‘Table 3. Experimental VLE data ofthe systems containing acrylonitrile or aceon at 32315 K(P and ar caked vas) Pion) u de i t Por) 5 ‘exisiieswaer . 16 mS]. S60 2883S La 1S21 68S) 3895.00 50D astm 1488 BisiTT mS 79 QNS2 7182 36208 MS6 5S I9OTB Lol 3490 Lae 5067 3853 NOG TSM TMK LONST HTH T8856 2087 36129 ASM SIM SRTRR LISD OTT Lowa sms 982A aceinitiletwaer Usoh 87 DMS TNSSB 000 BLAS SETS Tea 15847 L5e6l OSS HHL. 18ST} IDA 8 M508 STL S713 BB LOL RSID 8086S oD aT 263.26 1616S OBIT SMS LIS S246 M8 THOT 2ST) LM 58380 scyloitetaceloniie 216 OOD) RBA SH85 mee LOD ist WTR OORT gm 10191 265 0813 OL SSNH MRIS GS 978.0190 8981660190813 1.000) 852907 om 101 2831 HSL LOONS RHR TH 10 r 263 MGB 85S 1010510086 HB 8IZ Yc. 9m AST t00st 088 cronies water cestoitites eter corenit 3 2 00 02 04 06 08 10 02 04 06 08 1000 02 04 08 08 Vd Flg.2.xy-P dingrams of the systems containing acrylonitrile and actor a 323.18 K, (© ta, pha: @ vap. phase; — g! model eg; ——— met UNIFAC e3) LHWAHAK KONGHAK Vol. 35, Na. §, October, 1997‘Table 4. Fitted g* model parameters and mean deviations between vapor phase moe fracon of the sjtems containing acry- lontrie or acon at 323.15K. An Ay a ay scryniie wae Marl 299972233 60 van Laat 302 RID ass Wikon 149864591806 7811 mss NRIL 1357815 180678104280 OO UNIQUAC —TBLOBS—TERTBIL 00846 seco rw Meus 229761896 oon van Lat 25M 8402 0091 e Wika KAS 14550884 nist — Redich-Katar og, NEIL erscon 1132351703831 OB + mince eon UNIQUAC 4343854 211.1680 (61 wre a secon racine , Margules am om? wer van Last 0342 ats 007 ‘ig. 3, Excess molar volumes of the systems containing acrylonitrile Wilson 635557 148 0.0007 and acetonitrile at 298.15 K. RTL =3248116 40288-0300, a7 (© scyontlernter, Cacaonineewaer, anylniis- UNIQUAC- 1574482 194.5279 oor contre) ‘Table 5. Excess moar volumes(Vicn’ mol ofthe ystems cntanng arlantle or scrote at 298.18 K x ¥ 7 ¥ % ¥ a ¥ ‘elena ons a0 ootss ~ouues oss ~onea0 ass ~oo1ss oon on ota ors 09389 sis asm 0016s omnss onus onan ~ouse sere ~oons sez ams omnes ‘882 nes ore 09895 sie ses ons 0188 oss nea cums 09678 nase ass ann aon, mms? sts 00885 sms 00046 om ooo -cetoiieswate 001% ~030%6 ons ~0s7s 0486 —n4eee snes ozs nen mis 1380) osni7 oso ~patis sss 01525, 00 oan 03888 050 re) 0.39530 asst ass 159% =ns0n6 ass costs om ~0367 asi ons a2 03807 own 03168 ours 2st ssa anes sxnleitleacctniile ~00ne2 asta ona os ~oms7 nia ante anias ose onze 06595 ~ommn 0352 -a0138 ais 0is6 stot ons ams mss 9525 ~omirs amr ~aniss osss3 one 738s -om0 a2sit mms assia mse soo msTable 6. Fitted Redlich-Kister parameters for V" of the system con- taining acrylonitrile or acetonitrile and water at 298.15 K acrylonitrile acetonitrile acrylonitrile +water +water +acctonitrile A, = 3.89172 — 2.06287 ~ 0.12314 A; 4.11281 1.14346 0.00458 As 0.65525 — 0.58321 0.01846 A 0.55115 1.53889 ~ 0.01802 As — 1.17356 — 0.69887 — 0.06024 S{cm’ mol ') 0.0008 0.0023 0.0004 VEO - 7.97196 ~ 6.02730 ~ 0.15148 Vw 0.84837 0.66260 0.17836 0.80 ¥¢ 0.79 3 8 0.78 2 e 0.77 3 0.76 © 0.75 ° 0.74 s 3 0.75 £ = 0.72 2 Zon 0.70 150 200 250 wo 350 400 450 P (torr) Fig. 4. Relationship between pressure and acetonitrile composition of azeotropic point of the acetonitrile+water system.Table |. Voporliquid Equilibrio of Acrylonitrile-Acetonitrile System under 760 Mm, Total Pressure Activity Acrylonitrile Acrylonitrile ___Coefticients_ Boiling im Liquid. —_in Vapor, Acrylo- Aceto- Temp.,"C. Mole Mole nitrile nitrile 798 79 98 13 1.085 79.2 16.8 20.6 LSS 1027 785 31.7 36.0 1,060 Loa? 782 40.8 43.1 1.031 1.061 Ti 55.7 53.6 1.035 L054 4 73.0 9 1,007 1.080 73.3 91.7 24 L004 1.087 Table Il. Vapor-Liquid Equilibria of Acetonitrile Water System under 760 Mm, Total Pressure Activity Acetoniteile Acetonitrile Coefficients Boiling in Liquid, —_ in Vapor, Aceto- Temp..°C. Mole % = nitrile Water 5 29 26.3 13.050 1333 BLL 93 50.5 5.508 LNG 80.0 442 58.9 4.126 1.098 78.6 24 61.7 2.665 1,158 TA 40.2 65.5 1.851 1.378 7 80.7 66.4 1.826 1.669 76.6 62.7 es 1.490 1,184 76.0 71.8 728 1.205 2.438 76.6 a9 73.0 1.088 3.387 68 95.6 76.1 1.090 4.04 a4 98.6 5 0.982 8.277