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Principle :
Amperometry analysis is a type of
voltammetric analysis which is widely used
in food processing industries.
Amperometry:
A form of voltammetry in which we measure current as a
Amperometry
Amperometry is extended technique of D.C. polarography.
Well suited for trace level determination of metal ions.
One of the most distinguishing feature of this technique is that
like other voltammetric techniques, it can also indicate the nature
of the species dissolved in the solution
Does not merely limit itself to the total elemental content as is
the case with sophisticated non-electrochemical methods such as
neutron activation analysis, X-ray fluorescence and atomic
absorption spectroscopy
Amperometric Titration
DIFFERENT ELECTRODES
USED IN AMPEROMETRY
Though the traditional D.C. amperometric titrations are performed
with D.M.E. as the indicator electrode
Other electrodes have also been used for the purpose like Platinum
wire electrode, rotated at constant speed of 600 r.p.m. or more, has
been used on a large scale. [Latinen and Kolthoff, 1941] .
Mechanical mixing help in bringing the electroactive species to the
electrode surface, besides diffusion.
Consequently, limiting currents are much higher, about twenty
times, in comparison to those obtained with D.M.E.
Limitations of RPE
Other Electrodes