CHEMICAL ENGINEERING THERMODYNAMICS

ASSIGNMENT-2
NAME: - DEBASMITA KUMAR
CLASS: - B. ChE. UG-II
SECTION: - A-1
ROLL NO:-001310301014
DATE: - 02-02-2015
SUBSTANCE CHOSEN: - WATER (H2O)
I. CALCULATION OF ACENTRIC FACTOR
ANTOINE'S CONSTANTS
A=16.3872 B=3885.70 C= -42.980

Acentric Factor () = 0.344

(Calculated from the equation

Psat
r T
=1.0log )
r =0.7

II. EQUATION OF STATE

Temperature chosen= 413.15 K
Pressure chosen= 3.58965 bar
Vg from steam tables= 0.5085 m3/kg
Vf from steam tables= 1.080x10-3 m3/kg
hv from steam tables=2144 kJ/kg
EQUATION
OF STATE

Vg
(m3/kg)
(calculat
ed)

Percent
age
deviatio
n (Vg)

Vf
(m3/kg)
(calculat
ed)

Percenta
ge
deviation
(Vf)

Percent
age
deviation
(hv)

N.A.

hg-hf=
hv
(kJ/kg)
(calculat
ed)
2235.692

1. Ideal Gas
Equation
2. Van Der
Waals
Equation
3. RedlichKwong
Equation
4. SoaveRedlichKwong
Equation
5. Peng
Robinson
Equation
6. Law of
Correspondi
ng States
7.Generalise
d
Compressibil
ity
Correlation
8. LeeKesler

0.5316

4.5428%

N.A.

0.5243

3.1072%

2.2617x10

109.324%

2195.479

2.4011%

42.491%

2185.902

1.9544%

35.851%

2178.634

1.6154%

20.315%

2177.657

1.5698%

4.2767%

-3

0.5213

2.5172%

1.5389x10
-3

0.5195

2.1632%

1.4672x10
-3

0.5191

2.0846%

1.2994x10
-3

0.5234

2.9302%

2.2631
x10-3

109.546%

2191.688

2.2243%

0.5243

3.1072%

2.2622
x10-3

109.463%

2195.477

2.4010%

N.A.

N.A.

1.3171
x10-3

21.954%

N.A.

N.A.

Equation
9.
Generalised
Virial
Equation

Minimum
Minimum
Minimum
Minimum

0.5164

1.5537%

N.A.

N.A.

deviation(Vg) is for: Generalised Virial Equation

deviation(Vf) is for: Peng Robinson Equation
deviation(hv) is for: Generalised Virial Equation
deviation(overall): Peng Robinson Equation

2171.767

1.2951%