Test Ambang Syawal (Chemistry chapter 4, Form 5, Thermochemistry)

1) Construct Energy level diagram for exothermic and endothermic reaction below : a) Mg(S) + H2SO4(aq) MgSO4(aq) + H2(g) H = -467 kj b) Zn(s) + CuSO4(aq) ZnSO4(aq) + Cu(s) ) H = -190 kJ c) H2(g) + I2(s) 2HI(g) ) H = +53 KJ (6 marks)

2) An experiment was carried out for determination of the heat of precipitation. 25CM3 of 0.5 mol dm-3 Of NaCI solution added into 25 cm3 of 0.5 mol dm-3 AgNO3 solution. Initial tempt NaCI : 29 oC Initial Temp of AgNO3 : 28 oC Highest temperature of mixture : 32 oC a) Write ionic equation of the reaction that occurs (1m) b) Given Specific heat capacity of water = 4.2 J g-1 oC-1 and the density of solution = 1.0 g cm-3 Calculate amount of heat release in the experiment. i) Calculate the heat of precipitation in the experiment.(2m) ii) calculate heat of precipitation of the experiment.(2m) d) Draw energy level diagram for reaction that occurs in the experiment. (2m) e) Thus, define what is heat precipitation?(1/2 m)

3) Heat displacement of iron by magnesium given in thermochemical equation below Mg(s) + Fe2+(aq) Mg2+(aq) + Fe(s) ) H = -80 kJ mol-1 In an experiment using 100 cm3 of a solution containing iron(ii) ions, Fe2+, it is found that 5.6 g of iron is displaced. Calculate : a) Heat change during reaction(2m) b) Raise in temperature of the solution(2m) c) Concentration of solution used.(1/2) Specific heat capacity : 4.2 J g-1 oC-1 . Density solution 1g cm-1 RMM of Fe, 56

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