S N 1 reaction faster than

because is a tertiary alkyl halide and is a

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(ii) will undergo S N 1 reaction faster than

secondary alkyl halide and is a

primary alkyl halide. (1)

(ii) CH3CH2CH=CH2 + HBr → CH3CH2CH-CH3

Thymine is not present in RNA. (1)

17. Vitamin A and D are fat soluble vitamins.

Molecular Structure Linear or slightly Cross linked or heavily

0.0051 = 2.303 log 0.1 (1)

Ans.20. a = 409 pm, r = ?

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21. Ecell = 0.422 V

So, Ag / Ag is cathode and Cu2+/Cu is the anode.

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Ecell  Ereduction  EOxidation

(iii) The colloidal particles move towards oppositely charged

(ii) Linkage isomerism arises in coordination compounds containing

Example: Co(NH3 )5 NO2  Cl2 and Co(NH3 )5 ONO Cl2 (1)

Co3  (Ground state) 3d6 4s0 4p0

d2sp3 hybridisation of Co3+

Structural shape – Octahedral

Hybrid Orbitals- d2sp3

Magnetic behaviour- Diamagnetic (1)

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Cr3  (Ground state) 3d3 4s0 4p0

d2sp3 Hybridisation of Cr3 

Structural shape – Octahedral

Hybrid Orbitals- d2sp3

Magnetic behaviour- Paramagnetic (1)

sp3 hybrid orbitals of Ni

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Structural shape- tetrahedral

Hybid orbitals- sp3

Magnetic behaviour- Diamagnetic (1)

(ii) Phenol on releasing a proton forms phenoxide win which is resonance

(iii) NO2 groupshas -I effect or electron withdrawing inductive effect. (1)

25 (i) Ability to show variable oxidation state and to form complexes

(ii) Lanthanoid contraction

(iii) 5f, 6d and 7s levels are of comparable energies.

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(ii) Food preservatives are substances which present spoilage of food