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GEOLOGICAL SURVEY
PROFESSIONAL PAPER
1160
GEOLOGICAL SURVEY
H. William Menard, Director
CONTENTS
Page
Abstract ______________________________
Introduction ____________________________
Acknowledgments _________________________
Sulfide deposits __________________________
Deposits in stable tectonic settings _____________
Deposits in areas that have been tectonically active ____
Komatiites _________________________
Small intrusions _____________________
General characteristics ____________________
Nickel-laterite deposits _____________________
1
1
2
2
2
2
2
3
3
3
rage
4
6
6
9
10
11
12
13
ILLUSTRATIONS
FIGURES 1-8. Graphs showing:
1. Several hypothetical grade and tonnage relationships _____________
2, 3. Grade and tonnage of:
2. Nickel sulfide deposits associated with komatiitic rocks _______________
3. Nickel sulfide deposits in komatiitic rocks from four regions ________
4. Quality control of tonnage and grade for nickel sulfide deposits in komatiitic rocks from four regions
5-8. Grade and tonnage of:
5. Nickel sulfide deposits associated with small intrusions __________
6. Two types of nickel sulfide deposits _____________________
7. Nickel-laterite deposits ________________________________
8. Oxide nickel-laterite deposits _________________________________
5
7
8
9
10
11
12
13
TABLES
TABLES 1-6. Summary statistics for grade and tonnage of:
1. Fifty-two nickel sulfide deposits associated with komatiitic rocks ___________________
2. Nickel sulfide deposits in komatiitic rocks from each of four regions and from the regions as a pooled group
3. Nickel sulfide deposits associated with small intrusions _____________________
4. Nickel sulfide deposits _________________________________________
5. Nickel-laterite deposits __________________________________
6. Oxide nickel-laterite deposits ________________________
7
9
10
11
11
12
in
CONVERSION FACTORS
Inch-Pound equivalent
Metric unit
Specific combinationsContinued
Length
millimeter (mm)
meter (m)
kilometer (km)
=
=
=
Area
square meter (m2 )
square kilometer (km2 )
hectare (ha)
= 10.76
=
.386
= 2.47
Volume
cubic
liter
cubic
cubic
cubic
liter
liter
liter
cubic
centimeter (cm3)
(L)
meter (m3 )
meter
hectometer (hm3 )
meter
cubic meter
= 0.061
= 6,1.03
= 35.31
.00081
= 810.7
= 2.113
= 1.06
=
.26
=
.00026
=
6.290
Weight
gram (g)
gram
metric tons (t)
metric tons
=
=
=
=
0.035
.0022
1.102
0.9842
Specific combinations
kilogram per square
centimeter (kg/cm2 )
kilogram per square
centimeter
cubic meter per second
(mVs)
0.96
atmosphere (atm)
.98
= 35.3
Inch-Pound equivalent
Metric unit
=
.0353
= 91.47
3.28
5.28
= 1.8
degrees Fahrenheit (F)
= [(1.8xC)+32] degrees Fahrenheit
.9113
3.28
= 10.764
= 22.826
= 264.2
= 15.85
= 4.83
.62
= 612.43
2.048
.0142
Temperature
INTRODUCTION
ACKNOWLEDGMENTS
SULFIDE DEPOSITS
GENERAL CHARACTERISTICS
3. Experimental evidence (Green and others, 1975) in
dicates that these ultramafic flows were extruded
Although different in many details, different types of
at temperatures from 1,400-1,600 C. These sulfide deposits are strikingly similar. Largely, this
temperatures imply that the geothermal gradients results from basically similar mechanisms of formation.
controlling komatiite formation were much steeper Most nickel deposits associated with igneous rocks are
than those presently existing (Green, 1975).
believed to have been formed by separation of an im
4. Nickel deposits are associated with only the most miscible sulfide phase within a crystallizing silicate melt.
magnesium-rich members of the komatiitic suite Because of the strong affinity of sulfur for metals, dense
(Naldrett and Arndt, 1976).
droplets of immiscible sulfides combine with metallic
elements
in the melt and settle toward the bottom of the
Highly successful exploration models have been devis
magma.
Commonly,
massive metallic-sulfide deposits
ed using the nickel sulfide-komatiite association. Ex
form
in
topographic
or structural depressions at the
ploration has been directed toward shield areas in which
magma-chamber
base.
Successively overlying the
ancient erogenic belts and magnesium-rich ultramafic
massive-sulfide
ores
are
a
zone of disseminated sulfides
rocks exist. Particular attention is given to the basal
and
a
zone
of
barren
silicates.
Sulfide minerals within
contact where immiscible sulfides would most likely ac
deposits
commonly
are
pyrrhotite,
pentlandite,
cumulate. Since discovery of the Kambalda (Australia)
chalcopyrite,
and
minor
pyrite.
In
addition
to nickel,
deposits in 1966, this model has been used to find many
many
deposits
contain
significant
amounts
of
copper
other deposits throughout western Australia. Deposits
and
minor,
but
locally
recoverable,
amounts
of
cobalt,
associated with komatiites are now known from the
platinum-group
elements,
and
selenium.
Later
deforma
shield areas of Canada, Africa, and Australia. Addi
tional deposits in these areas surely exist. Further, large tion, metamorphism, or hydrothermal alteration may
shield areas, such as those in Greenland, Brazil, India, mobilize the sulfides and obscure the deposit's initial
the U.S.A., and the U.S.S.R., have favorable rock types magmatic character.
Tonnage of nickel sulfide varies greatly and is in
in which few or no nickel deposits have yet been
fluenced
by many factors. Perhaps most important are
discovered. Promising exploration targets are surely
(1)
the
size
of the igneous complex (as size of the igneous
present in these areas. The wide geographic distribution
complex
increases,
the potential for forming larger ton
of these deposits and the availability of grade and ton
nage
deposits
generally
also increases), (2) the nickel
nage data make this deposit subclass particularly
and
sulnir
content
of
the
magma (the potential for
suitable for grade and tonnage analysis.
larger tonnages increases as the nickel and sulfur con
tent of the magma increases), (3) the size of the trap in
which sulfides accumulate, (4) the nature of the magma
SMALL INTRUSIONS
circulation, and (5) postore deformation.
The grade of nickel sulfide deposits also varies, but it
The second subclass (small intrusions) for which appears to be controlled principally by the crystalliza
statistical analysis of grade and tonnage was attempted tion history of the magma, which in turn is closely tied to
contains several diverse types of deposits. Although the magma's primary sulnir and metal content. If the
division of these deposits into several smaller groups is magma were saturated with sulfur before many silicates
possible, placing them together in a broad subclass had crystallized, then an almost pure immiscible nickel
makes a large and homogeneous population that is sulfide phase could separate and concentrate to form a
amenable to statistical analysis and use in regional high-grade deposit. If, however, sulnir saturation were
resource assessments. The deposits are mostly small delayed, the immiscible sulfide phase would be intermix
and low grade; thus they have not been significant pro ed with silicate crystals and lower grade sulfide deposits
ducers of nickel, and little has been written about their would form. Other factors locally important in determin
geologic character. Most are in small- to medium-size, ing grade involve the circulation system of the magma
predominantly mafic intrusions that range in age from chamber, wallrock reactions, postmineralization
Precambrian to Tertiary. Their relatively large copper- mobilization of ore, and supergene alteration.
to-nickel ratio (generally greater than one copper to five
NICKEL-LATERITE DEPOSITS
nickel) reflects their mafic composition and is particular
ly useful in distinguishing these deposits from those
The contribution of nickel-laterite deposits to the
associated with the more ultramafic komatiites
(Naldrett and Cabri, 1976). The Great Lake, Lynn Lake, world nickel supply has been variable. In the late 1800's,
and Giant Nickel deposits of Canada are examples of production from New Caledonia deposits supplied most
of the world's nickel. However, with the development of
this subclass.
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INCREASING TONNAGE
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INCREASING TONNAGE
FIGURE 1.-Log-log plots illustrating several hypothetical tonnage and grade relationships. A, Closed ore system. The
dashed line shows the potential values for deposit grade and tonnage; the dot represents the actual deposit grade
and tonnage. B, Four separate ore systems similar to that in A. Because each system is isolated from the other,
grade and tonnage among the actual deposits (a,b,c,d) are independent; no correlation exists. C, Deposit type in
which chemical and physical factors (such as mineralogy) place limits on deposit tonnage and grade and thus tend to
restrict the part of the plot in which deposits fall (dots). Depending on the envelope (dashed line) produced by the
restrictions, a grade-tonnage correlation may be induced. D, Two different deposit types (dots and crosses) tend to
occupy discrete areas of the grade-tonnage plot. Although tonnage and grade are independent within each deposit
type, an inverse grade and tonnage correlation exists when the two deposit types are considered together.
1.00
0.32
0.60
3.16
316
1000
3.98
2.51
0.40
0.20
O
CC
o_
cc
(D
O
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1.00
0.00
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(D
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0.63
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O
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-0.40
0.40
-0.60
0.25
-0.80
8.5
8.0
7.0
7.5
LOG 10 TONNAGE (METRIC)
FIGURE 2.-Grade and tonnage of nickel sulfide deposits associated with komatiitic rocks.
5.5
6.0
6.5
Number of
deposits Median
(n)
Tonnage,
metric ___
52
8.49 xlO2
Nickel grade,
percent __
52
1.24
Standard
deviation
Vftj
(assymmetry)
62
(skewness)
6.93
0.86
0.49
2.31
-0.62
.09
.27
-.29
2.65
-0.62
0.16
9.0
1.00
3.16
10.0
I
31.6
100.
316
10(30
3.98
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0.40 ~
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g!
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2.51
-0.40
Abitibi region
Thompson region
Ungava region
West Australia region
<
-0.60
-0.80
5 .5
cc
UI
0.40 >
0.25
X
6.0
6.5
7.0
7.5
8.0
8.5
90
0.16
regions. Because the five remaining regions contain at proximately equal. Standard deviations (the square root
most four deposits each, they were excluded from an of variance) of average grade and tonnage within each
analysis of regional differences. The average nickel region (table 2) vary by about an order of magnitude.
grade and tonnage of deposits from the four regions are The large differences in the standard deviations plus the
plotted in figure 3, and summary statistics for the relatively small sample size of each region suggest that
observed distributions of both variables for each region the data probably do not meet the requirements of
and for all regions combined are presented in table 2.
techniques such as the analysis of variance. In such
The beta statistics for four regions are not significant situations a quality-control chart, showing grade and
ly different from values expected from theoretical tonnage, can aid in the interpretation of differences of
lognormal distributions. However, the average nickel the means of variances.
grade of the four groups together is significantly skew
Figure 4 presents the means of average grade and
ed. Thus, the data from the four regions meet one of the tonnage and the means plus and minus two standard er
requirements of most statistical methods (such as rors of the means for the deposits in the four regions.
analysis of variance) for testing for population (regional) Figure 4 reveals that differences between regions can be
differences. Another requirement of most methods is quite large. Given that large regional differences exist in
that variances (and covariances) of the regions be ap the average grade and tonnage of deposits, the question
Region
Abitibi
19
Ungava
West Australia
Four regions
8
14
41
Mean of
log Ni
grade
-0.0795
.0642
.2867
.2117
.1334
Standard
devia
tion
0.1224
.0600
.0288
.0678
.0781
0.5995
-.0152
- .5290
- .2937
1.9764
1 9694
2.2301
Mean of
log ton
nage
6.7858
7.5433
6.3590
6.8007
6.9293
1 9770
3.0858
Standard
devia
tion
1.7681
.5539
.1622
.6932
.8587
"
0.8285
-.1045
-.1050
.4256
.5050
1.8589
2.2541
1.9799
2.080
2.1266
Correla
tion coeffi
cient (r)
0.9166
.6116
- .2989
- .6417
-.6633
arises: Are the correlation coefficients of average grade ference that basically the same geological processes
and the tonnage of deposits within regions significantly formed the deposits in the four regions.
different? The correlation coefficients (table 2) of the
variables for the regions were tested to see if they were NICKEL SULFIDES ASSOCIATED WITH SMALL INTRUSIONS
different; the test could not establish significant dif
Nickel sulfide deposits associated with komatiitic
ferences among the correlation coefficients for the four rocks present one type of deposit found in orogenic
regions. These results suggest that although the regions belts; another type of deposit is associated with a variety
differ in the average grade and tonnage of deposits, the of small to medium-sized intrusions of predominantly
overall process that related the two variables may be the mafic composition. In many places, these deposits are
same. Thus, statistical results are consistent with the in associated with a diverse group of intrusions that in-
c
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co X
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-0.10
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-0.20 i
5.0i
A
FIGURE 4. -Quality-control chart (a plot of means and standard errors) of tonnage and grade for nickel sulfide deposits in komatiitic rocks. Data
are from four regions, plotted both as a group and as separate areas. X represents the means; bar extensions indicate plus and minus 2 stand
ard errors. A, For tonnage. B, For grade.
10
Number of
deposits Median
(n)
Variable
Tonnage,
metric
Nickel
grade,
percent _
50
50
1.27 xlO6
.60
Mean
Standard
devia
tion
^
(assymmetry)
b2
(skewness)
6.10
0.51
0.15
3.33
-0.09
- .22
.23
-.23
3.00
-0.09
0.10
0.316
1.0
3.16
10.
II
31 .6
2.51
0.20
1.58
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cc
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0.00 ~~
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_ 0.63 0
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UJ -0.20
CD
<
0.25
n on
4.5
PERCENT
IN
5.0
5.5
6.0
6.5
7.0
FIGURE 5.-Grade and tonnage of nickel sulfide deposits associated with small intrusions.
n ic
7.5
11
0.60
1.0
'
'
*
'
'
'
'
2.51
PERCENT
0.20
+
_,
UJ
'
10 00
3.98
_L
100
0.40
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<
10
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3"
1.00 g
0.00
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5.0
6.0
7.0
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8.0
9. 0
FIGURE 6. - Grade and tonnage of two types of nickel-sulfide deposits. Deposits associated with komatiitic rocks are represented by a dot (), and
those associated with small mafic intrusions are represented by a cross (+).
Arithmetic
Variable
Number of
deposits Median
(n)
Tonnage,
metric
102
3.34 xlO6
Nickel
grade,
percent
102
.87
Significant at the 1-percent level
Standard
devia
tion
(assymmetry)
Vft
62
(skewness)
Correla
tion co
efficient (r)
6.52
0.82
10.80
3.43
-0.0531
-.06
.30
-.03
2.62
-0.0531
NICKEL-LATERITE DEPOSITS
Average nickel grade and tonnage data for 64 nickellaterite deposits from six continents were collected. The
Arithmetic
Variable
Tonnage,
metric
Nickel
grade,
percent
Number of
deposits Median
(n)
64
40.48 xlO6
64
1.41
Mean
Standard
devia
tion
,Vfc,
(assymmetry)
(skewness)
Correla
tion co
efficient (r)
7.61
0.60
-0.05
3.42
-0.211
.15
.10
'.69
3.72
-0.211
&2
12
1. 00
3.16
10.0
31.6
100.
316.
1000.
\9
0.40
3162.
2.50
1Z
UJ
0.30 -
2.00 cc
CC
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UJ
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0.10
LU
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1.58 <
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~ 1.26 Z
UJ
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CD
3
0.00
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UJ
1.00 <
-0.10
I
6.5
6 .0
I
7.0
I
7.5
I
8.0
I
8.5
I
9.0
0.79
95
Number of
deposits Median
(n)
54
45.18xl06
54
1.36
Standard
deviation
V^
(assymmetry)
62
(skewness)
7.65
0.63
-0.21
3.35
-0.13
.13
.08
.19
3.59
-0.13
13
REFERENCES CITED
1.(M
3.16
10.0
31.6
100.
316.
I
1000.
3162.
I
2.50
0.40 -
'ERCENT
LU
Q
g
0.30
2.00 "
LU
Z
u,
Q
OC
1.58 0
0.20
<
OC
LU
LU
LU
." .'
.'.''""
0.10
1.26 S
o
_l
OC
LU
...
0.00
-0.10
6 .0
1.00
6.5
7.0
7.5
8.0
8.5
9.0
n fa
9.5
14