Chemistry 101 Homework Problem Set # 4 Due Monday, October 6

Name: Section (circle): 01 02 03

These questions are based on sections and sections 4.6-4.10, and 5.1-5.7 of the textbook: Timberlake, K. General, Organic and Biological Chemistry: Structures of Life (Platinum Edition) 1. Identify the following compounds as ionic or covalent and name each one. (Remember, prexes are only used for the covalent compounds.) (a) SBr2 (b) NI3 (c) K3 N (d) Ca3 (PO4 )2 (e) PbCl4 (f) Cl2 O7

2. Predict the shape and polarity of each of the following molecules: (a) H2 S (b) CF4 (c) NF3 (d) CCl3 H

3. Timberlake problem 4.66: Place the symbols for partially positive ( + ) and partially negative ( ) above the appropriate atoms in the following polar covalent bonds. (a) O-H (b) O-S (c) P-Cl (d) S-Cl

4. Here are a few specic heat questions: (a) How many calories must be added to 40.0 g of sand to raise its temperature from 23.2 C to 45.6 C?

(b) How many calories are released when 2.3 g of silver are cooled from 62.1 C to 21.7 C?

(c) If 4620 calories are added to a 1.287 kg block of copper, initially at 30.0 C, what is the nal temperature of the block?

(d) When 3.4 kilocalories are added to a 243 g sample of an unknown metal initially at 19.7 C, the temperature rises to 43.5 C. What is the specic heat of the metal? OVER

Chemistry 101, Fall 2003

Homework Problem Set 4, page 2

5. Timberlake, problem 5.18: Using the caloric values for foods, determine each of the following: (a) The total Calories (kcal) for 2 tablespoons of crunchy peanut butter that contains 6 g of carbohydrates, 16 g of fat and 7 g of protein.

(b) The grams of protein in 1 cup of soup that has 110 Calories (kcal) with 7 g of fat and 9 g of carbohydrates.

(c) How many grams of carbohydrates are in 1 can of cola if there are 140 Calories and no fat or protein?

(d) How many grams of fat are in 1 avocado if there are 405 Calories, 13 g of carbohydrates, and 5 g of protein.

6. Calculate the number of (a) calories needed to melt a 21.0 g ice cube

(b) joules released when 45.2 g of liquid water freezes

(c) calories release when 5.2 g of steam condenses

(d) kilojoules required to turn 987 mL of liquid water into steam

7. Calculate the TOTAL number of calories required to warm 2.0 gallons of liquid water, initially at 22.3 C to 100 C and turn it into steam.

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