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NGHIN CU X L NC THI THUC BO V THC VT BNG PHNG PHP OXI HO NNG CAO (QU TRNH FENTON NG TH)

Nh my sn xut thuc BVTV

Nc thi thuc BVTV

c t, kim loi nng Kh phn hy sinh hc cao


(cc nhim hu c bn vng - POPs: Persistent Organic Pollutants)

Gii thiu
Qu trnh oxi ho nng cao (AOPs: Advanced Oxidation Processes): L nhng qu trnh phn hu oxi ho da vo gc t do hot ng hydroxyl OH* c to ra ngay trong qu trnh x l (in situ). + Gc OH*: L tc nhn oxi ho mnh nht. + Oxi ho khng la chn mi HCHC kh phn hu (POPs) nh: - Hydrocacbon halogen ho (Trihalometan (THM), Tricloroetan , Tricloroetylen). - Hydrocacbon aromatic (BTEX- Benzen, Toluen, Etylbenzen, Xylen). - Polyclorbiphenyl (PCB). - Nitrophenol. - Cc ho cht TBVTV, dioxin, furan, thuc nhum,

To ra nhng hp cht v c khng c (CO2, H2O, cc acid v c,).

Gii thiu
AOPs

ANPO (Advanced Non-Photochemical Oxidation Processes) Oxi ho nng cao khng nh tc nhn nh sng

APO (Advanced Photochemical Oxidation Processes) Oxi ho nng cao khng nh tc nhn nh sng

Gii thiu
Nhm qu trnh ANPO Qu trnh Qu trnh Fenton Qu trnh Peroxon Qu trnh Catazon Qu trnh Oxi ho in ho Qu trnh Fenton in ho APO Qu trnh UV/H2O2 Qu trnh UV/O3 Qu trnh UV/H2O2 + O3 Qu trnh quang Fenton Tc nhn phn ng H2O2 v Fe2+ H2O2 v O3 O3 v cht xc tc H2O v nng lng in ha H2O vi ant Fe v nng lng in ha H2O2 v nng lng photon UV O3 v nng lng photon UV H2O2 /O3v nng lng photon UV H2O2 / Fe3+ (ion) v nng lng photon UV

Gii thiu
Qu trnh Fenton ng th Fe2+ + H2O2 Fe3+ + *HO + OHFe3+ + H2O2 Fe2+ + H+ + *HO2 *HO + Fe2+ OH- + Fe3+ *HO + H2O2 H2O + *HO2 Fe2+ + *HO2 Fe3+ + HO2Fe3+ + *HO2 Fe2+ + O2 +H+ Qu trnh Fenton d th Ngun st s dng trong xc tc c b sung t qung (Goethite: -FeOOH, Fe/SiO2, Fe/TiO2, Fe/than hot tnh, Fe/Zeolit,)

Cc yu t nh hng: -pH t 3 5, t c tc cao nht khi pH nm trong khong hp trn di 3. -T l Fe2+: H2O2 v loi ion Fe (Fe2+ hay Fe3+) l 0,3-1:10 mol/mol. -Cc anion v c: cacbonat (CO32-), bicacbonat (HCO3-), Clorua (Cl-) s tm bt cc gc hydroxyl *HO.

Gii thiu
Xc nh thng s trong qu trnh x l

p dng quy trnh x l vo thc t

Phng php AOP (Fenton ng th)

Tm quy trnh x l ph hp

PHNG PHP PHNG TIN


Th nghim nh hng

Diazinon 10 %

Fenonbucar 50 %

Isoprothiolane 40 %

C nh Fe2+ = 5,1 mg/L H2O2 = 25 mg/L Thay i pH

Tm pH thch hp

PHNG PHP PHNG TIN


Th nghim trn nc thi thuc BVTV (cng ty CPC)
Tm thng s thch hp

pH, H2O2, Fe2+, thi gian khuy v thi gian lng

Fenton

Tm thng s thch hp

Thi gian lu nc, chiu cao lp lc v lu lng np nc Suy gim ChE (enzyme Cholinesterase)

Hp ph

KT QU V THO LUN
Kt qu nh hng tm pH thch hp trn thuc BVTV
C nh H2O2 = 25 mg/L, Fe2+ = 5,1 mg/L
200
COD cn li (mg/L)

150 100 50 0 2,5 3 3,5 pH 4 5

350 300 250 200 150 100 50 0 2,5 3 3,5 pH 4 5

360
COD cn li (mg/L)

340 320 300 280 260 2,5 3 3,5 pH 4 5

COD cn li (mg/L)

pH thch hp t 3 n 3,5

KT QU V THO LUN
Kt qu nng COD, kim v pH ca nc thi

Ch tiu

n v

t 1

t 2

t 3

t 4

Trung bnh

pH kim tng COD

mgCaCO3/L mg/L

6,88 620

7,1 664

7,12 690

7,5 723

7,15 674,5

504,8

1.000

1.062,3

1.150

929,3

KT QU V THO LUN
Kt qu cc thng s ca qu trnh Fenton bc 1
C nh Fe2+ = 10 mg/L, H2O2 = 50 mg/L
400
C O D c n l i (m g /L )

C nh Fe2+ = 10 mg/L, pH = 3
340
C O D c n l i (m g /L )

380 360 340 320 300 2,5 3 3,5 pH 4 5

320 300 280 260 240 50 60 70 H2O2 (mg/L) 80 90

pH thch hp l 3

H2O2 thch hp l 80 mg/L

KT QU V THO LUN
Kt qu cc thng s ca qu trnh Fenton bc 1
C nh pH= 3, H2O2= 80mg/L
340
C O D c n l i (m g /L )

C nh H2O2= 80mg/L, Fe2+ = 30 mg/L, pH =3

320 300 280 260 240 25 28 30 Nng Fe2+ (mg/L) 32 35

310 300 290 280 270 260 250 240 230 220 10 20 30 40 50 60 Thi gian (pht)

Fe2+ thch hp l 30

Thi gian khuy thch hp l 30 pht

C O D c n l i ( m g /L )

KT QU V THO LUN
Cc thng s ca qu trnh Fenton bc 1

pH = 3 H2O2 = 80 mg/L Fe2+ = 30 mg/L Thi gian khuy: 30 pht Thi gian lng: 120 pht

Nc thi u vo COD = 929,3 mg/L

Nc thi u ra Fenton bc 1 COD = 455,4 mg/L Hiu sut x l COD l 50,9%

KT QU V THO LUN
Kt qu th nghim s dng cht tr lng PAC v st d
600 500 400 300 200 100 0 5 6 7 8 9 Mu i chng
C O D c n l i (m g /L )

PAC (mg/L)

PAC khng nh hng n qu trnh lng

Liu lng Fe2+ cn d

KT QU V THO LUN
Kt qu cc thng s ca qu trnh Fenton bc 2
Tnh ton nng Fe2+ = 30 mg/L, pH = 3 Khuy 30 pht v lng 120 pht
290
C O D c n l i (m g /L )
300 250
COD cn li (mg/L)

C nh H2O2 = 80 mg/L, pH = 3 Khuy 30 pht v lng 120 pht

280 270 260 250 240 230 50 60 70 H2O2 (mg/L) 80 90

200 150 100 50 0 10 15 20 25 30

Nng Fe2+ (mg/L)

H2O2 thch hp l 80 mg/L

Fe2+ thch hp l 20 mg/L

KT QU V THO LUN
Cc thng s ca qu trnh Fenton bc 2

pH = 3 H2O2 = 80 mg/L Fe2+ = 20 mg/L Thi gian khuy: 30 pht Thi gian lng: 120 pht

Nc thi u ra Fenton bc 1 COD = 455,4 mg/L

Nc thi u ra Fenton bc 2 COD = 220,3 mg/L

Hiu sut x l COD l 51,6%

KT QU V THO LUN
Kt qu th nghim hp ph
Chiu cao tng cng: 1,5 m Lu lng np nc: 123 ml/pht Tng thi gian lu: 60 pht

150,1

89

38,7

COD mg/L

Nc thi sau Fenton bc 2 COD = 220,3 mg/L

Nc thi u ra sau hp ph COD = 38,7 mg/L

KT QU V THO LUN

i chng

u ra Fenton bc 1

u ra sau hp ph (Thi ra mi trng)

Sau 46 h th nghim C bnh thng

Sau 10 h th nghim C cht

Sau 10 h th nghim C bnh thng

Sau 46 h C bnh thng

ChE c ch 1,4 % so vi i chng

KT LUN
Nc thi u vo H2O2 = 80 mg/L Fe2+ = 30 mg/L pH = 3 Thi gian khuy: 30 pht Thi gian lng: 120 pht H2O2 = 80 mg/L Fe2+ = 20 mg/L pH = 3 Thi gian khuy: 30 pht Thi gian lng: 120 pht Chiu cao ct than hot tnh: 1,5 m Lu lng np nc: 123 ml/pht Thi gian lu: 60 pht Hp ph u ra (Cng ty CPC) COD = 929,3 mg/L) Sau 1 h c cht

Fenton bc 1

COD = 455,4 mg/L) Sau 10 h c cht

Fenton bc 2

COD = 220,3 mg/L Sau 22 h c cht

COD = 38,7 mg/L Sau 46 h c vn bnh thng, t l ChE 1,4 % so vi i chng

KIN NGH

Kim tra ch tiu cc gc thuc i vi nc thi u ra v so snh vi quy chun QCVN 40: 2011/BTNMT Thit b vn hnh nn c np y Lng bn sinh ra sau qu trnh Fenton cn c nghin cu x l Lng than sau khi hp ph cn c nghin cu x l Kho st vi cc phng php AOPs khc Th nghim trn nhiu loi c khc nhau xc nh c ca nc thi.

CM N QU THY C V CC BN SINH VIN LNG NGHE

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