Basis : 100 mol

CH4 20%

conversion 90% of the limiting reactant

O2 60%
CO2 20%
Tinput
CH4

= 350 C

O2

= 1200 C

CO2

= 1200 C

Toutput
CH4

= 2000 C

O2

= 2000 C

CO2

= 2000 C

H2O

= 2000 C

CH4

2 O2

CO2

2 H2O

20 mol

60 mol

20 mol

18 mol

36 mol

18 mol

36 mol

2 mol

24 mol

38 mol

36 mol

mol CH4 (input)

= 20% 100 mol

= 20 mol

mol CH4 yang bereaksi

= 20 mol 90%
= 18 mol

mol CH4 (output)

= 20 mol 18 mol
= 2 mol

mol O2 ( input)

= 60% 100 mol

= 60 mol

mol O2 yang bereaksi

= 2 mol CH4 yang bereaksi

= 2 18 mol
= 36 mol

mol O2 (output)

= 60 mol 36 mol
= 24 mol

mol CO2 ( input)

= 20% 100 mol

= 20 mol

mol CO2 yang terbentuk

= 1 mol CH4 yang bereaksi

= 18 mol

mol CO2 ( output )

= 20 mol + 18 mol
= 38 mol

mol H2O ( input)

=0

mol H2O yang terbentuk

= 2 mol CH4 yang bereaksi

= 2 18 mol
= 36 mol

mol H2O ( output )

= 36 mol

Input:
35

H CH4 350 C

= mol CH4 (input)

Cp dT
25

35
2
5 2
9 3
= 20 mol 34,31+5,469 10 T +0,3661 10 T 11,00 10 T
25

= 20 mol [34,31 T +5,469 102

T2
T3
T4
+0,3661 105 11,00 109 ] 35
2
3
4 25

34,31(3525)+5,469 102

(3525)2
(3525)3
(3525)4
+0,3661 105
11,00 109
2
3
4
20 mol

]
=
20 mol [34,31 10+5,469 102
=

20 mol

100
1000
10000
+0,3661 105
11,00 109
]
2
3
4

( 343,1+2,7345+1,22 1032,75 105 ) J

mol

20 mol 345,84

0,346

kJ
mol

J
mol

20 mol

= 6,92 kJ
H O2 1200 C

= mol O2 ( input) [95Cp(1200C)]

= 60 mol Cp(1200C)[1200C 250C]
=

J
mol 0C )(950C)
60 mol

29,904

= 60 mol 2840,88
= 2,841

kJ
mol

J
mol

60 mol

= 170,46 kJ
H CO2 1200 C

= mol CO2 ( input) [95Cp(1200C)]

= 20 mol Cp(1200C)[1200C 250C]
=

J
mol 0C )(950C)
20 mol

38,994

J
mol )
20 mol

3704,43

= 3,704

kJ
mol

20 mol

= 74,08 kJ
Output :
200

H CH

0
4 200 C

= mol CH 4( output) Cp dT
25

200

= 2 mol

34,31+5,469 102 T + 0,3661 105 T 211,00 109 T 3

25

= 2 mol[34,31T +5,469 102

T2
T3
T4
+0,3661 105 11,00 109 ] 200
2
3
4 25

=
2

(20025)
( 20025)
(20025)
34,31(20025)+5,469 10
+0,3661 105
11,00109
2
3
4
2 mol
2

]
=
2 mol[34,31 175+5,469 102

30625
5359375
937890625
+0,3661 105
11,00109
]
2
3
4

( 6004,25+873,441+6,5402,579 ) J
mol

2 mol

2 mol 6881,652

2 mol 6,882

J
mol

kJ
mol

= 13,764 kJ
H O2 2000 C

= mol O2(output) [175Cp(2000C)]

= 24 mol Cp(2000C)[2000C 250C]
=

J
mol 0 C )(1750C)
24 mol

30,32

= 24 mol 5306
= 5,306

kJ
mol

J
mol

24 mol

= 127,344 kJ
H CO2 2000 C

= mol CO2 ( output ) [175Cp(2000C)]

= 38 mol Cp(2000C)[2000C 250C]
=

J
mol 0C )(950C)
38 mol

40,45

J
mol )
38 mol

7078,75

= 38 mol 7,079

kJ
mol

= 269,002 kJ
H H2O 2000 C

= mol H2O ( output ) [175Cp(2000C)]

= 36 mol Cp(2000C)[2000C 250C]
=

J
mol 0C )(950C)
36 mol

34,34

J
mol )
36 mol

3262,3

= 36 mol 3,2623

kJ
mol

= 117,443 kJ
0r

= 0f produk - 0freaktan
= 1(0fCO2) + 2(0f H2O) [1(0fCH4) + 2(0f O2)]
= - 393,5 kJ/mol + ( -483,66 kJ/mol) [ -74,85 kJ/mol + 0]
= -802,31 kJ/mol

n AR
0r
VA

+ H H
outlet

inlet

= 18 mol (-802,31 kJ/mol) + (13,764 kJ )+ 127,344 kJ +

269,002 kJ +117,443 kJ

(6,92 kJ + 170,46 kJ +74,08 kJ

= -14441,58 kJ + 276,08 kJ
= -14165,5 kJ
Komponen

INPUT
n( mol)

Cp dT
25

CH4
O2
CO2
H2O

20
60
20
100

(kJ/mol)
0,346
2,841
3,704
6,909

Q=H

OUTPUT
n( mol)

(kJ)
6,92
170,46
74,08
251,46

Cp dT

Q=H (kJ)

25

2
24
38
36
100

(kJ/mol)
6,882
5,306
7,079
3,2623
22,5293

13,764
127,344
269,002
117,43
527,54