Why does a nicely polished black shoe shine? First , lets understand the difference between the glossy polished surface and the dull one. It is a misconception that the polished surface is smooth and the dull one is irregular . Both are irregular , as there are no perfectly smooth surfaces. Examined under a microscope polished surfaces would be like razor blades. There are irregularities , depressions and scratches on any surface , both dull and polished. What matters is the size of these irregularities. If they are smaller than the wavelength of the incident light , then the rays are reflected correctly , at the angle of incidence. Such a surface gives mirror reflections , it shines and we call it polished . If on the other hand , the irregularities are larger than the wavelength of the incident light , the surface scatters the ray randomly and does not follow the reflection law. Such scattered light gives no mirror reflection and we call it dull . Thus a surface may be polished for some rays and dull for others .
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Unblackened surface of leather has a highly irregular
microstructure with peaks larger than the mean wavelength of visible light. By blackening it we smooth out the surface and lay the hairs that stick out down . Brushing removes any excess polish at projections and fills the troughs , reducing the irregularities down to a size which is comparable with the mean wavelength of visible light , and the surface becomes glossy .