Complete Energy BALANCE

CHAPTER 6
ENERGY BALANCE
6.1 Introduction
The concept of energy conservation as stated by the energy balance equationis a middle of
chemical engineering calculations. Just as mass balances are reviewed before, the energy
balance is essential to solve many problems.
6.2 Equations Used in Calculations
6.2.1 General Equations
Q Ws = H + Ek + Ep
(6.1)
The system kinetic energy associated with motion is directed such as straight line motion and
rotation system. The potential energy of the system is due to the state of the object of mass at
a certain height. However, we can ignore the kinetic energy, potential energy, and work
for our system because it is static (Ek = 0), no change in height (Ep = 0), and no
work on our system (Ws = 0). Thus Equation 6.1 can be further reduced to as Equation 6.2.
Q = H = Hout Hin
(6.2)
6.2.2 Equation for Reactive Process
H = Outlet ni ( i + f ) - Inlet ni (i + f)
(6.3)
6.2.3 Equation for Process with Phase Changes
6.2.4 Equation for Non-Reactive
6.2.5 Equation for Heat Capacity, Cp
6.2.6 Total Heat for Energy Balance (non-reactive process)

HTotal = (HOutlet - HInlet)
(6.8)
6.2.7 Total Heat for Energy Balance (reactive process)
HTotal = r + (HOutlet - HInlet)
(6.9)
6.2.8 Equation Heat of Reaction
r = vf = products lvlf - reactants lvlf
(6.10)
6.2.9 Equations Used in Calculation

Table 6.1 The Phase, Temperature and Pressure Change for i Component in Each Stream.
Heat Capacity of Gas

The correlation for the heat capacity of gas is a series expansion in temperature:
Cp=A+BT+C T2 + D T 3 + E T 4
Where
( CP =
Joule
, T=K)
mol.K
Cp = heat capacity of ideal gas

A, B, C, D, and E = regression coefficients for chemical compounds
T = temperature
Table 6.2 Cp Coefficient for Gas

B
C
Name
Methyl Ethyl
Ketone
Sec-Butanol
37.369
2.304510-1
5.738710-6
-8.816810-8
2.963710-11
22.465
3.513410-1
-1.285810-4
-1.193110-8
1.294010-11
Hydrogen
25.399
2.017810-2
-3.854910-5
3.188010-8
-8.758510-12
Water
1,1,2Trichloroethane
33.933
-8.418610-3
2.990610-5
-1.782510-8
3.693410-12
28.881
2.489310-1
-1.763910-4
5.263210-8
-3.566810-12
Heat Capacity of Liquid

The correlation for the heat capacity of liquid is a series expansion in temperature:
Cp= A+ BT +C T 2 + D T 3
Where
( CP =
Joule
, T=K)
mol.K
Cp = heat capacity of liquid

A, B, C, and D = regression coefficients for chemical compound
T = temperature
From thermodynamics, the change in enthalpy, H, at constant pressure is

H= Cp dT
Name
Table 6.3 Cp Coefficient for Liquid

A
B
Methyl Ethyl Ketone
61.406
7.532410-1
-2.381410-3
3.224010-6
Sec-Butanol
95.037
5.659310-1
-1.825610-3
2.667510-6
Hydrogen
50.607
-6.1136100
3.093010-1
-4.148010-3
Water
1,1,2Trichloroethane
92.053
-3.995310-2
-2.110310-4
5.346910-7
34.934
8.5054101
-2.330610-3
2.645510-6
6.3 Calculation of Energy Balance

R-101
T1 = 703.15 K
T2= 693.15 K
P1 = 1.411 atm
STREAM
COMPONENT
2-BUTANOL(2B)
MEK
H2
P2= 1.3126 atm
Stream 5 (Inlet)
n
106.8497
H
H1
Stream 6 (outlet)
n
2.136994
H
H2
104.7127
104.7127
H3
H4
SBA (v, 298.15, 1 atm)
SBA (v, 703.15, 1.411 atm)
SBA (v, 703.15, 1 atm)

703.15
^
H1 =
( c p ) SBA ( v ) dT
298.15
703.15
^
H 1=
( 2.2645 101 +3.5134 101 T 1.2858 104 T 21.1931 108 T 3 +1.2940 1011 T 4 ) dT
298.15
= 66305.95 kJ/kmol
=m/ V
= (7919.999/4.37 10
) =0.0018 kg/L
^
H 2 = (1.411-1)(74.12 kg/kmol)(1/0.018 L/kg)(8.314 J/mol.K)(1/0.08206
mol.K/L.atm)
= 171468.06/kmol 1/1000 kJ/J = 171.468 kJ/kmol
^
^
H1 = ( H 1 + H 2 ) n
H1 = (106.8497 kmol/hr)(66305.95 + 171.468 kJ/kmol) = 7103092.22 kJ/hr
SBA (v, 298.15 K, 1 atm)
SBA (v, 693.15 K, 1.3126 atm)
SBA (v, 693.15 K, 1 atm)
693.15
^
H1 =
( c p ) SBA ( v ) dT
298.15
693.15
^
H 1=
( 2.2645 101 +3.5134 101 T 1.2858 104 T 21.1931 108 T 3 +1.2940 1011 T 4 ) dT
298.15
= 64265 kJ/kmol
=m/ V
6
= (7919.999/9.17 10 ) = 0.000864 kg/L
^
mol.K/L.atm)
= 2716996.94 J/kmol 1/1000 kJ/J = 2716.99 kJ/kmol
^
^
H2 = ( H 1 + H 2 ) n
H2 = (2.136994kmol/hr)( 64265+ 2716.99 kJ/kmol) = 143120.02 kJ/hr
MEK (v, 298.15 K, 1 atm)
MEK (v, 693.15 K, 1.3126 atm)
SBA (v, 693.15 K, 1 atm)
693.15
^
H1 =
( c p ) MEK ( v ) dT
298.15
693.15
^
H 1=
( 3.7369 101 +2.3045 101 T +5.7387 106 T 2+(8.8168 108 )T 3 +2.9637 1011 T 4 ) dT
298.15
= 56485.49 kJ/kmol
=m/ V
= (7919.999/9.17 10
) = 0.000864 kg/L
^
H 2 = (1.3126-1)(72 kg/kmol)(1/0.000864 L/kg)(8.314 J/mol.K)(1/0.08206
mol.K/L.atm)
= 2639284.67 J/kmol 1/1000 kJ/J = 2639.28 kJ/kmol
^
^
H2 = ( H 1 + H 2 ) n
H2 = (104.7127 kmol/hr)( 56485.49 + 2639.28 kJ/kmol) = 6191114.3 kJ/hr
H2 (v, 298.15 K, 1 atm)
H2 (v, 693.15 K, 1.3126 atm)
H2 (v, 693.15 K, 1 atm)

693.15
^
H1 =
( c p ) H 2 ( v ) dT
298.15
8.7580 108 T 4
3.8549 105 T 2+ ( 3.1880 108 ) T 3 +()dT
2.5399 101+ 2.0178 102 T +
693.15
^ 1=
H
298.15
= -287918039.9 kJ/kmol
=m/ V
6
= (7919.999/9.17 10 ) = 0.000864 kg/L
^
mol.K/L.atm)
= 73313.46J/kmol 1/1000 kJ/J = 73.31kJ/kmol
^
^
H2 = ( H 1 + H 2 ) n
10
H2 = (104.7127 kmol/hr)( 73.31 -287918039.9 kJ/kmol) = - 3.015 10
kJ/hr
PUMP (B5)
28
1
Liquid
298.15
Stream
Phase
T( K )
P (atm)
Stream
References:TCE (l, 298.15 K, 1 atm)
Liquid
298.197
Phase
T( K )
Inlet and outlet unknown enthalpy for Pump (B5)
1.197
P (atm)
Component
^
H
n out
^
H out
TCE (l)
(kmol/hr)
4.9999
(kJ/kmol)
^
H1
(kmol/hr)
4.9999
(kJ/kmol)
^
H2
Stream 1
Since inlet stream is equal to the reference state,
^
H 1=0 kJ / kmol
TCE (l, 298.15 K, 1 atm)
TCE (l, 298.197 K, 1.197 atm)
Enthalpy for TCE outlet:

=m/V
= (667.0198/465.8271) =1.432 kg/L
^
mol.K/L.atm)
= 1859.335J/kmol 1/1000 kJ/J = 1.8593 kJ/kmol
H2 = (4.9999 kmol/hr)(1.8593kJ/kmol) = 9.2963 kJ/hr
PUMP (B3)
Stream
24
Liquid
298.1615
Phase
T( K )
Stream
Phase
T( K )
1.197
P (atm)
23
Liquid
298.15
1
P (atm)
References: H2O (l, 298.15 K, 1 atm)

Component
^
H
n out
^
H out
H2O (l)
(kmol/hr)
700.0001
(kJ/kmol)
^
H1
(kmol/hr)
700.0001
(kJ/kmol)
^
H2
Stream 23
^
H 2=0 kJ / kmol
H2O (l, 298.15 K, 1 atm)
H2O (l, 298.1615 K, 1.197 atm)
Enthalpy for H2O inlet:

=m/V
= (12610.7/12687.51) =0.994 kg/L
^
mol.K/L.atm)
= 351.71J/kmol 1/1000 kJ/J = 0.352 kJ/kmol
H1 = (0.352 kmol/hr) (700.0001 kJ/kmol) = 252.98 kJ/hr
Heater (E-104)
Stream
Phase
T( K )
P (atm)
16
VAPOUR
378
2.62
Stream
12
LIQUID
298
Phase
T( K )
2.62
P (atm)
References: MEK (l, 298 K, 1 atm), SBA (l, 298 K, 1 atm), H 2(v, 298 K,
1 atm), H2O (l, 298 K, 1 atm), TCE (l, 298 K, 1 atm)
Inlet and outlet unknown enthalpy for E-106

Component
^
H
n out
^
H out
MEK (l)
(kmol/hr)
10.3835
(kJ/kmol)
^
H1
(kmol/hr)
10.3835
(kJ/kmol)
^
H6
SBA (l)
0.0649312
^
H2
0.0649312
^
H7
H2(l)
0.0622103
^
H3
0.0622103
^
H8
H2O (l)
3.650637
^
H4
3.650637
^
H9
TCE (l)
7.42 104
^
H5
7.42 104
^
H 10
Stream 16 (SBA)
SBA (l, 298 K, 1 atm)
SBA(l, 372.70 K, 1 atm)
SBA (v, 378 K, 2.62 atm)
SBA(v, 372.70 K, 1 atm)
SBA(v, 378 K, 1 atm)
^
H a = 13480.4166 kJ/kmol
^
H b = 40960 kJ/kmol
378
^
Hc =
( c p ) MEK dT
372.70
5
9
= [22.465T + 0.17567T2 + (-4.286 10 T3+ (-2.9828 10 ) T4+ (-2.588
1012 ) T5]
= 123.994 kJ/kmol
5
3
= (819.5266/1.68 10 = 4.878 10
kg/L
^
H d = (2.62-1)(74 kg/kmol)(1/4.878 103 L/kg)(8.314 J/mol.K)(1/0.08206
mol.K/L.atm)
= 2489.9kJ/kmol
^
H 16
^
Ha+ ^
H b +
^
H c+ ^
H d = 57054.3 kJ/kmol
^
H16 = ( H 16 ) n
= 57054.3 kJ/kmol 0.0649312 kmol/hr
= 3704.6 kJ/hr
Stream 16 (MEK)
MEK (l, 298 K, 1 atm)
MEK(l, 352.79 K, 1 atm)
MEK (v, 378 K, 2.62 atm)
MEK(v, 352.79 K, 1 atm)
MEK(v, 378 K, 1 atm)
^
H a = 4371.72 kJ/kmol
^
H b = 31220 kJ/kmol
378
^
Hc =
( c p ) MEK dT
352.79
3
5
= [942.072 + 73.215 +0.03065+ (-8.903 10 + (6.036 10 )]
= 1015.31 kJ/kmol
3
= 4.878 10
kg/L
^
mol.K/L.atm)
= 2422kJ/kmol
^
H 16
^
Ha+ ^
H b +
^
H c+ ^
H d = 39029.02 kJ/kmol
^
H16 = ( H 16 ) n
= 39029.02 kJ/kmol 10.3835 kmol/hr
= 405257.83 kJ/hr
Stream 16 (H2O)
H2O (l, 298 K, 1 atm)
H2O (l, 373 K, 1 atm)
^
Ha =
373
( c p ) H 2 O dT
298
H2O (v, 378 K, 2.62 atm)
H2O (v, 373 K, 1 atm)
H2O (v, 378 K, 1 atm)
= [92.053T + (-0.01997)T2 + (-7.034 10 T3+ (1.3367 10
) T4]
= 6766.198kJ/kmol
H
=HV = 39.5 kJ/mol

373
^
HC =
( c p ) H 2 O ( g ) dT
298
= [33.933T + (-4.209 3 10
13
7.3868 10
)T2 + (9.9686 10 T3+ (-4.456 10
) T4+ (-
) T5]
= 169.5610 kJ/kmol
= 4.878 103
kg/L
^
mol.K/L.atm)
= 605653.49kJ/kmol
^
H 16
^
Ha+ ^
H b +
^
H c+ ^
H d = 652089.249 kJ/kmol
^
H16 = ( H 16 ) n
= 652089.249 kJ/kmol 3.650637kmol/hr
= 2380541.14 kJ/hr
Stream 16 (H2)
H2 (g, 298 K, 1 atm)
H2 (g, 378 K, 2.62 atm)
H2 (g, 378 K, 1 atm)
378
^
Ha =
( c p ) H 2 ( g ) dT
298
= 2031.92 + 64.5696 6.5786 + 0.3265 57.396

= 2032.842 kJ/kmol
= 4.878 103
kg/L
^
H b = (2.62-1)(2 kg/kmol)(1/4.878 103 L/kg)(8.314 J/mol.K)(1/0.08206
mol.K/L.atm)
= 67.29kJ/kmol
^
H 16
2100kJ/kmol
^
H16 = ( H 16 ) n
= 2100kJ/kmol 0.0622103 kmol/hr
= 130.64163 kJ/hr
Furnace (H-101)
Stream
Phase
T(
)
Vapor
140
P (atm)
1.47
Stream
Reference: SBA (l, 25, 1
5
Vapor
430
Phase
T(
)
atm)
1.44
P (atm)
Inlet and outlet unknown enthalpy for H-101

Component
^
H
n out
^
H out
SBA (v)
(kmol/hr)
106.8494
(kJ/kmol)
^
H1
(kmol/hr)
106.8494
(kJ/kmol)
^
H2
Stream 4
SBA (l, 25, 1 atm)
SBA (v, 140, 1.47 atm)
Ha
SBA (l, 99.7, 1 atm)
SBA (v, 99.7, 1 atm)
Hc
SBA (v, 140, 1 atm)
^
H 1=H a + H b + H c + H d
99.7
H a= ( c p ) SBA ( l ) dT
25
99.7
H a= ( 95.037+5.6593 101 T 1.8256 103 T 2 +2.6675 106 T 3 ) dT

25
H a=8445.34 kJ /kmol
H b=H v@ boiling point

H b=40.960 kJ /mol
H b=40960 kJ /kmol
140
H c = ( c p ) SBA ( v ) dT
99.7
140
H c = ( 22.465+ 3.513 101 T 1.2858 104 T 21.1931 108 T 3 +1.294 1011 T 4 ) dT

99.7
H c =1187.77 kJ /kmol
H d =^v P
1L
72.11 kg
Hd=
( 1.47 atm1 atm )
0.0032 kg
1 kmol
J
mol .
L .atm
0.08206
mol .
8.314
H d =1073054.75 J /kmol=1073.05 kJ /kmol
^
H 1=8445.34 kJ /kmol +40960 kJ /kmol+ 1187.77 kJ /kmol+1073.05 kJ /kmol
^
H 1=51666.16 kJ /kmol
Stream 5
Pressure change from 1.47 atm to 1.44 atm is negligible.
430
^
H 2= ( c p ) SBA ( v ) dT
140
430
H 2= ( 22.465+3.513 101 T 1.2858 104 T 21.1931 108 T 3 +1.294 1011 T 4 ) dT

140
^
H 2=20225.91 kJ /kmol
Inlet and outlet enthalpy for H-101

Component
^
H
n out
^
H out
SBA (v)
(kmol/hr)
106.8494
(kJ/kmol)
51666.16
(kmol/hr)
106.8494
(kJ/kmol)
20225.91
=n H = n out ^
Q=
H
H out n ^
H
out
( 106.8494 kmol/hr ) ( 20225.91 kJ /kmol )(106.8494 kmol /hr)(51666.16 kJ /kmol)

Q=
Q=3.359
106 kJ /hr
Heater (E-104)
Stream
Phase
T(
)
P (atm)
18
Liquid
25
Stream
Phase
T( )
P (atm)
22
Liquid
95
1
References: MEK (l, 25 , 1 atm), SBA (l, 25 , 1 atm), H2 (v,

25 , 1 atm), H2O (l, 25 , 1 atm), TCE (l, 25 , atm)
Inlet and outlet unknown enthalpy for E-104
Component
^
H
n out
^
H out
MEK (l)
(kmol/hr)
10.3835
(kJ/kmol)
^
H1
(kmol/hr)
10.3835
(kJ/kmol)
^
H6
SBA (l)
0.0649
^
H2
0.0649
^
H7
H2 (l)
0.0622
^
H3
0.0622
^
H8
H2O (l)
697.5673
^
H4
697.5673
^
H9
TCE (l)
0.023
^
H5
0.023
^
H 10
Stream 18
^
^ 3= H
^ 4= H
^ 5 =0 kJ /kmol
H 1= ^
H 2= H
Stream 22
Enthalpy for MEK outlet:

95
^
H 6= ( c p ) MEK ( l ) dT
25
95
^
H 6= ( 61.406+ 7.5324 101 T2.3814 103 T 2 +3.224 106 T 3 ) dT
25
^
H 6=5890.94 kJ /kmol
Enthalpy for SBA outlet:

95
^
H 7= ( c p ) SBA ( l ) dT
25
95
^
H 7= ( 95.037+5.6593 101 T 1.8256 103 T 2+ 2.6675 106 T 3 ) dT
25
^
H 7=7846.40 kJ /kmol
Enthalpy for H2 outlet:

95
^
H 8= ( c p ) H 2 ( v ) dT
25
95
^
H 8= ( 25.399+2.0178 102 T 3.8549 105 T 2 +3.1880 108 T 38.7585 1012 T 4 ) dT
25
^
H 8=1823.15 kJ /kmol
Enthalpy for H2O outlet:

95
^
H 9= ( c p ) H 2 O ( l ) dT
25
95
^
H 9= ( 92.0533.9953 102 T 2.1103 104 T 2 +5.3469 107 T 3 ) dT
25
^
H 9=6324.91 kJ /kmol

95
^
H 10= ( c p ) TCE ( l ) dT
25
95
^
H 10= ( 11.142+1.0501 T 3.0826 103 T 2 +3.5983 106 T 3 ) dT
25
^
H 10=3021.84 kJ /kmol
Inlet and outlet enthalpy for E-104
Component
^
H
n out
^
H out
(kmol/hr)
(kJ/kmol)
(kmol/hr)
(kJ/kmol)
MEK (l)
SBA (l)
10.3835
0.0649
H2 (v)
0
0
10.3835
0.0649
5890.94
7846.40
0.0622
0.0622
1823.15
H2O (l)
697.5673
697.5673
6324.91
TCE (l)
0.023
0.023
3021.84
=n H = n out ^
Q=
H
H out n ^
H
out
( 10.3835 ) ( 5890.94 ) + ( 0.0649 )( 7846.40 ) + ( 0.0622 ) ( 1823.15 )+ ( 697.5673 )( 6324.91 ) + ( 0.023 ) ( 3021.84 ) 0
Q=
Q=4.474
106 kJ /hr
Pump (B4)
Stream
Phase
T( )
References: MEK (l, 25 , 1
atm), H2 (v, 25 , 1 atm),
(l, 25 , 1 atm)
26
17
Liquid
25
1
P (atm)
atm), SBA (l, 25 , 1
Stream
Phase
T( )
Liquid
25
H2O (l, 25 , 1 atm), TCE
1.2
P (atm)

Component
^
H
n out
^
H out
MEK (l)
(kmol/hr)
0.5802
(kJ/kmol)
^
H1
(kmol/hr)
0.5802
(kJ/kmol)
^
H6
SBA (l)
0.0032
^
H2
0.0032
^
H7
H2 (v)
0.0005
^
H3
0.0005
^
H8
H2O (l)
0.0797
^
H4
0.0797
^
H9
TCE (l)
4.977
^
H5
4.977
Stream 17
^
^ 3= H
^ 4= H
^ 5 =0 kJ /kmol
H 1= ^
H 2= H
Stream 26

^
H 6=^v P
J
1L
72.11 kg
mol .
^
H 6=
( 1.2 atm1 atm )
1.367 kg
1 kmol
L . atm
0.08206
mol .
8.314
^
H 6=1068.90 J /kmol=1.0689 kJ /kmol

^
H 7=^v P
J
1L
74.122kg
mol .
^
H 7=
( 1.2 atm1 atm )
1.367 kg
1kmol
L .atm
0.08206
mol .
8.314
^
H 7=1098.72 J /kmol=1.0987 kJ /kmol

^
H 8=^v P
^
H 10
J
1L
2.016 kg
mol .
^
H 8=
( 1.2 atm1 atm )
1.367 kg
1 kmol
L . atm
0.08206
mol .
8.314
^
H 8=29.883 J /kmol=0.0299 kJ /kmol
Enthalpy for H2O outlet:

^
H 9=^v P
J
1L
18 kg
mol .
^
H 9=
( 1.2 atm1 atm )
1.367 kg
1 kmol
L . atm
0.08206
mol .
8.314
^
H 9=266.82 J /kmol=0.2668 kJ /kmol
^
H 10=^v P
J
1L
133.4 kg
mol .
^
H 10=
( 1.2atm1 atm )
1.367 kg
1kmol
L . atm
0.08206
mol .
8.314
^
H 10=1977.41 J /kmol=1.9774 kJ /kmol
Inlet and outlet enthalpy for Pump (B4)

Component
^
H
n out
^
H out
MEK
(l)
SBA
(l)
H2 (v)
(kmol/hr (kJ/kmo
)
l)
0
0.5802
(kJ/kmo
l)
1.0689
0.0032
0.0032
1.0987
0.0005
0.0005
0.0299
H2O (l)
0.0797
Stream
0.0797 160.2688
TCE
(l)
4.977
Stream
Phase
T( )
P (atm)
19
Vapor
130
2.65
Phase
0
4.977 Liquid
1.9774
105
T( )
P (atm)
Stream
22
Q= H =n HLiquid
= n out ^
H out n ^
H
Phase
out
95
T(
(kmol/hr
)
0.5802
2.65
1
P (atm)
( 0.5802 ) ( 1.0689
) + ( 0.0032 )( 1.0987 )+ ( 0.0005 )( 0.0299 )+ ( 0.0797 ) ( 0.2688 )+ ( 4.977 ) ( 1.9774 ) 0
Q=
Q=10.4866
kJ / hr
Distillation Column (T-101)
References: MEK (l, 25 , 1 atm), SBA (l, 25 , 1 atm), H2 (v, 25 , 1 atm), H2O (l, 25
, 1 atm), TCE (l, 25 , 1 atm)
Inlet and outlet unknown enthalpy for T-101

^
H
MEK
(kmol/hr)
10.3835
SBA
0.0649
^
H2
0.0000
^
H7
0.0649
^
H 12
H2
0.0622
^
H3
0.0000
^
H8
0.0622
^
H 13
H2O
697.5673
^
H4
693.9166
^
H9
3.6504
^
H 14
TCE
0.0230
^
H5
0.0223
^
H 10
0.0007
^
H 15
(kmol/hr)
0.0000
(kJ/kmol)
^
H6
n bottom
^
H bottom
(kJ/kmol)
^
H1
n top
^
H top
Component
(kmol/hr) (kJ/kmol)
^
10.3835
H 11
Stream 22
Enthalpy for MEK inlet:

95
^
H 1= ( c p ) MEK ( l ) dT
25
95
^
H 1= ( 61.406+7.5324 101 T 2.3814 103 T 2 +3.224 106 T 3 ) dT
25
^
H 1=5890.94 kJ /kmol
Enthalpy for SBA inlet:

95
^
H 2= ( c p ) SBA (l ) dT
25
95
^
H 2= ( 95.037+ 5.6593 101 T 1.8256 103 T 2+2.6675 106 T 3 ) dT
25
^
H 2=7846.40 kJ /kmol
Enthalpy for H2 inlet:

95
^
H 3= ( c p ) H 2 ( v ) dT
25
95
^
H 3= ( 25.399+2.0178 102 T 3.8549 105 T 2 +3.1880 108 T 38.7585 1012 T 4 ) dT
25
^
H 3=1823.15 kJ /kmol
Enthalpy for H2O inlet:

95
^
H 4 = ( c p ) H 2 O ( l ) dT
25
95
^
H 4 = ( 92.0533.9953 102 T 2.1103 104 T 2 +5.3469 107 T 3 ) dT
25
^
H 4 =6324.91kJ /kmol
Enthalpy for TCE inlet:

95
^
H 5= ( c p ) TCE (l ) dT
25
95
^
H 5= ( 11.142+1.0501 T 3.0826 103 T 2 +3.5983 106 T 3 ) dT
25
^
H 5=3021.84 kJ /kmol
Stream 19
H2O (l, 25, 1 atm)
H2O (v, 130, 2.65 atm)
Ha
H2O (l, 100, 1 atm)
H2O (v, 100, 1 atm)
H2O (v, 130, 1 atm)
Hc
^
H 9=H a + H b + H c + H d
100
H a= ( c p ) H 2 O ( l ) dT
25
100
H a= ( 92.0533.9953 102 T 2.1103 104 T 2+5.3469 107 T 3 ) dT

25

H b=39.500 kJ /mol
H b=39500 kJ /kmol
130
H c = ( c p ) H 2 O ( v ) dT
100
130
H c = ( 33.9338.4186 103 T +2.9906 105 T 2 1.7825 108 T 3 +3.6934 1012 T 4 ) dT

100
H c =1014.47 kJ /kmol
H d =^v P
J
1L
18 kg
mol .
Hd=
( 2.65 atm1 atm )
0.887 kg
1kmol
L . atm
0.08206
mol .
8.314
H d =3392.43 J /kmol=3.392kJ /kmol
^
H 9=6766.16 kJ /kmol +39500 kJ /kmol+1014.47 kJ /kmol+ 3.392kJ /kmol
^
H 9=47284.02kJ /kmol
TCE (l, 25, 1 atm)
TCE (v, 130, 2.65 atm)
Ha
TCE (l, 113.8, 1 atm)
TCE (v, 113.8, 1 atm)
TCE (v, 130, 1 atm)
Hc
^
H 10=H a + H b + H c + H d
100
H a= ( c p ) H 2 O ( l ) dT
25
113.8
H a= ( 11.142+1.0501 T 3.0826 103 T 2 +3.5983 106 T 3 ) dT

25

H b=34.820 kJ /mol
H b=34820 kJ /kmol
130
H c = ( c p ) H 2 O ( v ) dT
113.8
130
H c = ( 18.674+3.3443 101 T 3.4963 104 T 2 +1.8764 107 T 34.0744 1011 T 4 ) dT

113.8
H c =345.91 kJ /kmol
H d =^v P
J
1L
133.4 kg
mol .
Hd=
( 2.65 atm1 atm )
0.887 kg
1 kmol
L . atm
0.08206
mol .
8.314
H d =25141.70 kJ /kmol
^
H 10=4466.09 kJ /kmol+ 34820 kJ /kmol+345.91 kJ /kmol+25141.70 kJ /kmol
^
H 10=64773.70 kJ /kmol
Stream 16
n (l, 25, 1 atm)
n (l, 130, 2.65 atm)
n (l, 130, 1 atm)
Where i = 11, 12, 13, 14, and 15.

^
H i=H ai + H bi
Enthalpy of n = MEK
130
H a= ( c p ) MEK ( l ) dT
25
130
H a= ( 61.406+7.5324 101 T 2.3814 103 T 2 +3.224 106 T 3 ) dT

25
H a=9778.91kJ /kmol
H b= v^ P
J
1L
72.11 kg
mol .
H b=
( 2.651 ) atm
0.0049 kg
1 kmol
L. atm
0.08206
mol .
8.314
H b=2460.15 kJ /kmol
^
H 11=9778.91kJ /kmol +2460.15 kJ /kmol=12239.06 kJ /kmol
Enthalpy for n = SBA

130
H a= ( c p ) SBA (l ) dT
25
130
H a= ( 95.037+ 5.6593 101 T 1.8256 103 T 2+2.6675 106 T 3 ) dT

25
H a=12475.18 kJ /kmol
H b= v^ P
J
1L
74.122 kg
mol .
H b=
( 2.651 ) atm
0.0049 kg
1 kmol
L . atm
0.08206
mol .
8.314
^
H 12=12475.18 kJ /kmol+2528.79 kJ /kmol=15003.97 kJ / kmol
Enthalpy for n = H2
130
H a= ( c p ) H 2 ( v ) dT
25
130
H a= ( 25.399+2.0178 102 T 3.8549 105 T 2 +3.1880 108 T 3 8.7585 1012 T 4 ) dT

25
H b= v^ P
J
1L
2.016 kg
mol .
H b=
( 2.651 ) atm
0.0049 kg
1 kmol
L. atm
0.08206
mol .
8.314
H b=68.779 kJ /kmol
^
H 13=2764.20 kJ /kmol+68.779 kJ /kmol=2832.98 kJ /kmol
Enthalpy for n = H2O

130
H a= ( c p ) H 2 O ( l ) dT
25
130
H a= ( 92.0533.9953 102 T 2.1103 104 T 2+5.3469 107 T 3 ) dT

25
H a=9380.141kJ /kmol
H b= v^ P
J
1L
18 kg
mol .
H b=
( 2.651 ) atm
0.0049 kg
1 kmol
L . atm
0.08206
mol .
8.314
H b=614.10 kJ /kmol
^
H 14=9380.141 kJ /kmol+614.10 kJ / kmol=9994.24 kJ /kmol
Enthalpy for n = TCE

130
H a= ( c p ) TCE ( l ) dT
25
130
H a= ( 11.142+1.0501 T 3.0826 103 T 2 +3.5983 106 T 3 ) dT

25
H b= v^ P
J
1L
133.4 kg
mol .
H b=
( 2.651 ) atm
0.0049 kg
1 kmol
L. atm
0.08206
mol .
8.314
^
H 15=5879.43 kJ /kmol+ 4551.16 kJ /kmol=10430.59 kJ /kmol
Inlet and outlet enthalpy for T-101

^
H
^
H top
Component
MEK
(kmol/hr)
10.3835
(kJ/kmol)
5890.94
(kmol/hr)
0.0000
SBA
0.0649
7846.40
0.0000
H2
0.0622
1823.15
0.0000
697.5673
0.0230
6324.91
3021.84
693.9166
0.0223
H2O
TCE
n top
^
H bottom
n bottom
(kJ/kmol)
(kmol/hr) (kJ/kmol)
10.3835 12239.06
0.0649
15003.97
0.0622
47284.02
64773.70
3.6504
0.0007
2832.98
9994.24
10430.59
=n H = n out ^
Q=
H
H out n ^
H
out
[ ( 10.3835 ) ( 12239.06 ) + ( 0.0649 ) ( 15003.97 ) + ( 0.0622 )( 2832.98 )+ ( 3.6504 )( 9994.24 ) + ( 0.007 )( 10430
Q=
6
Q=28.503
10 kJ /hr
Extraction Column (V-103)

Stream
Stream
Phase
T( K
)
P (bar)
28
Liquid
298.1970
1.197384
Phase
T( K
)
P (bar)
17
Liquid
299.1418
1.01
Stream
15
Liquid
298.15
Phase
T( K
)
P (bar)
Stream
Phase
T( K
1.164569
)
P (bar)
18
Liquid
298.1992
1.01
Reference: SBA (l, 25, 1 bar)
Inlet and outlet unknown enthalpy for V-103

Stream 28
Component
(mol/hr)
TCE (l)
4999.999
^
H
(kJ/mol)
^
H1
TCE (l, 298.15K, 1bar barbar)
^
n x H
(kJ/hr)
1.585
TCE (l, 298.1970, 1.197384 bar)
Ha
TCE (l, 298.1970 K, 1 bar)
^
H 1=
Ha +
Hb
298.1970
H a=
( c p ) TCE ( l ) dT
298.15
298.1970
H a=
298.15
( 11.142+1.0501 100 T 3.0830 103 T 2+ 3.5983 106 T 3 ) dT
H a=0.0005379 kJ /mol
H b= v^ P

1.197384 1
1 000 L
0.08314 L .
mol . K
1m3
1kg
1 m3
H b=
1000 g 1000 kg
H b=0.002633 kJ /mol
^
H 1=0.0005379 kJ /mol+0.002633 kJ /mol
^
H 1=0.003171 kJ /mol
Stream 15
Component
^
H
MEK (l)
(mol/hr)
10963.69
(kJ/mol)
^
H1
(kJ/hr)
12.220
SBA
68.0850
^
H2
0.587
Hydrogen
138.1836
^
H3
0.00429
Water
697647.3
^
H4
0.5984
TCE
2.13658x10-6
^
H5
2.357x10-8
^
n x H
For MEK
MEK (l, 298.15 K, 1 bar)
H 1=^v P

1.164569 1
1 000 L
0.08314 L .
mol . K
1m3
3
1 kg
1m
H 1=
1000 g 1000 kg
1.1146 x 103 kJ /mol
MEK (l, 298.15K, 1.164569 bar)
For SBA
SBA (l, 298.15 K, 1 bar)
SBA (l, 298.15K, 1.164569 bar)
H 2=^v P

1.164569 1
1 000 L
0.08314 L .
mol . K
1m3
1 kg
1 m3
H 2=
1000 g 1000 kg
8.629 x 103 kJ /mol
For Hydrogen
H2 (l, 298.15 K, 1 bar)
H 3=^v P
H2 (l, 298.15K, 1.164569 bar)

1.164569 1
1 000 L
0.08314 L .
mol . K
1m3
3
1kg
1m
H 3=
1000 g 1000 kg
3.1068 x 105 kJ /mol
For Water
H2O (l, 298.15 K, 1 bar)
H2O (l, 298.15K, 1.164569 bar)
H 4 =^v P

1.164569 1
1 000 L
0.08314 L .
mol . K
1m3
1 kg
1m 3
H 4=
1000 g 1000 kg
7
8.5776 x 10 kJ /mol
For TCE
TCE (l, 298.15 K, 1 bar)
TCE (l, 299.1418K, 1 bar)
299.1418
H 5=
298.15
298.1418
H 5=
( 11.142 +1.0501 100 T 3.0830 103 T 2+3.5983 106 T 3 ) dT
298.15
H 5=0.01103092 kJ /mol
Stream 17
Component
^
H
^
n x H
MEK (l)
(mol/hr)
580.1836
(kJ/mol)
^
H1
(kJ/hr)
35.55
SBA
3153.71x10-3
^
H2
0.298
Hydrogen
1033.35x10-3
^
H3
0.0489
Water
79.6854
^
H4
7.273
TCE
4976.974
^
H5
54.9
For MEK
MEK (l, 298.15 K, 1 bar)
MEK (l, 299.1418K, 1 bar)
299.1418
H 1=
( c p ) MEK ( l ) dT
298.15
298.1418
H 1=
( 61.406+ 7.5324 101 T 2.3814 103 T 2 +3.2240 106 T 3 ) dT
298.15
H 1=0.06127 kJ /mol
For SBA
SBA (l, 298.15 K, 1 bar)
SBA (l, 299.1418K, 1bar)
299.1418
H 2=
( c p ) SBA ( l ) dT
298.15
298.1418
H 2=
( 95.037+5.6593 101 T 1.8256 103 T 2+ 2.6675 106 T 3 ) dT
298.15
H 2=0.0944 kJ /mol
For Hydrogen
H2 (l, 298.15 K, 1 bar)
H2 (l, 299.1418K, 1bar)
299.1418
( c p ) H 2 ( l ) dT
H 3=
298.15
298.1418
H 3=
( 50.607 +6.1136 10 0 T 3.0930 101 T 2 + 4.1480 103 T 3 ) dT
298.15
H 3=0.0473 kJ /mol
For Water
H2O (l, 298.15 K, 1 bar)
299.1418
H4=
( c p ) H 2 O ( l ) dT
298.15
H2O (l, 299.1418K, 1bar)
298.1418
H4=
( 92.0533.9953 102 T 2.1103 104 T 2+5.3469 107 T 3 ) dT
298.15
H 4 =0.09127845 kJ /mol
For TCE
H2O (l, 299.1418K, 1bar)
H2O (l, 298.15 K, 1 bar)
299.1418
H 5=
298.15
299.1418
H 5=
( 11.142 +1.0501 100 T 3.0830 103 T 2+3.5983 106 T 3 ) dT
298.15
H 5=0.01103092 kJ /mol
Stream 18
Component
^
H
^
n x H
MEK (l)
(mol/hr)
10383.4
(kJ/mol)
^
H1
(kJ/hr)
31.38
SBA
64.9312
^
H2
0.31
Hydrogen
62.2103
^
H3
0.155
Water
697567.5
^
H4
3159.3
TCE
23.0271
^
H5
0.01266
For MEK
MEK (l, 298.15 K, 1 bar)
MEK (l, 298.1992K, 1 bar)
299.1992
H 1=
298.15
298.1992
H 1=
( 61.406+ 7.5324 101 T 2.3814 103 T 2 +3.2240 106 T 3 ) dT
298.15
H 1=0.00302209 kJ /mol
For SBA
SBA (l, 298.15 K, 1 bar)
SBA (l, 298.1992K, 1bar)
298.1992
H 2=
298.15
298.1992
H 2=
( 95.037+5.6593 101 T 1.8256 103 T 2+ 2.6675 106 T 3 ) dT
298.15
H 2=0.00468 kJ /mol
For Hydrogen
H2 (l, 298.15 K, 1 bar)
H2 (l, 299.1418K, 1bar)
298.1992
H 3=
( c p ) H 2 ( l ) dT
298.15
298.1992
H 3=
( 50.607+ 6.1136 10 0 T 3.0930 101 T 2 + 4.1480 103 T 3 ) dT
298.15
H 3=0.00248 kJ /mol
For Water
H2O (l, 298.15 K, 1 bar)
H2O (l, 298.1992K, 1bar)
298.1992
H4=
( c p ) H 2 O ( l ) dT
298.15
298.1992
H4=
( 92.0533.9953 102 T 2.1103 104 T 2 +5.3469 107 T 3 ) dT
298.15
H 4 =0.00452896 kJ /mol
For TCE
H2O (l, 298.15 K, 1 bar)
H2O (l, 298.1992K, 1bar)
298.1992
H 5=
298.15
298.1992
H 5=
( 11.142+ 1.050110 0 T 3.0830 103 T 2+3.5983 106 T 3 ) dT
298.15
H 5=0.00055 kJ /mol
Mixer (B-17)
Stream
Phase
T( K
)
P (bar)
20
Liquid
297.9664
Stream
Phase
T( K
)
P (bar)
1.01
Stream
Phase
T( K
)
P (bar)
9
Liquid
299.113
1.01
10
Liquid
298.15
1.233654
Stream 20
Component
^
H
^
n x H
MEK (l)
(mol/hr)
10383.5
(kJ/mol)
^
H1
(kJ/hr)
-116.93
SBA
64.9312
^
H2
-1.129
Hydrogen
137.1503
^
H3
-1.29
Water
3650.637
^
H4
-61.7
TCE
0.742274
^
H5
-0.00148
For MEK
MEK (l, 298.15 K, 1 bar)
MEK (l, 297.9664K, 1 bar)
297.9664
H 1=
298.15
297.9664
H 1=
( 61.406+7.5324 101 T 2.3814 103 T 2+3.2240 106 T 3 ) dT
298.15
H 1=0.01126144 kJ /mol
For SBA
SBA (l, 298.15 K, 1 bar)
SBA (l, 297.9664K, 1bar)
299.1418
H 2=
298.15
298.1418
H 2=
( 95.037+5.6593 101 T 1.8256 103 T 2+ 2.6675 106 T 3 ) dT
298.15
H 2=0.0174 kJ / mol
For Hydrogen
H2 (l, 298.15 K, 1 bar)
H2 (l, 297.9664K, 1bar)
299.1418
H 3=
( c p ) H 2 ( l ) dT
298.15
298.1418
H 3=
( 50.607 +6.1136 10 0 T 3.0930 101 T 2 + 4.1480 103 T 3 ) dT
298.15
H 3=0.0094 kJ / mol
For Water
H2O (l, 298.15 K, 1 bar)
H2O (l, 2979664K, 1bar)
299.1418
H4=
( c p ) H 2 O ( l ) dT
298.15
298.1418
H4=
( 92.0533.9953 102 T 2.1103 104 T 2+5.3469 107 T 3 ) dT
298.15
H 4 =0.0169016 kJ / mol
For TCE
H2O (l, 298.15 K, 1 bar)
H2O (l, 297.9664K, 1bar)
299.1418
H 5=
298.15
299.1418
H 5=
( 11.142 +1.0501 100 T 3.0830 103 T 2+3.5983 106 T 3 ) dT
298.15
H 5=0.002 kJ /mol
Stream 9
Component
^
H
MEK (l)
(mol/hr)
11175.17
(kJ/mol)
^
H1
(kJ/hr)
-25.37
SBA
65.1248
^
H2
-0.228
Hydrogen
230835.4
^
H3
-438.59
Water
TCE
For MEK
^
n x H
MEK (l, 298.15 K, 1 bar)
MEK (l, 298.113K, 1 bar)
298.113
H 1=
298.15
298.113
H 1=
( 61.406+ 7.5324 101 T 2.3814 103 T 2 +3.2240 106 T 3 ) dT
298.15
H 1=0.00227147 kJ /mol
For SBA
SBA (l, 298.15 K, 1 bar)
299.1418
H 2=
298.15
SBA (l, 298.113K, 1bar)
298.1418
H 2=
( 95.037+5.6593 101 T 1.8256 103 T 2+ 2.6675 106 T 3 ) dT
298.15
H 2=0.0035 kJ / mol
For Hydrogen
H2 (l, 298.113K, 1bar)
H2 (l, 298.15 K, 1 bar)
299.1418
H 3=
( c p ) H 2 ( l ) dT
298.15
298.1418
H 3=
( 50.607 +6.1136 10 0 T 3.0930 101 T 2 + 4.1480 103 T 3 ) dT
298.15
H 3=0.0019 kJ /mol
Stream 10
Component
^
H
^
n x H
MEK (l)
(mol/hr)
93537.55
(kJ/mol)
^
H1
(kJ/hr)
150856
SBA
2071.869
^
H2
3433.7
Hydrogen
16.6159
^
H3
0.7492
Water
TCE
For MEK
MEK (l, 298.15 K, 1 bar)
MEK (l, 298.15K, 1.233654 bar)
H 1=^v P

1.233654 1
1 000 L
0.08314 L .
mol . K
1m3
1 kg
1 m3
H 1=
1000 g 1000 kg
1.6128 kJ /mol
For SBA
SBA (l, 298.15 K, 1 bar)
H 2=^v P
SBA (l, 298.15K, 1.233654bar)

1.233654 1
1 000 L
0.08314 L .
mol . K
1m3
1 kg
1 m3
H 2=
1000 g 1000 kg
1.6573 kJ /mol
For Hydrogen
H2 (l, 298.15 K, 1 bar)
H 3=^v P

1.233654 1
1 000 L
0.08314 L .
mol . K
1m3
1kg
1 m3
H 3=
1000 g 1000 kg
0.04509 kJ /mol
H2 (l, 298.15K, 1.233654 bar)
Condenser (E-103)
Stream
7
Vapor
Phase
T (K)
P (atm)
Stream
428.4892
1.28
8
Mixer
Phase
T (K)
P (atm)
298.15
1.26
Table 1 Inlet and Outlet (Unknown) enthalpy for the condenser (E-103)
Compo
unds
Stream 7
Stream 8 (Vapor)
Stream 8 (Liquid)
(kmol/hr)
(kJ/kmol)
(kmol/hr)
(kJ/kmol)
(kmol/hr)
(kJ.kmol)
MEK
104.7172
11.1752
93.5376
SBA
2.1370
0.0651
2.0719
104.7172
104.7052
7.5410-3
H2
Change in pressure is negligible since the pressure at stream 7 and stream 8 is approximately
same and the change is small.
Stream 7 (Inlet)
Enthalpy for MEK inlet:

352.79
^
H 1= ^
Hf +
428.4892
Cp(l ) dT +
298
Cp (v) dT
352.79
238360+ 159.75 ( 352.79298 ) +37.369 ( 428.4892352.79 ) +
0.23( 428.4892 352.79 ) 5.74 10 (428

+
2
220245.705 kJ /kmol
Enthalpy for SBA inlet:

352.79
^
H 2= ^
Hf +
428.4892
Cp(l ) dT +
298
Cp (v) dT
352.79
0.351(428.4892 352.79 ) 1.29 10 (4

292290+ 172.18 ( 352.79298 ) +22.465 ( 428.4892352.79 )+
271500.045 kJ /kmol
Enthalpy for H2 inlet:
428.4892
^
H 3= ^
Hf +
Cp (v) dT
298
2
0.0202( 428.4892 298 ) 3.85 10 ( 428.4892 298 ) 3.19 10

0+25.399 ( 428.4892298 )+
+
2
3
11446.054 kJ /kmol
Therefore, the total enthalpy flow and relative error for vapor phase in inlet stream is:
n H^ =104.7172 (220245.705 )+2.137 (271500.045 ) +104.7172 (11446.054 )

22445110.333 kJ / hr
2.36E7
| ManualHysys
|100 |22445110.333+
|100
Manual
22445110.333
Relative Error=
Stream 8 (Outlet): Vapor Phase

5.1
289.15
^
H4=^
Hf +
Cp(v) dT
298
238360+ 37.369 ( 298.15298 ) +
0.23(298.15 298 ) 5.74 10 (298.15 298 ) 8.82 10 (298.15

+
2
3
4
238344.33 kJ /kmol

298.15
^
H 5= ^
Hf +
Cp(v) dT
298
0.351(298.15 298 ) 1.29 10 (298.15 298 ) 1.19 10

292290+ 22.465 ( 298.15298 ) +
2
3
292272.667 kJ /kmol
298.18
^
^f+
H 6= H
Cp(v) dT
298
0+25.399 ( 298.15298 )+
4.31455 kJ /kmol
Therefore, the total enthalpy flow for vapor phase in outlet stream is:
n out H out =11.1752 (238344.33 ) +0.0651 (292272.667 ) +104.7052 ( 4.31455 )

2682120.747 kJ /hr
Stream 8 (Outlet): Liquid Phase

Watson Correlation:
^
^ v ( T B ) T c T out
H v ( T )= H
T c T B
0.38
0.0202(298.15 298 ) 3.85 10 (298.15 298 ) 3.19 10 (298.1
+
2
3
4
535.50298.15
^
H v (T )=31220
535.50352.79
0.38
34483.483 kJ /kmol
298.15
^
^ fH
^ v (T )+
H 7= H
23836034483.483+159.75 ( 298.15298 )
Cp (l ) dT
298
272819.5207 kJ /kmol
536.01298.15
^
H v (T )=40960
536.01372.70
0.38
47251.677 kJ /kmol
298.15
^
^ fH
^ v (T )+
H 8= H
Cp (l ) dT
29229047251.677+ 172.18 ( 298.15298 )
298
339515.8503kJ /kmol

298.15
^
^f+
H 9= H
Cp(v) dT
298
0+25.399 ( 298.15298 )+
0.0202(298.15 298 ) 3.85 10 (298.15 298 ) 3.19 10 (298.1
+
2
3
4
4.31455 kJ /kmol
Therefore, the total enthalpy flow for liquid phase in outlet stream is:
n out H^ out =93.5376 (272819.207 )+ 2.0719 (339515.8503 ) +7. 103 ( 4.31455 )

26222326.057 kJ / hr
The enthalpy flow and relative error for oulet stream (liquid phase + vapor phase):
n out H^ out =2682120.74722222326.057
28904446.804 kJ /hr
2.90E7
| ManualHysys
|100 |28904446.804+
|100
Manual
28904446.804
Relative Error=
0.33
Therefore, the heat duty of the condenser is:

nout H out n H
Q= H=
28904446.804(22445110.333)
out
6459336.47 kJ /h
Table 2 Inlet and Outlet enthalpy for condenser (E-103)

Compo
unds
Stream 7
Stream 8 (Vapor)
Stream 8 (Liquid)
(kmol/hr)
(kJ/kmol)
(kmol/hr)
(kJ/kmol)
(kmol/hr)
(kJ.kmol)
MEK
104.7172
-220245.705
11.1752
-238344.33
93.5376
-272819.521
SBA
2.1370
-271500.045
0.0651
-292272.667
2.0719
-339515.85
104.7172
11446.054
104.7052
4.31455
7.5410-3
4.31455
H2
Separator (V-101)
Stream
Stream
Phase
T (K)
P (atm)
8
Mixed
298.15
1.26
Phase
T (K)
P (atm)
11
Vapor
298.15
1.23
V-101
Stream
Phase
T( )
10
Liquid
298.15
1.23
P (bar)
Com
poun
ds
Stream 8 (Liquid)
n(kmol/ H(kJ/km
hr)
ol)
MEK
93.5376
SBA
2.0719
H2
7.5410-3
272819.5
21
339515.8
5
4.31455
Stream 8 (Vapor)
n(kmol/ H(kJ/km
hr)
ol)
11.1752
0.0651
104.7052
238344.3
3
292272.6
67
4.31455
Stream 10 (Liquid)
n(kmol/ H(kJ/km
hr)
ol)
Stream 11 (Vapor)
n(kmol/
H (kJ/
hr)
kmol)
93.5376
11.1752
2.0719
0.0651
7.5410-3
104.7052
Stream 10: Liquid phase

Enthalpy of MEK outlet:
Density , =
mass , m
volume , v
6744.9927 kg/hr
8614.676 L/hr
0.80076 kg /L
kJ
1L
72.11 kg
kmol . K
( 1.231.26 ) atm
0.80076 kg
1 kmol
L. atm
82.06
kmol . K
8.314
^
H 1=^v P
10.2659 kJ /kmol
Enthalpy of SBA outlet:

Density , =
mass , m
volume , v
153.5669 kg /hr
8614.676 L/hr
0.01783 kg /L
kJ
1L
74.12kg
kmol . K
(1.231.26 ) atm
0.01783 kg
1kmol
L . atm
82.06
kmol . K
8.314
^
H 2=^v P
12.6352 kJ /kmol
Enthalpy of H2 outlet:
Density , =
^
H 3=^v P
mass , m
volume , v
0.01460 kg/hr
8614.676 L/hr
1.69 106 kg/ L
kJ
8.314
1L
2.016 kg
kmol . K
( 1.231.26 ) atm
1 kmol
L . atm
1.69 106 kg
82.06
kmol . K
3625.7978kJ / kmol
Therefore, the enthalpy flow of stream 10 is:
n out H^ out =93.5376 (10.2659 )+2.0719 (12.6352 )+ 7.54 103 (7000.9647 )

1013.7650 kJ / hr
Stream 11: Vapor phase
Enthalpy of MEK outlet:

Density , =
mass , m
volume , v
805.8415 kg /hr
2.3E6 L/hr
3.50 10 kg / L
kJ
1L
72.11 kg
kmol . K
( 1.231.26 ) atm
4
1 kmol
L .atm
3.50 10 kg
82.06
kmol . K
8.314
^
H 4 =^v P
625.5665 kJ /kmol
Enthalpy of SBA outlet:

Density , =
mass , m
volume , v
4.8271 kg/hr
8614.676 L/hr
5.6033 10 kg /L
kJ
1L
74.12 kg
kmol . K
( 1.231.26 ) atm
4
1 kmol
L . atm
5.6033 10 kg
82.06
kmol . K
8.314
^
H 5=^v P
402.0604 kJ /kmol
Enthalpy of H2 outlet:
Density , =
mass , m
volume , v
211.0857 kg /hr
8614.676 L/hr
0.0245 kg /L
kJ
1L
2.016 kg
kmol . K
(1.231.26 ) atm
0.0245 kg
1 kmol
L . atm
82.06
kmol . K
8.314
^
H 6=^v P
0.25075 kJ /kmol
Therefore, the enthalpy flow of stream 11 is:
n out H^ out =93.5376 (625.5665 )+ 2.0719 (402.0604 ) +7.54 103 (0.25075 )

59347.0199 kJ /hr
Therefore, the heat duty of the condenser is:

n out ^
H out n ^
H
^
^
Q=
H=
(1013.765059347.0199)(28904446.804)
out
28844086.02kJ /hr
Com
poun
ds
Stream 8 (Liquid)
(kmol/h (kJ/km
r)
ol)
Stream 8 (Vapor)
(kmol/h (kJ/km
r)
ol)
272819.5
21
339515.8
5
238344.3
3
292272.6
67
MEK
93.5376
SBA
2.0719
H2
7.5410
-3
4.31455
11.1752
0.0651
104.7052
4.31455
Stream 10 (Liquid)
(kmol/h (kJ/km
r)
ol)
Stream 11 (Vapor)
(kmol/h
(kJ/
r)
kmol)
93.5376
-10.2659
11.1752
-625.5665
2.0719
-12.6352
0.0651
-402.0604
3625.797
8
104.7052
-0.25075
7.5410
-3
Mixer (B-19)
Stream
Phase
Stream
T (K)
Phase
P
T (atm)
(K)
P (atm)
23
Liquid
26
298.1615
Liquid
1.2
299.1844
1.2
Stream
25
Liquid
298.0686
1.2
Phase
T (K)
P (atm)
The changes of temperature is negligible since the temperature of all stream is approximately
same.
Compo
unds
Stream 26
(kmol/hr)
(kJ/kmol)
Stream 23
Stream 25
(kmol/hr)
(kJ/kmol)
(kmol/hr)
MEK
0.5802
0.5802
SBA
3.1510-3
3.1510-3
H2
4.6910-4
4.6910-4
H2O
0.07969
700.0001
TCE
4.97697
700.0799
-
4.97697
(kJ/ kmol)

Complete Energy BALANCE

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Complete Energy BALANCE

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CHAPTER 6

6.2.4 Equation for Non-Reactive

6.2.5 Equation for Heat Capacity, Cp

6.2.6 Total Heat for Energy Balance (non-reactive process)

6.2.9 Equations Used in Calculation

Heat Capacity of Gas

Cp = heat capacity of ideal gas

Table 6.2 Cp Coefficient for Gas

Heat Capacity of Liquid

Cp = heat capacity of liquid

From thermodynamics, the change in enthalpy, H, at constant pressure is

Table 6.3 Cp Coefficient for Liquid

Methyl Ethyl Ketone

6.3 Calculation of Energy Balance

P2= 1.3126 atm

SBA (v, 298.15, 1 atm)

SBA (v, 703.15, 1.411 atm)

SBA (v, 703.15, 1 atm)

SBA (v, 298.15 K, 1 atm)

SBA (v, 693.15 K, 1.3126 atm)

SBA (v, 693.15 K, 1 atm)

MEK (v, 298.15 K, 1 atm)

MEK (v, 693.15 K, 1.3126 atm)

SBA (v, 693.15 K, 1 atm)

H2 (v, 298.15 K, 1 atm)

H2 (v, 693.15 K, 1.3126 atm)

H2 (v, 693.15 K, 1 atm)

References:TCE (l, 298.15 K, 1 atm)

Inlet and outlet unknown enthalpy for Pump (B5)

TCE (l, 298.15 K, 1 atm)

TCE (l, 298.197 K, 1.197 atm)

Enthalpy for TCE outlet:

= (667.0198/465.8271) =1.432 kg/L

References: H2O (l, 298.15 K, 1 atm)

Inlet and outlet unknown enthalpy for Pump (B3)

H2O (l, 298.15 K, 1 atm)

H2O (l, 298.1615 K, 1.197 atm)

Enthalpy for H2O inlet:

= (12610.7/12687.51) =0.994 kg/L

H1 = (0.352 kmol/hr) (700.0001 kJ/kmol) = 252.98 kJ/hr

Inlet and outlet unknown enthalpy for E-106

SBA(l, 372.70 K, 1 atm)

SBA (v, 378 K, 2.62 atm)

SBA(v, 372.70 K, 1 atm)

SBA(v, 378 K, 1 atm)

MEK(l, 352.79 K, 1 atm)

MEK (v, 378 K, 2.62 atm)

MEK(v, 352.79 K, 1 atm)

MEK(v, 378 K, 1 atm)

H2O (l, 373 K, 1 atm)

H2O (v, 378 K, 2.62 atm)

H2O (v, 373 K, 1 atm)

H2O (v, 378 K, 1 atm)

= [92.053T + (-0.01997)T2 + (-7.034 10 T3+ (1.3367 10

=HV = 39.5 kJ/mol

)T2 + (9.9686 10 T3+ (-4.456 10

H2 (g, 378 K, 2.62 atm)

H2 (g, 378 K, 1 atm)

= 2031.92 + 64.5696 6.5786 + 0.3265 57.396

Reference: SBA (l, 25, 1

Inlet and outlet unknown enthalpy for H-101

SBA (v, 140, 1.47 atm)

SBA (v, 99.7, 1 atm)

SBA (v, 140, 1 atm)