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Gii thiu
Qu trnh oxi ho nng cao (AOPs: Advanced Oxidation Processes): L nhng qu trnh phn hu oxi ho da vo gc t do hot ng hydroxyl OH* c to ra ngay trong qu trnh x l (in situ). + Gc OH*: L tc nhn oxi ho mnh nht. + Oxi ho khng la chn mi HCHC kh phn hu (POPs) nh: - Hydrocacbon halogen ho (Trihalometan (THM), Tricloroetan , Tricloroetylen). - Hydrocacbon aromatic (BTEX- Benzen, Toluen, Etylbenzen, Xylen). - Polyclorbiphenyl (PCB). - Nitrophenol. - Cc ho cht TBVTV, dioxin, furan, thuc nhum,
Gii thiu
AOPs
ANPO (Advanced Non-Photochemical Oxidation Processes) Oxi ho nng cao khng nh tc nhn nh sng
APO (Advanced Photochemical Oxidation Processes) Oxi ho nng cao khng nh tc nhn nh sng
Gii thiu
Nhm qu trnh ANPO Qu trnh Qu trnh Fenton Qu trnh Peroxon Qu trnh Catazon Qu trnh Oxi ho in ho Qu trnh Fenton in ho APO Qu trnh UV/H2O2 Qu trnh UV/O3 Qu trnh UV/H2O2 + O3 Qu trnh quang Fenton Tc nhn phn ng H2O2 v Fe2+ H2O2 v O3 O3 v cht xc tc H2O v nng lng in ha H2O vi ant Fe v nng lng in ha H2O2 v nng lng photon UV O3 v nng lng photon UV H2O2 /O3v nng lng photon UV H2O2 / Fe3+ (ion) v nng lng photon UV
Gii thiu
Qu trnh Fenton ng th Fe2+ + H2O2 Fe3+ + *HO + OHFe3+ + H2O2 Fe2+ + H+ + *HO2 *HO + Fe2+ OH- + Fe3+ *HO + H2O2 H2O + *HO2 Fe2+ + *HO2 Fe3+ + HO2Fe3+ + *HO2 Fe2+ + O2 +H+ Qu trnh Fenton d th Ngun st s dng trong xc tc c b sung t qung (Goethite: -FeOOH, Fe/SiO2, Fe/TiO2, Fe/than hot tnh, Fe/Zeolit,)
Cc yu t nh hng: -pH t 3 5, t c tc cao nht khi pH nm trong khong hp trn di 3. -T l Fe2+: H2O2 v loi ion Fe (Fe2+ hay Fe3+) l 0,3-1:10 mol/mol. -Cc anion v c: cacbonat (CO32-), bicacbonat (HCO3-), Clorua (Cl-) s tm bt cc gc hydroxyl *HO.
Gii thiu
Xc nh thng s trong qu trnh x l
Tm quy trnh x l ph hp
Diazinon 10 %
Fenonbucar 50 %
Isoprothiolane 40 %
Tm pH thch hp
Fenton
Tm thng s thch hp
Thi gian lu nc, chiu cao lp lc v lu lng np nc Suy gim ChE (enzyme Cholinesterase)
Hp ph
KT QU V THO LUN
Kt qu nh hng tm pH thch hp trn thuc BVTV
C nh H2O2 = 25 mg/L, Fe2+ = 5,1 mg/L
200
COD cn li (mg/L)
360
COD cn li (mg/L)
COD cn li (mg/L)
pH thch hp t 3 n 3,5
KT QU V THO LUN
Kt qu nng COD, kim v pH ca nc thi
Ch tiu
n v
t 1
t 2
t 3
t 4
Trung bnh
mgCaCO3/L mg/L
6,88 620
7,1 664
7,12 690
7,5 723
7,15 674,5
504,8
1.000
1.062,3
1.150
929,3
KT QU V THO LUN
Kt qu cc thng s ca qu trnh Fenton bc 1
C nh Fe2+ = 10 mg/L, H2O2 = 50 mg/L
400
C O D c n l i (m g /L )
C nh Fe2+ = 10 mg/L, pH = 3
340
C O D c n l i (m g /L )
pH thch hp l 3
KT QU V THO LUN
Kt qu cc thng s ca qu trnh Fenton bc 1
C nh pH= 3, H2O2= 80mg/L
340
C O D c n l i (m g /L )
310 300 290 280 270 260 250 240 230 220 10 20 30 40 50 60 Thi gian (pht)
Fe2+ thch hp l 30
C O D c n l i ( m g /L )
KT QU V THO LUN
Cc thng s ca qu trnh Fenton bc 1
pH = 3 H2O2 = 80 mg/L Fe2+ = 30 mg/L Thi gian khuy: 30 pht Thi gian lng: 120 pht
KT QU V THO LUN
Kt qu th nghim s dng cht tr lng PAC v st d
600 500 400 300 200 100 0 5 6 7 8 9 Mu i chng
C O D c n l i (m g /L )
PAC (mg/L)
KT QU V THO LUN
Kt qu cc thng s ca qu trnh Fenton bc 2
Tnh ton nng Fe2+ = 30 mg/L, pH = 3 Khuy 30 pht v lng 120 pht
290
C O D c n l i (m g /L )
300 250
COD cn li (mg/L)
KT QU V THO LUN
Cc thng s ca qu trnh Fenton bc 2
pH = 3 H2O2 = 80 mg/L Fe2+ = 20 mg/L Thi gian khuy: 30 pht Thi gian lng: 120 pht
KT QU V THO LUN
Kt qu th nghim hp ph
Chiu cao tng cng: 1,5 m Lu lng np nc: 123 ml/pht Tng thi gian lu: 60 pht
150,1
89
38,7
COD mg/L
KT QU V THO LUN
i chng
u ra Fenton bc 1
KT LUN
Nc thi u vo H2O2 = 80 mg/L Fe2+ = 30 mg/L pH = 3 Thi gian khuy: 30 pht Thi gian lng: 120 pht H2O2 = 80 mg/L Fe2+ = 20 mg/L pH = 3 Thi gian khuy: 30 pht Thi gian lng: 120 pht Chiu cao ct than hot tnh: 1,5 m Lu lng np nc: 123 ml/pht Thi gian lu: 60 pht Hp ph u ra (Cng ty CPC) COD = 929,3 mg/L) Sau 1 h c cht
Fenton bc 1
Fenton bc 2
KIN NGH
Kim tra ch tiu cc gc thuc i vi nc thi u ra v so snh vi quy chun QCVN 40: 2011/BTNMT Thit b vn hnh nn c np y Lng bn sinh ra sau qu trnh Fenton cn c nghin cu x l Lng than sau khi hp ph cn c nghin cu x l Kho st vi cc phng php AOPs khc Th nghim trn nhiu loi c khc nhau xc nh c ca nc thi.