2011-03-17

Inorganic Chemistry
2011. 3. 11

:
010-3289-6194
031-791-9471
catalite@paran.com
www.enchem.co.kr

1. ()?
<>
- , , / *

< >
- ,
-. , ,
-. ,
-. .
-. .
, () () ,
-.

* - ; .
- ; / .
- /; .

2011-03-17

2.
. :
. :

: ,

.

1. (Coordination Number) (Oxidation states)
- : 4
- : 4 14,
ex) PF5- (Tirgonal bipyramidal), W(CH3)6 : -6
[Nd(H2O)9]3+ : 9
2

2011-03-17

1 ; (C), (H) (O), (N), (S)

, , C
(=).
2. ; 50, Ge, Si ,

-. ; , , , /,
-. ; -->>> ; Ge, Si
.
3. ; /
-. 19C
-. ; -> -> ()(2
)
cf. idea; -> ->
*
4. ; , (Inorganic chemistry Journal
70%)
-. ; (valence bonding theory), (Crystal field
theory), (Molecular Orbital Theory)
5. ; Energy

3.
: 4
1. (elements) :
2. (ionic compounds)
3. (molecular compounds)
4.
1. :
a) (Ar, Kr) (O2, H2)
b) (P4, S8, C60)
c) (Diamond, graphite)
d) (W, Co) (Hg, Ga)

2011-03-17

: 4
1. (elements) :

2. (ionic compounds)
3. (molecular compounds)
4.
2. (ionic compounds)
a) (NaCl)
b) (ZrO2), (, MgAl 2O 4),
(CaMg(SiO3)2)
c) , , ,
ex) AgCl, SiC, GaAs BN
d) , ex) [SiF6]2-, [Co(NH3)6]3+, [Fe(CN)6]3-,
[Ni(H2O)6]2+

: 4
1. (elements) :
2. (ionic compounds)
3. (molecular compounds)
4.
3. (molecular compounds) : ,
a) PF3, SO2, OsO4, UF6
b) PtCl2(PMe3)2, RuH(Co2Me)(PPh3)2 *(complex
metal compounds)
c) Ni(CO)4, Zr(CH2C6H5)4 (Organometallic
compounds
*(complex compounds) : (
) ,
.

2011-03-17

: 4

: 4
1. (elements) :
2. (ionic compounds)
3. (molecular compounds)
4.
4.
a) (YBa2Cu3O7)

4.
- (tetrahedron) (
4. (Platonic solids)
(regular polyhedron) .
- 5, 6, 7

5

1) .
2) .
3) .

2011-03-17

5.
(mechanism) ,
.
1) ( )
-
2)
(descriptive) ,
-

6.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.

-(acid-base) [(neutralization)]
(addition)
(elimination)
-(reduction-oxidation, redox)
(insertion)
(substitution) [(displacement)]
(rearrangement) [ (isomerization)]
(metathesis) [(exchange)]-NaNO3 + KCl NaCl + KNO3
(solvolysis)
(chelation)-
(cyclization) (condensation)
(nuclear reaction)

2011-03-17

7. - : 3
1. Arrhenius () ,

. .
: H+ HA H+ + A : OH- BOH B + + OH2. Bronsted-Lewry(-) ,
, : H+()
.
: (H+) HA H+ + A : (H+) NH3 + H+ NH4+
3. Lewis() ,
:
.
:
:

) -
)
1. HCl , HCl

, , HCl
.

2. Cl 8 ,
.

2011-03-17

8. Thermochemistry()
(standard states) : 25oC(295.15K), 1
(heat content) (enthalpy) : ,
.
- (enthalpy) : ,
- H = (H of ) - (H of )
- HO =
H ( - ) (exothermic reaction),
H ( + ) (endothermic reaction)
-

9.