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: S, ES, XRF

.

: S, ES.

[UV-Vis]


(Atomic Absorption Spectrometry, AAS)

, Flame Photometry (FF)

(inductively coupled plasma, ICP)


Atomic Absorption Spectrometry, AAS

(Atomic Absorption
Spectrometry), AAS o

.

.


I.


.

.

AAS

AAS
(T)/chopper

AAS

1.
eX(aq)

e(s)
2.
eX(s)

e(g)
3.
eX(g)

e +
4.
e

e*
5.
e*

e+ + e

AAS
1,2,3,4 FF ( ) 1,2,3,4,5.

Nj/No

Cs
Na
Ca
Zn

nm
852.1
589.0
422.7
213.9

g1/go
2
2
3
3

2000 oC
0.04
1x10-3
1x10-5
1x10-13

Nj/No= (g1/go) e-Ej/kT

3000 oC
0.072
0.06
4x10-3
6x10-8





..(10-3nm 10-2nm).

AAS
I. K

AAS

1.

.
(
)
2. .
.
3. :
.

II.

80-900/0

AAS, FF

O-
-
-
-
2-
-

oC
1900
2100
2200
2750
2800
3100

-: (FF)
- :
2-: Al, Si, Ti, La
-: < 200nm
:

D2


l (1-100 l ) mg


GFAAS

(Zeeman)

s 3+ +4 NaBH4+H+
AsH3+H2+2B2H6+4NaCl
AsH3 (800 oC)
As +3/2 H2


, LODs,

(As, Hg, Sb, Sn, Te)

Lambert-Beer
A= . b . C
A=- log T= 2- log ( % T)



HCl, HNO3,
H2SO4 ,

()
: 0.45


- :
(. l,
Zn )

4 oC
(1 mg/L)

AAS
(
D2)


AAS
70 LOD 0.01-10 ppm
Zr, Hf, Nb, Ta,
Ti, U

, ,


, ,
, LODs,
(As, Hg, Sb,
Sn, Te)

/ /

/ FF
FF
AAS





,
AAS, .

( )
.

1.

0,5 2 ml/min
10 30 ml/min

2.

3. 2-2
)

FF

Li
(standards) ( )
..



.
-:
Na

Na+ + e

+ + e
43-, SO42 .. EDTA

I ~c

FF
, ,
Ca.
B, La, K, Rb, Rh, Sr
.
.
AAS.

( ).
Li
.

()
()

,,:

:
,:

1-10 mg

:

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