2 :

  "- 2010 


 
 
 

%&' ()*

- :

:


     :  
:     -1.1

HCOO (aq ) :%  - HO (aq ) : $  - Na + (aq ) :  .,- &   . $/0 2 3 ) H 3O + ( aq )   :&'()
: (9 56  8 .1.2

4
3
ni ( HCO2 H ) = ni ( HO ) = C B .V = 10 2.10 = 2.10 mol
:;,5 &<= * & 
:8 *
HO ( aq ) HCO2

HCO2 H ( aq ) +

( aq )

CH 3OH ( aq )

  "! 

(mol)  
2.10 3
2.10 3 x

2.10 3
2.10 3 x

2.10 3 xm

2.10 3 xm

x -
x =0

x
xm

x
xm

x
x = xm

#  
$($ 

$%& ' 
$%)*  

3
G
{ = 0,72. {x + 2,5.10 :&  & .DE F-(G t &C( /, G &6= A .2.1

(S )

( mol )

G = K . Na + Na + + HO HO + HCOO HCOO

]) :&6= EG K0 *

:( &9N ) ( & t &C( /,     LG K0G 56  8  ,M*

x
n( HO ) 2.10 3 x

HO =
=
V
V
V
+
n( Na ) C B .V
=
= CB
:P,5 3  PRG O *  
Na + =
V
V

x
2.10 3 x
+ HCOO :P0S T, &6 K0G F=N )
G = K . Na + C B + HO
V
V

[HCOO ]= n( HCOO
V
[

: X O. C B =10 mol. m 3 V = 2.10 4 m 3 =E 3  E

2.10 3 x
x

+ 5,46.10 3
G = 0,01. 5,01.10 3 10 + 19,9.10 3
4
2.10
2.10 4

= 0,72 . x + 2,5.10 3

: P.& ) & & 6) HCOO

( aq )

:P,5  /A& 6 Y./G PEG -4.1

&8G/   $() P(G HO ( aq )  5G P,5  /A

HCOO = 5,46.10 3 S .m 2 .mol 1 < HO = 19,9.10 3 S .m 2 .mol 1

:P,5 ); \ t1/ 2 8 -5.1

x(t1/ 2 ) = 10 3 mol :_/) xm = 2.10 3 mol 56  8 K ^ x(t1/ 2 ) =

xm
:P,5 \ ); \ EG K ^
2

G (t1/ 2 ) = 0,72.x(t1/ 2 ) + 2,5.10 3

3
= 0,72 10 3 + 2,5.10 3 : G
{ = 0,72. {x + 2,5.10 :&6= EG  E
(S )
( mol )
= 1,78.10 3 S = 1,78 mS

t1/ 2 12 mn
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:8 =DaNM

mk.1957@hotmail.com

2 :




 
 
 
 - 2010 "
:

*)( '&%

: -

 :*+ # "'

(G -2.1  a ;)E : b
/,^ 0 d; ( (G 3/ E M & &<0  &:
CO2 + a.H + + b.e

CH 3OH + H 2O

F=9M(5 /, $; a = 6 8 H E L  ;(S <M$0 . b = 6

( * -2.2 3 ( /,0 d  A ) T(/0 d   & ) T(/) f0, ) B ( A ;) (2P0S
 <M$0 =; f5 T, (P0S / CH 3OH <0 3  -5 i30 d) E & .(&<0
* -2.3 E & ( &3/ ( /, P60 d :Rj
O2 + 4.H + + 4.e 2 H 2O

* 0 d A  ) 8M k-   ( 0 d B A0 ) 8M k- LRl (

-2.48 O8^ V %  DR 2$  : t =1 h 30 min &/)L
* 8 ( 56 /,=,M , 0 d = ;M L p :
2CH 3OH + 2 H 2O 2 CO2 + 12.H + + 12.e

"!   
  #

  $($

  )(mol

- x
x =0

'ni

ni

x (1h30 min) = x1

x1

x1

ni' 2.x1

ni 2.x1

12.x1

'  &$%

& ) 0 d = &

I .t
I .t
= ) n(e ):_/
* & ) 0 d = & n(e ) = 12.x1 :
12.F
F
* aG& ) % n(CH 3OH ) = n(CH 3OH )t =1h30 min n(CH 3OH )t =0 :

= . x1

^ K 8 :56
n(CH 3OH ) = (ni 2.x1 ) ni
= 2.x1
I .t
)(1
6.F
) m(CH 3OH ) .V (CH 3OH
= ) n(CH 3OH
=
) M (CH 3OH
) M (CH 3OH
=

 OE:

)( 2

); (1) ;.DE):s/  (2
M (CH 3OH ).I .t
6 . .F

V (CH 3OH ) =

32 45.10 3 5400
6^ 0,79 96500

0 ^ O8 %   2$:

mk.1957@hotmail.com

= 0,017 cm 3
V = 0,017 cm 3

www.physique-lycee.c.la

2 :




 
 
 
 - 2010 "
:

*)( '&%

: -

), 

  -1  : U
: 222
G -1.1 K  86 Rn
* , =G , * P = Z = 86 : G/ N = A Z = 222 86 = 136 :
238
92

: 222
 ^ -1.2 &.u / M 86 Rn
2
El = [ Zm p + ( A Z )mn m( 222
86 Rn)].c

= [86 1,0073 + 136 1,0087 221,9703].u.c 2

) = 1,8407 .u.c 2 ( u.c 2 = 931,5 MeV
= 1,8407 931,5 MeV
= 1714,6 MeV

, (G -1.3 5 ;, &8G/ (:

238
222
4
0
* )E & ( /:
92 U 86 Rn + x.2 He + y.1 e
* 6 . F=9G:

x = 4
16 = 4.x
238 = 222 + 4.x + 0 y

6 = 2.x y y = 2
92 = 86 + 2.x + (1). y

, 5  ) $ (  4, 5 ) =E 0 (  .2

-2!      :
m0 (G -2.1&    3  /, ;0 (: t0 &C
ln 2
m
= ); i3 .DE  :s/
 OE a0 = .N 0 (1) : ) N 0 = N A . 0 (2 )(3
t1/ 2
M
M .a0 .t1/ 2
= m0
ln(2).N A

222 5.103 3,9 86400

ln(2) 6,02.10 23

= 8,96.10 13 g
 ^ -2,2 ,  t1 D)& &. |=G 0 S/ ,Ezd PR   G ;0 a1 = 300 Bq / m 3
a
a
.t
.t
.t
^ . K S/ a (t1 ) = a1 = a0 .e 1 ,Ezd) e 1 = 1 :_/e 1 = 0 :
a1
a0
a
5000
) ln ( 0
)
( ln
a1
300
t1 = t1/ 2
= 3,9
ENM  & } O =/= 15,8 j :8
)l n ( 2
)l n ( 2

-./
 #0 1+2" 3'4 :( ".# +"/"  #
-1.1 &=G ON  K  P%G k) =8 ;) P  uC ;G : u R
-1.2 &5$ M ON 3M3  &/E u R G
mk.1957@hotmail.com

www.physique-lycee.c.la

 2 :

  "- 2010 


 
 
 

%&' ()*

- :

: q(t ) &/(S  $--(G  ~& 5  & E = A -1.3

u R + uC = E :G  ~& . u R = R.

dq
dq
: i = u R = R.i P=- ) D96l )  P6  . dt
dt
q
.P=- ) D96l\  %0 &= / M uC =
:&.DE  / C0
dq
dq q
RC0 . + q = EC0 : R. +
=E
:&~5  & E K0G
dt
dt C0

: A ;M% ); P= EG (G .2.1

dq d
= [ A.(1 e .t )] = . A.e .t :   M q (t ) = A.(1 e .t ) :P( K0
dt dt
.t
A.e
(RC0 . 1) + ( A EC0 ) = 0 : RC0 . . A.e .t + A.(1 e .t ) = EC0 :&~5  & E K0G

:s/ / ( RC0 . 1 = 0 ) ( A EC0 = 0 )

:a=/   M t ;0 $) R & E F-(G

A = EC0

q (t ) = EC0 .(1 e .t / RC 0 )
i (t ) =

1
RC0

:  P0S T, <$/ P( K0

:    z =EG -1.5

dq (t )
E .t / RC 0
d
&.DE  ); .D9
.e
:=E s/ / i (t ) = EC0 .(1 e .t / RC 0 ) :K0 i (t ) =
dt
R
dt
E
. = R.C0 8 i (t ) = . e .t / =E k) &-M9 M
R
[u ] [q ] = [q ] = T
( q = i . t ) ) [ ] = [R C ] = [R ] [C ] =
: &M%  EM -1.6
[i ] [u ] [i ]

.;)L  EM &M% s/ 

: i = f (t )  =,M C0 &E R &)- ( G -1.7
3
i (0) = 2 mA = 2.10 A ( 2)  t = 0 &C(  /,  z = 13 ms = 13.10 3 s (1) :8 * ); =
i ( 0) =
R=
C0 =

E
( 2' ) = R.C0 (1' )
R

:/ *

9
E
=
= 4500 : s/  (2)( 2) ;) i (0) 2.10 3

13.10 3
= 2,89.10 6 F : s/  (1)( 1) ;) 4500

:AM $50 #6 * :*+ 

( Da \ z=& ) -   zd; G & : Y &= * -2.1
( & E |  z) ) G =&  3^ : Z &=* 
.&<M$0 )&  -) K= M M3M3  R P( .2.2
: f = 540 kHz & ,d& 9(  - ; ); 0G X &= .3.2
f=

www.physique-lycee.c.la

1
2. . L.C

: & - X &= OE *

mk.1957@hotmail.com

 2 :

  "- 2010 


 
 
 

%&' ()*

- :

: ( LC1 ) -l F 3 f1 K ( *

f1 =

1
2. . L.C1

1
3

2. . 5,3.10 13,1.10

12

= 6,04.105 Hz = 604 kHz

: ( LC2 ) -l F 3 f 2 K ( *

f2 =

1
1
=
= 3,02.105 Hz = 302 kHz
3
12
2. . L.C2 2. . 5,3.10 52,4.10

- ; ); 0G X &=    M [302 kHz ; 604 kHz ]  8) T  / f = 540 kHz ^ D *
. f = 540 kHz & ,d& 9(

01
;G/ %  - F=9G :AB # )(' #%! #& -1
1 ( A, i1 , j1 ) OE     A( ^G -1.1
{ ( S ) O 8 } :&N& ,8 *
:&,8 i3 T, &-=9  - * 
R = R n ^ R - M - P< | 9  AG - P - M -  $ : 1 ( A, i1 , j1 ) OE ;  G/ %  - F=9G *
F = m.a G P + R n = m.a G

Px + Rx = m.a x mg sin( ) + 0 = m.a x : Ax1 (T, -Nd*

ax =

ay =

dv y
dt

dvx
= g sin( )
dt
= 9,8 sin( 20) = 2,35 m.s 2

:_/)

= 0 :  Ay1 (T, OG l ( S ) O 8  . L )G & ^M *

: B &9-/  G &,N vB (G -1.2

vx (t ) = g sin( ).t + (v x ) 0 :8 P)0 Fu ;, a x =

dvx
= g sin( ) / dt

dx
= v x (t ) = g sin( ).t :K0 (v x ) 0 = 0 &<=  S K ^
dt
1
x (t ) = g sin( ).t 2 + x0 : 8 &A )P)0 Fu ;, 2
1
RM K0/ x (t ) = g sin( ).t 2 :K0 x0 = 0 &<=  S K ^
2

v = g sin( ).t (1) RM K0/

1
x = g sin( ).t 2 ( 2)
2

v=
vB =

2.x.g . sin( )

:  = E s/  (2)( 1) ;M t a  -

:_/) xB = AB  B &9-/ ( ); S ) O 8 )  /, -

2. AB.g . sin( )

= 2 2,4 9,8 sin( 20)

4 m.s 1

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mk.1957@hotmail.com

 2 :

  "- 2010 


 
 
 

%&' ()*

- :

(S ) O 8 T, (AB ) |9  $-=9   -  z R (G -1.3

Py + R y = m.a y mg cos( ) + R = 0 : Ay1 (T, P + R n = m.a G &$8 & .DE  -NM

_/)

R = mg cos( ) = 70 9,8 cos(20) = 645 N

t f1 vC

: -. G #%, #& -2

m & lM t $G &C( /, vx =EG 8 -2.1

{ (S ) O 8 } :&N& ,8 *
:&,8 i3 T, &-=9  - * 
f1 = f1 .i ^ f1 - M - & ,/96l  AG - P = m.g . j - M -  $ F = m.a G P + f1 = m.a G
: (O, i , j ) OE ;  G/ %  - F=9G *
dv x
dv f
x=
= Cte
: OX - ( T, -Nd*
dt
dt
m
f
&<=  S K ^ vx =
.t + (vx ) 0
: 8 P)0 Fu ;,*
m

Px + f1 x = m.a x 0 f1 = m.a x = m.
v x (t ) =

f
.t + vC
m

: (v x ) 0 = vC

: f1 -  z f1 ^ -2.2
m.vC 70 4,67
f
.t D + vC = 0 f =
= 380 N
=
m
tD
0,86

: vx (t D ) = 0 &.DE F-(G D &9-/  /,

:| 9N ;, C &9-/ h 5Gl( G

Py + f1 y = m.a y m.g + 0 = m.

dv y
dt

dv y
dt

= g = Cte :T, _ ( OY - ( T, -Nd*

dy
= v y (t ) = g .t
: (v y ) 0 = 0 &<=  S K ^ v y = g.t + (v y ) 0 : 8 P)0 Fu ;, *
dt
1
1
y (t ) = g .t 2 + h : y0 = h &<=  S K ^ y (t ) = g .t 2 + y0 : 8 &A )P)0 Fu ;,*
2
2
:_/) y(t D ) = 0 F-( D &9-/ ); G  )/, *
1
1
2
2
0 = g .t D + h h = g .t D = 0,5 9,8 0,86 2 3,62 m
2
2
:34 -. G #0 1( #&% #%! #& -3

dv
2.v 2 + 0,7 = 0
dt

:&  ~& 5  & E ); F-( -3.1

{ (S ) O 8 } :&N& ,8 *
:&,8 i3 T, &-=9  - * 
P = m.g . j - M -  $ -

f = 140.v 2 . j ^ f - M - k<  0^l . AG FA = 637. j ^ FA - M -  R& E AG F = m.a G P + f + FA = m.a G
Py + f y + FAy = m.a y m.g + f + FA = m.

www.physique-lycee.c.la

: (O, i , j ) OE ;  G/ %  - F=9G *

dv y
dt

:T, _ ( OY N ( T, -Nd*

mk.1957@hotmail.com

 2 :

  "- 2010 


 
 
 

- :

%&' ()*

dv y
dv 140 2 637
f
F
dv
.v
2.v 2 + 0,7 = 0 :

+ 9,8 = 0 _/)
A + g = 0
dt
dt
70
70
dt
m m
: vl &( & , & . 8 -3.2
dv y

t = 0 |= )/, O< C/ & (&  - G &,N 3RG *

dt

dv y
2
2.(v y ) 2 + 0,7 = 0 :&-M ~& 5  & E DaNM *
2.(v y ) + 0,7 = 0 :
dt

(v y ) =

0,7
= 0,35 :  M
2
: &( & , s/  *

0,35 = 0,59 m.s 1 _/) (v y ) =

2

vl = (v y ) = 0,59 m.s 1 = 0,59 m.s 1

: vi+2 ai +1 ;- ( G -3.3

a=

dv
= 2.v 2 0,7
:&~5  & E DaNM ai +1 (G dt
ai +1 = 2.vi2+1 0,7 = 2 (1,80) 2 0,7 = 5,78 m.s 2

vi + 2 = vi +1 + ai +1 t

: & -u ENM vi+2 (G -

vi + 2 = (1,80) + 5,78 (0,195 0,18) = 1,71 m.s 1

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