FORMULARIO FISICOQUIMICA II

x+ x 2=1

M RT 20, f
Kf =
H FUS

P=( 1x 2) P

f =

P=x P 0
P=( 1x 2x3 ) P0

( xz )

f =KT

( Tz )

P P
DR=
P0

%DR=

P P
100
0
P

f =c

( Pz )

f =K

( z )

G=G 0 +nRT . ln (P)

dG=SdT +VdP

= 0+ RT . ln(P)

~
d=V dP

sol, LIQ =oLIQ , puro + RT . ln (x)

lnx=

H VAP

x 2=

RT 20
H VAP
RT 20

( T )

RT . ln (x2 )
~
V
~
=RT C

(T )

T =Kb . m2
M RT 20
Kb=
H VAP

RT . lnx
~
V

=hg=P HIDR

x 2=

y 2 Ptotal
P02
0

P P2

T =Kf . m

Ptotal=

M RT 20,b
Kf =
H VAP

Ptotal=P0 + x 2 ( P02P0 )

P2+ y 2 ( P P2 )


BL

BV

i
P

( )

ntot(vap ) ntot (liq)

y 2=

x 2=

x 2 P20
0

0
2

T , nk

V i

Gmez = H mez T S mez

0

P + ( P P ) x 2
y2 P 0

P02 ( P02 P 0 ) y 2

V real =V n+ V 2 n 2+ V 3 n3 +..

dG=SdT +VdP+ k d k

G mez
P

T , nk

=V mez

G mez =RT nk ln x k

Smez =R nk ln x k