Chemical refrigerants are assigned an R number (sometimes the label replaces it with the word Freon) which is

determined systematically according to molecular structure. The following is a list of refrigerants with their
Type/Prefix, ASHRAE designated numbers, IUPAC chemical name, molecular formula, CAS registry number /
Blend Name, Atmospheric Lifetime in years, Semi-Empirical Ozone depletion potential, net Global warming
potential over a 100-year time horizon, Occupational exposure limit/Permissible exposure limit in parts per
million (volume per volume) over a time-weighted average (TWA) concentration for a normal eight-hour work
day and a 40-hour work week, ASHRAE 34 Safety Group in Toxicity & Flammability (in Air @ 60C & 101.3
kPa) classing, Refrigerant Concentration Limit / Immediately Dangerous to Life or Health in parts per million
(volume per volume) & grams per cubic meter, Molecular mass in Atomic mass units uncertainty, Normal
Boiling Point (or Bubble & Dew Points for the Zeotrope(400)-series)(or Normal Boiling Point & Azeotropic
Temperature for the Azeotrope(500)-series) at 101,325 Pa (1 atmosphere) in degrees Celsius, Critical
Temperature in degrees Celsius and Critical Pressure (absolute) in kiloPascals.
Frigorifici chimice sunt alocate un numr de R (uneori eticheta se nlocuiete cu freon cuvntul), care se
determin sistematic n funcie de structura moleculara.Urmtoarea este o list de refrigerare cu tipul lor / Prefix,
numere de Ashrae desemnate, IUPAC denumirea chimic, formula molecular, numrul CAS Registrul / Blend
Nume, durata de via atmosferic n ultimii ani, semi-empirice Diminuarea stratului de ozon potenial, potenial
net de nclzire global de peste de 100 an orizontul de timp, limita de expunere profesional / limit de expunere
admis n pri per milion (de volum pe unitatea de volum), pe o medie ponderat n timp (TWA), concentraia
pentru o zi normala de lucru de opt ore i o sptmn 40 de ore de munc, ASHRAE 34 de siguran Grupul de
toxicitate i inflamabilitate (n aer @ 60 C i 101,3 kPa) classing, limita de concentraie de agent frigorific / un
pericol imediat pentru viaa sau sntatea n pri per milion (de volum pe unitatea de volum) i de grame pe
metru cub, masa molecular n uniti de mas atomic incertitudine, Punctul de fierbere n condiii normale
(sau Bubble & Puncte de rou pentru Zeotrope (400) de serie) (sau punctul de fierbere n condiii normale de
temperatur i azeotrop pentru Azeotrope (500) de serie), la 101,325 Pa (1 atmosfer), n grade Celsius,
temperatura critic n grade Celsius i de presiune critice (absolut), n kilopascali.
T
y
p
e

Number

PCC

R-10

CFC
CFC
H
H
CFC
H
PFC
HCC
HCFC
HCFC
H

R-11
R-12
R-12B1
R-12B2
R-13
R-13B1
R-14
R-20
R-21
R-22
R-22B1

IUPAC Chemical Name

Carbon tetrachloride
(Tetrachloromethane)
Trichlorofluoromethane
Dichlorodifluoromethane
Bromochlorodifluoromethane
Dibromodifluoromethane
Chlorotrifluoromethane
Bromotrifluoromethane
Tetrafluoromethane
Chloroform (Trichloromethane)
Dichlorofluoromethane
Chlorodifluoromethane
Bromodifluoromethane

Molecular
Formula

CAS
registry
number/
Blend
Name

CCl4

56-23-5

CCl3F
CCl2F2
CBrClF2 or CF2ClBr
CBr2F2
CClF3
CF3Br
CF4
CHCl3
CHFCl2
CHClF2
CHBrF2 or CHF2Br

75-69-4
75-71-8
353-59-3
75-61-6
75-72-9
75-63-8
75-73-0
67-66-3
75-43-4
75-45-6
1511-62-2

T
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HFC
HCC
HCFC
HFC
HCC
HFC
HC
PCC
CFC
CFC
CFC
CFC
CFC
CFC
CFC
H
CFC
PFC
HCC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HFC
HFC
HCC
HCC
HCFC
HCFC
HCFC
HCFC

Number
R-23
R-30
R-31
R-32
R-40
R-41
R-50
R-110
R-111
R-112
R-112a
R-113
R-113a
R-114
R-114a
R-114B2
R-115
R-116
R-120
R-121
R-121a
R-122
R-122a
R-122b
R-123
R-123a
R-123b
R-124
R-124a
R-125
R-E125
R-130
R-130a
R-131
R-131a
R-131b
R-132

IUPAC Chemical Name

Molecular
Formula

Trifluoromethane (Fluoroform)
Dichloromethane (Methylene chloride)
Chlorofluoromethane
Difluoromethane
Chloromethane
Fluoromethane
Methane
Hexachloroethane
Pentachlorofluoroethane
1,1,2,2-Tetrachloro-1,2-difluoroethane
1,1,1,2-Tetrachloro-2,2-difluoroethane
1,1,2-Trichlorotrifluoroethane
1,1,1-Trichlorotrifluoroethane
1,2-Dichlorotetrafluoroethane
1,1-Dichlorotetrafluoroethane
1,2-Dibromotetrafluoroethane
Chloropentafluoroethane
Hexafluoroethane
Pentachloroethane
1,1,2,2-Tetrachloro-1-fluoroethane
1,1,1,2-Tetrachloro-2-fluoroethane
1,1,2-Trichloro-2,2-difluoroethane
1,1,2-Trichloro-1,2-difluoroethane
1,1,1-Trichloro-2,2-difluoroethane
2,2-Dichloro-1,1,1-trifluoroethane
1,2-Dichloro-1,1,2-trifluoroethane
1,1-Dichloro-1,2,2-trifluoroethane
2-Chloro-1,1,1,2-tetrafluoroethane
1-Chloro-1,1,2,2-tetrafluoroethane
Pentafluoroethane
Pentafluorodimethyl ether
1,1,2,2-Tetrachloroethane
1,1,1,2-Tetrachloroethane
1,1,2-Trichloro-2-fluoroethane
1,1,2-Trichloro-1-fluoroethane
1,1,1-Trichloro-2-fluoroethane
Dichlorodifluoroethane

CHF3
CH2Cl2
CH2FCl
CH2F2
CH3Cl
CH3F
CH4
C2Cl6
C2FCl5
C2F2Cl4
C2F2Cl4
C2F3Cl3
C2F3Cl3
C2F4Cl2
C2F4Cl2
C2F4Br2
C2F5Cl
C2F6
C2HCl5
C2HFCl4
C2HFCl4
C2HF2Cl3
C2HF2Cl3
C2HF2Cl3
C2HF3Cl2
C2HF3Cl2
C2HF3Cl2
C2HF4Cl
C2HF4Cl
C2HF5
C2HF5O
C2H2Cl4
C2H2Cl4
C2H2FCl3
C2H2FCl3
C2H2FCl3
C2H2F2Cl2

CAS
registry
number/
Blend
Name
75-46-7
75-09-2
593-70-4
75-10-5
74-87-3
593-53-3
74-82-8
67-72-1
354-56-3
76-12-0
76-11-9
76-13-1
354-58-5
76-14-2
374-07-2
124-73-2
76-15-3
76-16-4
76-01-7
354-14-3
354-11-0
354-21-2
354-15-4
354-12-1
306-83-2
354-23-4
812-04-4
2837-89-0
354-25-6
354-33-6
3822-68-2
79-34-5
630-20-6
359-28-4
811-95-0
2366-36-1
25915-78-0

T
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HCFC
HCFC
HCFC
H
HCFC
HCFC
HCFC
HFC
HFC
HFC
HCC
HCC
HCFC
H
HCFC
HCFC
HCFC
HCFC
HCFC
HFC
HFC
HFC
HFC
HCC
HCC
HCFC
HCFC
HFC
HFC
HCC
HFC
HC
HC
CFC
CFC
CFC

Number
R-132a
R-132b
R-132c
R-132bB2
R-133
R-133a
R-133b
R-134
R-134a
R-E134
R-140

IUPAC Chemical Name

1,1-Dichloro-2,2-difluoroethane
1,2-Dichloro-1,1-difluoroethane
1,1-Dichloro-1,2-difluoroethane
1,2-Dibromo-1,1-difluoroethane
1-Chloro-1,2,2-Trifluoroethane
1-Chloro-2,2,2-Trifluoroethane
1-Chloro-1,1,2-Trifluoroethane
1,1,2,2-Tetrafluoroethane
1,1,1,2-Tetrafluoroethane
Bis(difluoromethyl)ether
1,1,2-Trichloroethane
1,1,1-Trichloroethane (Methyl
R-140a
chloroform)
R-141
1,2-Dichloro-1-fluoroethane
R-141B2
1,2-Dibromo-1-fluoroethane
R-141a
1,1-Dichloro-2-fluoroethane
R-141b
1,1-Dichloro-1-fluoroethane
R-142
Chlorodifluoroethane
R-142a
1-Chloro-1,2-difluoroethane
R-142b
1-Chloro-1,1-difluoroethane
R-143
1,1,2-Trifluoroethane
R-143a
1,1,1-Trifluoroethane
R-143m
Methyl trifluoromethyl ether
R-E143a
2,2,2-Trifluoroethyl methyl ether
R-150
1,2-Dichloroethane
R-150a
1,1-Dichloroethane
R-151
Chlorofluoroethane
R-151a
1-Chloro-1-fluoroethane
R-152
1,2-Difluoroethane
R-152a
1,1-Difluoroethane
R-160
Chloroethane (ethyl chloride)
R-161
Fluoroethane
R-170
Ethane
R-E170
Dimethyl ether
R-211 1,1,1,2,2,3,3-Heptachloro-3-fluoropropane
R-212
Hexachlorodifluoropropane
R-213
1,1,1,3,3-Pentachloro-2,2,3-

C2H2F2Cl2
C2H2F2Cl2
C2H2F2Cl2
C2H2Br2F2
C2H2F3Cl
C2H2F3Cl
C2H2F3Cl
C2H2F4
C2H2F4
C2H2F4O
C2H3Cl3

CAS
registry
number/
Blend
Name
471-43-2
1649-08-7
1842-05-3
75-82-1
431-07-2
75-88-7
421-04-5
359-35-3
811-97-2
1691-17-4
79-00-5

C2H3Cl3 or CH3CCl3

71-55-6

C2H3FCl2
C2H3Br2F
C2H3FCl2
C2H3FCl2
C2H3F2Cl
C2H3F2Cl
C2H3F2Cl
C2H3F3
C2H3F3
C2H3F3O
C3H5F3O
C2H4Cl2
C2H4Cl2
C2H4ClF
C2H4ClF
C2H4F2
C2H4F2
C2H5Cl
C2H5F
C2H6 or CH3CH3
CH3OCH3
C3FCl7
C3F2Cl6
C3F3Cl5

430-57-9
358-97-4
430-53-5
1717-00-6
25497-29-4
25497-29-4
75-68-3
430-66-0
420-46-2
421-14-7
460-43-5
107-06-2
75-34-3
110587-14-9
1615-75-4
624-72-6
75-37-6
75-00-3
353-36-6
74-84-0
115-10-6
422-78-6
76546-99-3
2354-06-5

Molecular
Formula

T
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p
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Number

CFC

R-214

CFC

R-215

CFC

R-216

CFC

R-216ca

CFC
CFC
PFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC

R-217
R-217ba
R-218
R-221
R-222
R-222c
R-223
R-223ca
R-223cb
R-224
R-224ca
R-224cb
R-224cc
R-225

HCFC

R-225aa

HCFC

R-225ba

HCFC

R-225bb

HCFC

R-225ca

HCFC

R-225cb

HCFC

R-225cc

HCFC

R-225da

HCFC

R-225ea

IUPAC Chemical Name

trifluoropropane
1,2,2,3-Tetrachloro-1,1,3,3tetrafluoropropane
1,1,1-Trichloro-2,2,3,3,3pentafluoropropane
1,2-Dichloro-1,1,2,3,3,3hexafluoropropane
1,3-Dichloro-1,1,2,2,3,3hexafluoropropane
1-Chloro-1,1,2,2,3,3,3-heptafluoropropane
2-Chloro-1,1,1,2,3,3,3-heptafluoropropane
Octafluoropropane
1,1,1,2,2,3-Hexachloro-3-fluoropropane
Pentachlorodifluoropropane
1,1,1,3,3-Pentachloro-2,2-difluoropropane
Tetrachlorotrifluoropropane
1,1,3,3-Tetrachloro-1,2,2-trifluoropropane
1,1,1,3-Tetrachloro-2,2,3-trifluoropropane
Trichlorotetrafluoropropane
1,3,3-Trichloro-1,1,2,2-tetrafluoropropane
1,1,3-Trichloro-1,2,2,3-tetrafluoropropane
1,1,1-Trichloro-2,2,3,3-tetrafluoropropane
Dichloropentafluoropropane
2,2-Dichloro-1,1,1,3,3pentafluoropropane
2,3-Dichloro-1,1,1,2,3pentafluoropropane
1,2-Dichloro-1,1,2,3,3pentafluoropropane
3,3-Dichloro-1,1,1,2,2pentafluoropropane
1,3-Dichloro-1,1,2,2,3pentafluoropropane
1,1-Dichloro-1,2,2,3,3pentafluoropropane
1,2-Dichloro-1,1,3,3,3pentafluoropropane
1,3-Dichloro-1,1,2,3,3-

Molecular
Formula

CAS
registry
number/
Blend
Name

C3F4Cl4

2268-46-4

C3F5Cl3

4259-43-2

C3F6Cl2

661-97-2

C3F6Cl2

662-01-1

C3F7Cl
C3F7Cl
C3F8
C3HFCl6
C3HF2Cl5
C3HF2Cl5
C3HF3Cl4
C3HF3Cl4
C3HF3Cl4
C3HF4Cl3
C3HF4Cl3
C3HF4Cl3
C3HF4Cl3
C3HF5Cl2

422-86-6
76-18-6
76-19-7
422-26-4
134237-36-8
422-49-1
134237-37-9
422-52-6
422-50-4
134237-38-0
422-54-8
422-53-7
422-51-5
127564-92-5

C3HF5Cl2

128903-21-9

C3HF5Cl2

422-48-0

C3HF5Cl2

422-44-6

C3HF5Cl2

422-56-0

C3HF5Cl2

507-55-1

C3HF5Cl2

13474-88-9

C3HF5Cl2

431-86-7

C3HF5Cl2

136013-79-1

T
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Number

HCFC

R-225eb

HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HFC

R-226
R-226ba
R-226ca
R-226cb
R-226da
R-226ea
R-227ca

HFC

R-227ca2

HFC

R-227ea

HFC

R-227me

HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC

R-231
R-232
R-232ca
R-232cb
R-233
R-233ca
R-233cb
R-233cc
R-234
R-234aa
R-234ab
R-234ba
R-234bb
R-234bc
R-234ca
R-234cb
R-234cc
R-234cd
R-234da
R-234fa
R-234fb
R-235
R-235ca

IUPAC Chemical Name

pentafluoropropane
1,1-Dichloro-1,2,3,3,3pentafluoropropane
Chlorohexafluoropropane
2-Chloro-1,1,1,2,3,3-hexafluoropropane
3-Chloro-1,1,1,2,2,3-hexafluoropropane
1-Chloro-1,1,2,2,3,3-hexafluoropropane
2-Chloro-1,1,1,3,3,3-hexafluoropropane
1-Chloro-1,1,2,3,3,3-hexafluoropropane
1,1,2,2,3,3,3-Heptafluoropropane
Trifluoromethyl 1,1,2,2-tetrafluoroethyl
ether
1,1,1,2,3,3,3-Heptafluoropropane
Trifluoromethyl 1,2,2,2-tetrafluoroethyl
ether
Pentachlorofluoropropane
Tetrachlorodifluoropropane
1,1,3,3-Tetrachloro-2,2-difluoropropane
1,1,1,3-Tetrachloro-2,2-difluoropropane
Trichlorotrifluoropropane
1,1,3-Trichloro-2,2,3-trifluoropropane
1,1,3-Trichloro-1,2,2-trifluoropropane
1,1,1-Trichloro-2,2,3-trifluoropropane
Dichlorotetrafluoropropane
2,2-Dichloro-1,1,3,3-tetrafluoropropane
2,2-Dichloro-1,1,1,3-tetrafluoropropane
1,2-Dichloro-1,2,3,3-tetrafluoropropane
2,3-Dichloro-1,1,1,2-tetrafluoropropane
1,2-Dichloro-1,1,2,3-tetrafluoropropane
1,3-Dichloro-1,2,2,3-tetrafluoropropane
1,1-Dichloro-2,2,3,3-tetrafluoropropane
1,3-Dichloro-1,1,2,2-tetrafluoropropane
1,1-Dichloro-1,2,2,3-tetrafluoropropane
2,3-Dichloro-1,1,1,3-tetrafluoropropane
1,3-Dichloro-1,1,3,3-tetrafluoropropane
1,1-Dichloro-1,3,3,3-tetrafluoropropane
Chloropentafluoropropane
1-Chloro-1,2,2,3,3-pentafluoropropane

Molecular
Formula

CAS
registry
number/
Blend
Name

C3HF5Cl2

111512-56-2

C3HF6Cl
C3HF6Cl
C3HF6Cl
C3HF6Cl
C3HF6Cl
C3HF6Cl
C3HF7

134308-72-8
51346-64-6
422-57-1
422-55-9
431-87-8
359-58-0
2252-84-8

C3HF7O

2356-61-8

C3HF7

431-89-0

C3HF7O

2356-62-9

C3H2FCl5
C3H2F2Cl4
C3H2F2Cl4
C3H2F2Cl4
C3H2F3Cl3
C3H2F3Cl3
C3H2F3Cl3
C3H2F3Cl3
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F4Cl2
C3H2F5Cl
C3H2F5Cl

134190-48-0
134237-39-1
1112-14-7
677-54-3
134237-40-4
131221-36-8
421-99-8
131211-71-7
127564-83-4
17705-30-5
149329-24-8
425-94-5
149329-25-9
149329-26-0
70341-81-0
4071-01-6
422-00-5
70192-63-1
146916-90-7
76140-39-1
64712-27-2
134237-41-5
28103-66-4

T
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Number

HCFC
HCFC
HCFC
HCFC
HFC
HFC
HFC

R-235cb
R-235cc
R-235da
R-235fa
R-236cb
R-236ea
R-236fa

HFC

R-236me

HFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HFC
HFC
HFC
HFC
HFC

R-FE-36
R-241
R-242
R-243
R-243ca
R-243cb
R-243cc
R-243da
R-243ea
R-243ec
R-244
R-244ba
R-244bb
R-244ca
R-244cb
R-244cc
R-244da
R-244db
R-244ea
R-244eb
R-244ec
R-244fa
R-244fb
R-245ca
R-245cb
R-245ea
R-245eb
R-245fa

IUPAC Chemical Name

3-Chloro-1,1,1,2,3-pentafluoropropane
1-Chloro-1,1,2,2,3-pentafluoropropane
2-Chloro-1,1,1,3,3-pentafluoropropane
1-Chloro-1,1,3,3,3-pentafluoropropane
1,1,1,2,2,3-Hexafluoropropane
1,1,1,2,3,3-Hexafluoropropane
1,1,1,3,3,3-Hexafluoropropane
1,2,2,2-Tetrafluoroethyl difluoromethyl
ether
Hexafluoropropane
Tetrachlorofluoropropane
Trichlorodifluoropropane
Dichlorotrifluoropropane
1,3-Dichloro-1,2,2-trifluoropropane
1,1-Dichloro-2,2,3-trifluoropropane
1,1-Dichloro-1,2,2-trifluoropropane
2,3-Dichloro-1,1,1-trifluoropropane
1,3-Dichloro-1,2,3-trifluoropropane
1,3-Dichloro-1,1,2-trifluoropropane
Chlorotetrafluoropropane
2-Chloro-1,2,3,3-tetrafluoropropane
2-Chloro-1,1,1,2-tetrafluoropropane
3-Chloro-1,1,2,2-tetrafluoropropane
1-Chloro-1,2,2,3-tetrafluoropropane
1-Chloro-1,1,2,2-tetrafluoropropane
2-Chloro-1,1,3,3-tetrafluoropropane
2-Chloro-1,1,1,3-tetrafluoropropane
3-Chloro-1,1,2,3-tetrafluoropropane
3-Chloro-1,1,1,2-tetrafluoropropane
1-Chloro-1,1,2,3-tetrafluoropropane
3-Chloro-1,1,1,3-tetrafluoropropane
1-Chloro-1,1,3,3-tetrafluoropropane
1,1,2,2,3-Pentafluoropropane
Pentafluoropropane
1,1,2,3,3-Pentafluoropropane
1,1,1,2,3-Pentafluoropropane
1,1,1,3,3-Pentafluoropropane

C3H2F5Cl
C3H2F5Cl
C3H2F5Cl
C3H2F5Cl
C3H2F6
C3H2F6
C3H2F6

CAS
registry
number/
Blend
Name
422-02-6
679-99-2
134251-06-2
677-55-4
677-56-5
431-63-0
690-39-1

C3H2F6O

57041-67-5

C3H2F6
C3H3FCl4
C3H3F2Cl3
C3H3F3Cl2
C3H3F3Cl2
C3H3F3Cl2
C3H3F3Cl2
C3H3F3Cl2
C3H3F3Cl2
C3H3F3Cl2
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F4Cl
C3H3F5
C3H3F5
C3H3F5
C3H3F5
C3H3F5

359-58-0
134190-49-1
134237-42-6
134237-43-7
67406-68-2
70192-70-0
7125-99-7
338-75-0
151771-08-3
149329-27-1
134190-50-4

Molecular
Formula

421-73-8
679-85-6
67406-66-0
421-75-0
19041-02-2
117970-90-8

2730-64-5
679-86-7
1814-88-6
24270-66-4
431-31-2
460-73-1

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HFC
HFC
HFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HFC
HFC
HCFC
HCFC
HCFC
HCFC
HCFC
HCFC
HFC
HCFC
HCFC
HCFC
HCFC
HFC
HFC
HC
CFC

Number
R-245mc
R-245mf
R-245qc
R-251
R-252
R-252ca
R-252cb
R-252dc
R-252ec
R-253
R-253ba
R-253bb
R-253ca
R-253cb
R-253ea
R-253eb
R-253ec
R-253fa
R-253fb
R-253fc
R-254cb
R-254pc
R-261
R-261ba
R-262
R-262ca
R-262fa
R-262fb
R-263
R-271
R-271b
R-271d
R-271fb
R-272
R-281
R-290
R-C316

IUPAC Chemical Name

Molecular
Formula

Methyl pentafluoroethyl ether

Difluoromethyl 2,2,2-trifluoroethyl ether
Difluoromethyl 1,1,2-trifluoroethyl ether
Trichlorofluoropropane
Dichlorodifluoropropane
1,3-Dichloro-2,2-difluoropropane
1,1-Dichloro-2,2-difluoropropane
1,2-Dichloro-1,1-difluoropropane
1,1-Dichloro-1,2-difluoropropane
Chlorotrifluoropropane
2-Chloro-1,2,3-trifluoropropane
2-Chloro-1,1,2-trifluoropropane
1-Chloro-2,2,3-trifluoropropane
1-Chloro-1,2,2-trifluoropropane
3-Chloro-1,1,2-trifluoropropane
1-Chloro-1,2,3-trifluoropropane
1-Chloro-1,1,2-trifluoropropane
3-Chloro-1,3,3-trifluoropropane
3-Chloro-1,1,1-trifluoropropane
1-Chloro-1,1,3-trifluoropropane
1,1,2,2-Tetrafluoropropane
Methyl 1,1,2,2-tetrafluoroethyl ether
Dichlorofluoropropane
1,2-Dichloro-2-fluoropropane
Chlorodifluoropropane
1-Chloro-2,2-difluoropropane
3-Chloro-1,1-difluoropropane
1-Chloro-1,3-difluoropropane
Trifluoropropane
Chlorofluoropropane
2-Chloro-2-fluoropropane
2-Chloro-1-fluoropropane
1-Chloro-1-fluoropropane
Difluoropropane
Fluoropropane
Propane
Dichlorohexafluorocyclobutane

C3H3F5O
C3H3F5O
C3H3F5O
C3H4FCl3
C3H4F2Cl2
C3H4F2Cl2
C3H4F2Cl2
C3H4F2Cl2
C3H4F2Cl2
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F3Cl
C3H4F4
C3H4F4O
C3H5FCl2
C3H5FCl2
C3H5F2Cl
C3H5F2Cl
C3H5F2Cl
C3H5F2Cl
C3H5F3
C3H6FCl
C3H6FCl
C3H6FCl
C3H6FCl
C3H6F2
C3H7F
C3H8 or CH3CH2CH3
C4Cl2F6

CAS
registry
number/
Blend
Name
22410-44-2
1885-48-9
69948-24-9
134190-51-5
134190-52-6
1112-36-3
1112-01-2

134237-44-8

56758-54-4
70192-76-6

460-35-5
40723-63-5
425-88-7
134237-45-9
420-97-3
134190-53-7
420-99-5

134190-54-8
420-44-0

74-98-6
356-18-3

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Number

CFC

R-C317

PFC

R-C318

PFC
HFC
HFC
HFC
HFC
HFC
HFC
PFC
PFC

R-3-1-10
R-329ccb
R-338eea
R-347ccd
R-347mcc
R-347mmy
R-365mfc
R-4-1-12
R-5-1-14

CFC

R-400

HCFC

R-401A

HCFC

R-401B

HCFC

R-401C

HCFC

R-402A

HCFC

R-402B

HCFC

R-403A

HCFC

R-403B

HFC

R-404A

HCFC

R-405A

IUPAC Chemical Name

Chloroheptafluorocyclobutane
Octafluorocyclobutane
(Perfluorocyclobutane)
Decafluorobutane (Perfluorobutane)
1,1,1,2,2,3,3,4,4-Nonafluorobutane
1,1,1,2,3,4,4,4-Octafluorobutane
1,1,1,2,2,3,3-Heptafluorobutane
Perfluoropropyl methyl ether
Perfluoroisopropyl methyl ether
1,1,1,3,3-Pentafluorobutane
Dodecafluoropentane (Perfluoropentane)
Tetradecafluorohexane (Perfluorohexane)

C4ClF7

CAS
registry
number/
Blend
Name
377-41-3

C4F8 or -(CF2)4-

115-25-3

Molecular
Formula

C4F10
355-25-9
C4HF9
375-17-7
C4H2F8
75995-72-1
C4H3F7
662-00-0
C4H3F7O
375-03-1
C4H3F7O
22052-84-2
C4H5F5
406-58-6
C5F12
678-26-2
C6F14
355-42-0
50% CCl2F2
R-12/114(50/50 wt%) OR
50% C2F4Cl2 OR
(60/40)(must be specified)
60% CCl2F2 40% C2F4Cl2
532% CHClF2 13+.5,R-22/152a/124 (532/13+.5,-1.5/341)
1.5% C2H4F2
MP-39[19][6]
341% C2HF4Cl
612% CHClF2 11+.5,R-22/152a/124 (612/11+.5,-1.5/281)
1.5% C2H4F2
MP-66[19][6]
281% C2HF4Cl
332% CHClF2 15+.5,R-22/152a/124 (332/15+.5,-1.5/521)
1.5% C2H4F2
MP-52[19]
521% C2HF4Cl
602% C2HF5 21% C3H8
R-125/290/22 (602/21/382)
HP-80[19][6]
382% CHClF2
382% C2HF5 21% C3H8
R-125/290/22 (382/21/602)
HP-81[19][6]
602% CHClF2
5+.2,-2% C3H8
R-290/22/218 (5+.2,-2/752/200)
752% CHClF2
ISCEON 69-S[6]
200% C3F8
5+.2,-2% C3H8
R-290/22/218 (5+.2,-2/562/390)
562% CHClF2
ISCEON 69-L[6]
390% C3F8
442% C2HF5
HP-62[19][6], FXR-125/143a/134a (442/521/42)
521% C2H3F3
70[19][6]
42% C2H2F4
R-22/152a/142b/C318
450% CHClF2
GREENCOOL
(450/71/5.51/42.52)
71% C2H4F2
G2015[6]

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Number

IUPAC Chemical Name

HCFC

R-406A

R-22/600a/142b (552/41/410)

HCFC

R-406B

R-22/600a/142b (652/41/310)

HFC

R-407A

R-32/125/134a (202/402/402)

HFC

R-407B

R-32/125/134a (102/702/202)

HFC

R-407C

R-32/125/134a (232/252/522)

HFC

R-407D

R-32/125/134a (152/152/702)

HFC

R-407E

R-32/125/134a (252/152/602)

HFC

R-407F

R-32/125/134a (302/302/402)

HCFC

R-408A

R-125/143a/22 (72/461/472)

HCFC

R-409A

R-22/124/142b (602/252/151)

HCFC

R-409B

R-22/124/142b (652/252/101)

HFC

R-410A

R-32/125 (50+.5,1.5/50+1.5,.5)

HFC

R-410B

R-32/125 (451/551)

HCFO

R-411A

R-1270/22/152a (1.5+0,1/87.5+2,

Molecular
Formula

CAS
registry
number/
Blend
Name

5.51% C2H3F2Cl
42.52% C4F8
552% CHClF2
41% C4H10
GHG[19][6]
410% C2H3F2Cl
652% CHClF2
41% C4H10
GHG-HP[6]
310% C2H3F2Cl
202% CH2F2
402% C2HF5
Klea 60[19][6]
402% C2H2F4
102% CH2F2
702% C2HF5
Klea 61[6]
202% C2H2F4
232% CH2F2
Klea 66[6],
252% C2HF5
AC9000[19]
522% C2H2F4
152% CH2F2
152% C2HF5
702% C2H2F4
252% CH2F2
152% C2HF5
602% C2H2F4
302% CH2F2
Genetron
302% C2HF5
Performax LT[19]
402% C2H2F4
72% C2HF5
461% C2H3F3
FX-10[19][6]
472% CHClF2
602% CHClF2
252% C2HF4Cl
FX-56[19][6]
151% C2H3F2Cl
652% CHClF2
252% C2HF4Cl
FX-57[6]
101% C2H3F2Cl
50+.5,1.5% CH2F2
AZ-20[6], Puron[6],
50+1.5,.5% C2HF5
Suva 9100[6]
451% CH2F2
AC9100[19]
551% C2HF5
1.5+0,1% C3H6 87.5+2, GREENCOOL

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Number

IUPAC Chemical Name

0% CHClF2 11+0,
1% C2H4F2
3+0,1% C3H6 94+2,
R-1270/22/152a (3+0,1/94+2,0/3+0,1)
0% CHClF2 3+0,
1% C2H4F2
3+0,1% C3H6 95.5+2,
R-1270/22/152a (3+0,1/95.5+2,
0% CHClF2 1.5+0,
0/1.5+0,1)
1% C2H4F2
702% CHClF2
R-22/218/142b (702/52/251)
52% C3F8
251% C2H3F2Cl
91% C3F8 882% C2H2F4
R-218/134a/600a (91/882/3+0,1)
3+0,1% C4H10
512% CHClF2
R-22/124/600a/142b
28.52% C2HF4Cl
(512/28.52/4.5/16.5+.5,1)
4.5% C4H10 16.5+.5,
1% C2H3F2Cl
502% CHClF2
R-22/124/600a/142b
392% C2HF4Cl
(502/392/1.5.5/9.5+.5,1)
1.5.5% C4H10 9.5+.5,
1% C2H3F2Cl
821% CHClF2
R-22/152a (821/181)
181% C2H4F2
251% CHClF2
R-22/152a (251/751)
751% C2H4F2
59+.5,-1% C2H2F4
R-134a/124/600 (59+.5,
39.5+1,.5% C2HF4Cl
1/39.5+1,.5/1.5+1,.2)
1.5+1,.2% C4H10
46.61.1% C2HF5
R-125/134a/600
501% C2H2F4
(46.61.1/501/3.4+.1,.4)
3.4+.1,.4% C4H10
791% C2HF5
R-125/134a/600 (791/18.31/2.7+.1,.5)
18.31% C2H2F4
2.7+.1,.5% C4H10
1.5.5% C3H8
R-290/22/152a (1.5.5/961/2.5.5)
961% CHClF2
2.5.5% C2H4F2
771% C2HF5
R-125/134a/E170 (771/191/41)
191% C2H2F4
41% C2H6O
0/11+0,1)

HCFO

R-411B

HCFO

R-411C

HCFC

R-412A

HFC

R-413A

HCFC

R-414A

HCFC

R-414B

HCFC

R-415A

HCFC

R-415B

HCFC

R-416A

HFC

R-417A

HFC

R-417B

HCFC

R-418A

HFC

R-419A

Molecular
Formula

CAS
registry
number/
Blend
Name
G2018a[6]
GREENCOOL
G2018b[6]
GREENCOOL
G2018c[6]
Arcton TP5R[6]
ISCEON 49[6]
GHG-X4[6],
Autofrost[6], ChillIt[6]
Hot Shot[19][6], Kar
Kool[6]

FRIGC (FR-12)[6]
ISCEON 59[6],
NU-22[6]

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Number

HCFC

R-420A

HFC

R-421A

HFC

R-421B

HFC

R-422A

HFC

R-422B

HFC

R-422C

HFC

R-422D

HFC

R-423A

HFC

R-424A

HFC

R-425A

HFC

R-426A

HFC

R-427A

HFC

R-428A

HFC

R-429A

IUPAC Chemical Name

Molecular
Formula

CAS
registry
number/
Blend
Name
Choice
Refrigerant[19]

88+1,0% C2H2F4 12+0,

1% C2H3F2Cl
581% C2HF5
R-125/134a (581/421)
Choice R421A[19]
421% C2H2F4
851% C2HF5
R-125/134a (851/151)
Choice 421B[19]
151% C2H2F4
85.11% C2HF5
R-125/134a/600a
11.51% C2H2F4
ISCEON 79[19]
(85.11/11.51/3.4+.1,.4)
3.4+.1,.4% C4H10
551% C2HF5
R-125/134a/600a (551/421/3+.1,.5)
421% C2H2F4
ICOR XAC1[19]
3+.1,.5% C4H10
821% C2HF5
R-125/134a/600a (821/151/3+.1,.5)
151% C2H2F4
ICOR XLT1[19]
3+.1,.5% C4H10
65.1+.9,1.1% C2HF5
R-125/134a/600a (65.1+.9,
31.51% C2H2F4
ISCEON MO29[19]
1.1/31.51/3.4+.1,.4)
3.4+.1,.4% C4H10
52.51% C2H2F4
R-134a/227ea (52.51/47.51)
47.51% C3HF7
50.51% C2HF5
R-125/134a/600a/600/601a
471% C2H2F4
RS-44 (new
(50.51/471/.9+.1,.2/1+.1,+.2/.6+.1,.2
1.9+.3,.1% C4H10 .
comp.)[19]
)
6+.1,.2% C5H12
18.5.5% CH2F2
R-32/134a/227ea (18.5.5/69.5.5/12.5)
69.5.5% C2H2F4
12.5% C3HF7
5.11% C2HF5
R-125/134a/600/601a
931% C2H2F4
RS-24 (new
(5.11/931/1.3+.1,.2/.6+.1,.2)
1.3+.1,.2% C4H10 .
comp.)[19]
6+.1,.2% C5H12
152% CH2F2
R-32/125/143a/134a
252% C2HF5
Forane 427A[19]
(152/252/102/502)
102% C2H3F3
502% C2H2F4
77.51% C2HF5
R-125/143a/290/600a
201% C2H3F3 .
RS-52[19]
(77.51/201/.6+.1,.2/1.9+.1,.2)
6+.1,.2% C3H8
1.9+.1,.2% C4H10
R-E170/152a/600a (601/101/301)
601% C2H6O
R-134a/142b (88+1,0/12+0,1)

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Number

HFC

R-430A

HFC

R-431A

HO
HO
HO
HO

R-432A
R-433A
R-433B
R-433C

HFC

R-434A

HFC

R-435A

HC
HC

R-436A
R-436B

HFC

R-437A

HFC

R-438A

HFC

R-439A

HFC

R-440A

HC

R-441A

HCFC

R-500

HCFC
HCFC

R-501
R-502

IUPAC Chemical Name

Molecular
Formula

CAS
registry
number/
Blend
Name

101% C2H4F2
301% C4H10
761% C2H4F2
R-152a/600a (761/241)
241% C4H10
711% C3H8
R-290/152a (711/291)
291% C2H4F2
R-1270/E170 (801/201)
801% C3H6 201% C2H6O
R-1270/290 (301/701)
301% C3H6 701% C3H8
R-1270/290 (51/951)
51% C3H6 951% C3H8
R-1270/290 (251/751)
251% C3H6 751% C3H8
63.21% C2HF5
R-125/143a/134a/600a
181% C2H3F3
RS-45[19]
(63.21/181/161/2.8+.1,.2)
161% C2H2F4
2.8+.1,.2% C4H10
801% C2H6O
R-E170/152a (801/201)
201% C2H4F2
R-290/600a (561/441)
561% C3H8 441% C4H10
R-290/600a (521/481)
521% C3H8 481% C4H10
19.5+.5,1.8% C2HF5
R-125/134a/600/601 (19.5+.5,
78.5+1.5,.7% C2H2F4
1.8/78.5+1.5,.7/1.4+.1,.2/.6+.1,.2)
1.4+.1,.2% C4H10 .
6+.1,.2% C5H12
8.5+.5,-1.5% CH2F2
451.5% C2HF5
R-32/125/134a/600/601a (8.5+.5,KDD5[19],
44.21.5% C2H2F4
1.5/451.5/44.21.5/1.7+.1,-.2/.6+.1,-.2)
ISCEON MO99[19]
1.7+.1,-.2% C4H10 .
6+.1,-.2% C5H12
501% CH2F2
R-32/125/600a (501/471/3.5)
471% C2HF5 3.5% C4H10
.6.1% C3H8
R-290/134a/152a (.6.1/1.6.6/97.8.5)
1.6.6% C2H2F4
97.8.5% C2H4F2
3.1.3% C2H6
R-170/290/600a/600
54.82% C3H8
HCR-188C[19]
(3.1.3/54.82/6.6/36.12)
42.12.6% C4H10
73.8% CCl2F2
R-12/152a (73.8/26.2)
Carrene #7[6]
26.2% C2H4F2
R-22/12 (75/25)
75% CHClF2 25% CCl2F2
R-22/115 (48.8/51.2)
48.8% CHClF2

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Number

HCFC
HCFC
HCFC

R-503
R-504
R-505

HCFC

R-506

HFC
HFC
HFC
HCFC

R-507[A]
R-508[A]
R-508B
R-509[A]

HC

R-510[A]

HC
HC
HC

R-511[A]
R-600
R-600a

HC

R-601

HC
HC
HC

R-601a
R-610
R-611
R-630
R-631
R-702
R-704
R-717
R-718
R-720
R-728
R-729

CFO
CFO

R-732
R-740
R-744
R-744A
R-764
R-784
R-1112a
R-1113

IUPAC Chemical Name

Molecular
Formula

CAS
registry
number/
Blend
Name

51.2% C2F5Cl
R-23/13 (40.1/59.9)
40.1% CHF3 59.9% CClF3
R-32/115 (48.2/51.8)
48.2% CH2F2 51.8% C2F5Cl
R-12/31 (78/22)
78% CCl2F2 22% CH2FCl
55.1% CH2FCl
R-31/114 (55.1/44.9)
44.9% C2F4Cl2
R-125/143a (50/50)
50% C2HF5 50% C2H3F3
AZ-50[19][6]
R-23/116 (39/61)
39% CHF3 61% C2F6
Klea 5R3[19][6]
R-23/116 (46/54)
46% CHF3 54% C2F6
Suva 95[19][6]
R-22/218 (44/56)
44% CHClF2 56% C3F8
Arcton TP5R2[6]
88.5% C2H6O
R-E170/600a (88.5/12.5)
12.5% C4H10
R-290/E170 (951/51)
951% C3H8 51% C2H6O
Butane
C4H10 or CH3CH2CH2CH3
106-97-8
Isobutane
C4H10 or CH(CH3)2CH3
75-28-5
C5H12 or
Pentane
109-66-0
CH3CH2CH2CH2CH3
Isopentane
C5H12 or (CH3)2CHCH2CH3
78-78-4
Ethoxyethane (Diethyl ether)
CH3CH2OCH2CH3
60-29-7
Methyl formate
HCOOCH3
107-31-3
Methylamine
CH3NH2
74-89-5
Ethylamine
CH3CH2(NH2)
75-04-7
Hydrogen
H2
1333-74-0
Helium
He
7440-59-7
Ammonia
NH3
7664-41-7
Water/Steam
H2O
7732-18-5
Neon
Ne
7440-01-9
Nitrogen
N2
7727-37-9
78.082% N2 20.945% O2 .
Air N2/O2/Ar (78.082/20.945/.934 vol%)
934% Ar
Oxygen
O2
7782-44-7
Argon
Ar
7440-37-1
Carbon dioxide
CO2
124-38-9
Nitrous oxide
N2O
10024-97-2
Sulfur dioxide
SO2
7446-09-5
Krypton
Kr
7439-90-9
1,1-Dichloro-2,2-difluoroethylene
C2Cl2F2
79-35-6
Chlorotrifluoroethylene
C2ClF3
79-38-9

T
y
p
e
PFO
HCO
HCO
HFO
HCO
HFO
HO
PFO
PFO
HCFO
HFO
HFO
HO

IUPAC Chemical Name

Molecular
Formula

Tetrafluoroethylene
Trichloroethylene (trielene)
cis-1,2-Dichloroethylene
1,1-Difluoroethylene
Chloroethylene (vinyl chloride)
Fluoroethylene (vinyl fluoride)
Ethene (Ethylene)
Hexafluoropropylene
Hexafluoropropene trimer
1-Chloro-3,3,3-trifluoropropene
2,3,3,3-Tetrafluoropropene
1,3,3,3-Tetrafluoropropene
Propene (Propylene)

C2F4
C2HCl3
C2H2Cl2
C2H2F2
C2H3Cl
C2H3F
CH2=CH2
C3F6
(C3F6)3
C3H2ClF3
C3H2F4
C3H2F4
C3H6 or CH3CH=CH2

Number
R-1114
R-1120
R-1130
R-1132a
R-1140
R-1141
R-1150
R-1216
RR-1233zd
R-1234yf
R-1234ze
R-1270

Types
Type

Meaning

Atoms in the
Molecule

CFC Chlorofluorocarbon
Cl, F, C
CFO Chlorofluoroolefin
HCFC Hydrochlorofluorocarbon H, Cl, F, C

CAS
registry
number/
Blend
Name
116-14-3
79-01-6
156-59-2
75-38-7
75-01-4
75-02-5
74-85-1
116-15-4
6792-31-0
2730-43-0
754-12-1
1645-83-6
115-07-1

Safety Classification of Refrigerants

Flammability in Air @
ASHRAE 34 Safety group
60C & 101.3 kPa
Higher Flammability
LFL or ETFL60 100
A3
B3
g/m3 OR HOC 19
MJ/kg[39]

HCFO
HFC
HFO
HCC
HCO
HC
HO
PFC
PFO
PCC
PCO

Hydrochlorofluoroolefin
Hydrofluorocarbon
Hydrofluoroolefin
Hydrochlorocarbon
Hydrochloroolefin
Hydrocarbon
Hydroolefin (Alkene)
Perfluorocarbon
Perfluoroolefin
Perchlorocarbon
Perchloroolefin

Halon/Haloalkane

H, F, C
H, Cl, C
H, C
F, C
Cl, C

Lower Flammability
LFL or ETFL60 > 100
g/m3 & HOC < 19
MJ/kg[39]
Lower Flammability
LFL or ETFL60 > 100
g/m3 & HOC < 19
MJ/kg[39]
with a maximum
burning velocity of 10
cm/s
No flame Propagation

A2

B2

A2L

B2L

A1
Br, Cl (in some but
Lower
not all), F, H (in some Flammability in Air @
Toxicity
but not all), C
60C & 101.3 kPa
OEL
400 ppm[22]

B1
Higher
Toxicity
OEL
< 400 ppm[22]

LFL = Lower Flammability Limit

ETFL60 = Elevated Temperature Flame Limit @ 60C
HOC = Heat Of Combustion
Compounds used as refrigerants may be described using either the appropriate prefix above or with the prefixes
"R-" or "Refrigerant." Thus, CFC-12 may also be written as R-12 or Refrigerant 12.
An alkene, olefin, or olefine is an unsaturated chemical compound containing at least one carbon-to-carbon
double bond.[40]
Compuii utilizati ca ageni frigorifici pot fi descrisi cu ajutorul fie prefixul corespunztor de mai sus sau cu
prefixele "R-" sau "agent frigorific". Astfel, CFC-12 poate fi, de asemenea, scris ca R-12 sau ca agent frigorific
12.
O alchena, olefina, sau olefine este un compus chimic nesaturate care conine cel puin o carbon-la-carbon
legtur dubl. [40]