Phu luc 5:

Tinh toan khng am bao o

anh gia cac yu t anh hng n KB.
1. Cng thc tinh kt qua.
M SO 2
(m2m1 )
M BaSO 4
0.1374(m2m1 )
S=
100=
100(g/100 g)
m
m

Trong o:
m: khi lng mu ban u ( g )
m1: khi lng chen nung ( g )
m2: khi lng chen va kt tua BaSO4 sau nung ( g )
0.1374: h s chuyn i t BaSO4 sang S.
2. Cac yu t anh hng.
Theo phng phap cua GUM ta tinh khng am bao o theo cac yu t
anh hng trn cng thc tinh kt qua. Cac yu t anh hng c xet trn s
nguyn nhn h qua:
KL chen sau
nung (m2)

KL chen (m1)

KL mu (m)
Hi u chun cn

sach (550oC)
Hi u chun cn

Hi u sut nung
Hi u chun cn

Sulfur

Ham lng SO42Con

ngi

ng
nht mu

Ham lng PO43-

MgNO3

thu hi

l p lai

2.1. Tinh toan KB

Cng thc tinh KB tng hp:
u2c ( y )=

Trong o:

2
f
. ( u ( x i ) ) = u2i
Xi

( )

uc ( y ) : KB tng hp,
2

(u ( x i ) ) : KB thanh phn,
f
Xi

( )

: H s phn b xac sut.

2.1.1. KB t cn mu.
Khi lng mu bi anh hng bi KB cua cn( phn b xac sut theo
hinh ch nh t). Do khi lng chen cn, chen cn va mu trong khoang 30 - 50g
nn chon KB trong dai 30 - 50 g cua chng nh n hi u chun.
u21=

2
f 2
1 2
2
. (u ( x 1 ) ) =
. ( u cn )
X1
3

( )

( )

2.1.2. KB t cn chen cn.

Khi lng mu anh hng bi KB cua cn (phn b ch nh t),
sach cua chen cn (phn b chun). Do khi lng chen cn va kt tua sau loc
trong khoang 10 - 30g nn chon KB trong dai 10 - 30 g cua chng nh n
hi u chun. sach cua chen cn c thc hi n bng cach cn chen cn a
c lam sach va nung 550oC, sau o thc hi n nung lai 550oC va cn lai, anh
gia sach qua l p lai cua 2 ln cn, chon l ch chun l p lai ln nht
tinh KB.
u22 +u23=

2
2
f 2
f 2
1 2
2
1 2
2
. (u ( x 2 ) ) +
. ( u ( x3 ) ) =
. ( ucn ) +
. ( RSD chen )
X2
X3
1,96
3

( )

( )

( )

( )

2.1.3. KB t cn chen cn sau nung kt tua.

Khi lng mu anh hng bi KB cua cn (phn b ch nh t),
tro hoa hoan toan cua lo nung (phn b chun). tro hoa hoan toan cua lo nung
c thc hi n bng cach cn chen va tro sau khi nung 550oC, sau o thc hi n
nung chen va tro lai 550 oC va cn lai, anh gia sach qua l p lai cua 2 ln
cn.

2
2
f
f
1
2
1
2
.( u( x4 )) +
. (u ( x5 ) ) =
. ( u cn ) +
. ( RSD nung )
X4
X5
1,96
3

( )

u24 +u 25=

( )

( )

( )

2.1.4. KB t ion PO43- va SO42- co trong MgNO3.

anh gia c cac yu t anh hng t hoa cht, theo chng chi cung cp
kem hoa cht MgNO3 cha cac ion nay, chung phan ng tao thanh kt tua vi
BaCl2 anh hng n kt qua phn tich, do o cn xac inh KB gy ra bi
cac yu t nay. Phn b xac sut cho yu t nay la phn b chun.
2
2
f 2
f 2
1 2
2
1 2
2
.( u ( x6 )) +
. (u ( x 7 ) ) =
. ( uPO 4 ) +
. ( uSO 4 )
X6
X7
1,96
1,96

( )

u26 +u27 =

( )

( )

( )

2.1.5. KB t tai lp.

KB t tai l p va thu hi se anh gia c cac yu t anh

hng t con ngi ( ng nht mu, thao tac thi nghi m), thit bi (lo nung),
mi trng
u28=

2
f
1
2
. ( u ( x8 ) ) =
. ( RSD S R )
X8
1,96

( )

( )

2.1.6. KB t thu hi.

u29=

2
f
1
2
.( u ( x9 )) =
. ( 100R )
X9
1,96

( )

( )

Do PTN cha tm c mu chun nn cha nh gi c thu hi, PTN

s b sung s liu nh gi thu hi khi co mu chun hc thm chun.
2.1.7. KB tng hp.

u=

i=1

u 2i

2.1.8. KB m r ng.
Chon h s phu k=2 vi tin c y 95%, KB cua PTN:
U=k.u=2.u