STK 2023 Physical Chemistry 2

Sem II (2014/2015)
Individual Assignment 2
INSTRUCTION: Submit answers for ALL questions.
Q.1. Enthalpies of formation of CO(g), CO 2(g) , N2O(g) and N2O4 (g) are -110
kJmol-1, -393 kJmol-1, 81 kJmol-1 and 9.7 kJmol-1 respectively. Find the rH for the
reation:
N 2O4 (g) + 3 CO (g) N2O(g) + 3 CO2(g)
Q.2. Calculate the entropy change in surroundings when 1.00 mol of H 2O (l) is
formed under standard conditions, fH = -286 kJmol-1
Q.3. At what T, the following reaction will be spontaneous?
Br2(l) Br2(g)
Where, H = 30.91 kJ/mol, S = 93.2 J/mol.K
Q.4. Calculate the standard reaction Gibbs energy for the following reaction. Is
this reaction spontaneous under standard conditions?
4KClO3(s) 3KClO4(s)+KCl(s)
KClO3(s)
KClO4(s)
KCl(s)

H(kJ/mol)
-397.7
-432.8
-436.7

S (J/mol.K)
143.1
151.0
82.6

Q.5. In a process, 701 J of heat is absorbed by a system and 394 J of work is done
by the system. What is the change in internal energy for the process?
Q.6. The reaction of cyanamide, NH2CN(s), with dioxygen was carried out in a
bomb calorimeter, and U was found to be -742.7 kJmol -1 at 298 K. Calculate
enthalpy change for the reaction at 298 K.
NH2CN(s) + 3/2 O2 (g) N2 (g) + CO2 (g) + H2O (l)