TCCS 016: 2013/NAFI1

TCCS TIU CHUN C S

TCCS 016: 2013/NAFI1
QUY TRNH XC NH HM !"N# $IM %&I
Appraisal procedure for determination of metal
0
TCCS 016: 2013/NAFI1
H'I (H)N# * 2013
1
TCCS 016: 2013/NAFI1
+, -., /01
n v bin son: T kim nghim Ha Phng Kim nghim
n v ngh ban h!nh: Phng kim nghim
T"#nh $%&': H(i )ng khoa h*+ T"%ng ',m -h.' /01ng n2ng /,m 'h3& s4n v5ng 1
- 6%an 78' $%&' ban h!nh: T"%ng ',m -h.' /01ng n2ng /,m 'h3& s4n v5ng 1
9%&:' nh ban h!nh s;: <9=TT->1 ng!& 'h?ng @01A nBm +3a Ci?m ;+ T"%ng
',m -h.' /01ng n2ng /,m 'h3& s4n v5ng 1D
@
TCCS 016: 2013/NAFI1
XC NH 2N# %&T HM !"N# NHI3U $IM %&I
45N# THI6T 4 IC(*MS
17 (H&M 8I ( 9:N#
= Ph0ng Eh?E n!& m2 '4 +?+h 7?+ nh )ng /o' h!m /01ng nhi% kim /oi FPbG -$G HgG HsG
-"G InG JKG -oG LiG -%G MnG NKG N"G Oa DDDP '"ong 'hQ+ EhRmG n2ng s4nG 'hS+ Bn +hBn n%2iG .'
v! n0T+ bUng 'hi:' b V-P=IND
= CiTi hn Eh?' hin +3a Eh0ng Eh?E:
IW% n0T+ Fmg<kgP
Li -% Mn Hs -$ Hg Pb
>XY
mW%
0G000Z 0G000Z 0G0010 0G000Z 0G000Z 0G0001 0G000Z
>X9
mW%
0G001Z 0G001Z 0G00A0 0G001Z 0G001Z 0G000A 0G001Z
ThQ+ EhRm ni +h%ng Fmg<kgP
Li -% Mn Hs -$ Hg Pb
>XY
mW%
0G01Z 0G[00 1AGA00 0G010 0G010 0G00Z 0G010
>X9
mW%
0G0[Z 1G@00 A\G\00 0G0A0 0G0A0 0G01Z 0G0A0
L2ng s4n '0i F"a%G +3G 6%4G]P
Li -% Mn Hs -$ Hg Pb
>XY
mW%
0G@00 0G@Z0 1G100 0G010 0G010 0G00Z 0G010
>X9
mW%
0G^00 0G_Z0 AGA00 0G0A0 0G0A0 0G01Z 0G0A0
L2ng s4n kh2 F+h`G +! EhG nga +;+G]DP
Li -% Mn Hs -$ Hg Pb
>XY
mW%
0G@00 0G@00 1G\00 0G010 0G010 0G00Z 0G010
>X9
mW%
0G^00 0G^00 ZG_00 0G0A0 0G0A0 0G01Z 0G0A0
IW% .' Fmg<kgP
Li -% Mn Hs -$ Hg Pb
>XY
mW%
0GZ00 0GZ00 1^GZ00 0G@00 0G@00 0G100 0G@00
A
TCCS 016: 2013/NAFI1
>X9
mW%
1GZ00 1GZ00 [\GZ00 0G^00 0G^00 0GA00 0G^00
IW% 'hS+ Bn Fmg<kgP
Li -% Mn Hs -$ Hg Pb
>XY
mW%
0G@00 0G@00 1G\00 0G010 0G010 0G00Z 0G010
>X9
mW%
0G^00 0G^00 ZG_00 0G0A0 0G0A0 0G01Z 0G0A0
27 N#UYN T;C
IW% 'hQ+ EhRmG n2ng s4nG 'hS+ Bn +hBn n%2iG .' /!m )ng nh.' 01+ v2 + ha bUng
a+i$ HLX
A
G H
@
X
@
v! H-/ '"n 'hi:' b Ii+"obavKD H!m /01ng 'cng kim /oi + '"ong mW%
01+ 7?+ nh '"n 'hi:' b V-P=IND
37 H2 S
Oi% mW% 0ZD[=->1<NT 0@D0[O ghi 6%? '"#nh Eha +h: $%ng $+h g;+G 'h%;+ 'hdD
Oi% mW% 0ZD[=->1<NT 0AD01 ghi 6%? '"#nh Eha +h: +h%Rn '"%ng gianD
Oi% mW% 0ZD@=->1<NTD0AD^_ ghi k:' 6%4 Eh,n 'e+hD
<7 H=A CH>T? CH>T CHUN
1DD Ha +h.':
[D1D1D H+i$ ni'"i+ fm g+ FHLX
A
P ^hiG IK"+k hog+ '0ng 0ng
[D1D@D H&$"o+h/o"i$K a+i$ fm g+ FH-/

P A_iG IK"+k hog+ '0ng 0ng

[D1DAD H&$"ogKn EK"o7i$K so/%'ion FH
@
X
@
P A0iG IK"+k hog+ '0ng 0ng
[D1D[D ja'K"G IK"+k hog+ '0ng 0ng
[D1DZD Y%ng $+h '%ning 1g</ F-KG -oG >iG IgG T/G kPG +3a hlng Hgi/Kn' hog+ '0ng 0ng
[D@D -h.' +h%Rn:
[D@D1D -h%Rn hmn h1E kim /oi FH/G OaG OKG OiG -aG -$G -oG -"G -%G JKG CaG KG >iG IgG InG
LaG LiG PbG NKG N"G TKG T>G MnP 10 mg</G Hgi/Kn' hog+ '0ng 0ngD
[D@D@D -h%Rn Hg 10 mg</G Hgi/Kn' hog+ '0ng 0ngD
[DAD Y%ng $+h:
[
TCCS 016: 2013/NAFI1
[DAD1D Y%ng $+h HLX
A
@i Fv<vP: -ho v!o ;ng ong Z00 m/ kho4ng A00 m/ H
@
XG 10 m/
$%ng $+h HLX
A
gm g+G 'hm H
@
X +ho :n v+h Z00m/D O4o 6%4n '"ong +ha& nhQa f&
kenG nhi' ( EhngG 'hni gian b4o 6%4n 1 nBmD
[DAD@D Y%ng $+h HLX
A
@iFv<vPG H-/ 0GZi Fv<vP: -ho v!o ;ng ong Z00 m/ kho4ng A00 m/
H
@
X %/'"a E%"KG 10 m/ HLX
A
gm g+G v! @DZ m/ H-/ gm g+G 'hm H
@
X +ho :n v+h
Z00m/D O4o 6%4n '"ong +ha& nhQa f& kenG nhi' ( EhngG 'hni gian b4o 6%4n 1 nBmD
[DADAD Y%ng $+h +h%Rn @ EEm Hg: Ho' +henh 7?+ 1 m/ $%ng $+h +h%Rn Hg 10 mg</ +ho v!o
b#nh nh mS+ Z m/ v! nh mS+ :n v+h bUng $%ng $+h HLX
A
@iD O4o 6%4n '"ong +hai
nhQa f& kenG nhi' ( EhngG 'hni gian b4o 6%4n 1 nBmD
[DAD [D Y%ng $+h +h%Rn hmn h1E FIi7 IK'a/s HP 100 EEb FHsG H/G OaG OKG OiG -aG -$G -oG
-"G -%G JKG CaG KG >iG IgG InG LaG LiG PbG NKG N"G TKG T>G MnPG @0 EEb FHgP: Ho' +henh 7?+ 1
m/ $%ng $+h +h%Rn hmn h1E kim /oi 10 EEm FHsG H/G OaG OKG OiG -aG -$G -oG -"G -%G JKG
CaG KG >iG IgG InG LaG LiG PbG NKG N"G TKG T>G MnP v! 1 m/ $%ng $+h +h%Rn @ EEm FHgP G
+ho v!o b#nh nh mS+ 100 m/ v! nh mS+ :n v+h bUng $%ng $+h HLXA @iG H-/ 0DZiD
O4o 6%4n '"ong +hai nhQa f& kenG nhi' ( EhngG 'hni gian b4o 6%4n A 'h?ngD
[DADZD Yl& +h%Rn /!m vi+ 1p Zp 10G 1ZG @0 EEb FHsG H/G OaG OKG OiG -aG -$G -oG -"G -%G JKG
CaG KG >iG IgG InG LaG LiG PbG NKG N"G TKG T>G MnPG 0D@G 1G @G AG [ EEb FHgP: 01+ Eha /olng
'c $%ng $i+h +h%Rn hmn h1E 100 EEb FHsG H/G OaG OKG OiG -aG -$G -oG -"G -%G JKG CaG KG >iG
IgG InG LaG LiG PbG NKG N"G TKG T>G MnPG @0 EEb FHgP vTi $%ng $+h HLX
A
@iG H-/ 0DZiD
O4o 6%4n '"ong +hai nhQa f& kenG nhi' ( EhngG 'hni gian b4o 6%4n 1 '%qnD
>0% r: ( '%&:n 'enh +3a 0nng +h%Rn l 01+ kh4o s?' s $4i t0p 100u EEb FHsG H/G OaG OKG
OiG -aG -$G -oG -"G -%G JKG CaG KG >iG IgG InG LaG LiG PbG NKG N"G TKG T>G MnPG t0p @0u EEb
FHgPD
[DAD^D Y%ng $+h "da m?& V-P=IN FHLX
A
@iv<vG H-/ 1iv<vP: Ho' 10 m/ $%ng $+h HLXA
gm g+G Z m/ $%ng $+h H-/ gm g+ v!o ;ng ong Z00 m/ v! nh mS+ :n v+h bUng
n0T+D O4o 6%4n '"ong +hai nhQa f& kenG nhi' ( EhngG 'hni gian b4o 6%4n 1 nBmD
@7 THI6T 4? 9:N# C:
1DD H 'h;ng V-P=IN hlng Hgi/Kn'G mo$K/: __007 hog+ '0ng 0ng
@DD > Ii+"obavK hlng Ii/Ks'onK mo$K/: v'ho$ XnK hog+ '0ng 0ng
ADD -,n Eh,n 'e+h + ( +henh 7?+ $ w 0D1mgD
[DD T3 s.&D
ZDD I?& 7a& mW%D
^DD O#nh nh mS+ 100m/
Z
TCCS 016: 2013/NAFI1
_DD Ii+"oEiEK''K Zm/G 1m/G 100/
hDD xng /& ',m nhQa 1Z m/G Z0 m/
\DD xng ong Z00m/
10DD 9%& '"#nh "da $yng +y: xng 'Kz/on v! $yng +y sa% khi sd $yng Eh4i 01+ "da 'hKo '"#nh
'Q sa%: '"?ng bUng a+K'onKG '"?ng bUng n0T+ m?&G ng,m '"ong $%ng $+h a+i$ ni'"i+ 10 i
kho4ng 1 ginG '"?ng n0T+ m?&G si% ,m 1Z Eho'G '"?ng n0T+ m?&G '"?ng e' nh.' [ /qn bUng
n0T+ +.'G "?o '"?nh byi v! sd $yngD
67 CCH TI6N HNH
1DD >.& mW% G nh, {n mW% | b4o 6%4n mW% '"0T+ Eh,n 'e+h:
= >.& mW% | O4o 6%4n mW% '"0T+ Eh,n 'e+h: IW% 01+ /.& Eh4i i $i {n '%,n 'h3 'hKo
+h0ng 0^ N 'a& h0Tng $Wn +h%ng HaD
@DD -h%Rn b mW% 'h2:
= ThQ+ hin 'hKo h0Tng $Wn +h0ng 0@ = N 'a& Eh0ng Eh?ED
= Lgo!i "aG $o mW% /! Eh,n 'e+h kim /oi ngng nn /0% r hn +h: 'i:E 7o+ '"Q+ 'i:E vTi kim
/oi nhUm '"?nh 'h2i nhi}m kim /oi 'c bn ngo!i v!o mW%D
= ~ing ;i vTi mW% .': N.& 6%a m s [0
0
-G sa% nghin mW% )ng nh.'D K:' 6%4 mW%
.' s 01+ 'enh '"n h!m /01ng +h.' kh2D
ADD -h%Rn b mW% 'hd: 9%i '+ +h%ng: -,n v! ghi +henh 7?+ Fm
1
gP hog+ ho' 1 m/ +h.' /ng:
Kho4ng 1D0g mW% 0T' F+ h!m /01ng n0T+ /Tn hn _0iPG 0DZg mW% kh2 v!o ;ng 'Kz/on
100m/D
~ing ;i vTi mW% .': +,n kho4ng 0G@Z gG ghi +henh 7?+ $ w 0G1 mgD
>0% r: Ti nhng nn mW% /G +qn 'hKo $i +hg' +h nhi' (G ?E s%.' khi sd $yng
Ii+"obavK 4m b4o an 'o!nD Tham kh4o kh;i /01ng +,n mW% 'c h0Tng $Wn +3a nh! s4n
7%.' Ii+"obavK IK'ho$ XnKD
[DD IW% kim sa': Nd $yng mW% vf' /i% +h%Rn YX~I = AD
ZDD IW% 'h%;+ 'hd '"ng: 'ha& mW% 'hd bUng 1 m/ H
@
XD
^D^D 2 + ha mW%
= Ho' [ m/ n0T+p AGZ m/ HLX
A
gm g+G 1 m/ H
@
X
@
v!o +?+ ;ng 'Kz/on '"nD
= ~ing vTi mW% .': -ho A m/ H-/G 1 m/ HLX
A
G &n kho4ng 1 ginD Thm @ m/ n0T+ v!
1GZ m/ H
@
X
@
D
^
TCCS 016: 2013/NAFI1
= Ti +?+ nn mW% /G 'ham kh4o h0Tng $Wn +3a nh! s4n 7%.' Ii+"obavK IK'ho$ XnK
'i:n h!nhD
= 2 + ha mW% '"n 'hi:' b Eh? mW% vi sng Ii+"obavKD
-h0ng '"#nh v2 + ha mW% vi sng bUng 'hi:' b v'ho$ onK
O0T+ Thni gian FEho'P Lhi' ( F
o
-P -2ng s%.' FjP
1 1Z @00 1@00
@ 1Z @00 1@00
FTi +?+ nn mW% /G 'ham kh4o +h0ng '"#nh Eh? mW% +3a 'hi:' b Ii+"obavK 4m b4o
an 'o!n +ho +on ng0ni v! 'hi:' bPD
IW% sa% khi v2 + ha Eh4i /! $%ng $+h )ng nh.' v! '"ong s%;'D
= Na% +h%&n $%ng $+h mW% 6%a ;ng /& ',m nhQa Z0 m/G '"?ng ;ng 'KE/on v! nE e' nh.' A
/qn bUng n0T+ %/'"a E%"KG Eha /olng mW% v! nh mS+ :n v+h FZ0 m/P hog+ +,n FZ0 gP Fm
@
g hog+ m/PD
= ;i vTi mW% + v?ng $q% hog+ +h.' kh2ng 'anG + 'h /*+ hog+ /& ',m '"0T+ khi Eh,n 'e+h
bUng m?& V-P=IND
= Ti mW% .'G 'i:E 'y+ Eha /olng mW% FJP 'hm kho4ng [ /qn '"0T+ khi Eh,n 'e+h '"n m?&
V-P=IND
= ;i vTi mW% n0T+ sinh ho'G n0T+ %;ng ng +hai: -ho v!o ;ng /& ',m nhQa Z0 m/ mW%
n0T+G 'hm 1 m/ HLX
A
gm g+ v! 0D@Z m/ H-/ fm g+G /+ %G Eh,n 'e+h '"n m?& V-P=
IND IW% '"ng /! n0T+ %/'"a E%"KD
A7 TI6N HNH (HBN TCCH TRN THI6T 4
= Kim '"a '#nh '"ng m?& v! +!i g+ +?+ 'h2ng s; Eh5 h1ED
Iass v/KmKn' Vn'K"g"a'ion TimK FsK+P<Poin' sK+<Iass
Z@ -" 0DA 0DA
ZZ In 0DZ 0DZ
Z^ JK 0DZ 0DZ
Z\ -o 0DA 0DA
^0 Li 0DZ 0DZ
^A=^Z -% 0DZ 0DZ
_
TCCS 016: 2013/NAFI1
^[=^^ Mn 0DZ 0DZ
_Z Hs @D0 @D0
_h NK AD0 AD0
hh N" 0DA 0DA
111 -$ 0DZ 0DZ
1A_ Oa 0DZ 0DZ
@01=@0@ Hg 0DZ 0DZ
@0^=@0_=@0h Pb 0DZ 0DZ
= Ti:n h!nh +h& b4ng mW% 'hKo 'hS 'Q sa%:
1D ~da m?&
@D 0nng +h%Rn
AD ~da m?&
[D IW% 'h%;+ 'hd '"ng
ZD IW% kim sa' F mW% -~I hog+ mW% 'hm +h%Rn P
^D ~da m?&
_D IW% 'hd F10 mW%P
hD ~da m?&D
\D im +h%Rn kim '"a
10D ~da m?& sa% +h& mW% 'hd
D7 TCNH T%N $6T QU'
1DD H!m /01ng kim /oi '"ong mW% 01+ 'enh 'hKo +2ng 'hS+:
- w -
i
J
T"ong :
-: H!m /01ng kim /oi '"ong mW% 'hd Fg<kgP
-
i
: H!m /01ng kim /oi '"ong $%ng $+h mW% 'hd 'enh 'c 0nng +h%Rn Fg<kgP
J: ( Eha /olng +3a mW%
E7 'M 4'% CH>T !"N# $6T QU' $IFM N#HIGM
1DD H s; '%ng 6%an 0nng +h%Rn ~
@
0G\\D
h
TCCS 016: 2013/NAFI1
@DD ( 'h% h)i +3a mW% +h%Rn nUm '"ong kho4ng 'c _0 1@0 i
107 TI IGU THAM $H'%
t1u T!i /i% h0Tng $Wn sd $yng 'hi:' b V-P=IN v! Sng $yng +3a hlng Hgi/Kn'D
t@u ng $yng +3a m?& Eh? mW% Ii"+obavK IK'ho$ XnKD
tAu HXH- \\\D10p HXH- \\AD1[D
t[u T-L ^[\^: @00\ ?+ nh h!m /01ng +?+ kim /oi '"ong .' bUng $+h +hi:' +0nng
'h3&D
\