1. Draw the Lewis structure of the following molecule, CH2CHCN. Describe the structure of the molecule. 2.

Using VSEPR, determine the shape of a) SCN- b) NO2- c) XeF2 d) XeF4 3. Give the symmetry of each bond in H-CC-H and give the hybrid or atomic wavefunctions that overlap to form each of the bonds. Where appropriate use the x, y, or z designations with the wavefunctions. Then, indicate whether the molecule is linear, planar or neither. 4. Discuss the hybridization of the carbons in allene, CH2CCH2. In particular, explain the relative orientations of the hydrogen atoms relative to those on the opposite end of the molecule.

5. Identify the products and write a balanced equation for the reaction of hydrogen with a) Chlorine b) sodium c) copper metal. Explain these reactions in terms on electron transfer or acid-base chemistry. 6. Draw a molecular orbital energy-level diagram and determine the bond order expected for each of the following diatomic species a)Li2 b) Li2+ c)Li2- . How many unpaired electrons are in each species? Identify if the species are paramagnetic or diamagnetic. Which has the shortest bond length? 7. Draw a molecular orbital energy-level diagram and determine the bond order expected for each of the following diatomic species a)F2 b) F2+ c)F2- . How many unpaired electrons are in each species? Identify if the species are paramagnetic or diamagnetic. Which has the shortest bond length? Which has the longest bond length? 8. Draw a MO diagram for the interaction of two identical transition metals. For our purposes, only consider the d-orbitals. Label the interaction types. 9. Draw a MO diagram for Carbon Monoxide. Fun Extras Which has the smallest X-P-X angle? PF3, PCl3, PBr3, PI3 Which has the smallest H-X-H angle? PH3 or NH3 Are axial or equatorial bonds longer in PCl5? Which has the smallest angle? H2O, F2O, or HOF