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.
: S, ES.
[UV-Vis]
(Atomic Absorption Spectrometry, AAS)
, Flame Photometry (FF)
(inductively coupled plasma, ICP)
Atomic Absorption Spectrometry, AAS
(Atomic Absorption
Spectrometry), AAS o
.
.
I.
.
.
AAS
AAS
(T)/chopper
AAS
1.
eX(aq)
e(s)
2.
eX(s)
e(g)
3.
eX(g)
e +
4.
e
e*
5.
e*
e+ + e
AAS
1,2,3,4 FF ( ) 1,2,3,4,5.
Nj/No
Cs
Na
Ca
Zn
nm
852.1
589.0
422.7
213.9
g1/go
2
2
3
3
2000 oC
0.04
1x10-3
1x10-5
1x10-13
3000 oC
0.072
0.06
4x10-3
6x10-8
..(10-3nm 10-2nm).
AAS
I. K
AAS
1.
.
(
)
2. .
.
3. :
.
II.
80-900/0
AAS, FF
O-
-
-
-
2-
-
oC
1900
2100
2200
2750
2800
3100
-: (FF)
- :
2-: Al, Si, Ti, La
-: < 200nm
:
D2
l (1-100 l ) mg
GFAAS
(Zeeman)
s 3+ +4 NaBH4+H+
AsH3+H2+2B2H6+4NaCl
AsH3 (800 oC)
As +3/2 H2
, LODs,
Lambert-Beer
A= . b . C
A=- log T= 2- log ( % T)
HCl, HNO3,
H2SO4 ,
()
: 0.45
- :
(. l,
Zn )
4 oC
(1 mg/L)
AAS
(
D2)
AAS
70 LOD 0.01-10 ppm
Zr, Hf, Nb, Ta,
Ti, U
, ,
, ,
, LODs,
(As, Hg, Sb,
Sn, Te)
/ /
/ FF
FF
AAS
,
AAS, .
( )
.
1.
0,5 2 ml/min
10 30 ml/min
2.
3. 2-2
)
FF
Li
(standards) ( )
..
.
-:
Na
Na+ + e
+ + e
43-, SO42 .. EDTA
I ~c
FF
, ,
Ca.
B, La, K, Rb, Rh, Sr
.
.
AAS.
( ).
Li
.
()
()
,,:
:
,:
1-10 mg
: