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NCERT Solutions for Class 12th Chemistry Chapter 2 Solutions

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NCERT Solutions for Class 12th Chemistry Chapter 2 Solutions

September 3, 2012 | Filed under: 12th Class,Book Solutions,Chemistry | Posted by: admin

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NCERT Solutions for Class 12th Chemistry Chapter 2 Solutions

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Question 2.23: Suggest the most important type of intermolecular attractive interaction in the following pairs. (i) n-hexane and n-octane (ii) I2 and CCl4 (iii) NaClO4 and water (iv) methanol and acetone (v) acetonitrile (CH3CN) and acetone (C3H6O). Answer (i) Van der Walls forces of attraction. (ii) Van der Walls forces of attraction. (iii) Ion-diople interaction. (iv) Dipole-dipole interaction. (v) Dipole-dipole interaction. Question 2.24: Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain. Cyclohexane, KCl, CH3OH, CH3CN. Answer n-octane is a non-polar solvent. Therefore, the solubility of a non-polar solute is more than that of a polar solute in the noctane. The order of increasing polarity is: Cyclohexane < CH3CN < CH3OH < KCl Therefore, the order of increasing solubility is: KCl < CH3OH < CH3CN < Cyclohexane Question 2.25: Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water? (i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform (vi) pentanol. Answer (i) Phenol (C6H5OH) has the polar group OH and non-polar group C6H5. Thus, phenol is partially soluble in water.
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(ii) Toluene (C6H5 CH3) has no polar groups. Thus, toluene is insoluble in water. (iii) Formic acid (HCOOH) has the polar group OH and can form H-bond with water. Thus, formic acid is highly soluble in water. (iv) Ethylene glycol has polar OH group and can form H bond. Thus, it is highly soluble in water. (v) Chloroform is insoluble in water. (vi) Pentanol (C5H11OH) has polar OH group, but it also contains a very bulky nonpolar C5H11 group. Thus, pentanol is partially soluble in water.

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