N TP CHNG OXI- LU HUNH

Dng 1. Hon thnh phng trnh phn ng.

Bi 1. T cc cht sau: Cu, C, S, Na
2
SO
3
, FeS
2
,O
2
, H
2
SO
4
. Vit tt c cc ptpu iu ch SO
2

Bi 2. Vit cc phng trnh hon thnh s chuyn ha sau:
3 4 2 3 2
e Fe O SO NaHSO SO F
Bi 3. Xc nh A,B,C,D v hon thnh s chuyn ha sau:
a/
2 2 4 3
B C B D S D H SO D BaSO H
b/NaHSO
3
AH
2
SO
4
ABCBaSO
4

c/ H
2
SO
4
ABH
2
SO
4
CFe
2
(SO4)
3
d/
(1) (2) (3) (4) (5)
2 2 4
H S B S C H SO C A
Bi 4. FeS H
2
S Na
2
S FeS Fe
2
(SO
4
)
3
FeCl
3
Fe(OH)
3

Bi 5. Zn ZnS H
2
S SO
2
H
2
SO
4
Fe
2
(SO
4
)
3
FeCl
3

SO
2
S Al
2
S
3

Bi 6. FeS
2
SO
2
S H
2
S SO
2
SO
3
SO
2
NaHSO
3
Bi 7. A + B D (mi trng thi) D + E A + G
A + O
2
E F + G X
E + O
2

2 5
400
o
V O
C
F E + G + Br
2
X + Y
X + K
2
SO
3
H + E + G
Bi 8 :Cho nhng cht sau : Cu , CuO, Mg, CaCO
3
, Al
2
O
3
, Fe
2
O
3
v Fe(OH)
3
. Hy cho bit nhng cht
no c kh nng tc dng c vi dd H
2
SO
4
c

nng v long. Vit tt c cc phng trnh phn ng xy
ra.
Dng 2. Bi tp nhn bit cht.
Bi 1. Trnh by phng php ha hc nhn bit cc l mt nhn ng cc dd sau:
a/NaCl, HCl, Na
2
SO
4
, H
2
SO
4
b/ NaCl, K
2
CO
3
, Na
2
SO
4
, HCl, Ba(NO
3
)
2
c/ HCl, H
2
SO
4
, K
2
SO
4
, KCl, MgCl
2
.
d/ KNO
3
, KCl,K
2
SO
4
,K
2
CO
3

e/ Na
2
CO
3
, Na
2
S, NaCl,Na
2
SO
4
Bi 2. nhn bit cc kh sau:
a/ SO
2
,CO2, HCl,O
2

b/ O
2
,O
3
,SO
2
,CH4.
c/ Cl2, H2, O3, O2, N2.
d/ HCl, NH3, SO2, H2, CO2.
Dng 3. Bi tp pha long axit.- Bi tp oleum.
Oleum l Axit bc khi C cng thc : H
2
SO
4
.nSO
2
nn khi tc dng H
2
O (n +1) H
2
SO
4

Nn : n
Oleum
=
1
4 2
n
n
SO H
. Khi pha trn dung dch th c th coi oleum l axit c nng :
n
). n (
80 98
98 1

sau
dng ng cho hoc cc kin thc dung dch tnh
Khi xc nh cng thc ca Oleum cn xc nh
4 2
SO H
n :
3
SO
n theo bi tp lp cng thc
Cu 1: Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ho 100
ml dung dch X cn dng 200 ml dung dch NaOH 0,15M. Phn trm v khi lng ca nguyn t lu
hunh trong oleum trn l
Cu 2: Ha tan 3,38g mt Oleum vo nc thu c dung dch A. trung ha A cn 800 ml dung dch
KOH 0,1M .
a) Hy xc nh cng thc ca Oleum
b) Cn ly bao nhiu gam A ha tan vo 200g nc thu c dung dch H
2
SO
4
10%
Cu 3: Ho tan 6,67g Oleum A vo nc thnh 200ml dung dch H
2
SO
4
. Ly 10 ml dung dch ny trung
ho va ht 16 ml dung dch NaOH 0,5M.. Xc nh cng thc ca A
Cu 4: C 1 loi oleum X trong SO
3
chim 71% theo khi lng. Xc nh cng thc ca X ?
Cu 5: Hy xc nh cng thc lum to thnh khi cho 180g dung dch H
2
SO
4
98% hp th ht 22,4 l
SO
3
(ktc). Tnh % khi lng SO
3
trong oleum
Cu 6: cho 24,64 lit SO
3
(ktc) hp th ht vo 90g dd H
2
SO
4
98%, thu c oleum c cng thc
H
2
SO
4
.nSO
3

Xc nh cng thc oleum

Cu 7. 500gam dd H2SO4 98% + m gam H2O thu c dung dch H2SO4 24,5%. Tnh m
H2O
?
Cu 8. 400gam dd H2SO4 98% + 200 gam H2SO4 12,25% thu c dung dch H2SO4 C%. Tnh C ?
Cu 9. 150gam H2SO4.4SO3 + m gam H2O dung dch H2SO4 60%. Tnh m ?
Cu 10. m
1
gam H2SO4.3SO3 + m
2
gam dung dch H2SO4 49% 500 gam dung dch H2SO4 73,5%.
Tnh m
1
, m
2
?
Dng 4. Bi tp SO2, H2S tc dng vi dung dch kim.
Cu 1. Dn t t 2,24 lt SO2 (ktc) vo dung dch nc vi trong c cha 0,075 mol Ca(OH)
2

Nu hin tng xy ra, vit PTP.
Tnh khi lng mui thu c sau phn ng
Cu 2. Thi SO2 vo dd cha 0,02 mol Ba(OH)2. Gi tr khi lng kt ta bin thin trong khong no
khi SO2 bin thin trong khong t 0,005 mol n 0,024 mol?
Cu 3. Hp th ht 0,672 lt SO2 (ktc) vo bnh cha 2 lt dung dch Ca(OH)2 0,01M. Thm tip 0,4gam
NaOH vo bnh ny. Khi lng kt ta thu c sau phn ng l?
Cu 4: Cho hp th ht 1,792 lit kh SO2 (ktc) vo 400ml dung dch NaOH 0,25M, sau phn ng thu
c dung dch A. Rt t t 200ml dung dch Ba(OH)2 c nng x(M) vo dung dch A thu c 8,68
gam kt ta v dung dch C. Gi tr x l ?
Cu 5. Sc 2,24 lt (ktc) SO2 vo 100ml hn hp dung dch gm KOH 1M v Ba(OH)2 0,75M. Sau khi
kh b hp th hon ton thy to m g kt ta. Tnh m ?
Cu 6. Sc 4,48 lt (ktc) SO2 vo 100ml hn hp dung dch gm KOH 1M v Ba(OH)2 0,75M. Sau khi
kh b hp th hon ton thy to m g kt ta. Tnh m ?
Cu 7. Hp th ton b x mol SO2 vo dung dch cha 0,03 mol Ca(OH)2 c 24 gam kt ta. ga tr x?
Cu 8: Cho V lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v
Ba(OH)2 0,12M, thu c 1,97gam kt ta. Gi tr ln nht ca V l Cu 20: Hp th hon ton 3,36 lit
kh CO2 ( ktc) vo 2 lit dung dch Ba(OH)2 a mol/l, sau phn ng thu c 9,85 gam kt ta. Gi tr a
l ?

Dng 5. Bi ton v dung dch H2SO4
1-Ha tan ht 11,1 gam hn hp 3 kim loi trong dung dch H
2
SO
4
long d thu c dung dch A v 8,96
lt kh (ktc) .C cn dung dch A thu c m gam mui khan . m c gi tr l :
A . 59,1 gam B. 35,1 gam C. 49,5 gam D. 30,3 gam
2-Ha tan ht 20,608 gam mt kim loi M bng dung dch H
2
SO
4
long d thu c dung dch A v V lt
kh (ktc) . C cn dung dch A thu c 70,0672 gam mui khan . M l :
A . Na B. Mg C. Fe D. Ca
3-Cho 13,33 gam hn hp Al,Cu,Mg tc dng vi dung dch H
2
SO
4
long d thu c dung dch A , 7,728
lt kh (ktc) v 6,4 gam cht rn khng tan . C cn dung dch A thu c bao nhiu gam mui khan ?
A . 40,05 gam B. 42,25 gam C. 25,35 gam D. 46,65 gam
4-Ha tan ht hn hp X gm 0,12 mol Fe v 0,24 mol kim loi M trong dung dch H
2
SO
4
long d thu
c dung dch A v 10,752 lt kh (ktc) C cn dung dch A thu c 59,28 gam mui khan . Ml :
A . Na B. Mg C. Ca D. Al
5-Cho 15,82 gam hn hp Al,Fe,Cu tc dng ht vi dung dch H
2
SO
4
c nng thu c dung dch A v
9,632 lt SO
2
(ktc) . C cn dung dch A s thu c s gam mui khan l :
A. 57,1 B. 60,3 C.58,81 D.54,81
6-Cho 13,248 gam mt kim loi M tc dng vi dung dch H
2
SO
4
c nng d thu c V lt kh H
2
S
(ktc) v dung dch A .C cn dung dch A . C cn dung dch A thu c 66,24 gam mui khan . V c
gi tr l :
A . 2,4640 lt B. 4,2112 lt C. 4,7488 lt D. 3,0912 lt
7-Ha tan ht m gam hn hp 3 kim loi bng H
2
SO
4
c nng d thu c 11,782 lt SO
2
(ktc) v dung
dch A . C cn dung dch A thu c 71,06 gam mui khan . m c gi tr l :
A. 20,57 B. 60,35 C.58,81 D.54,81
8-Ha tan hn hp A gm 16,8 gam Fe ; 2,7 gam Al v 5,4 gam Ag tc dng vi H
2
SO
4
c nng ch thot
ra kh SO
2
. S mol H
2
SO
4
tham gia phn ng l :
A. 1,25 mol B. 1,20 mol C.1,45 mol D.1,85 mol
9-Cho 7,40 gam hn hp kim loi Ag , Al , Mg tan ht trong dung dch H
2
SO
4
c nng d thu c hn
hp sn phm kh gm 0,015 mol S v 0,0125 mol H
2
S v dung dch A . C cn dung dch A thu c
bao nhiu gam mui khan ?
A . 12,65 gam B. 15,62 gam C. 16,52 gam D. 15,26 gam
10-Ha tan hon ton 49,6 gam hn hp X gm Fe , FeO , Fe
2
O
3
v Fe
3
O
4
dung dch H
2
SO
4
c nng thu
c dung dch Y v 8,96 lt kh SO
2
(ktc) . C cn dung dch Y thu c m gam mui khan . m c gi tr
l :
A . 145 gam B. 140 gam C. 150 gam D. 155 gam
11-Ha tan 6,76 gam hn hp ba oxit Fe
3
O
4
, Al
2
O
3
, v CuO bng 100ml dung dch H
2
SO
4
1,3 M va ,
thu c dung dch Y c ha tan cc mui . C cn dung dch Y thu c m gam hn hp cc mui khan .
m c gi tr l :
A . 15,47 gam B. 16,35 gam C. 17,16 gam D. 19,5 gam
12-Cho m gam hn hp A gm 3 oxit kim loi MgO , ZnO , Fe
2
O
3
ha tan va trong 300 ml dung dch
H
2
SO
4
0,1 M , thu c dung dch Y . C cn dung dch Y thu c 5,21 gam hn hp cc mui sunfat
khan . Ga tr ca m l :
A . 2,85 gam B.2,30 gam C. 2,35 gam D. 2,81 gam
13-Cho 2,81 gam hn hp gm 3 oxit MgO , ZnO , Fe
2
O
3
ha tan va trong 300 ml dung dch H
2
SO
4

long , thu c dung dch Y . C cn dung dch Y thu c 5,21 gam hn hp cc mui sunfat khan .
Nng mol/l ca dung dch H
2
SO
4
:
A . 0,5 M B. 0,1 M C. 0,3 M D. 0,4 M
14-Cho hn hp X gm 5,4 gam Al , 4,8 gam Mg v 13 gam Zn tc dng vi dung dch H
2
SO
4
c , nng
d thu c 0,175 mol mt sn phm kh duy nht l X . X l :
A . SO
2
B. S C. H
2
S D. H
2

15-Cho 9 gam hn hp Al v Mg c t l s mol Al: Mg = 4:3 tc dng vi tc dng vi H
2
SO
4
c nng
va (cha 0,5625 mol H
2
SO
4
) thu c 1 sn phm kh duy nht X . X l :
A . SO
2
B. S C. H
2
S D. H
2

16-Ha tan ht 1,360 gam hn hp 2 kim loi X,Y trong dung dch H
2
SO
4
long , thu c 0,672 lt kh
(ktc) v m gam mui . Ga tr ca m l :
A. 2,44 gam B. 4,42 gam C. 24.4 gam D. 4,24 gam
17-Ha tan hon ton 19,2 gam kim loi M trong dung dch H
2
SO
4
c nng d thu c kh mi xc .
Cho kh ny hp th hon ton trong 1 lt dung dch NaOH 0,6 M , sau phn ng em c cn dung dch thu
c 37,8 gam cht rn , kim loi M l :
A. Cu B. Ca C. Fe D. Mg
18-Oxi ha hon ton 14,30 gam hn hp bt cc kim loi Mg , Al , Zn bng oxi d thu c 22,3 gam
hn hp oxit . Cho lng oxit ny tc dng ht vi dung dch HCl th lng mui to ra l :
A. 48,.90 gam B. 36,60 gam C. 32,050 gam D. 49,80 gam
19-Cho 5,6 gam Fe tc dng vi dung dch H
2
SO
4
c nng thu c 0,84 lt kh (ktc) gm mt sn phm
kh duy nht . Sn phm kh duy nht l :
A . SO
2
B. S C. H
2
S D. H
2

20-Nung m gam bt st ngoi khng kh sau mt thi gian thu c hn hp X gm 4 cht c khi lng
75,2 gam . Cho X tc dng vi H
2
SO
4
c nng , d thu c 6,72 lt kh SO
2
duy nht (ktc) . Ga tr m l
:
A. 56 gam B. 5,6 gam C. 52 gam D. 11,2 gam
21-Ha tan hon ton 2,81 gam hn hp Fe
2
O
3
, MgO , ZnO trong 500 ml dung dch H
2
SO
4
0,1 M (va
) . Sau phn ng , khi lng hn hp mui khan khi c cn l :
A. 3,81 gam B. 4,81 gam C. 5,81 gam D. 6,81 gam
22-Cho 55,2 gam hn hp X gm 2 oxit kim loi FeO v Al
2
O
3
tan va trong 700ml dung dch H
2
SO
4

2M . C cn dung dch sau phn ng thu c m gam mui khan . Ga tr ca m l :
A. 98,8 gam B. 167,2 gam C. 136,8 gam D. 219,2 gam
23-Cho 2,54 gam hn hp Y gm 3 oxit FeO , MgO , Al
2
O
3
tan va trong 300 ml dung dch H
2
SO
4

0,2M . C cn dung dch sau phn ng thu c m gam mui khan . Ga tr ca m l :
A. 7,34 gam B. 5,82 gam C. 4,94 gam D. 6,34 gam
24-Cho 38,3 gam hn hp 4 oxit kim loi Fe
2
O
3
, MgO , ZnO v Al
2
O
3
tan va trong 800 ml dung dch
H
2
SO
4
1M . C cn dung dch th thu c a gam mui khan . Ga tr ca a l :
A. 68,1 gam B. 86,2 gam C. 102,3 gam D. 93,3 gam
25-Ha tan ht 4,20 gam hn hp 3 kim loi X,Y,Z bng dung dch H
2
SO
4
c , nng thu c 0,025 mol
S (sn phm kh duy nht ) . C cn dung dch thu c sau phn ng thu c m gam mui khan . Ga tr
ca m l :
A. 14,10 gam B. 11,40 gam C. 6,60 gam D. 1,410 gam
26-Ha tan hon ton 11,90 gam hn hp 3 kim loi X,Y,Z bng dung dch H
2
SO
4
c , nng thu c
7,616 lt kh SO
2
(ktc) , 0,640 gam S v dung dch X .C cn dung dch X thu c m gam mui khan .
Ga tr ca m l :
A. 50,30 gam B. 30,50 gam C. 35,00 gam D. 30,05 gam
27-Cho 1,26 gam hn hp Mg v Al c t l mol tng ng l 3:2 tc dng vi H
2
SO
4
c ,nng va thu
c 0,015 mol mt sn phm kh c cha lu hunh . Sn phm kh l :
A . SO
2
B. S C. H
2
S D. H
2
28-Ha tan hon ton a gam Fe
x
O
y
bng dung dch H
2
SO
4
bng dung dch H
2
SO
4
m c nng va ,
c cha 0,075 mol H
2
SO
4
thu c b gam mt mui c 168 ml kh SO
2
(ktc) duy nht thot ra . Cng
thc ca Fe
x
O
y
v gi tr ca a , b l :
A . Fe
3
O
4
; 3,48 ; 9 B. Fe
2
O
3
; 2,45 ; 7 C. FeO ; 3,45 ; 5 D. Fe
2
O
3
; 2,48 ; 5
29-Khi ha tan mt oxit kim loi ha tr II bng mt lng va dung dch H
2
SO
4
9,8% th thu c
dung dch mui c nng 14,8% . Cng thc phn t ca oxit kim loi l :
A . CaO B. CuO C. MgO D. BaO
30-Ha tan 9,6 gam mt kim loi M trong dung dch H
2
SO
4
c nng d thu c 3,36 lt kh SO
2
(ktc)
v thu c dung dch A . C cn dung dch A thu c mui sunfat khan . Kim loi M v khi lng
mui sunfat khan l :
A . Mg ; 21gam B. Fe ; 23 gam C. Cu ; 24 gam D. Zn ; 27 gam

31-Cho 29 gam hn hp Mg,Zn,Fe tc dng ht vi dung dch H
2
SO
4
long thy thot ra V lt kh (ktc) .
C cn dung dch sau phn ng thu c 86,6 gam mui khan . Ga tr ca V l :
A . 6,72 lt B. 13,44 lt C. 22,4 lt D. 4,48 lt
32-Ha tan m gam hn hp X gm FeO , Fe
2
O
3
, Fe
3
O
4
bng H
2
SO
4
c nng , d thu c 11,2 lt kh
SO
2
duy nht (ktc) v dung dch X . C cn dung dch X thu c 95 gam mui khan . . Ga tr ca m l :
A. 20 gam B. 30 gam C. 40 gam D. 50 gam
33-Ha tan hon ton 20,88 gam mt oxit st bng dung dch H
2
SO
4
c nng , d thu c V lt kh SO
2

(ktc) v dung dch X . C cn dung dch X thu c 58 gam mui khan . Ga tr ca V l :
A . 3,248 lt B. 13,45 lt C. 22,40 lt D. 4,48 lt
34-Ha tan 30 gam hn hp X gm FeO , Fe
2
O
3
, Fe
3
O
4
bng H
2
SO
4
c nng , d thu c 11,2 lt kh
SO
2
duy nht (ktc) v dung dch X C cn dung dch X thu c m gam mui khan . . Ga tr ca m l :
A . 56 gam B. 95 gam C. 52 gam D. 112 gam
35-Ha tan hon ton 11,9 gam Al , Zn vo dung dch H
2
SO
4
c nng , thu c dung dch X ; 7,616 lt
kh SO
2
(ktc) v 0,64 gam S . Tng khi lng mui trong X l :
A. 50,3 gam B. 49,8 gam C. 47,15 gam D. 45,26 gam
36-Ha tan hon ton 5,95 g hn hp hai kim loi Al v Zn bng dung dch H
2
SO
4
long th khi lng
dung dch tng 5,55 gam . Khi lng Al v Zn trong hn hp ln lt l :
A 2,95 g v 3 g B 4,05 g v 1,9 g C 3,95 g v 2 g D 2,7 g v 3,25 g
37-Cho 0,01 mol mt hp cht ca st tc dng ht vi H
2
SO
4
c nng (d) thot ra 0,112 lt kh SO
2

(ktc) (l sn phm kh duy nht ) . Cng thc ca hp cht st l :
A FeS B FeS
2
C Fe
2
O
3
D Fe
3
O
4

38- trung ha 50 ml dung dch NaOH 1,2 M cn V(ml) dung dch H
2
SO
4
30% (D=1,222 g/ml) .Ga tr
ca V l
A 8,02 B 7,02 C 9,02 D 6,02
39- thu c dung dch H
2
SO
4
25% cn ly m
1
gam dung dch H
2
SO
4
45% pha vi m
2
gam dung dch
H
2
SO
4
15% . T l m
1
/m
2
l
A. 1:2 B. 1:3 C. 2:1 D. 3:1
40-Cho KI tc dng vi KMnO
4
trong mi trng H
2
SO
4
, ngi ta thu c 1,51 gam MnSO
4
. S mol I
2

to ra sau phn ng l :
A . 0,00025 mol B. 0,025mol C. 0,25 mol D. 0,0025 mol