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Title: Chapter 19(1)
Started: November 8, 2009 5:18 PM
Submitted: November 8, 2009 6:43 PM
Time spent: 01:24:48
Total score: 5/12 = 41.67% Total score adjusted by 0.0 Maximum possible score: 12

1. Buffer Synthesis 1
Match the acid/base pair that is suitable for preparing a buffer of each given approximate
pH. You will need to refer to Tables in the book of weak acids and bases and polyprotic acid

HCOOH/NaHCOO 9

NaH2PO3/Na2HPO3 4

HOBr/NaOBr 7

Statement Response Value Correct Match


HCOOH/NaHCOO 4 Correct 4
NaH2PO3/Na2HPO3 9 Incorrect 7
HOBr/NaOBr 7 Incorrect 9

Score: 0/1

2. Indicator 5
Which indicator would be the best to use for a titration between 0.10 M HF with 0.10 M
NaOH? You will probably need to consult the appropriate table in the book.

Student Correct
Value Feedback
Response Answer
1. thymol blue, 100%
color change
at pH 8-10
2. bromothymol 0%
blue, color
change at pH
6-8
3. methyl red, 0%
color change
at pH 3-5
4. alizarin 0%
yellow R,
color change
at pH 10-12

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5. methyl 0%
violet, , color
change at pH
0-2

Score: 0/1

3. Chapter 11 Simple Buffer 16


Calculate the pH of a solution that is 0.079 M NH3 and 0.058 M NH4Cl.
Kb of NH3 is 1.8 x 10-5.

Student Response Value Correct Answer


Answer 2.12 0% 9.39

Score: 0/1

4. Chapter 11 Moderate Buffer 6


The pH of 0.5 M formic acic, HCOOH, is 2.02. Calculate the difference in pH when 6.38 g of
HCOONa is added to 338.1 mL of 0.50 M formic acid. Ignore any changes in volume.
The Ka value for HCOOH is 1.8 x 10-4.

Student Response Value Correct Answer


Answer 1.37 0% 1.47

Score: 0/1

5. Buffer Ratio 2

What is the buffer component ratio, ([NO2-]/[HNO2]) of a nitrite buffer that has a pH of
2.52. Ka of HNO2 is 7.1 x 10-4.

Student Response Value Correct Answer


Answer .235 100% 0.23

Score: 1/1

6. Additions to Buffer 1

A buffer that contains 0.380 M of acid, HA and 0.453 M of its conjugate base A-, has a pH of
4.20. What is the pH after 0.0297 mol of NaOH are added to 0.708 L of the solution?

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Student Response Value Correct Answer


Answer 4.45 0% 4.29

Score: 0/1

7. Chapter 11 Titrations SS 8
Calculate the pH during the titration of 24.8 mL of 0.425 M NaOH with 0.111 M HCl after
12.8 mL of the acid have been added.

Student Response Value Correct Answer


Answer 13.4 100% 13.38

Score: 1/1

8. Chapter 11 Titrations WS 23
Calculate the pH during the titration of 20.00 mL of 0.1000 M CH3COOH(aq) with 0.1000 M
NaOH(aq) after 20.41 mL of the base have been added.
Ka of acetic acid = 1.8 x 10-5.

Student Response Value Correct Answer


Answer 11 100% 11.01

Score: 1/1

9. Chapter 11 Titrations SW 7
Calculate the pH during the titration of 20.00 mL of 0.1000 M trimethylamine,
(CH3)3N(aq), with 0.1000 M HCl(aq) after 19.86 mL of the acid have been added.
Kb of trimethylamine = 6.5 x 10-5.

Student Response Value Correct Answer


Answer 10.5 0% 7.66

Score: 0/1

10. Chapter 11 Titrations EP SS 2


What is the volume in mL of 0.175 M NaOH(aq) needed to reach the equivalence
(stoichiometric) point in the titration of 54.6 mL of 0.557 M HCl(aq).

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Student Response Value Correct Answer


Answer 174 100% 173.8

Score: 1/1

11. Chapter 11 Titrations EPP SW 2


Determine the pH at the equivalence (stoichiometric) point in the titration of 44.9 mL of
0.208 M CH3NH2 by 0.426 M HNO3.
The Kb of CH3NH2 is 3.6 x 10-4.

Student Response Value Correct Answer


Answer 2.22 0% 5.71

Score: 0/1

12. Chapter 11 Titrations HEP SW 3


What is the volume in mL of 0.519 M HCl(aq) needed to reach halfway to the equivalence
(stoichiometric) point in the titration of 37.7 mL of 0.786 M methylamine
(Kb = 3.6 x 10-4).

Student Response Value Correct Answer


Answer 28.5 100% 28.5

Score: 1/1

Done

4 of 4 08-Nov-09 6:44 PM

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