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{\shp{\*\shpinst\shpleft6373\shptop1346\shpright9080\shpbottom1840\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 2707}}

{\sp{\sn geoBottom}{\sv 494}}
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{\shp{\*\shpinst\shpleft6573\shptop1426\shpright6586\shpbottom1773\shpfhdr0\shpw
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,346);(13,346);(13,0);(0,0);}}
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{\sp{\sn geoRight}{\sv 40}}

{\sp{\sn geoBottom}{\sv 347}}
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{\sp{\sn geoRight}{\sv 53}}

{\sp{\sn geoBottom}{\sv 347}}
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{\shp{\*\shpinst\shpleft6840\shptop1426\shpright6853\shpbottom1773\shpfhdr0\shpw
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{\shp{\*\shpinst\shpleft6880\shptop1426\shpright6920\shpbottom1773\shpfhdr0\shpw
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{\sp{\sn geoRight}{\sv 13}}

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{\sp{\sn geoRight}{\sv 26}}

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{\sp{\sn geoRight}{\sv 13}}

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{\sp{\sn geoRight}{\sv 26}}

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{\sp{\sn geoRight}{\sv 14}}

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{\sp{\sn geoRight}{\sv 27}}

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{\sp{\sn geoRight}{\sv 13}}

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{\sp{\sn geoRight}{\sv 26}}

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\pard\li5200\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li5200\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li5200\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li5200\ri0\sl-213\s
lmult0 \fs18\cf0\par\pard\li5200\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li5200\ri
0\sl-213\slmult0 \fs18\cf0\par\pard\li5200\ri0\sl-200\slmult0 \fs20\cf0\f0\chars
calex100 {ISSN: 0973-4945;}{ }\fs20\cf0\f0\charscalex100 {CODEN ECJHAO}\par\pard

\li6346\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100 {E-Journal of Chemistry }\

par\pard\li813\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {http://www.e-journ
als.net
2012,}\fs20\cf0\f0\charscalex100\b { 9(1), }\b0 \fs20\cf0\f0\charscalex100 {465
-470 }\par\pard\li2173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2173\ri0\sl-213\s
lmult0 \fs18\cf0\par\pard\li2173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li2173\ri
0\sl-213\slmult0 \fs18\cf0\par\pard\li2173\ri0\sl-213\slmult0 \fs18\cf0\par\pard
\li2173\ri0\sl-373\slmult0 \fs32\cf0\f0\charscalex100\b {Synthesis and Character
ization of }\b0 \par\pard\li1786\ri0\sl-360\slmult0 \fs32\cf0\f0\charscalex100\
b {Azo Dye Para Red and New Derivatives }\b0 \par\pard\li773\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-280\
slmult0 \fs18\cf0\f0\charscalex100 {
L ABD-ALREDHA R.ALRUBAIE}{\super \fs14\up3\cf0\f0\charscalex100 {*}}\fs20\cf0\f0\charscalex100 { a
nd R. JAMEEL MHESSN, }\par\pard\li2813\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li
2813\ri0\sl-386\slmult0 \fs20\cf0\f0\charscalex100 {Department of Pharmaceutical
Chemistry, }\par\pard\li2773\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex100 {Pha
rmacy College, Basrah University, Iraq }\par\pard\li3493\ri0\sl-280\slmult0 \fs1
8\cf0\f0\charscalex100\i {leaqaa2000@yahoo.com }\i0 \par\pard\li1560\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li1560\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1560\r
i0\sl-293\slmult0 \fs20\cf0\f0\charscalex100 {Received 5 February 2011; Revised
13 May 2011; Accepted 5 June 2011 }\par\pard\li1640\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li1640\ri0\sl-373\slmult0 \fs20\cf0\f0\charscalex100\b {Abstract:}\b0
\fs20\cf0\f0\charscalex100 { Azo dyes para red was synthesized. The prod
ucts were }\par\pard\li1640\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex100 {char
acterized by FTIR and UV-Visible spectrophotometers. The }\par\pard\li1640
\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100 {antibacterial activities of t
he compounds were studied using gram }\par\pard\li1640\ri0\sl-226\slmult0 \
fs20\cf0\f0\charscalex100 {positive and gram negative microorganism.}\par\pard\l
i773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-240\slmult0 \fs20\cf0\f0
\charscalex100\b {Keywords: }\b0 \fs20\cf0\f0\charscalex100 {Azo dye, Para red d
erivatives, Diazonium salts reaction, Synthesis }\par\pard\li773\ri0\sl-213\slm
ult0 \fs18\cf0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl
-320\slmult0 \fs24\cf0\f0\charscalex100\b {Introduction }\b0 \par\pard\li773\ri0
\sl-360\slmult0 \fs18\cf0\f0\charscalex100 {Azo dyes contain at least one nitrog
en-nitrogen double bond (N=N); however many different }\par\pard\li773\ri0\sl-24
0\slmult0 \fs18\cf0\f0\charscalex100 {structures are possible}{\super \fs12\up
4\cf0\f0\charscalex100 {1}}\fs16\cf0\f0\charscalex100 {. Monoazo dyes have o
nly one N=N double bond, while diazo and }\par\pard\li773\ri0\sl-226\slmu
lt0 \fs18\cf0\f0\charscalex100 {triazo dyes contain two and three N=N dou
ble bonds, respectively. The azo groups are }\par\pard\li773\ri0\sl-226\sl
mult0 \fs18\cf0\f0\charscalex100 {generally connected to benzene and naphthalene
rings, but can also be attached to aromatic }\par\pard\li773\ri0\sl-226\slmult0
\fs16\cf0\f0\charscalex100 {heterocycles or enolizable aliphatic groups. T
hese side groups are necessary for imparting }\par\pard\li773\ri0\sl-240\s
lmult0 \fs18\cf0\f0\charscalex100 {the color of the dye, with many different s
hades and intensities being possible. A common }\par\pard\li773\ri0\sl-226\slmul
t0 \fs18\cf0\f0\charscalex100 {example of an azo dye is shown in Figure 1. When
describing a dye molecule, nucleophiles }\par\pard\li773\ri0\sl-226\slmult0 \fs2
0\cf0\f0\charscalex100 {are referred to as }{ }\fs20\cf0\f0\charscalex100\i {
auxochromes}\i0 \fs20\cf0\f0\charscalex100 {, while the aromatic groups are
called }{ }\fs20\cf0\f0\charscalex100\i {chromophores}\i0 \fs20\cf0\f0\charsca
lex100 {. }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex100 {Togeth
er, the dye molecule is often described as a }\fs20\cf0\f0\charscalex100\i {chr
omogen}\i0 \fs20\cf0\f0\charscalex100 {. Synthesis of most azo dyes }\par\pard\
li773\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100 {involves diazotization of a
primary aromatic amine, followed by coupling with one or more }\par\pard\li773\
ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {nucleophiles. Amino- and hydro
xy- groups are commonly used coupling components}{\super \fs12\up3\cf0\f0\
charscalex100 {1}}\fs18\cf0\f0\charscalex100 {. }\par\pard\li773\ri0\sl-226\slmu
lt0 \fs20\cf0\f0\charscalex100 {Because of the diversity of dye components

available for synthesis, a large number of }\par\pard\li773\ri0\sl-226\s

lmult0 \fs20\cf0\f0\charscalex100 {structurally different azo dyes exist an
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acture}{\super \fs14\up3\cf0\f0\charscalex100 {3}}\fs20\cf0\f0\charscalex100 {.
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}}}}\pgwsxn10320\pghsxn14573\marglsxn666\margrsxn13\margtsxn666\margbsxn400\pard
\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\
par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-360\slmult0 \*
\tx1493\fs20\cf0\f0\charscalex100 {466 }\tab \fs20\cf0\f0\charscalex100 {L. A. R
. AL-RUBAIE }\fs20\cf0\f0\charscalex100\i {et al}\i0 \fs20\cf0\f0\charscalex100
{. }\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-2
13\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\
ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-360\slmult0 \fs18\cf0
\f0\charscalex100\b {
Figure 1. }\b0 \fs20\cf
0\f0\charscalex100 {Example of an azo dye structure }\par\pard\li1133\ri0\sl-293
\slmult0 \fs20\cf0\f0\charscalex100 {Azo dyes acquired wide interest in ap
plication to biological system and indicator in }\par\pard\li773\ri0\sl-22
6\slmult0 \fs18\cf0\f0\charscalex100 {complexometric titration of analytical che
mistry. Azo dyes are the most important group of }\par\pard\li773\ri0\sl-240\slm
ult0 \fs16\cf0\f0\charscalex100 {synthetic colorants. They are generally co
nsidered as xenobiotic compounds that are very }\par\pard\li773\ri0\sl-226
\slmult0 \fs18\cf0\f0\charscalex100 {recalcitrant against biodegradative process
es. Aromatic azo compounds especially are used }\par\pard\li773\ri0\sl-226\slm
ult0 \fs18\cf0\f0\charscalex100 {as acid-base indicators, also used in biologica
l strains and commercial colorants for clothing, }\par\pard\li773\ri0\sl-226\slm
ult0 \fs16\cf0\f0\charscalex100 {plastics, cosmetics and food beverages. Co
lor changes are caused by change in extent of }\par\pard\li773\ri0\sl-24
0\slmult0 \fs18\cf0\f0\charscalex100 {delocalization of electrons. More delo
calization shifts the absorption max to longer wave }\par\pard\li773\ri0\
sl-226\slmult0 \fs18\cf0\f0\charscalex100 {lengths and makes the light absorbed

redder, while less delocalization shifts the absorption }\par\pard\li773\ri0\sl226\slmult0 \fs20\cf0\f0\charscalex100 {max to shorter wavelengths. }\par\pard\l
i773\ri0\sl-293\slmult0 \fs18\cf0\f0\charscalex100 {
In pharmaceutical, azo
linkage was used to protect drug from undesirable reaction, such }\par\pard\li7
73\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {as prontosil was found to
protect against, and cure streptococcal infections in mice. }\par\pard\l
i773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {Interestingly prontosil was
inactive on bacterial cultures. Prontosil is totally in active in vitro }\par\pa
rd\li773\ri0\sl-240\slmult0 \fs18\cf0\f0\charscalex100 {but possesses excellen
t activity }{ }\fs18\cf0\f0\charscalex100\i {in vivo}\i0 {\super \fs12\up3\cf0
\f0\charscalex100 {4}}\fs18\cf0\f0\charscalex100 {. Due to the highly varia
ble nature of biological }\par\pard\li773\ri0\sl-226\slmult0 \fs16\cf0\f0\cha
rscalex100 {treatment systems and especially textile effluents, there are
a number of factors that may }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf
0\f0\charscalex100 {affect the biodegradation rate of azo dyes. Throughou
t the literature, researchers have }\par\pard\li773\ri0\sl-240\slmult0 \fs18
\cf0\f0\charscalex100 {discussed various problems associated with dye biod
egradation that may or may not be }\par\pard\li773\ri0\sl-226\slmult0 \fs1
8\cf0\f0\charscalex100 {anticipated or remedied. Non-dye related parameters
such as temperature, pH, type and }\par\pard\li773\ri0\sl-226\slmult0 \fs
16\cf0\f0\charscalex100 {source of reduction equivalents, bacteria consorti
um, and cell permeability can all affect the }\par\pard\li773\ri0\sl-226\
slmult0 \fs18\cf0\f0\charscalex100 {biodegradation of azo dyes and textile efflu
ents. Dye related parameters such as class and type }\par\pard\li773\ri0\sl-226\
slmult0 \fs18\cf0\f0\charscalex100 {of azo dye (}\fs18\cf0\f0\charscalex100\i {i
.e}\i0 \fs18\cf0\f0\charscalex100 {. reactive-monoazo), reduction metabolites, d
ye concentration, dye side-groups, }\par\pard\li773\ri0\sl-240\slmult0 \fs20\cf0
\f0\charscalex100 {and organic dye additives could also affect the biodegradabil
ity of azo dye wastewaters. }\par\pard\li773\ri0\sl-293\slmult0 \fs18\cf0\f0\cha
rscalex100 {
The azo dye structure can play a significant role in
the dye biodegradation rate. }\par\pard\li773\ri0\sl-226\slmult0 \fs16\cf0\
f0\charscalex100 {Depending on the number and placement of the azo link
ages, some dyes will biodegrade }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf
0\f0\charscalex100 {more rapidly than others. In general, the more azo linkages
that must be broken will cause }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\
f0\charscalex100 {the reduction rate to be slower. While there are not
a large number of studies that }\par\pard\li773\ri0\sl-226\slmult0 \fs18\c
f0\f0\charscalex100 {specifically address this factor, Brown and Laboureur
}{\super \fs12\up3\cf0\f0\charscalex100 {5}}\fs18\cf0\f0\charscalex100 { observ
ed that two poly-azo dyes }\par\pard\li773\ri0\sl-240\slmult0 \fs18\cf0\f0\c
harscalex100 {showed only moderate to variable biodegradation as compared
to four monoazo and six }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\c
harscalex100 {diazo dyes. The authors indicate that poly-azo dyes are less likel
y to degraded than mono- or }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\cha
rscalex100 {diazo dye types}{\super \fs14\up3\cf0\f0\charscalex100 {5}}\fs20\cf0
\f0\charscalex100 {. }\par\pard\li1133\ri0\sl-293\slmult0 \fs18\cf0\f0\charscale
x100 {The azo dye sulfonamides antibacterial drugs were the first effective chem
otherapeutic }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {age
nts that could be used systemically for the cure of bacterial infection in human
s. A series }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {of
azo dyes containing the sulfonamide functional group were synthesized a
s potential }\par\pard\li773\ri0\sl-240\slmult0 \fs18\cf0\f0\charscalex100 {ant
imicrobial agents, sulfonamide was classified into three different types; antiba
cterials that }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {ar
e aniline-substituted sulfonamides, prodrug that react to generate active sulfan
ilamides and }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {non
anilin sulfonamides. There are also other commonly used drugs that are
azo dyes }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {sulf
onamides or sulfanilamides (the diuretic furosemide,the diuretic chlorthl
idone and the }\par\pard\li773\ri0\sl-240\slmult0 \fs18\cf0\f0\charscalex100 {

oral hypoglycemic drug tolbutamide). Today, there are a few sulfonamides and e
specially }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {sulfon
amide\uc1\u8211Xtrimethoprim combination that are used extensively for opportun
istic infection }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex100 {
in the patients with AIDS}{\super \fs14\up3\cf0\f0\charscalex100 {6}}\fs20\cf0\f
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}}}}\pgwsxn10320\pghsxn14573\marglsxn666\margrsxn133\margtsxn666\margbsxn426\col
s2\colno1\colw3240\colsr-0\colno2\colw6280\pard\li773\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li773\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li773\ri
0\sl-226\slmult0 \fs24\cf0\f0\charscalex100\b {Experimental }\b0 \par\column\par
d\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par
\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \*\tx4680
\fs20\cf0\f0\charscalex100 {Synthesis and Characterization of Azo Dye Para Red }
\tab \fs20\cf0\f0\charscalex100 {467 }\par\pard\sect\sectd\sbknone\pgwsxn10320\
pghsxn14573\marglsxn666\margrsxn133\pard\li773\ri0\sl-266\slmult0 \fs22\cf0\f0\c
harscalex100\i {Preparation of azo dye para red (dye I) }\i0 \par\pard\li773\ri0
\sl-253\slmult0 \fs22\cf0\f0\charscalex100\i {Preparation of diazonium salt }\i0

\par\pard\li773\ri0\sl-293\slmult0 \fs18\cf0\f0\charscalex100 {Solution of 1

mL of concentrated sulfuric acid in 10 mL of distilled water was ad
ded in a }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {round
botton flask. While stirring, 1 g (7 mmol) of }\fs18\cf0\f0\charscalex100\i {p}
\i0 \fs18\cf0\f0\charscalex100 {-nitroaniline was added with stirring in }\par\p
ard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscalex100 {ice bath. Then solution
of 0.5 g (7 mmol) of sodium nitrate in 2 mL of distilled water was }\par\pard\l
i773\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex100 {added slowly.
}\par\pard\
li773\ri0\sl-320\slmult0 \fs22\cf0\f0\charscalex100\i {Synthesis of para red }\i
0 \par\pard\li773\ri0\sl-293\slmult0 \fs18\cf0\f0\charscalex100 {Solution of 1
g (7 mmol) of 2-naphthol in 10 mL
of 2.5 M sodium hydroxide was
added
}\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex100 {int
o the flask with the diazonium salt in an ice bath, with vigorously
stirring for a few }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charscal
ex100 {minutes. The mixture was acidified with 1 M sulfuric acid. The
product was dried under }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\cha
rscalex100 {vacuum-oven at 50 }{\super \fs14\up3\cf0\f0\charscalex100 {o}}\fs20\
cf0\f0\charscalex100 {C for 2 h. The melting point of product was estimated at
248-252 C, }\par\pard\li773\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100 {the r
ed product was characterized by FTIR and UV spectrophotometer as shows in Figure
s 2 }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex100 {and 5 respec
tively. }\par\pard\li773\ri0\sl-306\slmult0 \fs22\cf0\f0\charscalex100\i {Prep
aration of methylsulfonyl para red (dye II) }\i0 \par\pard\li773\ri0\sl-293\slmu
lt0 \fs20\cf0\f0\charscalex100 {Methane sulfonyl chloride (0.023 mL) was added d
rop wise over 15 minutes in an ice cooled }\par\pard\li773\ri0\sl-226\slmult0 \f
s20\cf0\f0\charscalex100 {solution of para red (0.461 mmol) and 5 mL tripropyl
amine. The resulting red suspension }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf
0\f0\charscalex100 {was stirred at 0 C for 20 minutes, extracted with c
hloroform, the dye II was dried under }\par\pard\li773\ri0\sl-240\slmult0
\fs20\cf0\f0\charscalex100 {vacuum-oven for 24 h at 50 C, the melting point was 2
67 C, the product was characterized }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0
\f0\charscalex100 {by FTIR and UV spectrophotometers, as shown in Figures 3 and
5 respectively. }\par\pard\li773\ri0\sl-306\slmult0 \fs22\cf0\f0\charscalex100\
i {Preparation of dye III }\i0 \par\pard\li773\ri0\sl-293\slmult0 \fs20\cf0\f0\c
harscalex100 {A solution of 1 g (7 mmol) of 4-amino-3-hydroxynaphthalene -1-sulp
honic acid in 10 mL of }\par\pard\li773\ri0\sl-240\slmult0 \fs18\cf0\f0\charscal
ex100 {2.5 M sodium hydroxide was added into the flask with the diazo
nium salt in an ice bath }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\c
harscalex100 {(form swelling) with vigorous stirring for 30 minutes. The mixture
was acidified with 1 M }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\charsc
alex100 {sulfuric acid, the product was filtered and washed with distil
led water. The dried
product }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0
\f0\charscalex100 {was decomposed at 280 C . The product was investigated by IR a
nd UV spectrophotometer, }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\charsc
alex100 {as shown in Figures 4 and 5 respectively. }\par\pard\li773\ri0\sl-333\s
lmult0 \fs24\cf0\f0\charscalex100\b {Results and Discussion }\b0 \par\pard\li773
\ri0\sl-293\slmult0 \fs20\cf0\f0\charscalex100 {The synthesis of an azo dye
requires two organic compounds- a diazonium salt and a }\par\pard\li77
3\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100 {coupling component. The general
synthesis of azo dyes is shown below: }\par\pard\li1133\ri0\sl-280\slmult0 \fs2
0\cf0\f0\charscalex100 {The diazonium salt reacts as an electrophile with an ele
ctron-rich coupling component, }\par\pard\li773\ri0\sl-240\slmult0 \fs20\cf0\f0\
charscalex100 {like a }{ }\fs20\cf0\f0\charscalex100 {\uc1\u946X}\fs20\cf0\f0\c
harscalex100 {-naphthol and naphthaline derivative through an electrophili
c aromatic substitution }\par\pard\li773\ri0\sl-226\slmult0 \fs18\cf0\f0\chars
calex100 {mechanism. The hydroxyl group (such as }{ }\fs20\cf0\f0\charscale
x100 {\uc1\u946X}\fs20\cf0\f0\charscalex100 {-naphthol) direct the aryl diaz
onium ion to the }\par\pard\li773\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex1
00 {para site unless that position is occupied, in which case the ion attaches o
rtho}{\super \fs14\up3\cf0\f0\charscalex100 {7}}\fs20\cf0\f0\charscalex100 {. }\

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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3600\shptop4546\shpright4493\shpbottom4560\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
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{\sp{\sn geoRight}{\sv 893}}
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{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(893,13);(893,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fBehindDocument}{\sv 1}}
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{\shp{\*\shpinst\shpleft4493\shptop4546\shpright4493\shpbottom4560\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoBottom}{\sv 14}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(893,13);(893,0);(0,0);}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
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{\sp{\sn geoRight}{\sv 1253}}
{\sp{\sn geoBottom}{\sv 14}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1253,13);(1253,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fBehindDocument}{\sv 1}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 893}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(893,13);(893,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 14}}
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{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 1200}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,466);(1200,466);(1200,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 973}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,346);(973,346);(973,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,346);(680,346);(680,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft3586\shptop4986\shpright4493\shpbottom5440\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 907}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,466);(920,466);(920,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\shp{\*\shpinst\shpleft4480\shptop4986\shpright5400\shpbottom5440\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,466);(920,466);(920,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft4600\shptop4986\shpright5293\shpbottom5333\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,346);(680,346);(680,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
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{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5386\shptop4986\shpright6653\shpbottom5440\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft6640\shptop4986\shpright7560\shpbottom5440\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
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{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft6760\shptop4986\shpright7453\shpbottom5333\shpfhdr0\shpw
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{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft7546\shptop4986\shpright8813\shpbottom5440\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2115\shpz40\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1267}}
{\sp{\sn geoBottom}{\sv 454}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,466);(1280,466);(1280,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft7666\shptop4986\shpright8706\shpbottom5213\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1040}}
{\sp{\sn geoBottom}{\sv 227}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1040,226);(1040,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft7666\shptop5213\shpright8706\shpbottom5440\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1040}}
{\sp{\sn geoBottom}{\sv 227}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1040,226);(1040,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft1506\shptop4973\shpright2693\shpbottom4986\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2118\shpz43\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1187}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1186,13);(1186,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft2693\shptop4973\shpright2693\shpbottom4986\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2119\shpz44\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 0}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft2693\shptop4973\shpright3586\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 893}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(893,13);(893,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3586\shptop4973\shpright3600\shpbottom4986\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2121\shpz46\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 14}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3600\shptop4973\shpright4493\shpbottom4986\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2122\shpz47\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 893}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(893,13);(893,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft4493\shptop4973\shpright4493\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 0}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft4493\shptop4973\shpright5386\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 893}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(893,13);(893,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5386\shptop4973\shpright5400\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 14}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5400\shptop4973\shpright6653\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1253}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1253,13);(1253,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft6653\shptop4973\shpright6653\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 0}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft6653\shptop4973\shpright7546\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 893}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(893,13);(893,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft7546\shptop4973\shpright7560\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 14}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft7560\shptop4973\shpright8813\shpbottom4986\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1253}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1253,13);(1253,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft1493\shptop5440\shpright2693\shpbottom5906\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2131\shpz56\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1200}}
{\sp{\sn geoBottom}{\sv 466}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,453);(1200,453);(1200,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft1613\shptop5440\shpright2586\shpbottom5786\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 973}}
{\sp{\sn geoBottom}{\sv 346}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,346);(973,346);(973,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
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{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
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{\shp{\*\shpinst\shpleft2680\shptop5440\shpright3600\shpbottom5906\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
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{\sp{\sn geoRight}{\sv 920}}
{\sp{\sn geoBottom}{\sv 466}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,453);(920,453);(920,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
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{\shp{\*\shpinst\shpleft2800\shptop5440\shpright3493\shpbottom5786\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 693}}
{\sp{\sn geoBottom}{\sv 346}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,346);(680,346);(680,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3586\shptop5440\shpright4493\shpbottom5906\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 907}}
{\sp{\sn geoBottom}{\sv 466}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,453);(920,453);(920,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
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{\sp{\sn fBehindDocument}{\sv 1}}
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{\shp{\*\shpinst\shpleft3706\shptop5440\shpright4386\shpbottom5786\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 680}}
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{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,346);(680,346);(680,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn geoRight}{\sv 1267}}
{\sp{\sn geoBottom}{\sv 254}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,253);(1280,253);(1280,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft7666\shptop5906\shpright8706\shpbottom6160\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2159\shpz84\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1040}}
{\sp{\sn geoBottom}{\sv 254}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,253);(1040,253);(1040,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft1493\shptop6160\shpright2693\shpbottom6173\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2160\shpz85\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1200}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1200,13);(1200,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft2680\shptop6160\shpright2693\shpbottom6173\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2161\shpz86\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 13}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft2693\shptop6160\shpright3600\shpbottom6173\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2162\shpz87\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 907}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(906,13);(906,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3586\shptop6160\shpright3586\shpbottom6173\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2163\shpz88\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 0}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3586\shptop6160\shpright4493\shpbottom6173\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2164\shpz89\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 907}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(906,13);(906,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft4480\shptop6160\shpright4493\shpbottom6173\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2165\shpz90\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 13}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft4493\shptop6160\shpright5400\shpbottom6173\shpfhdr0\shpw
r3\shpwrk0\shpfblwtxt1\shplid2166\shpz91\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 907}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(906,13);(906,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5386\shptop6160\shpright5386\shpbottom6173\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 0}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5386\shptop6160\shpright6653\shpbottom6173\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1267}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1266,13);(1266,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft6640\shptop6160\shpright6653\shpbottom6173\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 13}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft6653\shptop6160\shpright7560\shpbottom6173\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 907}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(906,13);(906,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}

{\sp{\sn fBehindDocument}{\sv 1}}

{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft7546\shptop6160\shpright7546\shpbottom6173\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 0}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft7546\shptop6160\shpright8813\shpbottom6173\shpfhdr0\shpw
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1267}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1266,13);(1266,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}{\shp
{\*\shpinst
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\absh14573\absw10320{\sp{\sn shapeType}{\sv 75}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn pibFlags}{\sv 2}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn fEditedWrap}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn pib}{\sv {\pict
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Table 1. }\b0 \fs20\cf0\f0\charscalex100 {Major
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pard\li0\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100 {\uc1\u957X}{\sub \fs14\c
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ri0\sl-253\slmult0 \*\tx893\fs20\cf0\f0\charscalex100 {\uc1\u957X}{\sub \fs14\cf
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00 {2}\par\column\pard\li0\ri0\sl-133\slmult0 \fs12\cf0\f0\charscalex100 {(Pheno
lic) }\par\column\pard\li0\ri0\sl-93\slmult0 \fs12\cf0\f0\charscalex100 {2}\par\
column\pard\li0\ri0\sl-120\slmult0 \fs14\cf0\f0\charscalex100 {3}\par\pard\sect\
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-0\colno5\colw2520\pard\li946\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100 {Dye
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arscalex100 {3390 }\par\column\pard\li0\ri0\sl-253\slmult0 \fs20\cf0\f0\charscal
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}\par\pard\li0\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex100 {1045.35 sym }\pa
r\pard\sect\sectd\sbknone\pgwsxn10320\pghsxn14573\marglsxn666\margrsxn133\cols4\
colno1\colw2133\colsr-0\colno2\colw2706\colsr-0\colno3\colw2640\colsr-0\colno4\c
olw2040\pard\li946\ri0\sl-226\slmult0 \fs20\cf0\f0\charscalex100 {Dye II }\par\c
olumn\pard\li0\ri0\sl-226\slmult0 \*\tx906\*\tx1800\fs20\cf0\f0\charscalex100 {1

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0 {- }\par\column\pard\li0\ri0\sl-226\slmult0 \*\tx1253\fs20\cf0\f0\charscalex10
0 {2962.46 asy. }\tab \fs20\cf0\f0\charscalex100 {1400 }\par\pard\li0\ri0\sl-22
6\slmult0 \fs20\cf0\f0\charscalex100 {2927.7 sym }\par\column\pard\li0\ri0\sl-22
6\slmult0 \fs20\cf0\f0\charscalex100 {- }\par\pard\sect\sectd\sbknone\pgwsxn1032
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li0\ri0\sl-226\slmult0 \*\tx906\*\tx1800\fs20\cf0\f0\charscalex100 {1521.73 }\ta
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{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3960\shptop11200\shpright5706\shpbottom11893\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2190\shpz13\shpbxpage\shpbypage

{\sp{\sn shapeType}{\sv 0}}

{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1746}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,693);(1746,693);(1746,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft4080\shptop11200\shpright5600\shpbottom11426\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 1520}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1520,226);(1520,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft4080\shptop11426\shpright5600\shpbottom11666\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1520,226);(1520,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft4080\shptop11666\shpright5600\shpbottom11893\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}

{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1520,226);(1520,0);(0,0);}}
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft5693\shptop11200\shpright7866\shpbottom11893\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 2173}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,693);(2173,693);(2173,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft5813\shptop11200\shpright7760\shpbottom11426\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn geoRight}{\sv 1947}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1946,226);(1946,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft5813\shptop11426\shpright7760\shpbottom11666\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}

{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1947}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1946,226);(1946,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft5813\shptop11666\shpright7760\shpbottom11893\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1946,226);(1946,0);(0,0);}}
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{\shp{\*\shpinst\shpleft2466\shptop11186\shpright3960\shpbottom11200\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\shp{\*\shpinst\shpleft3960\shptop11186\shpright3973\shpbottom11200\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}

{\sp{\sn fFlipH}{\sv 0}}
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{\shp{\*\shpinst\shpleft3973\shptop11186\shpright5693\shpbottom11200\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\shp{\*\shpinst\shpleft5693\shptop11186\shpright5706\shpbottom11200\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\shp{\*\shpinst\shpleft5706\shptop11186\shpright7853\shpbottom11200\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}

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{\shp{\*\shpinst\shpleft2453\shptop11893\shpright3973\shpbottom12586\shpfhdr0\sh
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{\shp{\*\shpinst\shpleft2573\shptop11893\shpright3866\shpbottom12240\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}

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{\shp{\*\shpinst\shpleft4080\shptop11893\shpright5600\shpbottom12120\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn shapeType}{\sv 0}}

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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\shp{\*\shpinst\shpleft5813\shptop11893\shpright7760\shpbottom12120\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}
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{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1946,226);(1946,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
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{\sp{\sn fFillOK}{\sv 1}}
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{\shp{\*\shpinst\shpleft5813\shptop12120\shpright7760\shpbottom12346\shpfhdr0\sh
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{\sp{\sn shapeType}{\sv 0}}

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{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1947}}
{\sp{\sn geoBottom}{\sv 226}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1946,226);(1946,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5813\shptop12346\shpright7760\shpbottom12586\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2212\shpz35\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1947}}
{\sp{\sn geoBottom}{\sv 240}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1946,226);(1946,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft2453\shptop12586\shpright3973\shpbottom13040\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2213\shpz36\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1520}}
{\sp{\sn geoBottom}{\sv 454}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,466);(1520,466);(1520,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft2573\shptop12586\shpright3866\shpbottom12933\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2214\shpz37\shpbxpage\shpbypage

{\sp{\sn shapeType}{\sv 0}}

{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1293}}
{\sp{\sn geoBottom}{\sv 347}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,346);(1293,346);(1293,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3960\shptop12586\shpright5706\shpbottom13040\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2215\shpz38\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1746}}
{\sp{\sn geoBottom}{\sv 454}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,466);(1746,466);(1746,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft4080\shptop12586\shpright5600\shpbottom12813\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2216\shpz39\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1520}}
{\sp{\sn geoBottom}{\sv 227}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1520,226);(1520,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft4080\shptop12813\shpright5600\shpbottom13040\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2217\shpz40\shpbxpage\shpbypage

{\sp{\sn shapeType}{\sv 0}}

{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1520}}
{\sp{\sn geoBottom}{\sv 227}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1520,226);(1520,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5693\shptop12586\shpright7866\shpbottom13040\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2218\shpz41\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 2173}}
{\sp{\sn geoBottom}{\sv 454}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,466);(2173,466);(2173,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5813\shptop12586\shpright7760\shpbottom12813\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2219\shpz42\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1947}}
{\sp{\sn geoBottom}{\sv 227}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1946,226);(1946,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5813\shptop12813\shpright7760\shpbottom13040\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2220\shpz43\shpbxpage\shpbypage

{\sp{\sn shapeType}{\sv 0}}

{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1947}}
{\sp{\sn geoBottom}{\sv 227}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,226);(1946,226);(1946,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 16777215}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft2453\shptop13040\shpright3973\shpbottom13053\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2221\shpz44\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1520}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1520,13);(1520,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3960\shptop13040\shpright3973\shpbottom13053\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2222\shpz45\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 13}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft3973\shptop13040\shpright5706\shpbottom13053\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2223\shpz46\shpbxpage\shpbypage

{\sp{\sn shapeType}{\sv 0}}

{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 1733}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(1733,13);(1733,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5693\shptop13040\shpright5693\shpbottom13053\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2224\shpz47\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 0}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(13,13);(13,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}
{\shp{\*\shpinst\shpleft5693\shptop13040\shpright7866\shpbottom13053\shpfhdr0\sh
pwr3\shpwrk0\shpfblwtxt1\shplid2225\shpz48\shpbxpage\shpbypage
{\sp{\sn shapeType}{\sv 0}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn rotation}{\sv 0}}
{\sp{\sn geoRight}{\sv 2173}}
{\sp{\sn geoBottom}{\sv 13}}
{\sp{\sn shapePath}{\sv 4}}
{\sp{\sn pVerticies}{\sv 8;5;(0,0);(0,13);(2160,13);(2160,0);(0,0);}}
{\sp{\sn pSegmentInfo}{\sv 2;12;16384;45824;1;45824;1;45824;1;45824;1;45824;2457
7;32768}}
{\sp{\sn fFillOK}{\sv 1}}
{\sp{\sn fFilled}{\sv 1}}
{\sp{\sn fillColor}{\sv 0}}
{\sp{\sn fLine}{\sv 1}}{\sp{\sn lineColor}{\sv 0}}
{\sp{\sn lineType}{\sv 0}}
{\sp{\sn fArrowheadsOK}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn fLayoutInCell}{\sv 1}}}}{\shp
{\*\shpinst
\shpleft2333\shptop2053\shpright8093\shpbottom5173

\shpfhdr0\shpwr3\shpwrk0\shpfblwtxt1\shplid2229\shpz49\shpbxpage\shpbypage
\absh14573\absw10320{\sp{\sn shapeType}{\sv 75}}
{\sp{\sn fFlipH}{\sv 0}}
{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn pibFlags}{\sv 2}}
{\sp{\sn fLine}{\sv 0}}{\sp{\sn fEditedWrap}{\sv 0}}
{\sp{\sn fBehindDocument}{\sv 1}}
{\sp{\sn pib}{\sv {\pict
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f0\charscalex100\b {Figure 4}\b0 \fs18\cf0\f0\charscalex100 {. IR Spectrum fo dy
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