Professional Documents
Culture Documents
PURE
project on urban
reduction of eutrophication
:
2012: (Project on Urban Reduction of
Eutrophication, PURE) , Vanha Suurtori 7, 20500 Turku,
Finland (); www.purebalticsea.eu
311 2 Pyry Finland Oy
PURE
.
: - , Entsorgungsbetriebe Lbeck; , ; , ; , .
: shutterstock.com/DmitriMaruta. .
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: 125
ISBN 978-952-5725-93-3 (.), 978-952-5725-94-0 (PDF)
2012 .
1. ............................................................................................................................................ 4
1.1
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1.2 .......5
2. ........................................................................................................................................................ 9
2.1 : .....................................................................................................................10
2.2 ................................11
2.3 ..........................................................................................14
2.4 :
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2.5 : PURE ........................17
3. .......................................................................................................................... 18
3.1 ...................................................................................................................................................................................19
3.2 .....................................................................................................................................20
3.3 .........................................................................................................................................22
3.4 : PURE ..........................25
3.5 : ......................................................................................................26
4. OC................................................................................................................... 28
4.1 .............................................................................................................................29
4.2 .................................................................................................................................................30
4.3 ...................................................................................................................33
4.4 : .............................................................................................................................34
4.5 .................................................................................................................................34
4.6 ........................................................................................................................................................35
4.7 ........................................................................................................................................................37
4.8 : PURE .....................38
5. ............................................................................................................... 39
5.1 ...................................................................................................................................................................................40
5.2 .............................................................................................................................................................................42
5.3 -.................................................................................................................................................44
5.4 -....................................................................................................................................................46
5.5 ........................................................................................................................................................47
5.6 :
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5.7 : ................................................................................................50
6. ......................................................................................................... 52
6.1 ...................................................................................................................................................................................53
6.2 .........................................................................................................................................................54
6.3 ..........................................................................................................................................................55
6.4 ....................................................................................................................................................59
6.5 :
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6.6 :
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6.7 : ................................................................................................................64
7. .......................................................................................................................................... 66
7.1 ...................................................................................................................................................................................67
7.2 .......................................................................................................................68
7.3 : PURE ...................70
7.4 : .................................................................................................................72
8. C ................................................................................................................................ 73
8.1 ...................................................................................................................................................................................74
8.2 .....................................................74
8.3 ......................................................................................................................................................76
8.4 : ........................................................................................................................78
9. ........................... 79
9.1 ...................................................................................................................................................................................80
9.2 .......................................................................................81
9.3 .............................................................................................................82
9.4 , .......................................................................................83
9.5 : ..................................................................................................................................83
10. ................................................................................................................ 84
10.1 .................................................................................................................................................................................85
10.2 ........................................................................................85
10.3 .............................................................................................................................87
10.4 : ...............................................................................................89
11. ..................................................................................... 90
11.1 .................................................................................................................................................................................91
11.2 ...........................................................................93
11.3 ..........................................................................................................................................95
11.4 : ...............................................................................................95
12.
.............................................................................................................................. 96
12.1 ...............................97
12.2
.........................................................................................................................................................................102
12.3 ....................................................................................................................................................................................111
13.
......................... 113
13.1
..................................................................................................................................................................114
13.2 ................................................................................115
13.3 .........................................................................................................................................116
13.4 - ................................118
13.5 .................................................................................119
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14
SLUDGE
DISPOSAL
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-
.
150 000350 000
. , ,
1520 ,
.
2050 ,
(
2030 / ). ,
, 412 . , ,
,
.
-
- -.
23% ,
.
. -
. ,
, ,
.
. 5-7: - (). :
Entsorgungsbetriebe Lbeck
5.5
,
,
() .
. ,
, (, ).
.
,
. : ,
47
, . 70 120 ,
.
.
. 25%
40%.
130 500 .
, , 24 , 710 36
, .
(Bucher Unipektin AG, 2011 .).
/
, ,
, .
2 10% .
, - ,
.
KEMICOND
50% (. 6.3). , KEMICOND
,
.
, ,
, ,
, . 24 /7
() (8 16 5 ).
. -
, .
, ,
180 000400 000 . ,
, 1520 ,
.
2050
,
(2030
/ ).
.
512 .
, ,
.
. 5-8: . :
Bucher Unipektin AG,
48
5.6 :
PURE , PIU
Jrmalas dens,
()
37 500 . 1000 ( )
.
. PURE
, , .
.
, .
,
47%.
3,5 / .
,
( 18%).
5,4 /
. .
,
. 5-9: ,
. : PIU Jrmalas dens
.
, , , ,
, .
. 5-10: .
: PIU Jrmalas dens
49
5.7 :
, , .
, , ,
.
.
,
. .
(, , ..),
.
.
. 5-2. ,
PURE, . 5-1.
5-1:
PURE. BioP =
50
BioP
PURE
22 %
8 /
19 %
8 /
18 %
5.4 /
19.7 %
11.4 /
20 %
8-12 /
19 %
5.3 /
, ZKW
37 %
500 /
()
. 5-2:
2035% 1
1824%
1522%
1824%
2835%
2230%
2028%
2230%
3040%
414 /
412 /
512 /
1525
/
512 /
, ,
(
)
,
,
(
)
, ()
, ()
-
()
,
()
()
, ,
()
,
()
( )
, -
()
()
,
()
()
51
6.
: HSY Water
6.1
()
, . , ,
. (),
( ) (SNV, 2003 .,
Umweltbundesamt 2009 ., WHO, 2003 .).
:
5570C
;
12 -
.
SLUDGE TYPE
,
.
.
6-1.
HYGIENISATION
METHOD
Thickened, possibly
aerobically stabilized
sludge
24% DS
Dewatered sludge
(possibly stabilized
aerobically or
an-aerobically)
20 40% DS
Thermal treatment
- pasteurisation
- other treatment
FINAL PRODUCT
Soil conditioner
or fertiliser
Chemical treatment
- lime stabilisation
- other treatment
Covering material
and landscaping
Biological treatment
- windrow composting
- tunnel composting
. 6-1:
53
6.2
, .
( ),
- .
,
:
() ;
;
;
;
;
.
6.2.1
, 1860- .
.
:
65C100C.
65C 30 , 70C
25 , 80C 10 .
( ) .
.
, . -
. ,
. ,
: ,
. 11,9
/ ( ) (UBA, 2009 .).
(UBA, 2009 .).
54
6.2.2
-
,
-
-
.
, -
-
.
.
(. 7)
, -
.
180C
.
(c ),
.
.
, -
, -
. -
-
(. 8).
4. -
. ,
-
, , -
, -
.
. 6-3: : shutterstock.com/Peter Gudella
-
.
,
,
, 6.4.
6.3
(CaO Ca(OH)2) 12 . 12 2 .
, , pH, .
(Ca(OH)2)
.
(. 5.4). (CaO),
, .
. , 5,
,
.
,
.
, , ,
, , 34 ,
510 36 , .
.
55
.
,
.
:
-
, ,
;
, -
;
;
,
.
, .
-
;
300400
.
. 6.3.4.
6.3.1
(2
4%), ,
(510% Ca(OH)2), .
, ,
. Ca(OH)2 ,
. -
, .
, ( / ),
.
6.3.2
-
(. 5.4). .
,
.
-,
.
,
;
-
;
-
;
-
, -
;
56
6.3.3
, , (2040%, .. ).
1520 . 12 .
CaO ,
, 60C , , .
,
(. 5). ,
, .
, ,
.
.
, , 1520 . ,
300400 CaO/ .
2 >12.
-.
2040 / .
1020 , 715 -/ ,
.
.
- (. 5.4).
, ,
200 000-400 000
. Iisalmi Water, , Savonlinna Water.
().
, .
6.3.4
, .
, .
.
.
, ( (Fe3(PO4)2)
(II) (FeO)) .
(H2O2), Fe2+
Fe3+, (III) (FePO4).
Kemicond. Kemicond ,
.
4 (H2SO4).
,
Kemicond. (NaOH)
.
57
,
, .
(
, Kemicond).
, , . ,
.
46 , 810 46
. ,
.
( ) , 220 H2SO4
27 H2O2
.
.
, ,
400 000700 000
.
. ,
, 1520 .
, -.
220 H2SO4/ , 27 H2O2/ .
5060 /
. 1525 , 1020 / ,
Kemicond.
.
Kemicond
50%
;
Kemicond -
38%45% (Brendler, 2006 .).
,
-.
.
.
,
. ,
, .
. 6-5: : ,
,
, ()
(
).
58
6.4
6.4.1
().
(60C 36 ) ,
. , .
:
, , -
;
,
,
. ,
.
.
.
, -
.
15%.
(. 3 5).
,
(), . (, ) -
6.4.2
, ,
,
,
. ,
- ,
, . .
, .
(, ()) . ,
, , 4050%
.
.
,
,
- .
, ,
,
.
, ,
, ,
. , . 1930- .,
1970- .
1990- .
: 50100 150200 ,
.
,
.
59
, ,
500 0003 000 000 , , .
.
, ,
1015 .
, (, ). ,
, ,
- .
,
, .
. ,
, 10 /
.
, .
( )
.
. 6-6: () - ().
: HSY Water O Jrve Biopuhastus
.
1 , , (),
, , - (), (), ()
.., , , , . .
60
6.4.3
, ,
, , , .
, . 46 , 6 2040
;
, , 2025 , 6
2040 .
5060 80100 .
.
(
500 0001 000 000 ),
.
1015 .
:
-
;
,
-
.
-
. ,
,
,
;
.
-
, -
,
, ,
, .
,
.
, ,
1,55
,
. ,
,
,
,
. , , 1520 .
75
120
.
, 100 200 / .
.
. , .
,
- .
, ( ) , , , . . ,
, , , , , ( ), , , .
.
61
6.5 :
PURE -, O
Jrve Biopuhastus, -
. - () 200 000 .
2700 (
).
.
- ,
.
6%.
4 / .
,
2024 55C.
22%. 8 /
.
.
.
.
, -
62
. 6-7: -. : O Jrve
Biopuhastus
-,
.
, , ,
.
, .
6.6 :
PURE , HSY
Water,
100
3 ( 1,1 ),
() (),
HSY Water. HSY Water PURE.
65 000 , 25 000 .
2,8 , 2,1 .
3,6% 1,3% . .
7,5 /. ,
,
4,1% (2011 .).
, : .
.
.
17 37 13
35,5 .
2,3% 2,7% .
( ). 29%.
4,5 /
6,1 / .
, . 69
. ,
. -
.
. ,
, (
).
HSY . , ,
.
. 2011 .
12,3 . 3 3,5
3 . , , 27 500 /, 4100 / ,
99% .
9 560 / ,
97% .
25 000 / (60% ), 4 500 / (35%
).
2011 .
.
2012 . , ,
, .
. 6-9.
, . : HSY Water
63
6.7 :
, .
. -
.
. 6-1.
PURE . 6-2.
. 6-1: . (, ,
, ), ( UBA, 2009 .).
(. 7)
( )
( )
. , . , , , .
, , , , , . , ,
. PURE
- () ().
64
. 6-2:
65
7.
. : metshallitus
7.1
,
. .
, .
, . , ,
2030%, 5090%.
, .
. , -
PRETREATMENT
,
, (,
) . . 7-1.
THERMAL DRYING
FINAL PRODUCT
Odorous gas to be
treated or to biofilter
Mechnical
sludge
dewatering
Thermal
drying
Optional:
pelletizing/
granulation
Final product
processing, e.g.
incineration
.
(). ,
(, ), .
. (
), .
(, , )
, (, , , , ), . , ,
, .
, , .. , .
, .
67
7.2
.
, ,
.
( ) ( ).
.
(2030% )
() ,
.
.
. ,
.
, 450460C ( ) 120160C ( )
510 ( ) 4060
( ).
,
. , ,
.
. . ,
,
(Burton et al., 2003).
( , , )
. , ,
. ,
4560
160200 190240C
.
8595, 95110C.
.
, ,
. (, )
68
. .
.
(Burton et al., 2003 .).
( 4560%)
.
( 85%) (
85%). ().
(. 8).
. (8590% ) -.
, ,
.
4560%.
.
-
. .
25% 95% ,
25% .
, .
50%
.
, ,
24
/7 ,
.
;
.
, , ,
. ,
.
,
.
. , , :
;
;
-
;
;
-
.
.
,
.
, ,
,
, -
.
,
.
. ,
. .
500 0002 000 000
. , , 1520 .
150 200
, ..
70100 /
.
. , ,
.
,
.
69
7.3 :
PURE , Zaklad
70
. 7-4: ,
, (). : ZWiK Szczecin
- 20%.
812 / . 96%, . .
, ,
.
. 7-5: , . :
ZWiK Szczecin
. . 177
000 . 1680
( ) .
, .
, 1,5 .
5% . 5%.
6,5 /
.
30C35C.
3,5%
24 .
19% .
5,3 / .
95% .
. (
238 ) 35%. 40% .
.
(
).
,
, , .
. 7-6: , . :
ZWiK Szczecin
71
7.4 :
. 7-1: ,
( )
(4590% )
( )
(4590% )
.
.
0,5-0,9 .
150-200 .
.
,
70-100 /
.
.
.
, . , , , (), (),
(, ) (,
, , , ).
().
72
8. C
: ,
8.1
. , .
, , .
, .
. , ,
, ,
(, ).
- ( ) (
2008/98/EC),
. , , ,
, .
-
.
,
. 8-1: VERA
. . : Vera Klrschlammverbrennung GmbH
150 000 . , ,
PURE ,
. - .
8.2
(, ),
.
. ,
. ,
.
(, )
. 90%
(
). ,
, ,
.
-
74
,
,
.
, , .
35 / , ,
, . , ,
, . : -
,
,
, .
, ,
,
,
.
, ,
. 8-2: -.
:
, , , 2030%. .
()
(Schmelz, 2011 .),
a -
.
.
. , ,
, ,
.
.
24 7 ,
.
,
.
,
.
(.
9.4).
,
, .
8.2.1
,
.
.
. ,
.
.
- , , ,
.
25 000 /
,
200 000250 000 /.
7085%
(
, ),
.
, -
, , 515%,
75
20% .
60100
. 35 . -
, ,
,
-
.
8.2.2 ()
, ,
,
. .
3 / .
, ,
(, , ).
, ,
.
, .
,
,
, -
, ,
.
.
2040
.
( ) (
).
8.3
,
. .
8.3.1
, , .
. ,
: .
.
, , 8501000. ,
. .
76
300
500 .
( 4001200 /
) .
.
. 45 ,
,
,
. .
, , , , ,
, (), .
8.3.2 ()
100% ()
1050% ( , ) ( ).
() , , .
. ,
.
1
, ,
.
( ) 850
950C.
.
650C .
77
:
, .
.
,
.
. , .
.
2040
,
. ,
, 2025 .
, 400600 . ( 4001200 / )
, , .
. 45
, , . .
.
: (), - () , ,
, , , ().
, , , , , , .
8.4 :
. 8-1:
78
.
<20%.
60100
.
8501000
,
.
2040 .
,
300500 .
850950C.
.
-
45 .
,
,
.
.
.
300500 .
45 .
.
9.
: shutterstock.com/Hywit Dimyadi
9.1
, ,
, .
. ,
, ,
() .
.
-
, , ,
.
.
.
.
, , ,
,
. (, ,
) . , , , ,
.
.
(
), , .
(.
7 8). - .
, , , ,
(, , )
(, ().
-
, , , (. 12).
.
75
50
25
Iceland
Switzerland
Norway
Greece
Malta
Netherlands
Slovenia
Slovakia
Romania
Estonia
Sweden
Finland
Belgium
Austria
Poland
Hungary
Italy
Germany
Czech Republic
Lithuania
Latvia
France
Luxembourg
Bulgaria
United Kingdom
Ireland
Spain
Cyprus
* , , , , 2008 .; , , , 2007 .;
, 2006 .; , , 2005 .; , 2004 .; , 2003 .; ,
2002 .; , 2000 .; .
80
9.2
40
. . , , :
60%, 20%.
,
, .
,
.
50-60- . XX -
, , .
. , , ,
.
20 .
, , 5985% (Palfrey, 2011 .),
2090% (Bergs, 2010 .).
, ,
, . ,
(. 9-1).
()
( 12).
.
,
. , , ,
.
.
. 9-2:
. : SIA Rgas dens
Cd
Cu
Ni
Zn
Pb
Hg
Cr
(2006 .)
1,9
207
27
715
52
1.5
50
0,46,9
73356
1166
3321 235
8.9114
0,24,6
14127
81
,
,
(
). (. 7).
.
( )
, . -
12.
,
, (),
(AOX) ().
,
(,
, . .) .
.
.
, ,
, , , .
, 35
.
, , , , .
(.
10.4 12).
(. 11).
.
9.3
,
. ,
.
, ,
,
.
.
, ,
..,
.
. 9-3: - ()
. :
82
9.4 ,
(. 8).
, ,
. ,
, , , ,
. , , ,
.
,
.
8%
20%.
,
. ,
,
.
,
.
11.
,
,
.
.
- ,
(. 12). , ,
. ,
,
, . ,
( )
,
.
( ) () ,
.
9.5 :
;
.
.
.
, ,
.
(,
).
.
, ,
:
, .
, ,
, ,
.
.
83
10
.
10.1
, , ,
, , ,
, . . ,
() .
, , .
, .
-
, ,
.
, ,
,
. ,
, .
.
(),
(). . , .
, ,
.
. .
,
,
.
. , 24 /7 ,
10.2
80
NH +4
NH 3
60
60
40
40
% NH3NH 3
Percent
.
(NH4+-N) (NH3):
100
80
Percent NH +4
100
% +4
%NH
. , ,
,
.
pK = 9.25
20
20
6
7
8 9
10
11
.510-1:
12(NH3) 13
(NH4+)
pH pH.
. 10-1: (NH3)
(NH4+) pH
85
Heat
exchange
NaOH
Washing
chemicali
(HCl)
Circulation
water
Ammonia
salt product
Heat
exchange
Reject water
before aeration
NH 3-air
. 10-2:
. ( > 10)
NH3 (. 10-1).
( ) , , .
,
. , .
( ) (. 10-2),
.
,
.
, ,
24 . ,
, 1520 .
,
, .
, ,
24 /7 .
.
, .
. -
.10-3: : shutterstock.com/Hansenn
Biovakka Oy
- . () . .
, . ,
. , .
.
.
86
10.3
. - (-),
, . , , , ,
.
10.3.1 -
- -.
.
( 40%), 60%
.
10.3.2
-
.
.
, -
-
. -
,
( -
).
,
, -
.
. -
.
. -
-
DEMON Canon.
-
3040 25.
.
nitrogen
cycle
NH4
N2
Methanol
NO
1990 .
.
(Planctomycetes), ,
(N2),
.
O2
NO2
O2
50%
. 10-4:
: , c 100200 ,
210 .
. .
.
- ( 60%)
/, ,
.
87
PRETREATMENT
Balancing
tank
Primary
sedimentation
Reject water
treatment tank
Sludge recirculation
SECONDARY TREATMENT
Clarifier
Excess sludge
. 10-5: -
, :
30;
.
- (Sequential Batch Reactor, SBR),
BABE.
, ,
,
, .
,
. ,
.
-
.
, ,
12
. , , 1520 .
2040 ,
.
.
.
20%.
, ,
.
2005 . . () Lakeuden Etappi. . () ,
. ()
- -, . () ( 2009 .) . () SHARON. . - ,
2012 . , ,
SHARON.
88
10.4 :
. 10-1: . - = -
.
.
( ),
.
.
1,53 .
(,
).
,
.
.
1,53 .
.
.
.
3040C,
25 .
,
.
.
1 2 .
.
2040 .
(
).
,
.
.
2 4 .
.
, ,
, , .
89
11
. : Metshallitus
11.1
,
. , , . ,
, (), . , :
, , (), .
, ( P2O5,
) 5 2,5%,
(USGS, 2012 .).
, , ()
.
, ,
. , () (. . 11-1),
.
,
, ,
(PHchstMengV 1980 .
() EC 648/2004
). , ,
. :
, ;
;
;
.
(, (
2005 .) -
.
. (SEPA)
2015 .
60% (SEPA, 2002 .). 2003 . ,
-
430
335
($/mt)
240
140
45
Sep-06
Mar-06
Sep-07
Mar-08
Sep-08
Mar-09
Sep-09
Mar-10
Sep--10
Mar-11
Sep-11
Mar-12
. 11-1: . : www.mongabay.com
91
< 0,5 / P
P: 45 %
20-100 / P
P: 45 %
10 / P
P: 50-60 %
64 / P
P: 80-90 %
. 11-3: . : shutterstock.com/Kymmcleod
92
-
.
, , . (. . 11-2).
,
,
.
:
, .
,
. ,
.
,
,
, .
,
.
, ,
. , , .
, 11.2. : , , .
: ,
,
.
45% (Jardin, 2010 .),
5060% (Adam, 2009 .), 80% (Jardin,
2010 .) 90% (Adam, 2009 .).
. ,
( , , ). ,
(. 11.3).
11.2
, , . , , , (. . 11- 2).
.
,
, . (2009 .):
DHV Crystalactor (
Ca(OH)2 NaOH), .
( PRISA AirPrex);
. (), 1998 ., MA ( , ).
,
. AirPrex 20022009 ., 2010 .
. ,
(Lengemann, 2011 .).
(MgCl2)
(). 100 /, 23 (Lengemann, 2011 .).
Ostara PEARL
( Mg(OH)2 NaOH)
20 3/
2007 . . ().
. ( ) .
C ( ) (
93
2009 . 2010 . ).
. ( )
2010 . (Ostara, 2010 .). 500 /. Crystal Green
.
. , , 23 .
3 Unitika PHOSNIX
( Mg(OH)2 NaOH)
620 3/. ,
, .
, =8,5-8,8 (NaOH Mg(OH)2). ,
. . 0,5-1,0
.
.
, (Nawa, 2009 .).
, ,
. KREPRO, LOPROX,
Aqua Reci Seaborne/Gifhorn (Adam, 2009 .). ,
. ,
. 2010 . Seaborne/Gifhorn
( MgO, NaOH, Na2S,
H2SO4 ), . 7,5
(Bayerle, 2009 .).
Mephrec
, ,
(Adam, 2009 ., Scheidig, 2009 ., Petzet and Cornel, 2011
.).
2000oC
,
. . ,
.
. 11-4:
. : shutterstock.com/Singkham
94
11.3
, (. 8 9), ,
. ,
. .
, , , .
.
.
:
, -
(,
RecoPhos);
, -
, (
: PASH, BioCon; -
AshDec Mephrec (Petzet
and Cornel, 2010 .).
, ,
, ,
,
35 (Hermann, 2012 .). ,
,
Thermphos International B.V. Ash-Dec
(Hermann, 2012 .).
1000
-
.
. ( Outotec)
.
, , SEPHOS, PASCH
BioCon, , Thermophos,
( .
Adam, 2009 .).
,
(Scheidig et al., 2009 .).
, , , ,
.
. ,
, .
.
11.4 :
, , .
,
, , .
, ,
.
, .
. 11-5:
, , ,
. :
,
95
12.
. : ,
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