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    Arvina Beanitari
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    This document summarizes information about the MOR framework type. It provides idealized cell data showing it is orthorhombic with space group Cmcm and specific unit cell dimensions. It lists the coordination sequences and vertex symbols that define the topology. It describes the secondary building units that make up the framework as 5-membered rings. It provides examples of specific materials that exhibit the MOR framework type, including the key type material mordenite. It gives additional crystal chemical data for mordenite itself.

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    This document summarizes information about the MOR framework type. It provides idealized cell data showing it is orthorhombic with space group Cmcm and specific unit cell dimensions. It lists the coordination sequences and vertex symbols that define the topology. It describes the secondary building units that make up the framework as 5-membered rings. It provides examples of specific materials that exhibit the MOR framework type, including the key type material mordenite. It gives additional crystal chemical data for mordenite itself.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    52 views2 pages

    Mor PDF

    Uploaded by

    Arvina Beanitari
    This document summarizes information about the MOR framework type. It provides idealized cell data showing it is orthorhombic with space group Cmcm and specific unit cell dimensions. It lists the coordination sequences and vertex symbols that define the topology. It describes the secondary building units that make up the framework as 5-membered rings. It provides examples of specific materials that exhibit the MOR framework type, including the key type material mordenite. It gives additional crystal chemical data for mordenite itself.

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    © All Rights Reserved
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    of 2

    218

    MOR

    Cmcm
    Framework Type Data

    framework viewed along [001]


    Idealized cell data:

    orthorhombic, Cmcm, a = 18.3, b = 20.5, c = 7.5

    Coordination sequences and vertex symbols:


    T1 (16,1)
    T2 (16,1)
    T3 (8,m)
    T4 (8,m)

    4
    4
    4
    4

    12
    12
    11
    11

    Secondary building units:

    22
    20
    24
    24

    38
    37
    39
    39

    60
    64
    54
    60

    88
    87
    86
    92

    115
    114
    126
    122

    155
    154
    156
    148

    204
    198
    195
    195

    242
    241
    242
    250

    5-1

    Composite building units:


    mor

    Materials with this framework type:


    *Mordenite(1)
    [Ga-Si-O]-MOR(2)
    Ca-Q(3)
    LZ-211(4)

    Large port mordenite(5)


    Maricopaite (interrupted framework)(6)
    Mordenite, USA(7)
    Na-D(8)

    55552812
    5555258
    452582582
    4525858

    219

    MOR

    Type Material: Mordenite


    Type Material Data
    Crystal chemical data:

    |Na8 (H2 O)24| [Al8Si40O96]-MOR


    orthorhombic, Cmcm, a = 18.1, b = 20.5, c = 7.5 (1)

    Framework density:

    17.2 T/10003

    Channels:

    [001] 12 6.5 x 7.0*  [001] 8 2.6 x 5.7***

    12-ring viewed along [001]

    limiting 8 ring along [001]


    between 12-ring channels

    References:
    (1)
    (2)
    (3)
    (4)
    (5)
    (6)
    (7)
    (8)

    Meier, W.M. Z. Kristallogr., 115, 439-450 (1961)


    Eapen, M.J., Reddy, K.S.N., Joshi, P.N. and Shiralkar, V.P. J. Incl. Phenom., 14, 119-129 (1992)
    Koizumi, M. and Roy, R. J. Geol., 68, 41-53 (1960)
    Breck, D.W. and Skeels, G.W. U.S. Patent 4,503,023 (1985)
    Sand, L.B. Molecular Sieves, pp. 71-77 (1968)
    Rouse, R.C. and Peacor, D.R. Am. Mineral., 79, 175-184 (1994)
    Gramlich, V. Ph.D. Thesis, ETH, Zrich, Switzerland (1971)
    Barrer, R.M. and White, E.A.D. J. Chem. Soc., 1561-1571 (1952)

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