TIN HNH TH NGHIM NC THI DT NHUM

PHNG PHP : OXY HA (FENTON)

XC NH T L TI U GIA H2O2 & FE2SO4
Chun b:
Mu nc thi Xuyn sau sinh hc hiu kh
H2SO4 5%
H2O2 30%
Phn st 5%
NaOH 5%
Cch tin hnh
Ly 6 cc 400ml nc thi c c tnh sau:
mu:
795
pH
7.9
iu chnh pH = 3.5; ghi nhn lng acid cn s dng
C nh H2O2: 300g H2O2 30% /m3 nc thi
Cho phn st vo theo t l H2O2/Fe2SO4 (t l mol)
Cc
1
2
T l
1/3
1/2
H2O2 30%
0.12
0.12
Lng phn st 5% tng
ng, ml
21.22
14.15
Khuy 1 gi
Nng pH ln 7 , ri chm polymer
Lng lc , o mu
Kt qu

Cc
H2SO4 5%, ml
Polymer ,ml
NaOH, ml
mu,Pt-Co
mu,Pt-Co (lc)
% loi trc lc

2
2.8
0.5
2.75
1005
850
-26%

3
1/1
0.12
7.07

3
2.8
0.5
3.2
163
141
79%

2.8
0.5
2.4
107
91
87%

Sau khi c c t l ti u H2O2/Fe2SO4 l: 1: 1

KHO ST MU THEO T L TI U
PP
Tin hnh thay i nng H2O2 t : 200,300,400,500,600g/m3 v b tng ng
lng phn st theo t l trn v kt qu:
Ly 5 cc 400ml nc thi c :
mu:
942.5 Pt-Co
pH
7.65

Kt qu

Cc
H2O2 30% g/m3 nt
H2O2 30%, 400ml
Fe2SO4 5%

1"

Cc
H2SO4 5%, ml
NaOH 5%, ml
Polymer ,ml
mu,Pt-Co
mu,Pt-Co (lc)
% loi mu trc lc
% loi mu sau lc

1"

2"

300
0.12
7.07

2.85
2.4
0.5
97
70
90%
92.6%

Chn: s liu cc 2 tnh ton chi ph vn hnh

3"
400
0.16
9.43

2"

500
0.2
11.79
3"

2.85
2.92
0.5
72
58
92%
93.8%

2.85
3.4
0.5
79
61
92%
93.5%

O&M cost
Chemcial
H2SO4 98%
NaOH 99%
H2O2 30%
Fe II 98%
Polymer 99%
Sum (VND/m3)
Chemcial
H2SO4 98%
NaOH 99%
H2O2 30%
Fe II 98%
Polymer 99%
Sum (VND/m3)

Unit

Cc 2
0.3571
0.4040
0.3000
1.8043
0.0128
15,901

Cc 3
0.3571
0.3030
0.3000
0.9022
0.0128
11,371

Unit

Cc 1"
0.3635
0.3030
0.3000
0.9022
0.0128
11,393

Cc 2"
0.3635
0.3687
0.4000
1.2029
0.0128
14,061

kg
kg
kg
kg
kg

kg
kg
kg
kg
kg

PHNG PHP : CHT KH MU

Chun b:
Mu nc thi Xuyn sau sinh hc hiu kh
Cht kh mu
1: Vimin 10%
2: Vu Hoang 2%
Phn st 3%
NaOH 5%
Cch tin hnh
Ly 2 cc 200ml nc thi c c tnh sau:
mu:
1050
pH
7.4 nm trong khong pH thch hp 7-8
Cho 1.8ml phn st 3% vo khuy
Cho cht kh mu ln lt vo 2 cc : 0.6 ml
Chnh pH ln trn 8.5 -9
Chm 0.25ml polymer ,lng lc & o mu
Kt qu
Cc
1 - Vimin
2 - Vu Hoang
Fe II 3%
1.8
1.8
Kh mu
0.60
0.60
NaOH 5%
0.05
0.05
Polymer 1%
0.25
0.25
mu:
63
169

O&M cost
Cc
Fe II 98%
Kh mu Vimin
Kh mu V Hong
NaOH 99%
Polymer 99%
Total (VN/m3)

n v
kg
kg
kg
kg
kg

n gi

1 - Vimin
3,700
40,000
30,000
11,800
68,000

0.4
0.3

0.0
0.0
14,715

4
1/0.5
0.12

5
1/0.25

3.54

0.12

6
1/0.125
0.12

1.77

0.88

5
2.8
0.5
1.4
175
119
78%

6
2.8
0.5
1.35
225
151
72%

1'

2'
1.20

###

21.22

14.15

1'
2.8
0.5
1.25
336
300
58%

2'
2.8
0.5
5.5
35
39
96%
high H2O2

2.8
0.5
3.6
41
62
95%

 b tng ng

4"

600
0.24
14.15
4"
2.85
4.17
0.5
78
54
92%
94.3%

Cc 4
0.3571
0.1768
0.3000
0.4511
0.0128
8,212

Cc 5
0.3571
0.1705
0.3000
0.2255
0.0128
7,303

Cc 6
0.3571
0.1578
0.3000
0.1128
0.0128
6,737

Cc 3"
0.3635
0.4293
0.5000
1.5036
0.0128
16,669

Cc 4"
0.3635
0.5265
0.6000
1.8043
0.0128
19,709

Cc 1'
0.3571
0.6944
3.0000
2.7066
0.0128
43,726

Unit price
3,500
11,800
7,800
3,700
68,000

Cc 2'
0.3571
0.4545 H2O2
3.0000
1.8048
0.0128 day
37,559 pump
HCL

30%
30%

5%
30%
day
pump
Fe II

Hoang 2%

5%
30%

0.702

day
pump
Khu mu

hch hp 7-8

2%
100%

0.08
day
pump
NaOH
2 - Vu Hoang

l/m3

m3-kg/day
9
3.00

180

5%
30%

0.05

day
pump
Polymer
1%
100%

0.017
day
pump

1
1
6
250
0
0
67
0.67
27.91666667
9
5.4
0.54
3.24
135
3.00
3.00
0.06
10.80
450.00
0.25
0.25
0.04
1.50
62.5
1.25
1.25
0.0128
7.50
312.5

1 - Vimin

2 - Vu Hoang
0.4592
0.3000

0.459
0.060
0.013
0.013

0.0126
0.0128
4,515

3 Fe2SO4
100%
5%
0.4

:1
334
2652 g/m3
53,047 kg/m3
21.22 ml/400ml

2 Fe2SO4
100%
5%
0.4

:1
334
1768 g/m3
35,365 kg/m3
14.15 ml/400ml

1 Fe2SO4
100%
5%
0.4

100%

:1
334
442 g/m3

:1
334
221 g/m3
4,421 kg/m3
1.77 ml/400ml

0.125 Fe2SO4
100%
5%
0.4

H2O2
34 100lit
90

H2O2
34
90

:1

H2O2
34
90

H2O2

:1

34
90

H2O2

334
1179 g/m3
23,576 ml/m3
9.43 ml/400ml

1 Fe2SO4
100%

34
90

334
111 g/m3
2,210 ml/m3
0.88 ml/400ml

1 Fe2SO4
100%
5%
0.4

H2O2

8,841 kg/m3
3.54 ml/400ml

0.25 Fe2SO4
100%
5%
0.4

34
90

334
884 g/m3
17,682 ml/m3
7.07 ml/400ml

0.5 Fe2SO4

5%
0.4

:1

H2O2

:1

334
1474 g/m3

34
120

H2O2
34
150

5kg

5%
0.4

29,471 ml/m3
11.79 ml/400ml

1 Fe2SO4
100%
5%
0.4

:1

334
1768 g/m3
35,365 ml/m3
14.15 ml/400ml

H2O2
34
180

ml
l
l
m3
l/p
ml
l
kg
m3
l/p
ml
l
l
m3
l/p
ml
l
l
m3
l/p
ml
l
l
m3
l/p
ml
l
l
m3
l/p

1l
1 m3
1 m3
6000 m3
1l
1 m3
1 m3
6000 m3
1l
1 m3
1 m3
6000 m3
1l
1 m3
1 m3
6000 m3

10m3

10m3
3m3

1l
1 m3
1 m3
6000 m3

5m3

1l
1 m3
1 m3
6000 m3

5m3

bomdl tinh cho chat khu mau 5%