CH 431 Summer 2010 Exam 1 Name: EID: 1. (20 points) Give the point groups of the following molecules: arth = O3y OBR D3) bysoch = C ON: ysoch Cs DN) nig TA 2s 2. (20 points) Give examples of real molecules/compounds with the following point groups: a Aviewé Boye ac ©) Das ip b EC Ue. dD. - Das Erie DDw fA bry] Coy CO 3. (20 points) (a) Give the symmetry species (Mulliken symbols) for the translations and rotations in the following molecules. (b) Give the total number of normal modes of vibration for these molecules. 2 TL TR ET ff ernad med, 230-6 5 MEO ’ )cHh TA i Cia ee ee . =F 4 ii) Clk Gy J> =A, 6,8 3 274 iv)SFe OW fT =T, , Bo-G5%I-C = 1S 4. (40 points) Use the character table for C2) to find the reducible representation (Ty ) and the symmetry species for the translations I'r, rotations Pg and vibrations yp of trans-dichloroethylene . State whether the vibrations are IR or Raman active (polarized or depolarized) and which bands are coincident (if any). a H DocT H sel EXT (AEeye Aft ug) =i & Ag. | Amn actwe 3. f Fo PoeneneD Ng =3 fee + renee =o wash Che 5 goers ; ne 5 mao Bod x g quan eed ge e278 Waves AE Co NCAT, ee aft ie +16} = OMe B. Vay = BS Cy 38 3 An 6 He Bu Tia = SAgtby t2An + 46q (12 vttarions (ets) Se gk Acie = & Baws , 2AL + 4B Jomo = b Bwos, Ag + By