Group 2 3ChE-A

Treatment of Results For Experiment 5

Abosorbance (x) VS. Wavelength (y)
For Solutions 1-5
40
30
20
10

Series1

0
0

100

200

300

400

500

600

700

800

-10
-20
-30
-40

Solution No.
1
2
3
4
5
6
7
8
9
10

pH measured
1
2.09
3.47
4.6
6.16
7.04
9.15
10.62
11.86
13

For Solution 1:
0.246 = a1, Hln (0.1) + a1,ln (0)
a1, Hln = 2.46
For Solution 10:
3.105 = a1, Hln (0) + a1,ln (0.1)
a1,ln = 31.05
For Hln and ln- of Solutions 2-8:
Sample Calculation:
Solution2:

Series2
900
Series3

Equation 1: 2.46Hln + 31.05ln- = 0.266

Equation 2: 30.0534Hln + 0.023ln- = 3.0152
Hln = 0.1003290436
ln- = 4.892287507E-04
Graph for logln-/Hln VS pH:

log ln-/Hln VS. pH

4
3
y = 0.1448x
R = 0.31

2
1
0
-1
-2
-3

10

For Solutions 6-10

35
30
25
20
Series1
15

Series2

10
5
0
0

100

200

300

Absorbance at 410
0.246
0.262
0.597
1.048
2.914
3.362
3.25
2.657
2.437
3.105

400

500

Absorbance at 540
3.0534
3.0152
1.7753
2.3155
0.3214
0.0797
0.0141
0.0047
0.0097
0.0023

600

700

800

Hln
0.1
0.100329044
0.059061172
0.077026056
0.01062326
0.002569271
0.000389089
9.09066E-05
0.000262712
0

900

ln0
4.89E-04
0.014547811
0.027649465
0.093006982
0.108073417
0.104639061
0.085564456
0.078465498
0.1

log ln-/Hln
-2.3119147
-0.6085044
-0.4449509
0.94225773
1.62390891
2.42964451
2.97369775
2.47519829
Ave pK = 5.98882025

3.0534 = a2, Hln (0.1) + a2,ln (0)

a2, Hln = 30.0534

0.0023 = a2, Hln (0) + a2,ln (0.1)

a2,ln = 0.023

/Hln VS. pH

y = 0.1448x
R = 0.31
log ln-/Hln Linear (log ln-/Hln -)
15

pK
4.401915
4.078504
5.044951
5.217742
5.416091
6.720355
7.646302
9.384802
-

ve pK = 5.98882025

pH measured
1
2.09
3.47
4.6
6.16
7.04
9.15
10.62
11.86
13

13
1.2
1
0.8
0.6
0.4
0.2
0
0

0.2

0.4

0.6

0.8

13

1.2