Caracterizações ABS e Vários Via DSC e FTIR

CHARACTERIZATION OF POLYMERS
BY MEANS OF TG-FTIR (III)

Ekkehard Fglein and Claire Louis
NETZSCH-Gertebau GmbH, Wittelsbacherstrae 42, D-95100 Selb, Germany
NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH, NETZSCH-Gertebau GmbH
DTG /(%/min)
Gram Schmidt
TG /%
0.60
395.5 C
0.00
0.50
sample:
PMMA, granule
sample mass:
5.06 mg
crucible:
Al2O3,
[1] 006-3-06-11.dt3
sample
carrier:
Al2O3 , corrosive rest.
TG
atmosphere:
nitrogen
(20 + 20 ml)
Gram Schmidt
heating rate:
20
K/min
DTG
80.0
60.0
-10.00
0.40
-20.00
0.30
-99.2 %
Absorbance Units
0.5
1.0
PMMA
Temperature of
decomposition
(DTG minimum):
1.5
10.00
100.0
391C
Main
decomposition
products:
-30.00
40.0
0.10
20.0
0.00
391.2 C
0.0
-40.00
0.0
0.20
H3C O C O
CH2 C
CH3 n
-50.00
4000
3500
3000
-60.00
2500
2000
Wavenumber cm-1
1500
1000
propionic acid,
methyl ester
Residual Mass: 0.8 % (596.8 C)

Y:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-11_PMMA\006-3-06-11_PMMA_392.0
100.0
200.0
300.0
Temperature /C
400.0
500.0
C:\OPUS\search\Hit858.0
PMMA
5.062 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-11_PMMA\006-3-06-11.dt3
METHACRYLIC ACID, METHYL ESTER
250.0
-0.6 %
0.25
2.5
Gram Schmidt
Flow /(ml/min)
DTG /(%/min)
TG /%
NH3
5.00
Temperature of
decomposition
(DTG minimum):
458.7 C
0.00
90.0
200.0
872.0 C
sample:
80.0
sample mass:
crucible:
sample
carrier:
70.0
atmosphere:
heating rate:
-5.00
PA66, granule
9.85 mg
[1] 006-3-06-14.dt3
-63.3 %
TG
Al2O3,
Flow (purge1)
Al2O3 Flow
, corrosive
(purge2) rest.
nitrogen
Schmidt
air
Gram
DTG
20 K/min
0.15
-10.00
150.0
873.1 C
60.0
CO2
0.20
0.10
Absorbance Units
1.0
1.5
PA66
2.0
100.0
454C
-15.00
Main
decomposition
products:
0.5
100.0
50.0
H
H O
O
N (CH2)6 N C (CH2)4 C n
-20.00
0.05
-1.4 %
-25.00
50.0
0.0
40.0
454.2 C
30.0
0.00
4000
3500
3000
-30.00
nitrogen
20.0
0.0
100.0
200.0
300.0
400.0 500.0 600.0

Temperature /C
700.0
800.0
2500
2000
Wavenumber cm-1
1500
1000
air
Y:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-14_PA66\006-3-06-14_PA66_450.0
CARBON DIOXIDE
AMMONIA
CYCLOHEXANECARBOXYLIC ACID, METHYL ESTER
900.0
PA66
ammonia,
cyclohexane carboxylic
acid, methyl ester
9.850 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-14_PA66\006-3-06-14.dt3
DTG /(%/min)
Gram Schmidt
TG /%
80.0
60.0
0.20
sample:
ABS, plate
sample mass:
8.02 mg
[1] 006-3-06-18.dt3
crucible:
Al2O3, TG
sample carrier:
Al2Schmidt
O3 , corrosive rest.
Gram
DTG(20 + 20 ml)
atmosphere:
nitrogen
heating rate:
20 K/min
-10.00
0.15
-94.3 %
0.10
CH
453C
-20.00
Main
decomposition
product:
0.5
40.0
C N
CH2 CH n CH2 CH CH CH2
CH2
m
Temperature of
decomposition
(DTG minimum):
0.00
462.8 C
Absorbance Units
1.0
1.5
ABS
ABS (450C)
SAN (428C)
2.0
0.25
100.0
0.05
-30.00
0.00
-40.00
0.0
20.0
452.9 C
4000
3500
3000
2500
2000
Wavenumber cm-1
1500
1000
0.0
100.0
200.0
300.0
400.0
Temperature /C
500.0
600.0
acetonitrile,
phenyl
Y:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-19_ABS\006-3-06-19_ABS_450.0
ABS
9.430 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-19_ABS\006-3-06-19.dt3
Y:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-17_SAN\006-3-06-17_SAN_428.0
SAN
10.290 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-17_SAN\006-3-06-17.dt3
ACETONITRILE, PHENYL-,
exo
0.00
1.0
PBT
80.0
0.25
sample:
PBT, plate
[1] 006-3-06-15.dt3
sample
mass:
9.59
mg
TG
crucible:
Al2O3,
Gram Schmidt
DTG
sample carrier:
Al
2O3 , corrosive rest.
[2] c-DTA_006-3-06-15.dt3_0.mt3
atmosphere:
nitrogen (20 + 20 ml)
c-DTA
heating rate:
20 K/min
1.00
-10.00
0.20
0.80
-93.6 %
0.15
-20.00
Absorbance Units
0.5
1.20
60.0
0.10
0.40
0.05
0.20
-40.00
20.0
0.00
-0.5
-50.00
4000
0.00
413.6 C
100.0
200.0
300.0
400.0
Temperature /C
500.0
3500
3000
2500
2000
Wavenumber cm-1
1500
1000
-0.20
0.0
Main
decomposition
product:
0.0
-30.00
O
C O CH2 CH2 CH2 CH2 O
414C
0.60
227.9 C
40.0
-60.00
Y:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-15_PBT\006-3-06-15_PBT_417.0
600.0
BENZOIC ACID
TEREPHTHALIC ACID, DIBUTYL ESTER
PBT
terephthalic acid,
dibutylester
9.590 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-15_PBT\006-3-06-15.dt3
DTG /(%/min)
Gram Schmidt
TG /%
2.0
Temperature of
decomposition
(DTG minimum):
60.0
0.00
-10.00
0.15
-20.00
-97.8 %
0.10
-30.00
40.0
Absorbance Units
1.0
0.20
sample:
[1.1] 006-3-06-17.dt3SAN, granule
TGmg
sample mass:
10.29
Gram Schmidt
O3 ,
crucible:
Al2DTG
sample carrier:
Al2O3 , corrosive rest.
atmosphere:
nitrogen (20 + 20 ml)
heating rate:
20 K/min
425C
0.5
SAN
436.0 C
80.0
1.5
100.0
Main
decomposition
product:
C N
CH2 CH n CH2
CH
0.05
-40.00
20.0
0.0
O
C
Temperature of
decomposition
(DTG minimum):
10.00
1.40
0.30
417.8 C
1.5
c-DTA /K
Gram Schmidt
DTG /(%/min)
TG /%
100.0
0.00
424.8 C
0.0
-50.00
4000
3500
3000
Residual Mass: 700.0 C, 2.2 %
100.0
200.0
300.0
400.0
Temperature /C
500.0
600.0
2500
2000
Wavenumber cm-1
1500
1000
acetonitrile,
phenyl
700.0
Y:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-17_SAN\006-3-06-17_SAN_428.0
ACETONITRILE, PHENYL-,
All measurements were carried out employing alumina crucibles, heating rate: 20 K/min, atmosphere: nitrogen, purge gas flow rate: 40 ml/min
SAN
10.290 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-17_SAN\006-3-06-17.dt3

Caracterizações ABS e Vários Via DSC e FTIR

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Caracterizações ABS e Vários Via DSC e FTIR

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CHARACTERIZATION OF POLYMERS

BY MEANS OF TG-FTIR (III)

Residual Mass: 0.8 % (596.8 C)

5.062 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-11_PMMA\006-3-06-11.dt3

METHACRYLIC ACID, METHYL ESTER

Residual Mass: 34.6 % (987.3 C)

400.0 500.0 600.0

9.850 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-14_PA66\006-3-06-14.dt3

Residual Mass: 5.7 % (696.9 C)

9.430 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-19_ABS\006-3-06-19.dt3

10.290 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-17_SAN\006-3-06-17.dt3

Residual Mass: 6.4 % (646.7 C)

TEREPHTHALIC ACID, DIBUTYL ESTER

9.590 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-15_PBT\006-3-06-15.dt3

Residual Mass: 700.0 C, 2.2 %

10.290 | NETZSCH TG 209 F1 | Z:\Commissions\823-xxx-06\006-3-06-TG209F1-FTIR-MS\006-3-06-17_SAN\006-3-06-17.dt3

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