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TABLE OF CONTENT
PHYSICAL CHEMISTRY
ATOMIC STRUCTURE...........................................................................................................1
CHEMICAL BONDING...........................................................................................................2
CHEMICAL EQUILIBRIUM....................................................................................................3
ACID BASE............................................................................................................................4
IONIC EQULIBRIUM..............................................................................................................5
CHEMICAL KINETICS...........................................................................................................6
OXIDATION-REDUCTION..................................................................................................... 7
VOLUMETRIC ANALYSIS..................................................................................................... 8
MOLE CONCEPT................................................................................................................... 9
CHEMICAL ENERGETICS.................................................................................................... 9 - 10
ELECTRO CHEMISTRY........................................................................................................ 11
SOLUTION AND COLLIGATIVE PROPERTIES...................................................................11 - 12
NUCLEAR CHEMISTRY........................................................................................................ 12
GASEOUS STATE................................................................................................................. 13
SOLID AND LIQUID STATE.................................................................................................. 14
SURFACE CHEMISTRY & COLLOIDAL STATE.................................................................. 15
INORGANIC CHEMISTRY
s
s
la
PERIODIC TABLE................................................................................................................. 16
EXTRACTIVE METALLURGY............................................................................................... 17
s- BLOCK ELEMENTS..........................................................................................................17
BORON FAMILY.....................................................................................................................18
CARBON FAMILY...................................................................................................................18
OXYGEN FAMILY...................................................................................................................19
HALOGEN FAMILY.................................................................................................................20 - 21
TRANSITION ELEMENTS (D-BLOCK ELEMENTS).............................................................21
COORDINATION COMPOUNDS............................................................................................21
ORGANIC CHEMISTRY
GOC........................................................................................................................................22
ALKANES...............................................................................................................................23
ALKENES...............................................................................................................................23
ALKYNES...............................................................................................................................23
HALOGEN COMPOUNDS.....................................................................................................23
ALCOHOLS............................................................................................................................24
PHENOLS...............................................................................................................................24
ETHERS................................................................................................................................. 25
CARBONYL COMPOUNDS...................................................................................................25
CARBOXYLIC ACIDS............................................................................................................26
NITROGEN COMPOUNDS....................................................................................................26
CARBOHYHYDRATES, AMINO ACIDS AND POLYMERS...................................................26
CHARACTERISTIC REACTIONS OF DIFFERENT ORGANIC COMPOUNDS....................27
IMPORTANT REAGENT.........................................................................................................28 -29
MAIN USE OF COMPOUNDS............................................................................................... 29
SMELL OF SOME COMPOUNDS......................................................................................... 29
IDENTIFICATION TESTS....................................................................................................... 30
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PHYSICAL CHEMISTRY
ATOMIC STRUCTURE
2 2
n2
n h
2
=
0.529
A, rn = n r1
2
2
4p mZe
Z
1.
rn =
2.
PE
Z2
ET = KE =
= - 13.6 2 eV
2
n
3.
DE =
4.
v=
2
4
hc 2p me 1 1
=
2- 2
2
l
h
n1 n2
s
s
la
1 1
1
= RZ 2 2 - 2 , R = 1.0968 107 m-1
l
n1 n2
n(n - 1)
2
13.7
eV / atom
n2
9. Photoelectric effect: hv = hv 0 + mv 2
10. Orbital angular momentum: l (l + 1)
h
2p
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CHEMICAL BONDING
1. % ionic character
s
s
la
1
2
3. -DH f = H S + Hd + IE + D H EG - E L
4. M.O. theory:
(a) Bond order = 1 ( Nb - N a )
2
(b) Higher the bond order, higher is the bond dissociation energy, greater
is the stability, and shorter is the bond length.
(c )
Species
Bond order
Magnetic properties
H2
1
Diamagnetic
+
H2
0.5
Paramagnetic
Li2
1
Diamagnetic
5. Q = 1 [V + SA - ( q )]
2
6. Former charge = V- L + 1 S
7. VSEPR theory
(a) (LP LP) repulsion > (LP BP) > (BP BP)
(b) For NH3 Bond Angle 106045' because H2O molecule contains 2LP
and 2BP where as NH3has ILP and 3BP.
8. Bond angle:
Decrease in bond angle down the gp is due to LP BP repulsion
(a)NH3> PH3 > AsH3
(b)H2O > H2S > H2Se
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CHEMICAL EQUILIBRIUM
1.
K p = K c( RT )? n g where D ng =n p -n R
2.
(a)
(b)
(C)
s
s
la
Le chatelier's principle
Increase of reactant conc. (Shift forward)
Decrease of reactant conc. (Shift backward)
Increase of pressure (from more moles to less moles)
Decrease of pressure (from less moles to more moles)
For exothermic reaction decrease in temp. (Shift forward)
For endothermic increase in temp. (Shift forward)cTime Total
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ACID BASE
1.(a). Lewis Acid (e- pair acceptor) CO2 , BF3 , Alcl 3 , Zncl 2 , Fecl3 , PCl 3 ,Sicl4 ,SF6 , normal cation
(b). Lewis Base (e- pair donor) NH3 , ROH, ROR, H2 O, RNH2 , R 2 NH,R 3 N, normal anion
2. Dissociation of Weak Acid & Weak Base
(a). Weak Acid K a = Cx 2 / (1-x) or K a = Cx2
(b). Weak Base K b = Cx 2 / (1-x) or K b = Cx2
s
s
la
3. Buffer solution:
(a)
(c )
4.
Necessary condition for showing neutral colour of Indicator pH = pKln or [HIn] = [In- ] or [InOH]=[In + ]
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IONIC EQULIBRIUM
1. Relation between ionisation neutral constant (K i ) & degree of ionisation (a ): Ki =
a2
a 2C
=
(Ostwald's dilution law)
(1-a )V (1-a )
Ki
orV C a
C
2. Common ion effect : By addition of X mole/ L of a common ion, to a weak acid (or weak base)a becomes equal to
Ka
X
s
s
la
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CHEMICAL KINETICS
1. Unit of Rate constant:
K = mol 1- Dn lit Dn -1 sec -1
s
s
la
1
x
K2 =
t a (a - x)
2.303
b( a - x )
log
t ( a - b)
a(b - x )
a0 - at
t
x = kt & t1/ 2 =
a0
2K
5. Arrhenius equation:
- Ea / RT
K = Ae
& slope =
- Ea
2.303RK
whenT , thenk = A (\ e - Ea / RT = 1)
T -T
2
a
2
1
6. log k = 2.303R T T
1
1 2
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OXIDATION-REDUCTION
1. Oxidant itself is -reduced (gives O2)
Or Oxidant e (s) Acceptor
Reductant itself is- oxidised (gives H2)
Or reductant e (s) Donor
2. (i) Strength of acid O.N
(ii) Strength of base 1/ O.N
3. (a) Electro Chemical Series:- Li, K, Sr, Ca, Na, Mg, Al, Mn, Zn, Cr, Fe,
Cd, Co, Ni, Sn, Pb, H2, Cu, I2, Hg, Ag, Br2, Cl2, Pt, Au, F2
s
s
la
4. (a) Formal charge = Group No. [No. of bonds+ No. of non- bonded e-s]
(b)At A node Oxidation, Cathode Reduction
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VOLUMETRIC ANALYSIS
1. Equivalent weight of element = Atomic wt of the element
n factor
s
s
la
6. Molarity (M)=
= N 2 V2
(after dilution)
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MOLE CONCEPT
1.Mole concept
GAM 1gm atom 6.02 1023 atom.
23
volume (L )
22.4
s
s
la
CHEMICAL ENERGETICS
1. First Law: DE= Q + W
Expression for pressure volume work W = -P DV
Maximum work in a reversible expansion:
W = -2.303n RT log
V2
P
= - 2.303nRT log 1
V1
P2
DH = D E + Dn g RT
[Dn g = n p ( g ) - nr ( g ) ]
3.Kirchoff's equation:
DE T2 = D E T1 + DCv (T2 - T1 )[cons tan tV ]
DHT2 = DHT1 + D Cp (T2 - T1 )[cons tan tP]
4. Entropy(s): Measure of disorder or randomness
DS= S p - S R
DS =
qrev
V
P
= 2.303nr log = 2 = 2.303nr log 1
T
V1
P2
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Class
10
s
s
la
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Class
11
ELECTRO CHEMISTRY
1. M = Z. I.t
2. Degree of dissociation: a =
0.0591
[Pr oducts]
nFE 0
log10
& E0 cell =E 0anode +E 0 cathode & Keq = antilog
n
[Re ac tan ts]
0.0591
0
s
s
la
0
cell
D G
-DG0 = 2.303RT log Kc & Wma x = + nFE 0 & DG = DH + T
T p
E cell - 0.2415
0.0591
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Class
12
0
1000 Kb p - p
s
s
la
NUCLEAR CHEMISTRY
1. Radius of the nucleus: R = R 0 A 1/3
2. The amount N of the radioactive substance left after 'n' half lives =
N 0 (initial amount)
2n
0.693
l
4. Rate of disintegration:
dN
2.303
N
= l .N & l =
log10 0 orN = N 0e - lt
dt
t
N
Average life (t AV ) =
5.
tdn
=
N0
1
= 1.44t1/ 2
l
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Class
13
GASEOUS STATE
1. Ideal gas equation: PV = nRT
(i)
R = 0.0821 litre atm. K-1 mole-1
(ii) R = 62.4 liters mm Hg K-1 mole-1
(iii) R = 8.314 * 107 ergs K-1 mole-1
(iv) R =2 cals K-1 mole-1
(v) R =8.314 J K-1 mole-1
2. Velocities related to gaseous state
RMS velocity C =
3 PV
3RT
3P
=
=
M
M
d
s
s
la
pM
1
density of gas
5. Z (compressibility factor)=
PV
; Z = 1for ideal gas
nRT
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Class
14
p
= 0.52
6
bcc =
p 3
= 0.68
8
fcc. =
p 2
=0.74
6
hcp =
p 2
=0.74
6
diamond =
p 3
=0.34
6
s
s
la
3a
4
fcc =
2a
4
4. Relationship between radius of void (r) and the radius of the sphere (R ):
r (tetrahedral) = 0.225 R; r(octahedral) = 0.414 R
5. Paramagnetic : Presence of unpaired electrons [attracted by magnetic
field]
6. Ferromagnetic: Permanent magnetism []
7. Antiferromagnetic: net magnetic moment is zero []
8. Ferrimagnetic: net magnetic moment is there[]
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Class
15
2.
3.
4.
5.
6.
7.
s
s
la
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Class
16
INORGANIC CHEMISTRY
PERIODIC TABLE
1. General electronic configuration (of outer orbits)
s- block
p- block
d-block
f- block
ns1-2
ns2np1-61-10 1-2
(n -1)d ns
(n-2)s2p6d10f1-14 (n-1)s2p6d0 or 1 ns2
s
s
la
C
3.
IP a
1
1
1
1
a
a
a
Metallic character Reducing character Basic Nature of oxide Basic nature of hydroxide
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Class
17
EXTRACTIVE METALLURGY
1. Floatation is a physical method of separating a mineral from the gangue
depending on differences in their wettabilities by a liquid
2. Roasting is the process of heating a mineral in the presence of air.
3. Calcination is the process of heating the ore in the absence of air.
4. Electrolytic reduction: Highly electropositive metals are extracted by the
electrolysis of their oxides and hydroxides.
s
s
la
s- BLOCK ELEMENTS
1. Atomic radii: Li < Na < K < Rb < Cs
2. Ionic radii: Li+ < Na+ < K+ < Rb+ < Cs+
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Class
18
BORON FAMILY
1.
2.
3.
4.
CARBON FAMILY
s
s
la
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Class
19
OXYGEN FAMILY
1. Melting and boiling point of hydrides
H2O > H2Te > H2Se > H2S
2. Volatility of hydrides
H2O > H2Te > H2Se > H2S
3. Thermal stability of hydrides
H2O > H2S > H2Se > H2Te
4. Reducing nature of hydrides
H2S < H2Se < H2Te
5. Covalent character of hydrides
H2O < H2S < H2Se < H2Te
s
s
la
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Class
20
HALOGEN FAMILY
1. Bond energy of halogens: Cl2 > Br2 > F2 > I2
2. Bond length in x2 molecule: F2 > Cl2 > Br2 > I2
3. Solubility of halogen in water: F2 > Cl2 > Br2 > I2
4. Oxidizing power: F2 > Cl2 > Br2 > I2
5. Enthalpy of hydration of X- ion: F- > Cl- >Br- > I-
s
s
la
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Class
21
HALOGEN FAMILY
17. Oxidizing power of oxyacids of chlorine
HCIO < HCIO2 < HCIO3 < HCIO4
18. Thermal stability of oxyacids of chlorine
HCIO < HCIO2 < HCIO3 < HCIO4
19. Stability
of anions of oxyacids of chlorine
CIO- > CIO2- > CIO3- > CIO4-
s
s
la
1. The
element
with
exceptional
configuration
are
24
5
1
29
10
1
Cr [Ar] 3d 4s , Cu [Ar] 3d 4s
Mo4742 [Kr] 4d1055s11, Pd7846 [Kr] 4d1410 5s100 0
Ag [Kr] 4d 5s , Pt [Xe] 4f 5d 6s
Au79 [Xe] 4f145d106s1
COORDINATION COMPOUNDS
1. Coordination number is the number of the nearest atoms or groups in the
coordination sphere.
2. Ligand is a Lewis base donor of electrons that bonds to a central metal
atom in a coordination compound.
3. Paramagnetic substance is one that is attracted to the magnetic field, this
result on account of unpaired electrons present in the atom/molecule/ion.
4. Effective atomic number EAN = (Z Oxidation number) + (2 *
Coordination number)
5. Factors affecting stability of complex
(i) Greater the charge on the central metal ion, greater is the stability.
(ii) Greater the ability of the ligand to donate electron pair (basic strength)
greater is the stability.
(iii) Formation of chelate rings increases the stability.
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Class
22
ORGANIC CHEMISTRY
GOC
1. The order of decreasing electro negativity of hybrid orbital's is sp > sp2 >
sp3
2. Conformational isomers are those isomers which arise due to rotation
around a single bond.
3. A meso compound is optically inactive, even though it has asymmetric
centers (due to internal compensation of rotation of plane polarized light)
s
s
la
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Class
23
ALKANES
1. Pyrolytic cracking is a process in which alkane decomposes to a mixture
of smaller hydrocarbons, when it is heated strongly, in the absence of
oxygen.
2. Combustion is a process in which hydrocarbons from carbon dioxide and
H2O (l) when they are completely burnt in air/O2.
ALKENES
s
s
la
ALKYNES
HALOGEN COMPOUNDS
1. The order of reactivity is
(a)RI > RBr > RCl > RF
(b)Ally halide > Alkyl halide > Vinyl halide
(c) Alkyl halide > Aryl halide
2. SN1 reaction: mainly 30 alkyl halides undergo this reaction and form
racemic mixture. SN1 is favoured by polar solvent and low concentration
of nuclephile.
3. SN2 reaction:Mainly 10 alkyl halides undergo this substitution. SN2 reaction
is preferred by non-polar solvents and high concentration of nucleophile.
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Class
24
ALCOHOLS
1. Alkenes are converted to alcohol in different ways as follows
Reagent
dil H2SO4
B2H6 and H2O2
Oxymercuration demercuration
Types of addition
- Markovnikov
- Anti- Markovnikov
- Markovnikov
2. Oxidation of
10 alcohol aldehyde carboxylic acid
(with same
(with same
no. of C atom)
no. of C atom)
s
s
la
PHENOLS
1.
Phenol
2.
Phenol
CHCl3/OH
Salicyaldehyde
(Reimer- Tieman reaction)
CO2
D
3. Acidity of phenols
(a) Increase by electron withdrawing substituents like
-NO2, -CN, -CHO, -COOH, -X, -NR
3
(b)
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Class
25
ETHERS
Al 2O3
1.
2ROH
2.
RONa + X R'
3.
ROR + 2 H2 SO 4
4.
ROR + H2 O
R - O - R + H2 O
2500 c
ROR' + NaX
(Williamson's synthesis)
D
(conc.)
dil. H2 SO4
2RHSO 4 + H 2O
2ROH
s
s
la
CARBONYL COMPOUNDS
1. Formation of alcohols using RMgX
(a) Formaldehyde + RMgX
Hydrolysis
Hydrolysis
1 0 alcohol
20 alcohol
3 0 alcohol
Hot conc.
Alkali
no a H-atom
Crossed- cannizzaro reaction gives alcohol with aryl group or bigger alkyl
group.
3. Aldol condensation:
Benzoin
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Class
26
CARBOXYLIC ACIDS
1. The rate of esterification decrease when alcohol, acid or both have
branched substitutents.
2. Ortho effect: All ortho substituted benzoic acids (irrespective of type of
substitutent) are stronger than benzoic acid. As this group decrease outer
resonance of ring towards acid which increase acidic nature.
NITROGEN COMPOUNDS
s
s
la
1. Order
of basicity: (R = -CH3 or C2H5)
20 > 10 > 30 > NH3
2. Hofmann degradation
Amides
Br2 /KOH
10 amine
Product
Aniline
Azoxy, Azo and finally hydrazobenzene
Phenyl hydroxyl amine
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Class
27
Type of reactions
Substitution
(Mostly free radical)
Electrophilic addition
(c) Arenes
Electrophilic substitution
Neucleophilic Substitution
s
s
la
Nucleophilic addition
Lucas test
Victormayer's test
Hinsberg test
Fehling's test
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Class
28
IMPORTANT REAGENT
1. D iH2 SO4 [or Cons. H2 SO4 + H2 O
Dehydrating agent (+ HOH)
U se
(a) CH 2
CH 2
(b) C2 H5 OC2 H5
dil. H2 SO4
dil. H2SO4
10 alc
"
ald, 20 alc
OH
-Hx
alc. KOH
-HCl
3. Cu or ZnO / 3000C
CH2
2C2 H5 OH
CH3
CH 2
"
CH 2
s
s
la
ketone, 30 alc
"
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alkene (exception)
Class
C6 H5 NO2
SnCl2 / HCl
6H
29
C6H5NH2
"
Cis - 2 - butene
(main product)
s
s
la
"
Poly prope ne
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Class
30
IDENTIFICATION TESTS
(a) Unsaturated compound (Bayer's reagent) Decolorizing the reagent
(b) Alcohols (Ceric Ammonium nitrate solution) Red coloration.
(c) Phenols (Neutral FeCl3 solution) violet/deep blue coloration.
(d) Aldehydes and ketones (2, 4-D.N.P.) orange Precipitate
(e) Acids (NaHCO3 solution) Brisk effervescence (CO2 is evolved)
s
s
la
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