LABORATORY 1B

lI
t.

Problenrs

Draw the NMR spectrum for each of the following compounds. Draw the peaks in the approximate positions where they would appear in a recorded spectrum. Also indicate the splitdng panern of the peaks.

a.

Acetone

b.

Propane

c-

Tohcne

d.

,-Buyl ethyl ether

e.

Ethyl acetate

974
I

NUCLEAR MAGNETTC RESONANCE SPECTROSCOPY: A SECOND VtStT

f.

Benzaldehyde

876543210
Common molecular moieties have easily distinguishable patterns in NMR
spectra. Match the

following molecular moieties with the generalized spectra shown below.

a.

xrcH-cHY,

b.

xrcH-cH2Y

c.

xcH2-cHrY

d.

xcH2crl3

LABORATORY 18

The following pairs of isomers can be easily distinguished by NMR.Identify the appropriate
spectrum for each isomer and explain all the peaks.

a.

r-Butyl ethyl ether and isopropyl propyl ether

b.

Methyl butanoate and isopropyl acetate

NUCLEAR MAGNETTC RESONANCE SPECTROSCOPy: A SECOND VtStT

These five spectra were recorded from different isomers with our molecular formula
CsHeClO.
They all contain a carbonyl functionaliry. Determine the structure of the different isomers.

LABORATORY 18

,
,

I,
I
I
I,

5.

The following spectra are from the isomers of CrHrOr. Identify the different compounds based
on the NMR spectra.

I
T
I
I,
I
I,
,

I,
,
,
,
D

t
I
,

t
I
t
,
,
D
D

101