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Atoms
Light
Light is a kind of electromagnetic
radiation.
All forms of electromagnetic
radiation move at 3.00 x 108 m/s.
Parts of a Wave
Crest
Wavelength
Amplitude
Origin
Trough
Parts of a Wave
Origin the baseline of a wave
Crest - high point on a wave
Trough - low point on a wave
The amplitude of a wave is the
waves height from the origin to a
crest, or from the origin to a
trough.
Wavelength
Wavelength (represented by ,
the Greek letter lambda) is the
shortest distance between
equivalent points on a continuous
wave.
Wavelength - distance from crest
to crest or trough to trough
Wavelength is usually expressed
in meters (m).
Frequency
Frequency (represented by f ) is the
number of waves that pass a given
point per second.
Units are cycles/sec or hertz (Hz)
Relationship Between
Frequency and Wavelength
c = fl
The Electromagnetic
Spectrum
High
Low
energy
energy
Radio Micro Infrared
Ultra- XGamma
waves waves .
violet Rays Rays
Low
High
Frequency
Frequency
Long
Short
Wavelength
Wavelength
Visible Light
E=hf
E = energy of the photon (J Joules)
f = frequency (Hz)
h is Plancks constant
h = 6.63 x 10-34 Joules.sec
STOP HERE
Bohrs Model
The orbits are circular and are at
different levels.
Amounts of energy separate one level
from another.
Modern View
The atom has two
regions and is 3dimensional.
The nucleus is at
the center and
contains the
protons and
neutrons.
Modern View
The electron
cloud is the
region where you
might find an
electron and most
of the volume of
an atom.
Lets look
at the
Bohr
Model in
greater
detail
Bohrs Model
Bohr proposed that electrons must
have enough energy to keep them in
constant motion around the nucleus.
Electrons have energy of motion that
enables them to overcome the
attraction of the positive nucleus.
Bohrs Model
Nucleus
Electron
Orbit
Energy Levels
Bohrs Model
Increasing energy
Fifth
Fourth
Third
Second
First
Nucleus
Further away
from the
nucleus
means more
energy.
Electrons
reside in
energy levels.
The Quantum
Mechanical Model
The Quantum
Mechanical Model
The lowest allowable energy state
of an atom is called its ground
state.
When an atom gains energy, it is
said to be in an excited state.
The Quantum
Mechanical Model
When the atom is in an excited state,
the electron can drop from the
higher-energy orbit to a lower-energy
orbit.
As a result of this transition, the atom
emits a photon corresponding to the
difference between the energy levels
associated with the two orbits.
Atomic Spectrum
What Color Tells Us
About Atoms
Atomic Spectrum
By heating a gas
of a given
element with
electricity, we
can get it to give
off colors.
Atomic Spectrum
Each element
gives off its own
characteristic
colors.
The spectrum
can be used to
identify the atom.
Ultraviolet
Visible
Infrared
Question
Question
b) An electron falls from energy
(410 nm)
Question
c) An electron falls from energy
Question
d) An electron falls from energy
Question
e) An electron falls from energy
(blue)
Question
f) An electron falls from energy
(red)
The Quantum
Mechanical Model
A three-dimensional region
around the nucleus called an
atomic orbital describes the
electrons probable location.
Energy Levels
Energy Levels
Sublevels
Principal energy levels contain
energy sublevels.
Principal energy level 1 consists of
a single sublevel, principal energy
level 2 consists of two sublevels,
principal energy level 3 consists of
three sublevels, and so on.
Sublevels
Sublevels are labeled s, p, d, or f.
The s sublevel can hold 2 electrons,
the p sublevel can hold 6 electrons,
the d sublevel can hold 10
electrons, and the f sublevel can
hold 14 electrons.
s block
p block
d block
f block
Orbitals
Sublevels contain orbitals.
Each orbital may contain at most
two electrons.
s orbitals
One s orbital
for every
energy level
Spherical
shaped
Called the 1s, 2s, 3s, etc orbitals
p orbitals
Start at the second energy level
3 different directions
3 different dumbbell shapes
p Orbitals
d orbitals
Start at the third energy level
5 different shapes
f orbitals
Start at the fourth energy level
Have seven different shapes
f orbitals
Summary
# of
Max # of
shapes electrons
Starts at
energy level
10
14
s block
p block
d block
f block
s1
s- block
s2
s2
d2
d3
d4
d5
d6
d7
d8
d9 d10
The p-block
p1 p2
p3
p4
p5
p6
f - block
1
2
3
4
5
6
6
7
3d
2
3
4
5
6
7
4f
5f
Electron Configurations
Electron configurations represent
the way electrons are arranged in
atoms.
Aufbau principle - Electrons enter
the lowest energy first.
Electron Configurations
This causes difficulties because of
the overlap of orbitals of different
energies.
At most there can be only 2
electrons per orbital, and they must
have opposite spins.
Electron Configuration
1s2
2 electrons
1s2 2s2
4 electrons
total
20 electrons
total
56 electrons
total
88 electrons
total
108 electrons
total
Electron Configuration
Electron Configuration
7s 7p 7d 7f
6s 6p 6d 6f
5s 5p 5d 5f
4s 4p 4d 4f
3s 3p 3d
2s 2p
1s
Electron Configuration
Electron Configuration
7s 7p 7d 7f
6s 6p 6d 6f
5s 5p 5d 5f
4s 4p 4d 4f
3s 3p 3d
2s 2p
1s
Question
Question
Question
Question
Question
Example
Example
2 + 2 + 6 + 1 = 11
Question
(sulfur - S)
Question
(copper - Cu)
Question
(germanium - Ge)
Example
Example
[Ne]
s block
p block
2
3
d block
4
5
6
7
f block
Neonnoble
The
is in light
gas configuration
electron
blue; magnesium
configuration
additional
is 3s2is.
in bright
for
magnesium
yellow. is: [Ne] 3s2
Example
Example
[Ar]
s block
p block
2
3
d block
4
5
6
7
f block
Argon
The
additional
noble
is ingas
lightconfiguration
electron
blue; nickel
configuration
is
is in
4s2 3d8.
bright
(Remember
for
nickel
yellow.
is: you
[Ar] subtract
4s2 3d8 1 from the d
sublevel row number.)
Question
Question
Question
Valence Electrons
Valence Electrons
Valence Electrons
Valence Electrons
Valence Electrons
Question
(4)
b) bromine (Br)
(7)
Question
c) iron (Fe)
(2)
d) potassium (K)
e) aluminum (Al)
(1)
(3)
Question
Write a Lewis dot diagram for
chlorine.
Question
Write a Lewis dot diagram for
calcium.
Question
Write a Lewis dot diagram for
potassium.