You are on page 1of 128

:

PURE

project on urban
reduction of eutrophication

Part-financed by the European Union


(European Regional Development Fund
and European Neighbourhood and
Partnership Instrument)

:
2012: (Project on Urban Reduction of
Eutrophication, PURE) , Vanha Suurtori 7, 20500 Turku,
Finland (); www.purebalticsea.eu
311 2 Pyry Finland Oy
PURE
.
: - , Entsorgungsbetriebe Lbeck; , ; , ; , .
: shutterstock.com/DmitriMaruta. .
:
:

Part-financed by the European Union


(European Regional Development Fund
and European Neighbourhood and
Partnership Instrument)

: , .
: 125
ISBN 978-952-5725-93-3 (.), 978-952-5725-94-0 (PDF)
2012 .

1. ............................................................................................................................................ 4
1.1
PURE ........................................................................................................................................5
1.2 .......5

2. ........................................................................................................................................................ 9
2.1 : .....................................................................................................................10
2.2 ................................11
2.3 ..........................................................................................14
2.4 :
PURE ......................................................................................................................................................................16
2.5 : PURE ........................17

3. .......................................................................................................................... 18
3.1 ...................................................................................................................................................................................19
3.2 .....................................................................................................................................20
3.3 .........................................................................................................................................22
3.4 : PURE ..........................25
3.5 : ......................................................................................................26

4. OC................................................................................................................... 28
4.1 .............................................................................................................................29
4.2 .................................................................................................................................................30
4.3 ...................................................................................................................33
4.4 : .............................................................................................................................34
4.5 .................................................................................................................................34
4.6 ........................................................................................................................................................35
4.7 ........................................................................................................................................................37
4.8 : PURE .....................38

5. ............................................................................................................... 39
5.1 ...................................................................................................................................................................................40
5.2 .............................................................................................................................................................................42
5.3 -.................................................................................................................................................44
5.4 -....................................................................................................................................................46
5.5 ........................................................................................................................................................47
5.6 :
PURE .......................................................................................................................................................................49
5.7 : ................................................................................................50

6. ......................................................................................................... 52
6.1 ...................................................................................................................................................................................53
6.2 .........................................................................................................................................................54
6.3 ..........................................................................................................................................................55
6.4 ....................................................................................................................................................59
6.5 :
PURE - ..........................................................................................................................................................62
6.6 :
PURE ..............................................................................................................................................................63
6.7 : ................................................................................................................64

7. .......................................................................................................................................... 66
7.1 ...................................................................................................................................................................................67
7.2 .......................................................................................................................68
7.3 : PURE ...................70
7.4 : .................................................................................................................72

8. C ................................................................................................................................ 73
8.1 ...................................................................................................................................................................................74
8.2 .....................................................74
8.3 ......................................................................................................................................................76
8.4 : ........................................................................................................................78

9. ........................... 79
9.1 ...................................................................................................................................................................................80
9.2 .......................................................................................81
9.3 .............................................................................................................82
9.4 , .......................................................................................83
9.5 : ..................................................................................................................................83

10. ................................................................................................................ 84
10.1 .................................................................................................................................................................................85
10.2 ........................................................................................85
10.3 .............................................................................................................................87
10.4 : ...............................................................................................89

11. ..................................................................................... 90
11.1 .................................................................................................................................................................................91
11.2 ...........................................................................93
11.3 ..........................................................................................................................................95
11.4 : ...............................................................................................95

12.
.............................................................................................................................. 96
12.1 ...............................97
12.2
.........................................................................................................................................................................102
12.3 ....................................................................................................................................................................................111

13.
......................... 113
13.1
..................................................................................................................................................................114
13.2 ................................................................................115
13.3 .........................................................................................................................................116
13.4 - ................................118
13.5 .................................................................................119

14. ................................................................... 121


................................................................................................................................................... 125

1.

: shutterstock.com/Kekyalyaynen

1.1

PURE

(Project on Urban Reduction of Eutrophication, PURE)


,
. PURE

. ,

- .
: ,

PURE
- . PURE 2011 .
, .


.

, ,
, , , , , .

,
, , ,
,

. 1-1: : shutterstock.com/PanicAttack

. ,
, ,
() .
, ,
, - , .
,

.

1.2

PURE (Helsinki Commission, HELCOM). , , , , , , , ,


.

( ).


, ,


.

(, 2007 .) 2021 .,
. 28E/5 (, 2007 .) , , , ,
. PURE


-
.


.

. 2012 .


28E/5, , ,
. / .

(Land-based
Pollution Group, LAND)
,
.

. 1-2: 9 . ,
85 , 4 (
).
53 . , , ,
.

PURE

(Commission on Environment, EnvCom)
(Union of the Baltic Cities,
UBC)
,
100 ,
, ,
.
13 . . PURE
.

(John Nurminen
Foundation)
:
,
.
. PURE ,
,
.


(Baltic
Marine Environment Protection Commission,
HELCOM)
,
.
( ).
PURE .

- . SIA Rgas dens ()


SIA Rgas dens ,
.
( ) -


1 000 000 .

( ). PURE SIA Rgas
dens
. ,
2008 .
100 .


()
, 300 000 ,
.
. .
,


.
PURE
.

- . Jrmalas dens
()
. . ,
. 30 000 . PURE
. ,
, .

- . (Zakad
Wodocigw i Kanalizacji Sp z o.o. w Szczecinie
ZWiK) ()
. .

. PURE (
418 000 )
( 177 000 ),
.

. (Entsorgungsbetriebe Lbeck)
()
. :
0,2 /, 99,0% ( 400 000 ).
PURE

PURE,
.

Jrve Biopuhastus O ()
Jrve Biopuhastus,

, , - ,
200 000 .
( ).
PURE
- ,


.

.
(Urzad Miejski w
Gdansku) ()
. ,
455 000 ,
- (GiWK),
-

. 1-3:
PURE

.

. PURE
, . PURE.

Mariehamns stad, ()
( 30 000 ).
.
PURE

.

2.

: shutterstock.com/skyfish

2.1 :
. , , 3,5
, , , 2020 . 4
. : ,
.


.


(.
12) . , ,
, .
: .
. ,
,

,
. , , , ,
,
.


, .
, , .

.

, , ,
, -
, ,
.

10

. 2-1: : shutterstock.com/Enieni



,

, , .
, .

, .
, , - ,
. .
- .

, ,
,

.
: ,
50 .
,
. ,
100
. ,
(Schrder et al.,
2011 .).


.

.
,
.

2.2

. , ,
, , , , .
, , .
,
,
. -
. ,
,
. , , , , ,
,
() .
:

, ;
;
,
;

,
;

.

. 2-2: : shutterstock.com/Kekyalyaynen

11

,
.

, , , - .


.
, , , .
,
, , , , , ,

(. 2-1).
.
(. 2-3).
.

.
.

; .
4%, 67% (ATVDVWK-M 368E, 2003 .)
( ). . 10 20 , ,
(ATV-DVWK131E, 2000 .).
,
, ( ).
( , . .
).
, (,
), , , ,
(, ).
.

. 2-1: ,
( , , - )
(Milieu, WRc RPA 2008 .)

2005 / 2006 .

2010 .

2020 .

( /
)

( /
)

( /
)

50000

50000

70000

140021

140000

140000

33000

33000

147000

155000

155000

2059351

2000000

2000000

23942

25000

50000

71252

80000

80000

523674

520000

950000

180000

180000

200000

210000

250000

250000

3405240

3433000

3928000

* , , Milieu et al. 2008 . .


Pyry Finland Oy PURE ,
.

12

Figure 2-1. Different types of sludges generated in urban waste water

treatment plant processes.

Primary
sedimentation

Aeration basin

Clarifier

Returned activated
sludge
Primary sludge
Secondary / excess
sludge

Thickening

Digestion

Digested sludge

Dewatering

Dewatered
sludge

. 2-3: ,

,

0,51,0%.

7080%. , , .
, (ATVDVWK-M 368E, 2003 .) , ,
( 3.3) .
(
3.2).
(,
)
/ ( )
.
, ( 4), .

.
,
( 3540C) . , ,
.
( ),
, -

. ( 5)
c 95% 60-80%.

.
( , 6), ( 7) ( 8).
. ( 9)
- ( 12).
, , .
:

( ) -
100%
). -

. -
-
.


. , -

, -
-
. , -

.
-
,

13

, .

.
-
,
( 10).




(, ).

.


10% (Kopp J., 2010 .). -

(
< 10 000 ), ( 10 000100 000
) ( > 100 000 ).

2.3

Flow sheet 5: (Small and mid size waste water treatment plants with aerobic stabilization)


SLUDGE
THICKENING
Aerobic stabilized
excess sludge

Pretreatment
(thickening)

SLUDGE
DEWATERING

SLUDGE
DISPOSAL

(Mobile)
dewatering

Agriculture,
landscaping

Flow
6
.sheet
2-4:

(Primary and)
excess sludge)

SLUDGE
THICKENING

SLUDGE
DEWATERING

Pretreatment
(thickening)

(Mobile)
dewatering

SLUDGE
HYGIENIZATION

Windrow
composting

. 2-5:

14

SLUDGE
DISPOSAL

Final product
processing

treatment plants (and for small waste water treatment plants in Sweden, Finland
and Denmark. Another possibility for small plants to pump / transport their

sludge to bigger plants for sludge handling.


SLUDGE
THICKENING
(Primary and)
excess sludge

SLUDGE
DEWATERING

Pretreatment
(thickening)

Digestion, dewatering
and disposal on a
large plant

(Mobile)
dewatering

Flow sheet 8: (Figure 11-3 typical sludge handling for medium


- large waste water treatment plants)

. 2-6:

THICKENING

STABILIZATION

DEWATERING

HYGIENIZATION
DISPOSAL

Primary sludge

Optional: e.g.,
composting or
lime treatment

Gravity
thickening
Digestion

Excess sludge

Agriculture,
landscaping

Dewatering

Mechanical
thickening

Flow sheet 9: (Figure 11-4 Typical sludge handling for large waste water
treatment plants)
. 2-7:

THICKENING

Primary sludge

STABILIZATION

DEWATERING

Gravity
thickening

INCINERATION

DISPOSAL

Optional:
Drying
Digestion
Dewatering

Excess sludge

DRYING

Mechanical
thickening

Monoincineration
Ashes to landfill
or other use
Coincineration

. 2-8:

15

2.4 :
PURE ,

Gdanska Infrastuktura Wodocigowo-Kanalizacyjna Sp. z o. o.,



() ,
PURE. ( MUCT), .
781 000 ,
18 374 ( ).

3,7 , ,
( 4,8%), .

- 6%. 3,4 /
.
,

. 28 37C. 3,1%.
.

19,7%. 11,4 /
. (
) 31,4%.
.

16


, (
40,5%) . , 100%
. . .
10 ,
.

. .

-
. 2013 .
( ).


2015 .
, .
. 2-9: .
: GiWK

2.5 :

PURE ,

. () 300
000 . . PURE
.
.
2010 . , (
)
.

. ,
.
.
.
, . .
100 000 3.

2002 . - .
-

.
- .
,
.
,

.
, .
,
30 . .

.

. 2-10: . :

17

3.

: ,

3.1
97,099,5%.
.
, (. - 2.3).
:

, .
.
/
,
. , 0,51,0%,
4,0%.
,
.
, , , .
, .
, , , ,

. .
, (.
5), ( , ).
.
, ,
.
. ( )
,
.

. 3-1: : shutterstock.com/John Kasawa

,
( Pyry
PURE; Burton, F.L et al., 2003 .; DWA M-381E, 2003
.) ,
PURE. ,
PURE , .

, ,
.
.

19

3.2
,

. ,
, , .
. ,
.


. ,
() .
:
.

. (. 3-1).
90% .
, , ,
.
820 . ,
(H2S)

.

. (>
4 )


. , ,
, , , .
.
( ())
,
,
( ).
,
, .
.

/

.
. , .

. , , -

. 3-1:
(DWA-M 381E, 2007 .), (Burton, F.L et al., 2003 .)

20

()

510 %

46 %

58 %

23 %

34 %

, . 3,03,5%
.
,

, .

)
(
). ,
,
.

, ,

, ,


.
12 .
(
, ).
.


. . (150 000400 000 ),
, , .

40 , 2025 ,
1015 .
(26 /
). ( )
0,53 .

.

. 3-2:
(). : Entsorgungsbetriebe Lbeck

.
(

Figure 4-2. Schematic diagram of a gravity thickener.

SLUDGE INFLUENT
WEIR

OUTLET CONCENTRATED SLUDGE


. 3-3:

21


, , , (), , (), (), (), (), (), -
(), (), ().
(, () - ()
. , , , . ( )
, , , , ,
. .

3.3
. .

.
.
,
.
(24 /7 ). ( ) (,
8 /5 16
/5 ). (. 3.2).


.
70 000 150 000 , 1520
. 2 .
-
, .

. 3-4:
(). : ZWiK Szczecin

. (, ),
.

3.3.1

22

. , ,
. .
.

0,51% 47% .
90% .
, , -

.
20 3/ 100 3/.
, .
24 , 510 36
( ). .



( 37 / ). .
26 .
.

,

410 .

3.3.2
,


.
, .
,
.
.
10 3/ 70 3/
. 90% . 57%
.


, - ,
.
, , 23
, 715 3 ,
.
.

, ,

(37 / ). 410
. 26
.
.

,
.

. -

. 3-5: () (). : PIU Jrmalas dens ZWiK Szczecin

23

3.3.3
,

( ) , 5.3.
,
, .

.
,
.
. .
, , 24180 /. 90% .
57%.
,
.

,
. .

, ().

, ,

.
3 10 ( 37 / ).
, , 26 .

.

. 3-6: () (). : ZWiK Szczecin Entsorgungsbetriebe Lbeck

3.3.4
.
5.2.

.

,
.

, . .
,

24

, 57%.
, .

, ,
(1,01,5 / ),
. , ,
.

3.4 :
PURE , SIA Rgas

dens,
. 1 000 000 .

6857 ( ),
. ( 2012 .)
, PURE.
4% 5% ( 2,5 ).
(24 / ). 57%,
3%.
37C 1420 .
2500 3,
5
(). 2 ( ),
38,9%.
45%
55% . .
-

. 3-7: . : SIA Rgas dens

( 8 / ) ,
22%.
, . ,
.
. 3-8: .
: SIA Rgas dens

25

3.5 :


. , .
, .
, , .


.
,
.
a,
.

. 3-9: : shutterstock.com/Nostal6ie

26

, .
, , ,
. , .

. 32. , , .
PURE . 33.


, -

. , , .

. 3-2:

47 %

57 %

57 %

57 %

26 /

26 /

26 /

11,5 /

5200 3/,

20100 /

1070 /

24180 /


(),

()
(),

(),
()

(),

(),
(),

()
(),

(ZKW) (),

, ()

()

()

- ()

. 3-3: PURE


PURE

6%

4,0 /

57 %

24 /

47 %

3,5 /

6%

3,4 /

()

6%

35 /

()

6,5 %

6,5 /

(ZKW)

56 %

1,5 /

27

4.

OC

. : , Metshallitus

OC

4.1
. .
.
, .
, .

( 3540C), (5357) .

, .
( )
.
,
.
. :
() ().

(LaCour et al., 2004 .).


30 , , ,

PRETREATMENT
FOR DIGESTION
Primary
sedimentation
if existing

. ; ,
.

.
: . .
.
,

, .
, ,
,
(),
.
. 4-1.

ANAEROBIC
DIGESTION

TYPICAL POST-PROCESSING
AFTER DIGESTION

or

Flocculant aid
addition

Biogas
(energy production)

OPTIONAL:
Sludge thickening
& other methods
(disintegration)

Digestion

Digested
sludge

Sludge
dewatering
20-40% DS

Heating and mixing


Clarifier

Reject water to waste water


or reject water treatment

. 4-1:

29

OC

4.2
, , 3540C.
,

,
.
, , 2025
. 1415 ,
, 14
.
,
, ,

.
.
, , .

, ,
. .

4.2.1

, .

.
. , ,
(
) .

, , ,

.

,
. ,
. .
( )
,
.

. (),

, (. 4.5).
615 ,
2535 3040
.
,
.

30

. 4-2: ()
(). : Entsorgungsbetriebe Lbeck SIA Rgas dens

OC

4.2.2

.
(.
3). ,
.


47%,
.
. .
.
, , ,
(. 4.2.4).
, .
: .

.
, .
(, Cambi)
(Walley, 2007 .), (Xie et al.,
2005 .) (Machnicka et
al.) ( HPF-,

Envor Oy, ()). .



. ,

, ,
,
.

( ) ,
.

.

.

,
.
,
(Burton et al., 2003 .,
Hammer, 2001 ., Vesilind, 2003 .).


.
(Burton et al., 2003 .).

. 4-3: (). : GiWK

31

OC

4.2.3
, .
.
, . , ,
(). -

. 4-4: : shutterstock.com/chris2766

.
MA ( )
(- ), , .


.
(510C), ,
,
. , ,

3540C.

. .

.

4.2.4

.


, , , .

,
,
.
.
, ,

. ; : (i)
( , , ); (ii)
; (iii)

, , -

32


(Vesilind, 2003 .).
.

. ,

, . , , ,
.

OC

4.3
, ,
, .
.
, .
,
, , .
, ,
.
,
.
. ,

, , . ,
, , -
(, )

.
. ,

,
,
.

. 4-5: : shutterstock.com/Hansenn

515 , .
, 5080
1 000 000 .
, , 1520 ,
3040 .
100 150 , 100
400 / ,
.
, , ,
.
23 ;


.


.
, .
, . , 35 .
. . .
, , , , , , , , ..
, , , . (
) PURE . 5-1.

33

OC

4.4 :


,
.

.
,
20 .

.


.
(
) ,
,
,

.

4.5
. (CH4)
5864%, (CO2) 3040%.
(H2S). , ,
, (CH4) 70%.
(100%) 10 /, 5,86,4 /.
,
.

. ,

.

400 450 3 .
, . .
( ) -

.
. .
, , ,
( ) , ,
25 .
.

.
, .
,


.

. 4-6: , ().
: Entsorgungsbetriebe Lbeck

34

OC

. 50%
.

, .
,
.

.


.
,
5%. , -

, ,
(Vesilind, 2003 .).

4.5.1


.
(<0,01%), ,
. , ( ) .

,
.
,
12 . .

.

. 4-7: , . : SIA Rgas dens

4.6
.
, . 40%.
, .
.

, , .
:
35% . ,


.

, .
, , -

35

OC

.
, .
.
.
(, )
,
, .
. , ,
. ,
, .
:
;
,
-
;

;

;
-
.

. 4-8: () (). :
Entsorgungsbetriebe Lbeck ZWiK Szczecin

,

.

. 4-9: , (). : SIA Rgas dens

36

OC

4.7

, . ()
. . ,
.


25 (ATV-DVWK-M 368E, 2003 .).
.
, (Einfeldt, 2011 .).

,

,
(. 6.2.2).
.
,
, .

37

OC

4.8 :
PURE ,

Entsorgungsbetriebe Lbeck,
(ZKW)
()
.
( 30 000 ),
, ( 350 000 ),
-.
2- ,

.

.
. 9000
( )
.
.
2,54,0% .
( )
5,5%
(13 / ) .

18
3739 2,5%.
. 62% , ,
4000 , . 3 844
10 .

38

41,7%,

100%. 100%.
-
3639%.
.
.

.

, ,
- .
, ,
- .
2005 ., , , .
( )
.
,
, .

. 4-10: . .
: Entsorgungsbetriebe Lbeck

5.

: shutterstock.com/Marteric

5.1
,
.
. ()
,
. ,
.

,
, .
, ,
, ,
.

, , 19%30%. 40%. , -
.
.


.
, ,
.
,
, (), .
(. 4.2.2). , .
. -

( )
.



-,
. -
-, , , .
,

- , .
,
-
.
,
(,
, , , ), ( ,
, , , , ) ( 20, , ,
, , ). ,

. -

.
, .
,
(. 11). , ,
.


.
20 (Kopp, 2010 .).

40



, -.
, .


,
.
. , ( Pyry
PURE; Burton et al., 2003 .;

DWA-366 M, 2011 .). ,



PURE, ,

,
.

. 5-1: Rofitec.
.:

. ,
48C
5% , 20C
(Kopp, 2010 .).


. , , . , . ;
Rofitec,
. , -
(Ilian et al., 2011 .).


(, , ) (
). , .
, .
. , ,
. , .
, ( )
(Nielsen, 2007 ., Schillinger, 2006 .).
,
/ . ,
.
, (BIOPROS, 2008 .).

41

5.2


. g (
) .
. 5-2.
, . ,
() .
, .

,
. ,
.
, :
;
, . .
;
;

-
;
,
. . , .
25 , 715
36 , .
.


/
, , -

,
. , , ,

.
, .
. ,
.
, .


, ,
.
,
,
.
3240% ,
26
32%, 1824%,
2230%.

, ,

(24
/7 ).
, .

. 5-2: . .: Flottweg SE

42

.
(8 16 5 ). ,

.
515 , , .
.
( 20004000
) ( 8000 ) .
, .


.
, , .
( 2500 g):

,
,
;
-
, ,
;
, -

;

.

,
.
, .

,


.

. ,

. , -

. 5-3: ().
: SIA Rgas dens PIU Jrmalas dens

,
(Guyer, 2011 .).

- .

,

.

, ,
100 000250 000 . ,
, 1520 ,
1015 .
2090
( ), 3035 /
, .. , .
.
4 14 . , , ,
,
-

43

.
.
(
) ,
.
.
. 5-4:
- (). :
,

5.3 -

- ,
, ,
.
, .
, -.


.
.
,
,
.
.

.

, .
.
. ,

,
.

,
-.
- . 5-5.
- 36 , 510 36 , .
.

44


. . , .
.
,
- (3%).


-
, .
-
3035% ,
2430%,
1522%,
2028%.

-

/
-
, , .
.


1.
BellmerTM

5.
( )

2.

4.

3.

. 5-5: -. : Bellmer GmbH

-
.
,

. ,
,
100 000 , , (), .



.

, ,

- (24 /7 ).
,

(8 16 5 ).
, . -
,
.

.
.
/ .
, .
.

-
.
, ,
12 .
- .

.
, ,
. ,
12 , ,
.

-. , ,
,

. , ,

.

, ,
.

45

- .

, ,

80 000 250 000 . , , 1520 ,
12 .


-.
2050
, 2030
/ . .
.
412 -

. 5-6: -
(). : ZWiK Szczecin


.

.

5.4 -

- , . .
60 . , .
,
.
, , 24 , 715
36 ,
.
.


-,
,
.
.
-
(1525 /)
(512 /). .
,

(,
).
40%,
3050% .

46

,
(. 6.3). : / 45%
, 35%
40%
.

-

/
- ,
, , . -

.

, ,

. -
, .
,
.

, ,

- (8 16
5 ).

,
-.

.
- .
,
.

, ,
-

-,
-.
-
-
.
150 000350 000

. , ,
1520 ,

.
2050 ,
(
2030 / ). ,
, 412 . , ,
,
.

-
- -.

23% ,
.
. -
. ,
, ,
.
. 5-7: - (). :
Entsorgungsbetriebe Lbeck

5.5
,
,
() .
. ,
, (, ).
.

,
. : ,

47

, . 70 120 ,
.
.
. 25%
40%.
130 500 .
, , 24 , 710 36
, .
(Bucher Unipektin AG, 2011 .).


/
, ,
, .
2 10% .
, - ,
.

KEMICOND

50% (. 6.3). , KEMICOND
,
.

, ,

, ,
, . 24 /7
() (8 16 5 ).

. -
, .

, ,
180 000400 000 . ,
, 1520 ,

.
2050
,
(2030
/ ).

.
512 .
, ,
.

. 5-8: . :
Bucher Unipektin AG,

48

5.6 :
PURE , PIU

Jrmalas dens,
()
37 500 . 1000 ( )
.

. PURE
, , .
.
, .
,
47%.
3,5 / .
,
( 18%).
5,4 /
. .
,

. 5-9: ,
. : PIU Jrmalas dens

.
, , , ,
, .

. 5-10: .
: PIU Jrmalas dens

49

5.7 :

, , .
, , ,
.

.
,
. .

(, , ..),
.
.
. 5-2. ,

PURE, . 5-1.

5-1:
PURE. BioP =

50

BioP

PURE

22 %

8 /

19 %

8 /

18 %

5.4 /

19.7 %

11.4 /

20 %

8-12 /

19 %

5.3 /

, ZKW

37 %

500 /

()

. 5-2:

2035% 1

1824%

1522%

1824%

2835%

2230%

2028%

2230%

3040%

414 /

412 /

512 /

1525
/

512 /

, ,
(
)

,
,

(
)

, ()
, ()
-
()
,
()

()
, ,
()

,
()
( )
, -
()
()

,
()

()

51

6.

: HSY Water

6.1
()
, . , ,
. (),
( ) (SNV, 2003 .,
Umweltbundesamt 2009 ., WHO, 2003 .).

:
5570C
;
12 -
.

SLUDGE TYPE

,
.
.
6-1.

HYGIENISATION
METHOD

Thickened, possibly
aerobically stabilized
sludge
24% DS

Dewatered sludge
(possibly stabilized
aerobically or
an-aerobically)
20 40% DS

Thermal treatment
- pasteurisation
- other treatment

FINAL PRODUCT

Soil conditioner
or fertiliser
Chemical treatment
- lime stabilisation
- other treatment
Covering material
and landscaping
Biological treatment
- windrow composting
- tunnel composting

. 6-1:

53

6.2
, .
( ),
- .
,
:
() ;
;

;
;
;
.

6.2.1
, 1860- .

.
:
65C100C.
65C 30 , 70C
25 , 80C 10 .
( ) .

.
, . -

. ,
. ,
: ,
. 11,9
/ ( ) (UBA, 2009 .).



(UBA, 2009 .).

. 6-2: - (). : O Jrve Biopuhastus

54

6.2.2
-
,
-
-
.
, -
-
.

.
(. 7)
, -
.

180C

.
(c ),
.
.




, -
, -
. -
-
(. 8).


4. -
. ,
-
, , -
, -
.
. 6-3: : shutterstock.com/Peter Gudella

-

.
,
,
, 6.4.

6.3

(CaO Ca(OH)2) 12 . 12 2 .
, , pH, .


(Ca(OH)2)

.
(. 5.4). (CaO),
, .
. , 5,
,

.
,
.

, , ,
, , 34 ,
510 36 , .
.

55


.
,
.
:
-
, ,
;
, -

;


;

,
.

, .
-
;
300400
.
. 6.3.4.

6.3.1
(2
4%), ,
(510% Ca(OH)2), .
, ,
. Ca(OH)2 ,

. -

, .

, ( / ),

.

6.3.2
-
(. 5.4). .
,
.
-,
.

,
;
-
;
-
;

-
, -
;

. 6-4: . : Entsorgungsbetriebe Lbeck

56

6.3.3
, , (2040%, .. ).
1520 . 12 .
CaO ,
, 60C , , .

,
(. 5). ,
, .
, ,
.

.
, , 1520 . ,
300400 CaO/ .

2 >12.
-.
2040 / .
1020 , 715 -/ ,

.
.

- (. 5.4).

, ,

200 000-400 000


. Iisalmi Water, , Savonlinna Water.
().

, .

6.3.4
, .
, .
.

.

, ( (Fe3(PO4)2)
(II) (FeO)) .
(H2O2), Fe2+
Fe3+, (III) (FePO4).


Kemicond. Kemicond ,
.

4 (H2SO4).

,
Kemicond. (NaOH)
.

57

,
, .
(
, Kemicond).
, , . ,
.
46 , 810 46
. ,
.
( ) , 220 H2SO4
27 H2O2
.
.

, ,

400 000700 000
.
. ,
, 1520 .
, -.
220 H2SO4/ , 27 H2O2/ .
5060 /
. 1525 , 1020 / ,

Kemicond.
.
Kemicond
50%
;
Kemicond -
38%45% (Brendler, 2006 .).
,
-.
.
.

,
. ,

, .

. 6-5: : ,


,
, ()
(
).

58

6.4
6.4.1


().
(60C 36 ) ,
. , .
:

, , -
;

,
,


. ,
.

.

.

, -
.
15%.
(. 3 5).
,
(), . (, ) -

6.4.2
, ,
,
,

. ,
- ,
, . .
, .

(, ()) . ,
, , 4050%
.
.
,
,
- .

, ,
,
.
, ,
, ,
. , . 1930- .,
1970- .
1990- .

: 50100 150200 ,
.

,
.

59

, ,

500 0003 000 000 , , .

.
, ,
1015 .

, (, ). ,
, ,

- .

,

, .
. ,
, 10 /
.

, .
( )
.

. 6-6: () - ().
: HSY Water O Jrve Biopuhastus


.
1 , , (),
, , - (), (), ()
.., , , , . .

60

6.4.3
, ,
, , , .

, . 46 , 6 2040
;
, , 2025 , 6
2040 .

5060 80100 .

.
(
500 0001 000 000 ),
.
1015 .

:
-

;
,
-
.
-
. ,
,
,
;
.
-
, -

,
, ,
, .

,
.

, ,

1,55
,
. ,
,
,
,
. , , 1520 .
75
120
.
, 100 200 / .
.

. , .

,
- .



, ( ) , , , . . ,
, , , , , ( ), , , .
.

61

6.5 :

PURE -, O

Jrve Biopuhastus, -
. - () 200 000 .
2700 (
).

.
- ,
.
6%.
4 / .
,
2024 55C.
22%. 8 /
.
.
.
.
, -

62

. 6-7: -. : O Jrve
Biopuhastus

-,
.
, , ,
.
, .

. 6-8. (). : O Jrve Biopuhastus

6.6 :

PURE , HSY

Water,
100
3 ( 1,1 ),

() (),
HSY Water. HSY Water PURE.
65 000 , 25 000 .
2,8 , 2,1 .
3,6% 1,3% . .
7,5 /. ,
,
4,1% (2011 .).
, : .
.
.
17 37 13
35,5 .
2,3% 2,7% .
( ). 29%.
4,5 /
6,1 / .
, . 69
. ,
. -

.

. ,
, (
).
HSY . , ,
.

. 2011 .
12,3 . 3 3,5
3 . , , 27 500 /, 4100 / ,
99% .
9 560 / ,
97% .
25 000 / (60% ), 4 500 / (35%
).
2011 .
.
2012 . , ,
, .

. 6-9.
, . : HSY Water

63

6.7 :


, .

. -

.

. 6-1.

PURE . 6-2.

. 6-1: . (, ,
, ), ( UBA, 2009 .).

(. 7)

( )


( )


. , . , , , .
, , , , , . , ,
. PURE
- () ().

64

. 6-2:

65

7.

. : metshallitus

7.1
,
. .
, .
, . , ,
2030%, 5090%.
, .
. , -

PRETREATMENT

,
, (,
) . . 7-1.

THERMAL DRYING

FINAL PRODUCT

Odorous gas to be
treated or to biofilter
Mechnical
sludge
dewatering

Thermal
drying

Optional:
pelletizing/
granulation

Final product
processing, e.g.
incineration

Sludge liquor to waste water treatment


. 7-1:

.
(). ,
(, ), .
. (
), .
(, , )
, (, , , , ), . , ,
, .
, , .. , .
, .

67

7.2
.
, ,
.
( ) ( ).
.
(2030% )
() ,
.
.


. ,
.
, 450460C ( ) 120160C ( )
510 ( ) 4060
( ).

,

. , ,

.

. . ,
,
(Burton et al., 2003).

( , , )
. , ,
. ,
4560
160200 190240C
.
8595, 95110C.

.

, ,
. (, )

68

. .
.
(Burton et al., 2003 .).
( 4560%)
.

. 7-2: (). : GiWK

( 85%) (
85%). ().
(. 8).
. (8590% ) -.
, ,
.

4560%.
.

-
. .

25% 95% ,
25% .
, .
50%
.

, ,

24
/7 ,
.
;
.
, , ,

. ,
.
,
.

. , , :
;

;
-

;

;
-
.

.
,
.

, ,
,

, -
.
,
.
. ,


. .
500 0002 000 000

. , , 1520 .
150 200
, ..
70100 /
.

. , ,
.
,
.

. 7-3: (). : ZWiK Szczecin

69

7.3 :

PURE , Zaklad

Wodocigow i Kanalizacji Sp z.o.o. w Szczecinie ZWiK



. () .
418 000 , 6300 (
) ( 50005500 ),
,
. . .
,
2 .
2,5%.

6%.

- 6% . 35 / .
( 3,5%).
37 20 . ( ) 350 , 37%.
70%,
25 .

70

. 7-4: ,
, (). : ZWiK Szczecin


- 20%.
812 / . 96%, . .
, ,
.
. 7-5: , . :
ZWiK Szczecin


. . 177
000 . 1680
( ) .
, .
, 1,5 .
5% . 5%.
6,5 /
.
30C35C.
3,5%
24 .

19% .

5,3 / .
95% .
. (
238 ) 35%. 40% .

.
(
).
,
, , .

. 7-6: , . :
ZWiK Szczecin

71

7.4 :

. 7-1: ,


( )
(4590% )


( )
(4590% )



.
.


0,5-0,9 .
150-200 .


.
,

70-100 /
.
.

.



, . , , , (), (),
(, ) (,
, , , ).
().

72

8. C

: ,

8.1
. , .
, , .
, .
. , ,
, ,
(, ).

- ( ) (
2008/98/EC),
. , , ,
, .
-
.
,

. 8-1: VERA
. . : Vera Klrschlammverbrennung GmbH

150 000 . , ,
PURE ,
. - .

8.2

(, ),
.
. ,
. ,
.
(, )

. 90%
(
). ,
, ,
.

-

74

,
,
.
, , .
35 / , ,
, . , ,
, . : -

,
,
, .
, ,
,
,
.

, ,
. 8-2: -.
:


, , , 2030%. .
()
(Schmelz, 2011 .),
a -
.

.
. , ,
, ,
.
.


24 7 ,

.
,
.
,

.

(.
9.4).

,
, .

8.2.1
,
.
.

. ,
.
.
- , , ,
.

25 000 /
,

200 000250 000 /.
7085%

(
, ),
.


, -

, , 515%,

75

20% .
60100
. 35 . -

, ,

,
-
.

8.2.2 ()
, ,
,
. .
3 / .
, ,
(, , ).
, ,


.
, .
,
,
, -

, ,
.
.

2040
.

( ) (

).

8.3
,
. .

8.3.1


, , .

. ,
: .

.
, , 8501000. ,
. .

76

. 8-3: (). : ZWiK


Szczecin

300
500 .
( 4001200 /
) .
.

. 45 ,
,
,
. .



, , , , ,
, (), .

8.3.2 ()

100% ()
1050% ( , ) ( ).
() , , .

. ,
.
1
, ,
.


( ) 850
950C.
.
650C .

. 8-4: . .: Vera Klrschlammverbrennung GmbH

77

:
, .
.

,
.
. , .
.


2040

,
. ,
, 2025 .

, 400600 . ( 4001200 / )


, , .
. 45
, , . .



.
: (), - () , ,
, , , ().
, , , , , , .

8.4 :
. 8-1:

78

.

<20%.

60100
.

8501000
,

.

2040 .

,

300500 .
850950C.
.
-
45 .
,


,
.
.
.

300500 .

45 .


.

9.

: shutterstock.com/Hywit Dimyadi

9.1
, ,
, .
. ,
, ,
() .
.
-
, , ,
.
.

.

.
, , ,
,
. (, ,
) . , , , ,
.
.

(
), , .
(.
7 8). - .


, , , ,
(, , )
(, ().
-

, , , (. 12).
.

. 9-1: , 2009 .* (% ). : Eurostat


100

75

50

25

Iceland

Switzerland

Norway

Greece

Malta

Netherlands

Slovenia

Slovakia

Romania

Estonia

Sweden

Finland

Belgium

Austria

Poland

Hungary

Italy

Germany

Czech Republic

Lithuania

Latvia

France

Luxembourg

Bulgaria

United Kingdom

Ireland

Spain

Cyprus

Data not available


Others
Incineration
Landfill
Compost and other applications
Agricultural use

* , , , , 2008 .; , , , 2007 .;
, 2006 .; , , 2005 .; , 2004 .; , 2003 .; ,
2002 .; , 2000 .; .

80

9.2

40
. . , , :
60%, 20%.
,
, .
,
.
50-60- . XX -
, , .

. , , ,
.

20 .
, , 5985% (Palfrey, 2011 .),
2090% (Bergs, 2010 .).
, ,
, . ,

(. 9-1).

()
( 12).
.
,

. , , ,
.
.

. 9-2:
. : SIA Rgas dens

(, Bergs 2008 .).


,
, .


. (
),
.
.

. 9-1: / (Palfrey, 2011 .)

Cd

Cu

Ni

Zn

Pb

Hg

Cr

(2006 .)

1,9

207

27

715

52

1.5

50

0,46,9

73356

1166

3321 235

8.9114

0,24,6

14127

81

,
,
(
). (. 7).
.

( )
, . -

12.

,
, (),
(AOX) ().
,
(,
, . .) .

.


.

, ,
, , , .
, 35
.

, , , , .
(.
10.4 12).

(. 11).

.

9.3
,
. ,
.

, ,
,
.

.

, ,
..,
.
. 9-3: - ()
. :

82

9.4 ,

(. 8).
, ,
. ,
, , , ,
. , , ,
.
,
.
8%
20%.
,
. ,
,
.
,
.
11.
,
,
.
.


- ,
(. 12). , ,
. ,
,
, . ,
( )
,
.
( ) () ,

.

9.5 :
;

.



.
.


, ,
.


(,
).
.
, ,
:
, .


, ,
, ,

.

.

83

10
.

10.1
, , ,
, , ,
, . . ,
() .
, , .
, .
-
, ,

.

, ,
,
. ,
, .

.
(),
(). . , .

, ,
.



. .

,
,
.
. , 24 /7 ,

Figure 11-1: Equilibrium diagram for ammonia (NH3) nitroge


and ammonium (NH4+) with changing pH value.

10.2

NH4+ (.) + OH-(.) > H2O + NH3 (.),


(.) . .
, NH4-N

80

NH +4

NH 3

60

60

40

40

% NH3NH 3
Percent


.
(NH4+-N) (NH3):

100

80

Percent NH +4

100

% +4
%NH

. , ,
,
.

pK = 9.25
20

20

6
7
8 9
10
11
.510-1:
12(NH3) 13

(NH4+)
pH pH.

. 10-1: (NH3)
(NH4+) pH

85

Figure 11-2: Principal process scheme of ammonia stripping


process.

Circulation air

Heat
exchange

NaOH
Washing
chemicali
(HCl)

Circulation
water
Ammonia
salt product

Heat
exchange
Reject water
before aeration

NH 3-air

. 10-2:

. ( > 10)

NH3 (. 10-1).

( ) , , .
,
. , .
( ) (. 10-2),

.

,
.

, ,


24 . ,
, 1520 .
,
, .

, ,

24 /7 .


.

, .
. -

.10-3: : shutterstock.com/Hansenn


Biovakka Oy
- . () . .
, . ,
. , .
.
.

86

10.3
. - (-),
, . , , , ,
.

10.3.1 -
- -.
.
( 40%), 60%
.

, . , , (Beier et al., 2008 .)


- , , SHARON, SAT PANDA.

10.3.2

-
.
.
, -
-
. -
,
( -
).
,
, -
.
. -

.

. -
-
DEMON Canon.
-
3040 25.
.

nitrogen
cycle

NH4

N2

Methanol

NO

1990 .
.
(Planctomycetes), ,
(N2),
.

O2
NO2

O2
50%

. 10-4:

: , c 100200 ,
210 .
. .
.
- ( 60%)
/, ,
.

87

PRETREATMENT

Balancing
tank

REJECT WATER TREATMENT

Primary
sedimentation

Reject water
treatment tank

Sludge recirculation

SECONDARY TREATMENT

Clarifier

Excess sludge

. 10-5: -


, :

30;

.

- (Sequential Batch Reactor, SBR),

BABE.

, ,

,
, .
,

. ,
.
-
.

, ,


12
. , , 1520 .
2040 ,
.
.



.
20%.
, ,
.

2005 . . () Lakeuden Etappi. . () ,
. ()
- -, . () ( 2009 .) . () SHARON. . - ,
2012 . , ,
SHARON.

88

10.4 :

. 10-1: . - = -

.
.



( ),

.

.

1,53 .

(,
).

,
.



.


1,53 .
.

.
.
3040C,

25 .


,
.
.


1 2 .
.

2040 .


(
).


,
.
.


2 4 .


.

, ,
, , .

89

11

. : Metshallitus

11.1
,
. , , . ,
, (), . , :
, , (), .
, ( P2O5,
) 5 2,5%,
(USGS, 2012 .).

, , ()
.
, ,

. , () (. . 11-1),
.
,
, ,
(PHchstMengV 1980 .
() EC 648/2004
). , ,
. :

, ;
;
;
.
(, (

2005 .) -
.
. (SEPA)
2015 .

60% (SEPA, 2002 .). 2003 . ,
-

Phosphate rock price chart

430

335

($/mt)

240

140

45

Sep-06

Mar-06

Sep-07

Mar-08

Sep-08

Mar-09

Sep-09

Mar-10

Sep--10

Mar-11

Sep-11

Mar-12

. 11-1: . : www.mongabay.com

91


< 0,5 / P
P: 45 %


20-100 / P
P: 45 %


10 / P
P: 50-60 %


64 / P
P: 80-90 %

. 11-2: (P), ( : Jardin,


2010 . Adam, 2009 .)

(CEEP, 2003 .). 2010 .


(MMM, 2011 .).
:

;
;
-
;

. 11-3: . : shutterstock.com/Kymmcleod

92

-
.
, , . (. . 11-2).

,
,
.
:
, .
,

. ,


.
,
,
, .

,
.

, ,
. , , .
, 11.2. : , , .

: ,
,
.

45% (Jardin, 2010 .),
5060% (Adam, 2009 .), 80% (Jardin,
2010 .) 90% (Adam, 2009 .).

. ,

( , , ). ,


(. 11.3).

11.2

, , . , , , (. . 11- 2).
.
,
, . (2009 .):

DHV Crystalactor (
Ca(OH)2 NaOH), .

( PRISA AirPrex);

. (), 1998 ., MA ( , ).
,

. AirPrex 20022009 ., 2010 .
. ,
(Lengemann, 2011 .).

( Ostara PEARL, Unitika


PHOSNIX, Darmstadt
DHV Crystalactor).
OSTARA
PEARL, Unitika PHOSNIX, AirPrex DHV Crystalactor
20 3/ 250 3/.
,

- .
,
.
, (Adam, 2009 .). , , ,
, , , .
90- . Geestmerambacht



(MgCl2)
(). 100 /, 23 (Lengemann, 2011 .).
Ostara PEARL
( Mg(OH)2 NaOH)
20 3/
2007 . . ().
. ( ) .
C ( ) (

93

2009 . 2010 . ).
. ( )
2010 . (Ostara, 2010 .). 500 /. Crystal Green

.
. , , 23 .
3 Unitika PHOSNIX
( Mg(OH)2 NaOH)
620 3/. ,
, .
, =8,5-8,8 (NaOH Mg(OH)2). ,
. . 0,5-1,0
.


.
, (Nawa, 2009 .).


, ,
. KREPRO, LOPROX,
Aqua Reci Seaborne/Gifhorn (Adam, 2009 .). ,
. ,
. 2010 . Seaborne/Gifhorn
( MgO, NaOH, Na2S,
H2SO4 ), . 7,5
(Bayerle, 2009 .).
Mephrec
, ,
(Adam, 2009 ., Scheidig, 2009 ., Petzet and Cornel, 2011
.).
2000oC
,
. . ,
.

. 11-4:
. : shutterstock.com/Singkham

94

11.3
, (. 8 9), ,
. ,
. .
, , , .
.
.


:
, -
(,
RecoPhos);
, -
, (
: PASH, BioCon; -
AshDec Mephrec (Petzet
and Cornel, 2010 .).
, ,
, ,
,
35 (Hermann, 2012 .). ,
,
Thermphos International B.V. Ash-Dec


(Hermann, 2012 .).
1000
-

.
. ( Outotec)
.

, , SEPHOS, PASCH
BioCon, , Thermophos,
( .
Adam, 2009 .).

,
(Scheidig et al., 2009 .).
, , , ,
.

. ,
, .

.

11.4 :


, , .
,
, , .
, ,

.
, .
. 11-5:
, , ,
. :
,

95

12.


. : ,

-
. . ,
, ,
. ,
.

12.1

-
,
. , , ,
-
. (
,
, , ),

.
,
.
-
, . ,
, , ,
.
-

, 1 2011 .
( , ):

. 12-1:
- .
: shutterstock.com/Pedro Miguel Sousa

1. 12 1986 . , , ,
(86/278/EEC)
2. 21 1991 . (91/271/EEC)

3. 12 1991 .
(91/676/)
4. 26 1999 . (1999/31/EC)
5. 4 2000 . (2000/76/
EC)

97

6. 3 2000 , 94/3/EC,
1() 75/442/EEC , 94/904/,
1 (4) 91/689/EEC
(2000/532/)
7. 27 2001 .
(2001/77/EC)

8. (EC) 13 2003 .
(2003/2003)
9. 19 2008 . , (2008/98/EC)
10. 16 2008 .
, 82/176/
EEC, 83/513/EEC, 84/156/EEC, 84/491/EEC, 86/280/EEC, 2000/60/EC
(2008/105/EC) ,
.
,
.

(86/278/EEC).

(2008/98/EC)
- ,
,
, ,
-

. 4
,
,
, , , ,
.

, .


(, ,
) , 2000/532/EC1.
, ,
, , , . ,
. ,
, , , ,
, ,
. , , (, ).

- 12 2010 .
- .


(91/271/)
, ,

. 14 , ,
,
, .
, 2001 . ;
1 2002 .

. 12-2:
.
: - , Entsorgungsbetriebe Lbeck

98

, 1 1999 .
- 31 2005 .

.
16 ,
2 (
). -
30 1993 2.

(86/278/
EEC)
, , 3
,
. - ,

. ,
2(b) ,
: ,
, ,

.
, .
()
,
.
4. ,
, ( ). IIA
IIB (
, -

): ,
.
: , , , ,
.


,
- . ,
, .
.
10 -
,
, ,
- ,

.

. - 3
(. . 12
1989 .) 3
.

(1999/31/EC)
, , ,
.

,

(///),
, ,
, .
,

, , ,
. , , ,
- .

,
2003/2003 .

, -

, .

99

( )
.
(
).
, ; , 2(h),
, ( ),
, .
, ,
- 2003 . (
, ,
) , ,
/
. :
2006 .
,
1995 ., 75%;
2009 . 50%;
2012 . 35%.
3 . -

- , , 2 , . . 16 2001 .

(91/676/EEC) ,

(2008/105/EC)

. - ,
. ,
,
.
75/440/EEC ,
- .
,
, (
).
, ,
33
,
. ,
, (), ,
(), , ,

86/278/EC (, , ,
,
) 8 , , (--) .
, ,
, ,
. 75/440/EEC
,
- .

(2000/76/
) (2001/77/EC)
. 12-3:

- .
: shutterstock.com/Chepko Danil Vitalevich

100

, ,

. ,
, , , () , , ( ),
.
, , .
-

. 28 2005 .
, ,
,
28 2002 .

, , ,
, , .
,
. ,
(2001/77/EC).


, REACH
(Registration, Evaluation, Authorisation and Restriction of
Chemicals) , , , ,
, , , . ,
,
. (European
Chemicals Agency, ECHA)
2010 . ,
REACH5.
, -

, .
6(1) 6(2) , ,
, , :
 ) -
;
 )
;
 )
-
-
, ,

 )
-

.
,
,
, (CEN)
1993 . 308
(TC308). CEN TC 308

.
.
ISO/TC190
, CEN/TC223
CEN/TC292 .



. 3-
( 2000 .)
. (1) ()
(2) ,
,
.
()
- , ,

. ,
, . ,
, .
, .
REACH.

101

,
, , ,
, , , , . ,
, ,


, . ,
,
.

1) ( )

;

, 3-

; , .
,
.

,
,

. , :
( ), , , ,

.

2010 .
, , , ,
,
, , . ,
3- .
:

2) ,

,
;
3) ,

.

,
, .
2011 .

12.2

- . : 1) , , , ; 2)
; 3) , , .
:

;
- -
:
-- ;

102

--
;
--
,
;
--
(,
) ;

--,
;


,

, ,
.
( ).

--
.
-
, ,
, , ,
;
, -
.

12.2.1
. 12-1: ,
, , .

, ,
.

( )

Cd

Cr

Cu

( )

300

600

100

( )

100

600

2,5

( )

0,8

100

1000

( )

10 (5)*

900

86/278 ( )

2040

( , pH>5,8
(
5,5))
( )
( )
( )
86/278 ( ,
pH 67)

Zn

As

150

1500

50

100

800

0.8

30

120

4000

25

800

200

900

1000
1 750

1625

300400

750
1 200

2500
(2000)*
2 500
4 000

0,5

200

100

0,2

60

60

150

0,4
0,5
1,5
(1)*

60
30

40
40

0.3
0.5

30
15

40
40

100

60

50

100

100150
100
200
(150)*

50140

11.5

3075

50300 150300

13

Hg
Ni
Pb
/

//
(
)

1,5

300

600

100

100

1500

( )

1,75

100

600

2,5

50

100

800

( )

( )

86/278 ( )

150

12000

100

3000

15000

30000

* <5% pH 56

103

.12-2: , ,
(--- = )

,
,

---

---

, ,
,

,

---

---

104

(
(
(
)
( )
)

)

,
,

---

(),
Salmo
nella;
() (9),

(),
100 1

()

---

(AOX),

() (6),

()/

()

---

---

-
, ,

,



,
(



)


, ,
( - ( ,
)
)
/

. P:



NH4-N:
150 /
1

7 /
1

5 /
3

: 12
,
4
:

: 1, 4 12

:
3
,

:

:
,
2 ,
:
, 10



,

+

SEPA

,

.
:


2005
. :

---

2005 .



5%

: 12
-


:
(


)



(86/278/EEC)


(1999/31/EC)

(2000/76/EC)

105

12.2.2
. 12-3: , ,


( )

( (
)
)


(
)


/
, , - <1000
; ,
2 1

---

,
,
, , ,
100C

---

---

,
,
,

, III
C

Escherichia coli, Clostridium


perfringens, , 6

---

+ , , ,

EC

Salmonella

, -
, ,


, - (


100 ,
,

---

---

---

,
, 3 .

106

(
)


(
)

---

: 2, 4, 6 12

, 4, 3, 2, 1

:
+ 5

. P:
40 / 1
, NH4-N:
30 / 1

.
P: 40 / 1
, N:

: 1, 2, 3, 4 12

:

,
, ,

,

,
;
.

---




:
+ . ;


: --


: (
,
)

:

,
170 / - ,
,

1 -
:
--
+
100 //

3 /
1

: 1, 4 12

S: 2, 3 6

:

,

,
: ( )
, , - + ,
15 //

: ---

: 1-2
:
-


(86/278/EEC)


(1999/31/EC)

(2000/76/EC)

107

. 12-4: , ,

(
)

Cd

Cr

Cu

( )

20

1000

1000

16

( )

10

600

800

140/400

( : I 1,5/20
/II )

Hg
Ni
/

Pb

Zn

As

300

750

2500

10

200

500

2500

75/1000

1/8

50/300

140/750

300/2 500

( )

20

1000

500

16

300

750

2500

86/278 (
)

2040

10001750

1625

300400

7501200

25004000

( )

100

50

1,5

50

100

300

( )*

0,50,9

4090

1570

0.1-0.5

1570

2040

50100

( : ,
/,
)

1/1.5

50/80

50/80

0.6/1.0

50/60

50/80

160/260

( : //)

1/2/3

50/75/100

40/60/80

80/120/180

86/278 (
, 6<pH<7)

13

25/50/75 0,8/1,2/1,5 20/35/50


50140

11,5

3075

50300

150300

//
( )

150

( :
30/35
,
/,
)
(
:
, 100/150
/,
)

4500

12000

100

3000

15000

30000

600/700

1 000/1200

8/10

250/300

300/350

5 000/6000

7 000/
10 000

8 000/
12 000

50/100

2 000/
3 000

10 000/
15 000

20 000/
30 000

30000

( )
86/278
( )

150

12000

100

3000

15000

* ( /
, / ) pH (56; 6,17 >7),
6 .
( / pH 56) ( / pH >7).

108

12.2.3
. 12-5:

. ,

( )

Cd

Cr

Cu

Hg

Ni

Pb

Zn

As

( : I/ II)

15/30

500/1 000

750/
15 000

7,5/15

200/ 400

250/500

1 750/
3 500

42131


86/278 ( )

2040

10001750

1625

300400

7501 200

2500
4 000

6**

3*

2.1

4*

32/6*

23*

( /
)

0,5/2

33/132

20/80

32/130

55/220

55/10


86/278 ( ,
pH 6-7)

13

50140

11.5

3075

50300

150300

( ,
pH>5,5)

//
(
)

86/278 ( )

150

12000

100

3000

15000

30000

*
** Cr (III)

109

110

* I / II

,
, ,
,


(
)
(
)

( )

---

---

,
,


: ---

/
, ,
,

: 12
:


-

-
( (1999/31/EC)


(86/278/



EEC)

(2000/76/EC)

. N
- 300 /

1 ; .
Escherichia coli

:


>100/1000*,
>20%,
Salmonella, N>0,6% :
:
- 10 /

,

P2O5 >1,5%




5 ,


- 7 /


( ( (


- ( )
) )
)

, ,
,
, ,

. 12-6:
(N = )

12.3
-
: ; - , ;
. :
. ,
() .
- , ,
,
-
, -
, , ,

. ,
.
,
, .
.

.
, ,
.
,
, , , ,

. , . ,

.

.
, , , , -
, ,
,

(CEN).

. 12-4: : ,


, . :
;
-
;
,
;
-
.
,
.
, ,
. ,
.
, , , , ,
,
, ,
.

111

,

.
,
, , , , ,
.

( ),
, . ,
(7 / 1 , 5 /
3 3 /
1 ).
.

(
) (10 / 5 7 / 3 ).
,
, , ,
. , , ,

,
(, ,
- ), - ,
.
, , ,

,
. ,

(
). - , 15 1 .

, , ,
,
, ,
. .

.
, .

. 12-5: . :
shutterstock.com/Gerard Koudenburg

112

13.



, .
: , .

, , , ..
. , -
, ,
.

13.1

50%
, (Starberg et al., 2005 .).
,
( . 5.7).

,

.

(Barber,
2009 .).
,
,
, :
,
,
(Arnold,
2010 .).

,
. ,
; ,

(Arnold, 2010 .).
, ,
. ,
. , Ultrawaves GmbH,
. ()
1,5,
(Nickel, 2011 .).

, , , .
, . , ,
.


. , , ,

,
,

114

- , ,
.

. 13-1: : shutterstock.com/Hraska

13.2

, . , .
, , . .
,
- , , ,
.

20 . ,
,
,
. ,
,
, (. 9 11).
, , - ,
.
.
, ,
,

.

. , , , .
, (, ) (
). ,


.
- , , ,
, (Aubain et al., 2002 .). ,
(, , ), .

, .
, ,
, (WEA),

. WEA

(Control
of hazardous substances in the Baltic Sea region,
COHIBA)(Nakari et al., 2011 .).
(Monitoring and Assessment Group,
MONAS)(HELCOM MONAS, 2011 .). EUREAU
WEA

, ..

.

115

WEA

.
COHIBA
(Mathan et al., 2012 .).
, ,
, , ,

.


(Aubain et al., 2002 .).


,
,
. ,
, , (. 12).
, ,
, , ,
. ,
.

13.3
, , . 7080-. XX . ,
, .
, . .
1950. 2000.
, 75%(UNEP,
2011 .). . ,
.
, ,
90%. ,
,
.
. 80% .
, ,

. ,

(Schrder et al., 2011 .).
, , ,

116

.

( )
(); (EEA, 2011 .).
40%
(Milieu, 2008 .),
, ,
(Schrder et al., 2011 .).
(Common Agriculture Policy, CAP) . ,

, . ,

,
.

(. 11). , ,
-


, , . , , ,
(Schrder et al., 2011 .). , , ,
, ,
,
.
,
( ,
,
, , ) -
. , , .
,
, , , , , .

:
80% ,
30% ,

50% (Milieu et al., 2008 .).



, ,

10%. ,

. .
, , - , ,
, , .

.
, ,
, ,
(Schrder, 2011 .).
(.11.1), , 2015 .
60%.
ICL Fertilizers
Europe 1015%(SCOPE,
2012 .; ICL Fertilizers Europe, 2012 .).

. 13-2: :

117

13.4 -


, , , ,
(. 12).
.
, . 1999
. ,
. , ,
.


. ,
: ,
,
,

.

, , , ,
, , . ,
-

. 13-3: : shutterstock.com

118

/ . ,
,
, , , .


. 3- (2000 .)
.

() , . 2010 . , ,
, 3- .
() , ,
,
, .
,
, . , , .
,
, , , ( ) .

,
, . , ( ),
,
.

13.5

, . , ()
.
, , .
, .

.
. 1980- .
260
, 120 7.
, (. 1.2),
,

, .
, ,
,
.
,
, ,
, .
,
. , -

.
25%
( , 2010 .).
, ,
(, ).

. 13-4: : ,

.
2007 . 28E/7
(, 2007 .)
. 2011 .

8 2013 . ,
2017 .
,
.
, ,
, , .
.
,
2015 .
2000 .,
(Blueprint Safeguard Europes Water).
2012 . -

http://www.helcom.fi/Recommendations/en_GB/front/

8 () 259/2012 14 2012 .,
(EC) 648/2004
(, ).
9

http://ec.europa.eu/environment/waste/framework/end_of_waste.htm

119

(
), (EC, 2012 .).

- EUREAU (EUREAU, 2012 .).
, ,
. , EUREAU,
-
. ,

. 13-5: : ,

120

,
. EUREAU
,
,
,
,

, , , .
.

9 ( ), , .

14.
Adam, C. 2009. Techniques for P-recovery from wastewater, sewage sludge and sewage sludge ashes an overview. In
BALTIC 21. Seminar on Phosphorus recycling and good agricultural management practice. 29.30.9.2009. Berlin.
Arnold, M. 2010. Is waste water our new asset? VTT Impulse 2/2010. http://www.digipaper.fi/vtt_impulse/56725/
ATV-DVWK-A 131E 2000. Dimensioning of Single-Stage Activated Sludge Plants, German water and waste water
association ( ATV-DVWK, DWA). . http://www.dwa.de,

ISBN 978-3-935669-96-2, 2000.

ATV-DVWK-M 368E 2003. Biological Stabilisation of Sewage Sludge, German water and waste water association
( ATV-DVWK, DWA). .

http://www.dwa.de, ISBN 978-3-937758-71-8, 2003.

Aubain, P., Gazzo, A., le Moux, J., Mugnier, E. 2002. Disposal and recycling routes for sewage sludge. Synthesis
report 22 February 2002. Arthur Andersen, EC DG Environment B/2.

http://ec.europa.eu/environment/waste/sludge/pdf/synthesisreport020222.pdf

Barber, W. P. F. 2009. Influence of anaerobic digestion on the carbon footprint of various sewage sludge treatment
options. Water and Environment Journal 23: 170-179.
Barjenbruch, M., Berbig C., Ilian J., Bergmann M. 2011. Sewage sludge dewatering without flocculant aid.
(Schlammentwsserung ohne Flockungshilfsmittel). WWT-online.de 10/2011.

http://www.wwt-online.de/sites/wwt-online.de/files/schlammentw%C3%A4sserung_ohne_
flockungshilfsmittel.pdf, 30.5.2012 ( ).

Bayerle, N. 2009. Phosphorus recycling in Gifhorn with a modified Seaborne process. (P-Recycling in Gifhorn mit dem
modifizierten SeaborneProzess). Proceedings of BALTIC 21 Phosphorus Recycling and Good Agricultural Management
Practice, 28.30.9.2009. Berlin ( ).
Beier M., Sander M., Schneider Y., Rosenwinkel K.-H. 2008. Energy-efficient nitrogen removal. (Energieeffiziente
Stickstoffelimination). DWA, KA, 55 2008 ( ).
Bergs C.-G. 2010. New demand by sewage sludge and fertiliser regulation. (Neue Vorgaben fr Klrschlamm nach der
Klrschlamm-(AbfKlrV) und Dngemittelverordnung (DMV)). VKU Infotag Klrschlamm, 9.11.2010 (
).
Berliner Wasserbetriebe 2012. http://www.bwb.de/content/language2/html/4951.php,
22.5.2012.
BIOPROS 2008. Short rotation plantations. Guidelines for efficient biomass production with the safe application of
wastewater and sewage sludge. . www.biopros.info, l 18.9.2012.
BMBF&BMU 2005. http://www.phosphorrecycling.de, 20.09.2012
Brendler, D. 2006. Use of the KEMICOND-Method with chamber filter presses Results;. (Einsatz des KEMICONDVerfahrens auf Kammerfilterpressen Ergebnisse aus der Praxis). Der Kemwaterspiegel 2006, http://www.kemira.

com/regions/germany/SiteCollectionDocuments/Brosch%C3%BCren%20Water/Wasserspiegel%202006.
pdf. ( ).

Burton, F.L , Stancel H.D.,. Tchobangoulos, G. 2003. Wastewater engineering, treatment and reuse. Metcalf and Eddy
Inc, 4th edition. McGraw Hill.
CEEP 2003. SCOPE Newsletter # 50. http://www.ceep-phosphates.org/Files/Newsletter/scope50.pdf. Centre
Europen dEtudes des Polyphosphates.
CEEP 2012. SCOPE Newsletter # 84. http://www.ceep-phosphates.org/Files/Newsletter/ScopeNewsletter84.
pdf. Centre Europen dEtudes des Polyphosphates.
DWA-M 366DRAFT 2011. Mechanical dewatering of sewage sludge. (Maschinelle Schlammentwsserung). Entwurf
German water and waste water association (DWA). . http://www.dwa.de, ISBN 978-3-942964-05-0, 2011. ( ).

121

DWA-M 381E 2007. Sewage sludge thickening, German water and waste water association (DWA),
http://www.dwa.de, ISBN 978-3-941897-43-4, 2007.
Ener-G. About Digester Gas Utilisation. http://www.energ.co.uk/about-digester-gas-utilisation
Einfeldt, J. 2011. Sludge handling in small and mid-size treatment plants. PURE workshop on sustainable sludge
handling. Lbeck 7.9.2011. . http://www.purebalticsea.eu/index.php/pure:presentations_from.
European Commission, DG Environment 2011. Conclusions of the Expert Seminar on the sustainability of
phosphorus resources, 17 2011 . .

http://ec.europa.eu/environment/natres/pdf/conclusions_17_02_2011.pdf

European Commission, DG Environment 2012. A Blueprint to safeguard Europes Waters.

http://ec.europa.eu/environment/water/blueprint/index_en.htm,
http://ec.europa.eu/environment/water/pdf/blueprint_leaflet.pdf.

European Environment Agency EEA 2011. Resource efficiency in Europe Policies and approaches in 31 EEA
member and cooperating countries. EEA Report 5/2011.
European Federation of National Associations of Water and Waste Water Services EUREAU 2012. EUREAU
position on the Water Blueprint.

http://eureau.org/sites/eureau.org/files/documents/2012.02.28-EUREAU_PP_Blueprint.pdf
Guyer, J.P. 2011. An introduction to Sludge Handling, Treatment and Disposal. CED Engineering.
Hammer, M.J. and Hammer, M.J. Jr 2001. Water and Waste water technology.

HELCOM 2007. Recommendation 28E/5. Municipal wastewater treatment. Helsinki Commission, HELCOM Baltic Sea
Action Plan, Helsinki. http://www.helcom.fi/Recommendations/en_GB/rec28E_5/
HELCOM 2007. Recommendation 28E/7. Measures aimed at the substitution of polyphosphates (phosphorus) in
detergents. Helsinki Commission, HELCOM Baltic Sea Action Plan, Helsinki.

http://www.helcom.fi/Recommendations/en_GB/rec28E_7/

HELCOM 2011. Monitoring and Assessment Group (MONAS), Meeting 15/2011, 4-7 October 2011. Document 6/4
Application of Whole Effluent Assessment in the Baltic Sea region (COHIBA Project), Document 13/1 Minutes of
the 15th Meeting of the HELCOM Monitoring and Assessment Group (HELCOM MONAS). C. http://meeting.

helcom.fi/web/monas/1.

Hermann, L. (Outotec Oyj, Oberusel) 2012. , .


ICL Fertilizers 2012. http://www.iclfertilizers.com/fertilizers/Amfert/pages/environment.aspx. 10.9.2012.
Ilian J. 2011. Sewage sludge dewatering with the Rotations-Filtertechnik. (Klrschlammentwsserung durch RotationsFiltertechnik)., Sewage sludge forum, Rostock, 17.11.2011 ( ).
Jardin, N. 2011. P-Recovery out of sewage sludge and sewage sludge ashes-Status of development (Phosphorrckgewinnung
aus Klrschlamm und Klrschlammasche Stand der Entwicklung). Ruhrverband, DWA Klrschlammtage Fulda,
30.3.2011. ( ).
Kopp, J. 2010. Properties of Sewage sludge. (Eigenschaften von Klrschlmmen). Presentation on the VDI conference,
2010. ( ).
La Cour Jansen J, Gruvberger C, Hanner N, Aspegren H and A. Svrd 2004. Digestion of sludge and organic waste
in the sustainability concept for Malm, Sweden. Water SciTechnol. 2004; 49(10): 163-9.
Lengemann, A. 2011. Berliner Wasserbetriebe, MAP Recovery example: from a problem to marketing. (MAP Recycling
am Beispiel von einem Problem bis zur Vermarktung), Klrschlammforum Rostock, 17.11.2011. ( ).
Machnicka, A., Grbel, K., Suschka, J. 2009. The use of hydrodynamic disintegration as a means to improve
anaerobic digestion of activated sludge. Water SA Vol. 35 No. 1 January 2009. . http://www.wrc.org.za/.
Mathan, C., Marscheider-Weidemann, F., Menger- Krug, E., Andersson, H., Dudutyte, Z., Heidemeier, J.,
Krupanek, J., Leisk, ., Mehtonen, J., Munne, P., Nielsen, U., Siewert, S., Stance, L., Tettenborn, F., Toropovs,
V., Westerdahl, J., Wickman, T., Zielonka, U. 2012. Recommendation report. Cost-effective management options to
reduce discharges, emissions and losses of hazardous substances. WP5 Final Report. Control of hazardous substances in

122

the Baltic Sea region COHIBA project. Federal Environment Agency of Germany (UBA). . http://www.cohiba-

project.net/publications/en_GB/publications/.

Milieu Ltd , WRc and Risk & Policy Analysts Ltd (RPA) 2008. Study on the environmental, economic and social
impacts of the use of sewage sludge on land, volume 2. DG ENV.G.4/ETU/2008/0076r.

http://ec.europa.eu/environment/waste/sludge/pdf/part_ii_report.pdf

MMM 2011. Suomesta ravinteiden kierrtyksen mallimaa. Tyryhmmuistio 2011:5. ISBN 978-952-453-6493, ISSN 1797-4011. Helsinki. http://www.mmm.fi/attachments/mmm/julkaisut/tyoryhmamuistiot/
newfolder_25/5xN59lPQI/trm2011_5.pdf. ( ).
www.mongabay.com, http://www.mongabay.com/images/commodities/charts/chart-phosphate.html, 22.5.2012.
Nakari, T., Schultz, E., Sainio, P., Munne, P., Bachor, A., Kaj, L., Madsen, K. B., Manusadianas, L., Mielzynska,
L., Parkman, H., Pockeviciute, D., Pllume, A., Strake, S., Volkov, E., Zielonka, U. 2011. Innovative approaches to
chemicals control of hazardous substances. WP3 Final report. Control of hazardous substances in the Baltic Sea region
COHIBA project. Finnish Environment Institute SYKE. . http://www.cohiba-project.net/publications/en_GB/
publications/.
Nawa, Y. 2009. P- recovery in Japan the PHOSNIX process. A Poster from BALTIC 21 Phosphorus Recycling and Good
Agricultural Management Practice, September 28- 30, 2009. http://www.jki.bund.de/fileadmin/dam_uploads/_
koordinierend/bs_naehrstofftage/baltic21/8_poster%20UNITIKA.pdf, 22.5.2012.
Nickel, K., Velten, S., Srensen, J., Neis, U. 2011. Sludge Disintegration: Improving Anaerobic and Aerobic
Degradation of Biomass on Wastewater Treatment Plants. Presentation at the PURE Workshop on sustainable sludge
handling. Lbeck 7.9.2011. . http://www.purebalticsea.eu/index.php/pure:presentations_from.
Nielsen, S. 2007. Sludge treatment in reed bed systems and recycling of sludge and environmental impact. Orbicon.
http://www.orbicon.com/media/UK_Artikel_Sludge_treatment_recycling_smn.pdf, last access 18.9.2012.
Ostara 2010. Ostara Group, Questions and answers. http://www.ostara.com/files/u2/Ostara_Q__A.pdf
Palfrey, R. 2011. Amendment of the EC sewage sludge directive (Novellierung der EG-Klrschlammrichtlinie
Folgenabschtzung), DWA Klrschlammtage Fulda, 29.3.2011. ( ).
Petzet, S., Cornel, P. 2011. Recovery of phosphorus from waste water. Presentation at the PURE-workshop in Lbeck.
7.9.2011. . http://www.purebalticsea.eu/index.php/pure:presentations_from.
Petzet S., Cornel, P. 2010. New ways of Phosphorus recovery out of Sewage sludge ashes (Neue Wege des
Phosphorrecyclings aus Klrschlammaschen). Technical University Darmstadt, DWA KA 4/2010. ( ).
PhchstMengV 1980. Verordnung ber Hchstmengen fr Phosphate in Wasch- und Reinigungsmitteln (Phosphathch
stmengenverordnung), 4.6.1980. ( ).
Scheidig, K. 2009. Prsentation und Diskussion des Mephrec-Verfahrens, 9. Gutachtersitzung zur BMBF/BMUFrderinitiative P-Recycling,

http://www.jki.bund.de/fileadmin/dam_uploads/_koordinierend/bs_naehrstofftage/baltic21/Scheidig.pdf,

30.9.2009, last access 14.8.2012. ( ).

Schmelz, K-Georg, 2011. Sludge handling in Bottrop. Presentation at the PURE Workshop on sustainable sludge
handling. Lbeck 7.9.2011. . http://www.purebalticsea.eu/index.php/pure:presentations_from.
Schillinger, H. 2006. Sewage sludge treatment by dehydratation and mineralisation in reed beds. International workshop
on Innovations in water conservation. 21.-23.2.2006. Tehran water and wastewater company, Iran. http://www.
rcuwm.org.ir/En/Events/Documents/Workshops/Articles/7/15.pdf, 18.9.2012.
Schrder, J.J., Cordell, D., Smit, A.L., Rosemarin, A. 2011. Sustainable Use of Phosphorus, EU Tender ENV.B.1/
ETU/2009/0025, Wagenigen UR Report 357.
SEPA 2002. Swedish Environmental Protection Agency (Naturvrdsverket). Action plan for recycling of phosphorus
from sewage. Main report to the good sludge and phosphorus cycles. (Aktionsplan fr terfring av fosfor ur avlopp.
Huvudrapport till bra slam och fosfor i kretslopp). Raport 5214. ( , ).
SNV 2003. Statens Naturvrdverk. Risk fr smittspridning via avloppslamm. SNV Rapport 5215. Stockholm. ( ).

123

Starberg, K., Karlsson, B., Larsson, J. E., Moraeus, P. & Lindberg, A. 2005. Problem och lsningar vid
processoptimering av rtkammardriften vid avloppsreningsverk. Svenskt Vatten AB. Svenskt Vatten Utveckling (SVU)
/ VA-forsk 2005-10. http://boffe.com/rapporter/Avlopp/Slam/VA-Forsk_2005-10.pdf. ( ).
Swedish Chemical Agency 2010. Phosphates in detergents. Questions and answers.
Umweltbundesamt 2009. Requierements of hygienisation for the amendment of the sewage sludge regulation
(Anforderungen an die Novellierung der Klrschlammverordnung unter besonderer Bercksichtigung von
Hygieneparametern) http://www.umweltdaten.de/publikationen/fpdf-l/3742.pdf. ( ).
UNEP Yearbook 2011. Emerging issues in our global environment, Phosphorus and food production.

http://www.unep.org/yearbook/2011

US Geological Survey (USGS) 2012. Annual Publications about Mineral Commodity Summaries Phosphate Rock,
http://minerals.usgs.gov/minerals/pubs/commodity/phosphate_rock/mcs-2012-phosp.pdf, 22.5.2012.
Vesilind, P. Aarne 2003. Wastewater Treatment Plant Design. Water Environment Federation.
Walley, P. 2007. Optimising thermal hydrolysis for reliable high digester solids: loading and performance, European
Biosolids and Organic Resources Conference, 2007, Aqua Enviro, Manchester, UK.
WHO 2003. Guidelines for the Safe Use of Wastewater and Excreta in Agriculture Microbial Risk Assessment Section by
S. A. Petterson & N. J. Ashbolt.
Xie, Xing, Ghani, Ooi and Ng, 2005. Ultrasonic disintegration technology in improving anaerobic digestion of sewage
sludge under tropic conditions, Paper Presented to 10th European Biosolids and Biowaste Conference, UK. November
2005.

124

. 2-1: ,
( , ,
- ) (Milieu, WRc RPA 2008 .)......................................................... 12
. 3-1:
(DWA-M 381E, 2007 .), (Burton, F.L et al., 2003 .)....................................................................... 20
. 3-2: .............................................................................. 27
. 3-3:
PURE .......................................................................................................................................................27
5-1:
PURE. BioP = ......................... 50
. 5-2: .............. 51
. 6-1: . (, , , ), (
UBA, 2009 .). ................................................................................................................................................64
. 6-2: ......................................................................................................................................................................65
. 7-1: ,
...................................................................................................................................................................72
. 8-1: ............................................. 78
. 9-1: /
(Palfrey, 2011 .)..............................................................................................................................................................81
. 10-1: . - = -.....................................................................................................................................................89
. 12-1: , , ,
.
, ,
....................................................................................................................................................................................103
.12-2: , ,
(--- = )........................................................................................................................................................................104
. 12-3: , ,
.......................... 106
. 12-4: , ,

.................................................................................................................................108
. 12-5: .
,
. ................................................................................................................................................................109
. 12-6: (N = )........................................... 108

125

www.purebalticsea.eu

The publication reflects the authors views and the Managing


Authority cannot be held liable for the information published
by the project partners.

126

You might also like