Phng php phn tch ph nguyn t

(AAS)
Ngi thc hin: V Th Duyn

Ni dung
1. S xut hin ph AAS
2. Nguyn tc, trang b ca php o
3. K thut nguyn t ha mu

1. S xut hin ph AAS

(photon)

hp th

pht x

(photon)

2. Nguyn tc, trang b ca php o

Nguyn tc:
Ha hi v nguyn t ha mu => to mi
trng hp th bc x.
Chiu chm tia (c bc sng c
trng) vo m hi NT t do => sinh ph
AAS
Thu ph, phn gii, A

 Trang b:

1: Ngun pht tia bc x n sc

2: H thng ha hi v nguyn t ha mu
3: H thng n sc v detector
4: B phn ghi kt qu o

Ngun cp chm tia n sc

Nhim v: cung cp chm tia n sc ca
nguyn t pt.
Yu cu:
Cng ln, nhy, n nh
Thay i c, lp li tt
Thun khit, khng cho ph ph
Bn theo thi gian

=> Cc n p ng c: HCL, EDL..

u, nhc im
u im:
nhy, chn lc cao (10-4 10-5%)
Khng cn lm giu trc khi pt, tn t mu, pt
nhanh chng, trnh nhim bn mu khi x l
ng tc n gin

Nhc im:
H thng my t tin
Yu cu dng c, ha cht c tinh khit
cao

3. K thut nguyn t ha mu
Nhim v: to mi trng hp th tia bc x
Yu cu:
Nng lng ln ha hi v nguyn t ha
mu
n nh, iu chnh c, lp li tt
Bn, thun khit, khng cho ph ph
Tn t mu

=> C 2 k thut: nguyn t ha ngn la (F-AAS)

v nguyn t ha khng ngn la (GF-AAS)

K thut NTH ngn la

Dng nng lng nhit ca ngn la n kh
NTH mu
t bi hn hp kh (1 kh oxi ha v 1 kh
chy)
Loi kh

T l kh

Nhit (C)

K.K

Propan

6/1.4

2200

K.K

Axetylen

4.2/1.2

2450

K.K

Hydro

4/3

2050

Oxy

Axetylen

1/1

3000

N2O

axetylen

2/1.8

2900

 Cu to ngn la:
Phn ti: nhit 500
1000 oC
Vng trung tm: nhit
cao, khng mu hay
xanh nht
Phn ui v v: nhit
thp, mu vng hay
xm

Cc qu trnh xy ra trong ngn la

Hn hp sol kh c dn vo ming n NTH
Dung mi bay hi -> cc ht mu mn
Bt mu c nung nng => cc qu trnh nhit
ha, ha l xy ra:
Qu trnh chnh: sinh ph AAS
Qu trnh ph: khng sinh ph

i tng v phm vi ng dng

Hu ht cc kim loi v mt s kim nng c ppm (k thut FAAS) v c ppb (k thut ETA-AAS) vi sai s khng ln hn 15%
Xc nh cc kim loi trong cc mu qung, t, ,nc,mu y
hc, sinh hc,sn phm vi lng trong phn bn v thc n gia
sc
Phn tch phi kim t dng do hn ch v trang thit b v
nhy (to vng t ngoi xa)

Cc yu t nh hng
Cc yu t v ph:
S hp th nn
S chen ln cc vch ph
S hp th ca cc ht rn

Cc yu t vt l

nht, sc cng b mt dd mu
Hiu ng lu li
S ion ha cht phn tch
S pht x ca cc nguyn t phn tch

Cc yu t nh hng
Yu t ha hc
Nng v loi acid

Yu t ha hc
nh hng ca cc cation
nh hng ca anion l trong mu

nh hng nn mu
nh hng ca dung mi hu c