303.732.4; 004.

942
.. 1, .. 2, .. 3

R. Kulishenko, A. Isachenkov, V. Kholodnov

OPTIMAL OPERATIVE
CONTROL OF THE PROCESS
OF AMMONIA SYNTHESIS
UNDER PARAMETRIC
UNCERTAINTY

St. Petersburg State Institute of Technology (Technical University) Moskovskii pr. 26, St Petersburg, 190013, Russia
e-mail: admin@sa.lti-gti.ru

-
( ), 190013, , ., 26,
e-mail: admin@sa.lti-gti.ru

The article deals with simulation, system analysis and steadystate optimal control of an ammonia synthesis process system under parametric uncertainty. Kellogg process of ammonia synthesis loop with four-bed axial-flow quench converter
is the subject of our study. For the object simulation Aspen
Plus software is used. To describe the ammonia synthesis
process promoted by iron catalysts plug-in module developed
by the authors is applied. The problem of optimal operative
control based on the techno-economic criteria denoting current notional profit is solved. The set of uncertain parameters
is limited on the basis of the sensitivity analysis results. In
this study the interval and probabilistic parameter uncertainty
forms are considered.

,

- ()
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Kellogg .
Aspen Plus. .
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.
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Keywords: chemical-engineering system, ammonia synthesis, parametric uncertainty, Aspen Plus, Kellogg process

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, , e-mail: admin@sa.lti-gti.ru
Kulishenko Roman Yu., assistant lecturer of systems analysis department, e-mail: admin@sa.lti-gti.ru
, , e-mail: alex.isachenkov@yandex.ru
Isachenkov Alexander A., post-graduate student of technology of catalysis department, e-mail: alex.isachenkov@yandex.ru
3
, - . , , e-mail: holodnow@yandex.ru
Kholodnov Vladislav V., Dr.Sci (Eng), Professor of systems analysis department, e-mail: holodnow@yandex.ru
2

27 2014
Received August 27, 2014

86

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() 26 2014

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(123-C)

(124-C, 180-C)

(117-C, 125-C)

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105-D2, 105-D3, 105-D4)

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1. ..
// 2013. 5/2(13). . 4-7.
2. .., .., .., .. / . .. . : , 1982. 296 .
3. Grossmann I.E., Floudas C.A. Active constraints
strategy for flexibility analysis in chemical processes. // Comp.
Chem. Eng. 1987. V. 11. 6 P. 675-693.
4. .. ..
: :
. . : . , 2008. 319 .
5. .. [ .]. : : - / . . ..
. : , 2001. 497 .
6. Jennings J.R. Catalytic Ammonia Synthesis: Fundamentals and Practice Fundamental and Applied Catalysis. Language of
Science. Springer Science & Business Media, 1991. 451 p.
7. Froment G. H., Bischoff K.B. Chemical Reactor
Analysis and Design: 2nd Edition. New York: John Wiley & Sons,
1990.
8. .., ..,
.. - - // ().
2011. 10. . 61-70.

91