Input parameters: Temperature of last ice melting (Tm), Temperature of homogenization

(Th )
System: NaCl-H2 O

Equations

Salinity (wt% NaCl equivalent)

= 1.76958*t_m - 4.2348e-2*pow(t_m, 2.0) + 5.2778e-4*pow(t_m, 3.0)
Where t_m is the negative of depresión of freezing point from zero

Input parameters : Temperature of homogenization (Th ) and Temperature of dissolution

of halite (Td )
System: NaCl – H2 O

Salinity (wt% NaCl eq) = 26.218+7.2e-3*t_d+1.06e-4*pow(t_d,2.0) (where t_d is

dissolution temperatura of halite in deg C)

For NaCl-H2 O

Density at temperature of homogenization ( T h)

rhoth(i)= bcoef(1)-bcoef(2)*fth(i)**2-bcoef(3)*fth(i)**4
+bcoef(4)*fscl(i)-bcoef(5)*fth(i)*fscl(i)
+bcoef(6)*fth(i)**2*fscl(i)
+bcoef(7)*fth(i)**3*fscl(i)-bcoef(8)*fth(i)**8*fscl(i)
+bcoef(9)*fth(i)*fscl(i)**2-bcoef(10)*fth(i)**2*fscl(i)**2
-bcoef(11)*fscl(i)**3+bcoef(12)*fth(i)**2*fscl(i)**3
-bcoef(13)*fth(i)**2*fscl(i)**7

Where fth is Th/100 and fscl = wt%NaCl eq/10

Bcoef 1 to 13 are the coefficients of the regression equation

bcoef/0.9923,3.0512e-2,2.1977e-4,8.6241e-2,4.1768e-2,
1.4825e-2,
1.446e-3,3.0852e-9,1.3051e-2,6.1402e-3,1.2843e-3,3.7604e-4,
9.9594e-9/
Equation for isochore for an NaCl-H2 O fluid
dP/dT (bar/0 C) = aS + bS Th + cS Th2

whe re as ,bs and cs are the salinity dependent parameter. Integration of this equation
between the limits of Th to T(any te mpe rature above Th)would give the pressure.
T
P (a S bS Th c S Th2 )dT
Th

aS =18.28+1.44413S+0.00472441S2 -0.0024213S3 +0.000038064S4

bs=0.019041-1.5268x10-2 S+5.66012x10-4 S2 -4-2329x10-6 S3 -3.0354x10-8 S4

cs=-1.5988x10-4 +3.6892x10-5 S – 1.9473 x 10-6S2 + 4.1674 x 10-8 S3 – 3.3008 x 10-10 S4

whe re S is the salinity in wt% NaCl.

Parameters:

Temperature of melting of CO 2 (Tm,CO2 ), Temperature of homogenization of CO 2 (Th,CO2 ),

Mode (liquid or vapor)

Density of the pure CO 2 inclusion is obtained from the following expression

0.347 ( i 1) / 3
2
dl / v T T
1 C0 1 Ci 1
dc Tc i 1 Tc

//c*********Calculation of CO2 density from Parry, 1986*******

c_zero=1.9073793;
c_1=0.38225012;
c_2=0.42897885;
d_zero=-1.7988929;
d_1=-0.71728276;
d_2=1.7739244;
t_crit_co2=304.21;
d_crit_co2=0.01059;
fact=1-((th_co2+273.15)/t_crit_co2);
(if homogenization is to liquid phase then)
fact=c_zero*pow(fact,0.347)+c_1*pow(fact,0.666666)+c_2*fact;

(if homogenization is to vapor phase then)

fact=d_zero*pow(fact,0.347)+d_1*pow(fact,0.666666)+d_2*fact;

fact=fact+1;
fact=fact*d_crit_co2;
d_co2=fact*44.0;

Calculation of isochors of pure CO 2 inclusion

aCO2 a(T ) 73.03x106 71400T 21.57T 2 (in this equation T is in deg C)

bCO2 = 29.7

R=83.12 cm 3 bar / deg V = (1/d_co2)*molecular weight of CO 2

RT a
P (in this equation T is in deg K)
V b T 1 / 2V (V b)