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(viscosity)
(surface tension)(diffusion
coefficient)
(1)
(Tc)
(Pc)
c)
(critical point)
(g/cm 3 )
(g/cms)
(cm 2 /s)
10-3
10-4
10-1
10-2
10-5
0.2-0.9
10-4
10-3
S C F
Andrews1869
1879HannayHogarth
1937Michels
1950
(compressibility)(density)
(polar)(solubility)
(dielectric constant)
1970
1978
Bremen
2004623
CO 2
(supercritical carbondioxide,
SF-CO 2 )CO 2
72.8
(Pc72.8atm, Tc
31.1)
1.
(supercritical fluid
SF-CO 2
extraction, SCFE)
(mass transfer)
(extraction)(separation)
(cleaning)(coating)
(impregnation)(particle
(entrainer)
formation)(reaction)
(1)
31.1
atm
g/ml
CO 2
31.1
72.8
0.468
N 2 O
36.4
72.5
0.452
0.322
H 2 O
28.8
38.7
NH 3
132.5
112.8
0.235
CH 4 O
239.5
80.9
0.272
CH 4
-82.6
46
0.162
C 2 H 4
9.3
50.3
0.218
C 2 H 6
32.2
48.8
0.203
C 3 H 11
96.7
42.4
0.217
C 3 H 6
91.9
46.2
0.233
C 6 H 6
289.0
48.9
0.302
C 7 H 8
318.6
47.1
0.292
C 3 H 6 O
235.0
47.0
0.278
274.7
47.7
0.237
28.9
39.2
0.579
CH 3 CN
CF 3 Cl
10
) ( 1 0 9 )
(2)
(supercritical drying)
solutions, RESS)
1978
PGSS)(supercritical
Bremen
anti-solvent, SAS)
by supercritical fluids,SEDS)
2.
3.
1990
4.
( 1 0 6
11
RaytheonCool Clean
5.
1995
199911
2003
1000
(Subcritical water
oxidation, SCWO)
1.
P154-P166112007
2.S u b r a m a n y a m B . , R a j e s w s k i R . a n d S n a v e l y K . ,
Pharmaceutical processing with Subcritical carbon dioxide, J.
Pharm. Sci., 86, 885~890(1997)